Materials Flow of Platinum Group Metals

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Material Flows of PGMs

Materials Flow of Platinum Group Metals - A Quantitative Analysis of PGM-Applications, Deficits and Optimization Potential in Germany Dr.-Ing. Christian Hagelüken1, Peter Ryan2 1

Umicore Precious Metals Refining Rodenbacher Chaussee 4 D -63403 Hanau-Wofgang, Germany

2

GFMS London Hedges House, 153-155 Regent Street London W1B 4JE, UK

Abstract Platinum group metals (PGMs) are used in substantially increasing quantities in many of today's key technologies (catalysis, electronics, fuel cells). Primary production of these metals is concentrated in only a few countries of the world and partially is connected with considerable environmental impacts. Recycling of PGMs is ecological advantageous and essential for the sustainable use of PGMs. Efficient recycling technologies for PGM bearing materials have been established for many years and have been used successfully. However, the recycled PGM quantities are substantially below the original PGM input for the various applications. A reliable data base in this context was not in existence and flows as well as cycles of materials were not transparent. A research project, jointly conducted by Umicore Precious Metals Refining and Germany's leading environmental research institute, Öko-Institut, with funding from Germany's Federal Ministry of Education and Research, has now shed much more light on this subject. The analysis, which in its depth and breadth is unique, showed substantial differences between application fields, ranging from PGM lifecycle-efficiencies > 90% on the one side (e.g. chemical catalysis) to < 40% in areas like autocatalyst and electronics. Other key findings of the investigation are that Germany’s inventory of PGMs in fabricated products stands at around 240 tonnes and that recycling from this covers just under half of the country’s annual gross demand. The detailed statistics, analysis and conclusions were published in March 2005 in German language at GDMB Medienverlag [1]. At the end of June, an English language edition was published in conjunction with the London based precious metal analysts GFMS [2]. This includes a new section placing the German results in a global context and assessing whether any material changes had occurred since the early research was carried out. An executive summary was also added by GFMS. The first section of the main report concerns estimates of the division of gross PGM demand by end-use sector and how much of each sector’s requirements are met by recycled PGMs, generating a figure for the amount of PGMs ‘irretrievably lost’ each year. This research was then extended to assess the standing inventory of PGMs in each sector of end-use. Proceedings of EMC 2005, Vol. 4, Dresden, Germany, Sept. 18-21, 2005, pp 1697-1712

Hagelüken, Ryan The second section covers possible future improvements to the amount of PGMs that can be recycled. A major reason behind the report’s ministerial funding was a desire to raise recycling efficiencies. This desire was based on environmental concerns as recovery from scrap tends to generate far less carbon dioxide and sulphur dioxide than mining of primary PGMs. To that end, the report recommends various measures to improve recovery rates. As for its global relevance, Germany makes an excellent case study. Not only is it a major industrial consumer of PGMs, but the country is frequently ‘ahead of the game’ on environmental matters. Pointers can therefore be deduced as to what is already achievable with current technologies and practices and where recovery rates might be going as we move forward.

1

Project background and scope of investigation

With the acquisition of the former Degussa precious metals activities in 2003, Umicore has emerged as a global leader in advanced precious metal products and refining services for these metals. Closing the loop at the end of the product lifecycle is a key element in the company's strategy. The business unit Umicore Precious Metals Refining operates refining facilities in Hanau (Germany), Guarulhos (Brazil) and Hoboken near Antwerp (Belgium), and serves a worldwide customer base. In the Hoboken integrated metals smelter and refinery, a wide range of metals from complex precious metals bearing materials are recovered and recycled back into the market: gold, silver and the PGMs (palladium, platinum, rhodium, iridium, ruthenium), special metals (selenium, tellurium, indium), secondary metals (antimony, tin, arsenic, bismuth) and base metals (copper, lead, nickel). Important feed materials are industrial wastes and by-products from other non-ferrous industries (e.g. drosses, mattes, speiss, anode slimes), precious metal sweeps & bullion, spent industrial catalysts, as well as consumer recyclables such as car exhaust catalysts and electronic components including printed circuit boards. In total, 250,000 tonnes of feed materials are treated annually in a highly flexible flow sheet generating minimal waste. The plant is one of the world's largest and most advanced precious metals refining facilities with a capacity of some 50 tonnes of PGMs, over 100 tonnes of gold and 2,400 tonnes of silver. With the company's now extensive activities in the precious metals markets, it became evident that there is a general lack of reliable, detailed analysis concerning the material flows and lifecycle efficiencies of the PGMs. The limited information that is available typically provides aggregated data on net demand within the main application segments. However, with the exception of automotive catalysts, no gross demand data is reported. The bridge between net and gross demand is achieved through recycling and here a lot of open questions exist: -

