List of spectrum Appendix I - MDPI

List of spectrum Appendix I: MS, IR, UV, 1H NMR, 13C NMR, DEPT-135 and HMBC spectra of EH-1

Figure A: MS spectrum of EH-1.

75 70 65

2150 1722

60

539 687

%T

55

1449 1186

50

2924

45 40

805

3335 35 30 4000

1079 3500

3000

2500

2000

Cm

Figure B: IR spectrum of EH-1.

-1

1500

1000

500

319

0.40

340

0.35 0.30

A

0.25 0.20

247

0.15 0.10 0.05 0.00 250

300

350

400

450

500

Wave length (nm)

ppm (t1)

ppm (t1)

7.0

6.0

3.850 ppm (t1)

5.0

Figure D: 1H NMR spectrum of EH-1.

4.0

4.696

4.705

4.712

4.720 4.710 4.700 4.690 ppm (t1)

3.800

3.0

4.721

3.773

3.801 3.789

3.817

2.064

7.100

3.846 3.836

3.874 3.865

7.069 7.059

7.130 7.121

7.284

Figure C: UV spectrum of EH-1.

2.0

1.0

0.0

85.0

64.100 63.788

66.352 66.220

4.807

66.220 63.788

77.332 77.015 76.697

79.598 78.937

83.584

91.383

124.193 123.755

133.556 132.416

90.0 ppm (t1)

80.0 67.0 66.0 65.0 64.0 ppm (t1)

ppm (t1)

100

50

13

ppm (t1)

100

Figure F: DEPT-135 spectrum of EH-1.

4.807

63.787

66.218

132.414

133.555

Figure E: C NMR spectrum of EH-1.

50

0

Figure G: HMBC spectrum of EH-1.

Appendix II: MS, IR, UV, 1H NMR, 13C NMR and DEPT-135 spectra of EH-2

Figure H: MS spectrum of EH-2.

80 78 76

2235 1745

538

1449 1229

%T

74

807

72

2922 70

3437

68

1110 66 4000

3500

3000

2500

2000

W a v e N u m b e r(c m

Figure I: IR spectrum of EH-2.

1500 -1

)

1000

500

1 .4

317 1 .2 1 .0

A

0 .8

340

247

0 .6 0 .4 0 .2 0 .0 250

300

350

400

450

500

W a v e le n g t h ( n m )

4.291

4.305

4.320

3.819 3.805

1.272

2.065

3.533

7.284 7.136 7.126 7.077 7.067

Figure J: UV spectrum of EH-2.

3.850 ppm (t1)

4.320 4.310 4.300 4.290 ppm (t1)

ppm (t1)

7.0

6.0

5.0

Figure K: 1H NMR spectrum of EH-2.

4.0

3.0

2.0

1.0

3.800

0.0

83.541

89.608

4.803

57.124

65.008

72.680

124.093 123.882

133.544 132.400

124.50 124.00 123.50 ppm (t1) 90.0 ppm (t1)

100

ppm (t1)

85.0

80.0

50

0

13

ppm (t1)

100

Figure M: DEPT-135 spectrum of EH-2.

4.806

57.123

65.009

72.684

132.403

133.550

Figure L: C spectrum of EH-2.

50

0

Appendix IV: MS, IR, UV, 1H NMR, 13C NMR and DEPT-135 spectra of EH-3

Figure N: MS spectrum of EH-3. 80

70

2231

3444

60

1549 1376 50

%T

2926 1750

1044

1227

40

30

20

785 4000

3500

3000

2500

2000

W a v e N u m b e r (c m

Figure O: IR spectrum of EH-3.

1500 -1

)

1000

500

1 .2

318 340

1 .0

A

0 .8

0 .6

247 0 .4

0 .2

0 .0 250

300

350

400

450

500

W a v e le n g th ( n m )

7.150 ppm (t1)

7.100 4.900 ppm (t1)

ppm (t1)

7.0 1

6.0

5.0

Figure Q: H NMR spectrum of EH-3.

