a second occurrence in Russia - Norsk Geologisk Forening

0 downloads 0 Views 560KB Size Report
intrusion, Kola Peninsula; a second occurrence in Russia. ... P. Men'shikov & L. P. Barkova, Geological Institute, Kola Science Centre, Russian Academy.
Loveringite from the Last-Yavr mafic-ultramafic intrusion, Kola Peninsula; a second occurrence in Russia AND REW Yu. BA RKOV, YEVGENY E. SAVCHENKO, YURII P. MEN'SHIKOV & LARISSA P. BA RKOVA

& Barkova, L. P. : Loveringite from the Last-Yavr mafic-ultramafic

Barkov, A. Yu., Savchenko, Ye. E., Men'shikov, Yu, P.

intrusion, Kola Peninsula; a second occurrence in Russia. Norsk Geologisk Tidsskrift, Vol. 76, pp. 1 15 - 1 20. Oslo 1996. ISSN 0029- 196X. Loveringite,

(Ca, REE)(Ti, Fe, Cr),1038 ( a member of the crichtonite group) occurs in orthocumulates (plagioclase-bearing

orthopyroxenites) of the Last-Yavr intrusion, which obviously represents a fragment of the Proterozoic Fedorova Tundra-Pana Tundra layered intrusion. The occurrence is situated immediately adjacent to the Archaean wall rocks at a lower structural leve! of the intrusion. The loveringite is closely associated with a typical intercumulus assemblage (phlogopite, quartz, albite-rich plagioclase, ilmenite, rutile and Ca-amphibole). Its composition is characterized by a relatively low content of REE and high concentrations of Cr and Mg. The rellectance values are in good agreement with published data; VHN 100= 9 1 2- 1 085. The unit-cell dimensions are a= 10.40 (3), c= 20.83 (6)

Å.

A. Yu. Barkov•, Ye. E. Savchenko, Yu. P. Men'sh ikov & L. P. Barkova, Geological Institute, Kola Science Centre, Russian Academy of Sciences,

14

184200

Fersman Street,

Apatity, Russia. • Present address: Department of Geosciences and Astronomy, University of

Oulu, FTN-90570 Oulu, Finland.

Introduction

between the hetter known Fedorova Tundra and Pana

Loveringite, (Ca, REE)(Ti, Fe, Crb 038, a rare member of

the

crichtonite

group,

was

first

described

by

Gatehouse et al. ( 1978) from the Early Proterozoic Jim­

Tundra intrusions (Fig. l ). The intrusions are located between Archaean granitoids and the Palaeoproterozoic Seidorechensky volcanogenic-sedimentary sequence. Fea-

berlana layered intrusion, Australia. The mineral has also been discovered in the Bushveld layered complex, South Africa (Cameron 197 8; 1979), and later in several Early Proterozoic mafic-ultramafic layered intrusions in Finland: Narankavaara, Penikat (Alapieti 1982; Alapieti

& Lahtinen 1986) and Koitelainen (Tarkian & Mutanen 1987). Another Fennoscandian occurrence of members of the loveringite-davidite series was reported by Olerud (1988) from an Early Proterozoic albite felsite, Norway. Segalstad ( 1984) described an unusual Ti-rich oxide min­

cs;:]1 �2 r:::3:::;] �4 !S]s �6 �7

eral, the chemistry of which resembles that of the crich­ tonite group. Lorand et al. (1987) reported an occurrence of loveringite from the Early Palaeozoic Laouni complex, AJgeria. More recently, loveringite was identified in the Burakovsky layered intrusion, Russian Karelia (Barkov et al. 1994). Minerals of the loveringite-crichtonite series have also been found in the Khibina alkaline complex, Kola Peninsula, Russia (Barkov et al., in prep.). In this paper we report a second Russian occurrence of

loveringite,

from

the

Last-Yavr

intrusion,

t

N o 2 '--L....J KM

Kola

Peninsula.

Fig.

l. Simplified geological sketch-map of the contact area between the Fe­

dorova Tundra and Pana Tundra layered intrusions, showing location of the Last-Yavr intrusive body. Modified from Radchenko et al. ( 1980)

l. Geological

contacts; 2. Schists and mylonites after mafic and ultramafic rocks; 3. Archaean

Brief geological description The Last-Yavr mafic-ultramafic intrusion is situated in the central part of the Kola Peninsula, at the contact

granitoids;

4. Palaeoproterozoic Seidorechensky complex of volcanic and sedi­

mentary rocks; 5. Faults; 6. Position of drill hole No. 72; 7. Mafic-ultramafic igneous rocks. Abbreviations used: Ff= Fedorova Tundra,

PT= Pana Tundra,

LY = Last-Yavr intrusions. The inset shows the approximate location of the area on the Kola Peninsula.

116 Table

A. Yu. Barkov et al.

NORSK GEOLOGISK TIDSSKRIFT 76 (1996)

I. Representative electron microprobe analyses (in wt.%) of minerals in loveringite-bearing pyroxenite from Last-Yavr. En

Aug

Si02

55. 1 7

52.99

Ti02

0. 1 5

Al203

Pl

Phi

Am

Ap

Chr

co re

rim

59.06

60.30

40. 4 1

48. 1 0

n.a.

n.a.

n.d.

0.62

n.d.

n.d.

2.63

0.40

n.a.

n.a.

0.30

1.17

2.27

25.57

25.85

14.55

1 1 .38

n.a.

n.a.

9. 82

Cr203

0.33

0.64

n.d.

n.d.

0.7 1

0. 1 0

n.a.

n.a.

43. 1 8

V20,

n.d.

0.04

n.d.

n.d.

0.05

n.d.

n.a.

n.a.

0.74 1 1 .75

Fe203 FeO

10. 8 1

6. 1 8

0. 12

0. 10

5.89

7.7 1

0. 1 9

0.24

MnO

0.27

0. 1 7

n.d.

n.d.

0.04

0. 1 3

n.a.

n.a.

MgO

30.70

1 8.65

n.d.

n.d.

22.65

17.05

n.a.

n.a.

CaO

1.14

1 7.32

7.10

7. 1 3

0.04

10.79

54.64

54.39

n.d.

SrO

n.a.

n.a.

n.a.

n.a.

n.a.

n.a.

0. 1 1

n.d.

n.a.

Na20

0. 1 6

0.46

7.21

8.07

0.47

2. 1 0

n.a.

n.a.

n.a.

K20

n.d.

n.d.

0.03

O.o3

8.6 1

0. 1 0

n.a.

n.a.

n.a.

29.61 0.45 1.32

Ce203

n.a.

n.a.

n.a.

n.a.

n.a.

n.a.

0.2 1

0. 1 2

n.a.

NiO

0.09

0.05

n.a.

n.a.

0. 1 3

0.06

n.a.

n.a.

n.d.

ZnO

n.a.

n.a.

n.a.

n.a.

n.a.

n.a.

n.a.

n.a.

P20s

n.a.

n.a.

n.a.

n.a.

n.a.

n.a.

42.08

42.30

n.a.

n.a.

n.a.

n.a.

n.a.

n.d.

0.06

1 .45

1.56

n.a.

0.0 1

0.33

0.36

97.97

98.35

98.25

Cl

Cl-O 99.99

Total

99.39

1 0 1.48

99.09

96. 1 8

0.84

98.0 1

Number of cations 0= 1 1

0= 8 Si

1.94

1.94

Ti