Which recycling potentials derive from the strong increase in PGM demand since the 1980s?

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Material Flows of PGMs -

What PGM materials are evading recycling and why do these losses occur?

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Why are actual recycling volumes often far behind the expected quantities?

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What kind of lifecycle structures exist in the various PGM application fields?

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Why are recycling loops in some areas working highly efficiently but not in others?

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What are the deficiencies and what measures have to be taken to improve PGM supply from recycling?

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How will PGM demand evolve in the coming years and what contribution to PGM supply can we expect from recycling?

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What are the ecological consequences of these developments?

And so the idea was born to systematically approach these questions in a research project, for which partial funding was obtained from the German Federal Ministry of Education and Research, in the frame of their funding programme "Research for the environment", sub-programme "Sustainable Economics". Work on the project commenced in August 2001 and the final report was submitted to the ministry in August 2004. Areas of investigation have been all relevant application segments for PGMs (table 1).

Table 1:

Application Areas for Platinum Group Metals (PGMs)

automotive catalysts chemical & oil refining catalysts electronics

glass manufacturing dental applications jewellery

electroplating fuel cells others

The base year for data collection in Germany was 2001/02. A qualitative reference is made beyond the German situation to the worldwide PGM-industry and global statistics are updated with 2004 figures on demand/supply and PGM-price development. Through the collaboration with the Öko-Institut, an experienced scientific partner with a long established expertise in recycling management, material flow analysis and scenario techniques became a vital member of the research team. The combination of the Öko-Institut’s methodology and expertise, Umicore's insights and knowledge of the market and the valuable contribution of external experts enabled the project to proceed with great success. Some interim results have already been presented at international conferences before and raised considerable interest. With GFMS, a well reputed precious metals analyst was enlisted for the English language publication to make the results accessible to an international audience.

Proceedings of EMC 2005, Vol. 4, Dresden, Germany, Sept. 18-21, 2005, pp 1697-1712

Hagelüken, Ryan

2

Global PGM-significance and the contribution of Germany

The net demand for platinum, palladium and rhodium has almost tripled from 150 tonnes per year in 1980 to over 400 tonnes in 2004 and the development of new technologies in the automotive, chemical and energy industries will, most likely, lead to further expansions in demand. Figure 1 and 2 show the development of global net demand since 1980, figure 3 displays the development of PGM-prices, which have been heavily impacted by the development on the demand side.

600 mt/year

Global net demand for Pt,Pd,Rh

Numbers based on JM 2004

500 Σ 1980-2004 7235 t PGM:

400

Rh 295 t Pd 3660 t

300

Pd

Pt 3280 t

Rh

200 100

Pt

19 80 19 82 19 84 19 86 19 88 19 90 19 92 19 94 19 96 19 98 20 00 20 02 20 04

0

Figure 1: Global net demand for platinum, palladium and rhodium 1980-2004

300 250 200 150

mt/yr

Palladium Welt-Nachfrage nach

net demand

250

Autocat.-net Others

Palladium 200 Autocat.Others Jeweller Electronic Dental

100

Petroleum

net-demand

Platinum

Jewellery Investment

150

Glass Elektronics Chemical

100

50

50

0

0

1980 1982 1984 1986 1988 1990 1992 1994 1996 1998 2000 2002 2004

mt/yr

1980 1982 1984 1986 1988 1990 1992 1994 1996 1998 2000 2002 2004

Figure 2: Global net demand palladium and platinum by application fields

Proceedings of EMC 2005

Material Flows of PGMs (in $/troz) P t/ P d: L on don fixing , R h:JM -base 2 6 .0 1 .01 : $ 1 0 9 4 /tro z