4.0

4.850

3.0

2.0

4.350 ppm (t1)

4.300

1.0

0.0

4.277

4.344 4.340 4.326 4.322 4.315 4.306 4.293

1.274

2.164 2.064

4.862 4.851 4.846 4.835

7.072 7.062

7.134 7.124

7.284

Figure P: UV spectrum of EH-3.

ppm (t1)

100

Figure S: DEPT-135 spectrum of EH-3. 100

50 4.805

20.807

150

61.735

67.170

132.491

133.542

ppm (t1)

13 50 0

Figure R: C NMR spectrum of EH-3.

0 4.794

20.795

61.735

64.100

66.319

67.169

79.084

79.645

83.591

90.539

123.606

124.347

132.483

133.534

170.924

Appendix V: MS, IR, UV, 1H NMR, 13C NMR and DEPT-135 spectra of EH-6

Figure T: MS spectrum of EH-6. 80

70

539

3458

%T

60

2232

2930

807

1367

50

1045 40

4000

1230

1746

30

3500

3000

2500

2000

W a v e N u m b e r (c m

Figure U: IR spectrum of EH-6.

1500 -1

)

1000

500

0 .7

3 1 9

3 4 0

0 .6 0 .5

A

0 .4 0 .3

2 4 7

0 .2 0 .1 0 .0 2 5 0

3 0 0

3 5 0

W a v e

4 0 0

le n g th

4 5 0

5 0 0

(n m )

1.597

2.145 2.065

3.513

4.270

4.332 4.323 4.317 4.299 4.288

4.361 4.352

4.446

4.456

4.464

4.474

7.284 7.138 7.128 7.080 7.070

Figure V: UV spectrum of EH-6.

4.470 4.460 4.450 ppm (t1)

4.350 ppm (t1)

ppm (t1)7.0

6.0

5.0

Figure W: 1H NMR spectrum of EH-6.

4.0

3.0

2.0

1.0

4.300

0.0

ppm (t1)

100

Figure Y: DEPT-135 spectrum of EH-6. 85.0

100

50 4.794

20.840

150

56.990

65.336

ppm (t1)

69.976

133.534 132.459

ppm (t1) 80.0

50 0

Figure X: 13C NMR spectrum of EH-6.

0

80.003 79.583

83.551

88.954

4.788

20.834

69.977 66.354 65.334 64.115 56.984

124.225 123.744

133.530 132.457

170.654

ppm (t2)

7.0

6.0

Figure Z: HMBC spectrum of EH-6.

5.0

4.0

3.0

2.0

1.0

Appendix VI: IR, UV, 1H NMR, 13C NMR, DEPT-135 and HMBC spectra of EH-7

80

70

540 1549

2918

60

2228

1382

%T

1045 50

1230

1753 40

786

30

4000

3500

3000

2500

2000

1500

1000

500

-1

Wave Number (cm )

Figure A1: IR spectrum of EH-7. 1 .0

321 0 .8

341

A

0 .6

0 .4

247

0 .2

0 .0

250

300

350

400

W a v e le n g th (n m )

Figure B1: UV spectrum of EH-7.

450

500

4.950

4.968 4.964

4.982

4.375

4.394

4.404

2.160 2.066

4.450

4.422

4.439

4.453

4.468

4.482

7.284 7.142 7.101 7.133 7.111

ppm (t1)

4.400 4.980 4.970 4.960 4.950 ppm (t1)

7.0 ppm (t1)

6.0

5.0

Figure C1: 1H NMR spectrum of EH-7.

4.0

3.0

2.0

1.0

0.0

ppm (t1)

150

100

Figure E1: DEPT-135 spectrum of EH-7. 67.0 66.0 ppm (t1)

100

50

65.0

4.839

80.0

20.710

ppm (t1)

46.080

85.0

66.434

133.054

133.567

ppm (t1) 64.0

50 0

Figure D1: 13C NMR spectrum of EH-7.

0

64.084

66.434 66.210

80.224 79.900

83.767

88.181

4.804

20.676

88.181 83.767 80.224 79.900 77.332 77.219 77.015 76.697 66.434 66.210 64.084 46.071

124.909 123.041

133.543 133.032

170.298

ppm (t2)

7.0

6.0

Figure F1: HMBC spectrum of EH-7.

5.0

4.0

3.0

2.0