Green dipping technologies – a case study how ...

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Jun 26, 2014 - New production process. Price drivers ... Purchasing Manager of a Major Tire Producer ... Secured supplies through multi-site manufacturing.
Green dipping technologies – a case study how regulatory constraints influence innovation and its application June 26, 2014

Bernhard Müller Head of R&D Glanzstoff Industries

Susbtitution of materials…. New technology New chemicals New production process

Price drivers Regulatory drivers Patent drivers …

…turns out to be very often a chicken or egg dilema knowledge for your safety

A case study on material substitution…. Anno 1986 „Rayon will be completely substituted by polyester within the next 5 years“ Purchasing Manager of a Major Tire Producer

There were good reasons to believe it, since •

PET had a lower price



Quick progress in PET-development („only the sky is the limit - attitude“)



Rayon was a mature product – hardly any innovation



PET spinning was described to be less pollutant then rayon spinning…

Anno 2014… (3 decades later) knowledge for your safety

Rayon is still used in large quantities….! [kto]

· PET has penetrated the low-end and middle-end tire segment

Source: Notch report and unpublished data

BUT Rayon is still used due to its • Unique Material Properties (thermal stability) • Changed Consumer Behavior (rapid growth of premium cars and premium tires in the last years) • Demanding Legislation asked for higher standards in production -> environmental drawbacks during production have been solved

Source: Glanzstoff Industries

Substitution of materials on industrial scale is a multidimensional process . knowledge for your safety

Overview 1. Introduction • Rayon subsitution by PET 2. Glanzstoff Industries • Key Figures • Tire reinforcement materials 3. Sustainability • Greener production • GWP PET vs. Rayon 4. Dipping • RFL technology • LBL • RF free 5. Conclusion

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2. Glanzstoff Industries – Key figures Major European Converter for Technical Fibers vertically integrated in Rayon Technology leader in textile high-tenacity viscose endless filaments. Product applications:

•Tire Reinforcement •Mechanical Rubber Goods •Composites •Textile Personal Protection Equipment

Capacities

•Rayon yarn: •Twisting •Weaving •Dipping of Fabric •Single End Cord

12.500 t.p.a 31.500 t.p.a 31.000 t.p.a 31.000 t.p.a 5.000 t.p.a

Headquarters: St. Pölten (AUT) Production: Glanzstoff Bohemia (CZ); Textilcord (Lux), Sicrem (I) Number of Employees: 760 Turnover: 150 Mio € p.a. ISO 9001 certified knowledge for your safety ISO 14001 certified

2. Production sites • Located in the center of Europe, close to the Europian Tire Manufactures • Long lasting customer relations

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2. Tire Reinforcement Overlay: Nylon66, Aramid, Hybrid (AR/NY)

Single-End-Cord

Full width Fabric

Carcass Plies: Rayon, Polyester, Aramid, Hybrid (RY/PET)

Full width Fabric

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2. Conversion

• • • • • •

50+ years experience in converting technical yarns for Tire & MRG Industries Multi-material Product portfolio (Rayon, PET, PA66, Aramid, Hybrids, PVA) State of the art machinery thanks to continuous investments Secured supplies through multi-site manufacturing Quality & Service oriented Recent developments in biodegradable composites

Twisting 31.500 t.p.a.

Weaving 31.000 t.p.a.

Dipping – fabric 31.000 t.p.a

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Dipping – SEC 5000 t.p.a.

2. Dip Unit to produce dipped fabric

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3. Sustainability We understand „sustainability“ as the capacity to endure. socially responsible

Social

Sustainable

Environment

Economic

environmentally friendly Confidential & Proprietary

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economically viable

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12

PET –HMLS Dipped fabric

10

9,0

8

+2,4

RAYON dipped fabric

6,4

[to

CO2-eq/to product]

3.2 GWP: Rayon vs. PET-HMLS dipped fabric

6

Sustainability contribution of Rayon

29% lower GWP

+1,2

Conversion •

4

6,6

5,2

2

0



Fiber production Rayon yarn produced according to state of the art technology has a comparable GWP to PET-HMLS As dipped fabric rayon has a significant lower CO2footprint than PET-HMLS

Sources: Rayon and conversion data based on LCA study Glanzstoff (2013/2014); PET data public available (2014)

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4. Dipping– RFL Technology (all fibers) – Industry standard Schematic cross section Rubber (calandering) Hydrophobic interaction Vulcanization

Fiber

Resorcinolformaldehyd-Latex Hydrophobic Interaction Covalent linkage Pre-dip

Hydrophobic Interaction

Fiber

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Cross section dipped rayon cord

Alternatives should be either: Cheaper Better More sustainable

4.1 DIP - Chemistry : Formation of “RF-Resin” O

OH H

H

Formaldehyde

OH -

H2O

Resorcinol

OH

OH

OH

OH

OH

OH

OH

OH

OH HO

OH

DIP-Resin

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4.2 Dipping– Layer-by-layer Technology (PET) Step 1

Step 2 Rubber (calandering) Hydrophobic interaction Vulcanization

Fiber

RF free (different cross-linkers)

Resorcinolformaldehyd-Latex Hydrophobic Interaction Covalent linkage LBL Hydrophobic Interaction Changing surface properties cheaper

Fiber PET

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Fiber

4.2 Layer-By-Layer (LBL) principle

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4.2 Layer-By-Layer Activation - results Originally developed for low temperature dipping (