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Figure 3: Price development for Pd, Pt, Rh, 1981-June 2005 (monthly high, low, average)

Given the scale of its economy and its manufacturing industry, Germany represents a fascinating and highly relevant case study for the PGM industry around the world. The research team’s detailed suctorial analysis together with their conclusions and findings, are in many cases strongly reflective of situations that exist in many other industrialised nations. Germany’s relevance in the context of the global PGM industry can be readily established by setting out a number of its key credentials. -

In 2003 Germany’s real GDP per capita was US$32,870. Germany was ranked world number 9 ahead of the USA at number 10. Germany also accounted for 22% of EU15 total GDP.

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Population 82.4m in 2003. Germany is the EU25’s most populous nation and represents 18% of the enlarged EU, followed by France and the UK, each with some 59m to 60m people.

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Germany posted a record trade surplus of US$146bn in 2003, the largest of any nation in the world. This is likely to be exceeded by a considerable margin in 2004.

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In 2004, Germany’s chemical industry generated US$145bn of sales and represented 25% of the EU chemical industry total. By comparison, the US chemical industry generated sales of $417bn.

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Germany is home to BASF and Bayer, the world’s largest and third largest chemical companies.

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Germany is the largest manufacturer of motor vehicles in the EU. In 2003 it produced 5.5m vehicles and ranked world number 3 behind the USA and Japan.

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After Luxembourg, Germany has the second highest ownership of passenger cars per capita of any EU country and ranks number 6 in the world.

Proceedings of EMC 2005, Vol. 4, Dresden, Germany, Sept. 18-21, 2005, pp 1697-1712

Hagelüken, Ryan

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Germany’s density of personal computer usage is the highest in the EU. Over 60% of households are equipped with PCs. Germany ranks world number 4 in terms of internet usage with 42m users.

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Some of the world's leading precious metal refiners and manufacturers are based in Germany.

The following table and graphic places Germany into context against global net demand for PGMs in 2001, the base year selected by the project team. Table 2: Germany's net demand for PGMs in comparison to worldwide demand for 2001 (base year) in mt/yr world Europe North America Japan Germany % of world % of Europe % of North America % of Japan

Pt 193,8 47,0 40,3 40,7

Pd 178,8 59,3 84,1 42,6

13,0 7% 28% 32% 32%

7,3 4% 12% 9% 17%

Rh 18,0 5,1 6,0 4,0

total 390,6 111,4 130,4 87,3

0,8 4% 15% 13% 19%

21,0 5% 19% 16% 24%

sources: JM, Umicore/Öko-Institue, GFMS

16% ROW

22% Japan Europe

29%

Germany 19%

North America

34% North America

Japan

Other regions

Europe

Germany

Figure 4: Global net PGM demand by region (base year 2001) In 2001 Germany’s net consumption of PGMs represented 5% of global net demand. At first glance this may seem quite modest but given that this level is broadly in line with Germany’s contribution to global GDP, the result is perhaps not so surprising. When viewed in relation to Europe’s demand for PGMs, Germany’s share is also reasonably consistent with its share of EU GDP, which stood at 22% in 2001. It should be borne in mind that non-EU countries are also included in PGM demand estimates for Europe. Therefore, on a like for like basis the relationship between Germany’s share of EU GDP and its share of EU net demand for PGMs will actually be considerably closer. Proceedings of EMC 2005

Material Flows of PGMs

3

PGM demand interdependencies and the measuring of recycling efficiency

Previously available surveys of the PGM market (e.g. Johnson Matthey and more recently GFMS [3,4]) have concentrated on providing global supply and demand balances. These are presented on a regional basis and look mainly at net demand. With the exception of autocatalysts, no information is provided on gross demand, which ultimately manifests itself in PGM products. The gap between both figures is caused by the recycling returns of any one sector. The interdependence of different demand quantities is displayed in figure 5: PGMrefiners

• From prod. scrap

Recycling • from „end-ofPGMproduct manufacturers

Gross demand

+ =

life“ products

Losses • prod. process • not collected • recycling loss

Net demand = Market

+

PGMlifecycle efficiencies

growth/ new applications PGM-mines (+ stockpiles)

Figure 5: PGM demand interdependencies In the focus of the project were gross demand, recycling quantities and PGM-losses, since these factors are needed to calculate PGM lifecycle efficiency. The measurement of recycling efficiency is achieved by calculating recycling quotas for each PGM application. Recycling quotas (or ratios) have been calculated on two fundamentally different bases, „static“ and „dynamic“. -

„Static recycling ratios“ compare current levels of supply from recycling with current gross demand. In an application where PGM demand is rising, a product with a lifecycle of several years (e.g. an autocatalyst) will yield an inherently low ratio. Conversely, in an application where demand has been falling (e.g. electronics) the ratio will be inherently high.

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By contrast, „dynamic recycling ratios“ compare current levels of supply from recycling with the gross demand for that application at the time the recycled products were originally manufactured. This measure eliminates the distorting effects of rising or falling demand and represents the true measure of recycling efficiency within any given application.

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In application fields with either short lifecycles (e.g. 1 year or less) or stable levels of demand, the static and dynamic recycling measurements will both yield similar results.

Proceedings of EMC 2005, Vol. 4, Dresden, Germany, Sept. 18-21, 2005, pp 1697-1712

Hagelüken, Ryan

4

German PGM statistics

The following paragraphs summarise the key statistical findings of the investigation in Germany. Much more background and details are given in the recent publications [1, 2].

4.1 The contribution of recycling Figures 6 and 7 illustrate the quantitative results for Germany. The country’s gross demand for PGMs in the base year (2001) was approximately 38 tonnes (1.2m ounces) of which platinum comprised 58%, palladium 37% and rhodium 5%. 25

45 40

Demand 100% 20

35

Supply

25

$217m*

55%

45%

20

mt/yr

30

mt/yr

Two thirds went into

14% 15

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10

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consumer products

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46%

Platinum

Palladium

5 0

0 Gross demand

Recycling

Platinum

New metal

Palladium

Losses

Rhodium

* current value

Rhodium

Autocatalyst

Glass

Process catalyst

Jewellery

Dental

Electronics

Other

Plating

Figure 6: PGM demand-supply balance for Germany and gross demand by sectors (base year 2001)

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Autocatalyst production accounted for 40% of total PGM gross demand, chemical industry catalysts 22% and glass industry products 13%. Jewellery accounted for 9% of gross demand.

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45% of gross demand was satisfied by recycled PGMs. New purchases represented only 55%.

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Recycling of glass industry products and industrial catalysts accounted for over two-thirds of the total amount of PGMs recycled in Germany (fig. 7).

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85% of gross demand in the glass and industrial catalyst sectors was satisfied by recycling.

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PGMs recycled from scrapped autocatalysts represented only 12% of gross autocatalyst demand.

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In the base year 10 tonnes (320,000 ounces) of PGMs escaped recycling and were considered "lost". 50% of this was platinum with palladium comprising 40% and rhodium 10%. At current prices this represents a value of over US-$ 200 million (fig. 6). A breakdown of losses by sector is given in figure 7.

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Material Flows of PGMs

12

Recycling by sector

mt/yr

10 8

10% 13%

6

25%

Two thirds came from industrial applications. 21% 11%

4 2

48% 60%

0 Base year 2001 Platinum

Palladium

Rhodium

Glass

Process catalyst

Jewellery

Autocatalyst

Dental

Electronics

Plating

Other

Figure 7: PGM recycling and PGM losses by sectors in Germany for base year 2001

4.2 Germany's PGM inventory Germany’s national inventory of PGMs was estimated in the region of 240 tonnes. This comprised 50% platinum, 45% palladium with the balance rhodium (fig. 8). 18%

IT hardware

Palladium 109 t Platinum 121 t

18%

Jewellery

Dental

10%

Vehicles

Rhodium 12.4 t

Industrial processes

42% 12%

Figure 8: Germany's PGM inventory by metals and by sector (for base year 2001) -

The majority (88%) of the national inventory is contained in consumer durable products held by private individuals. End-of-life PGM recycling from these sources is conducted through “indirect cycles” (see next chapter).

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42% of the country’s inventory is contained in autocatalysts fitted to vehicles in service.

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Electronic hardware and jewellery each accounted for approximately 18% of inventory with PGMs contained in dental prosthetics representing a further 10%.

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Only 12% of the national inventory resides in industrial processes. In the main this comprises PGMs contained in industrial catalysts and in equipment used to manufacture high purity glass. PGMs recovered from industrial processes are recycled through “direct cycles”.

Proceedings of EMC 2005, Vol. 4, Dresden, Germany, Sept. 18-21, 2005, pp 1697-1712

Hagelüken, Ryan Looking at the very high share of consumer products, both in PGM net demand and inventory, it can be questioned if PGMs really are "industrial metals" as it is often postulated. And yet end-oflife consumer goods generate only 1/3 of all recycled PGMs. The reasons are twofold: Certainly the long lifecycles of consumer products like automotive catalysts or electronics have an impact, but on top of this, fundamental differences can be observed in the recycling structures.

5

Recycling systems

The report identifies two distinctly different forms of recycling structures, “direct cycles” and “indirect cycles”. These are commonly referred to as closed (direct) and open loop (indirect) systems.

5.2 Closed loops – key characteristic: recycling from industrial processes Closed loops (fig. 9) prevail in industrial processes where PGMs are used to enable the manufacture of products or intermediates which typically contain no PGMs. Typical examples are PGM process catalysts (e.g. Pt/Rh catalyst gauzes used in the oxidation of ammonia to produce nitric acid) or PGM-equipment used in the glass industry.

Figure 9: Closed (direct) loop recycling typically for industrial PGM-applications

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The PGMs invariably survive the process in which they are used. Their physical location is confined to the immediate vicinity of the user’s plant. The user retains ownership of the PGMs and the system boundaries are restricted and well defined.

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In such processes the technical performance of the PGM products used (e.g. catalysts) is critical. As a result, close relationships exist between users of the PGM products and providers. Third parties are rarely involved.

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Typically, the provider of the PGM product operates (or can access) refining facilities through which PGMs contained in spent products can be recycled into new PGM products.

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As a result, closed loop systems are inherently efficient and more than 90% of the PGMs used in industrial processes is typically recovered and recycled.

Proceedings of EMC 2005

Material Flows of PGMs

5.2 Open loops – key characteristic: recycling from consumer durables Open loop systems (fig. 10) are prevalent in the recycling of PGMs from end-of-life consumer durable products i.e. vehicles (autocatalysts), electronic hardware (components) and dental prosthetics.

Figure 10: Open (indirect) loop recycling for consumer products (example: autocat recycling) -

Consumer durables, in the main, are held by members of the general public. By the time such products reach the end of their useful lives (e.g. catalyst equipped cars) ownership may have changed hands several times and no connection remains between the final owner and its manufacturer.

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Little or no direct financial benefit exists to encourage final owners to ensure recycling of endof-life products. Environmental concern and the need to find an outlet are the key drivers.

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Once consumer products enter the recycling system there are frequently a number of parties involved in the chain before PGM bearing materials reach the stage of final refining. These include collectors, dismantlers, traders and pre-treatment facilities.

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Recovery methods and awareness of PGM values is often limited. This results in inadequate removal and segregation of PGM bearing materials and irretrievable losses e.g. to shredders.

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The involvement of “informal” participants in the early stages of the recycling chain is significant. In such operations, working practices and regulatory compliance are poor. Especially the autocatalyst recycling sector has even attracted considerable criminal energy over the years.

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Significant numbers of end-of-life vehicles and electronic hardware (e.g. computers and mobile telephones) in Germany are exported for use in other less developed countries. As a result, the PGMs contained in such products escape recycling in Germany, and in many cases, will be lost for ever due to poor recycling infrastructures and environmental awareness in the importing countries.

Proceedings of EMC 2005, Vol. 4, Dresden, Germany, Sept. 18-21, 2005, pp 1697-1712

Hagelüken, Ryan

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In end-of-life electronic hardware, PGM values are often extremely low and their recovery and recycling may not be economically viable.

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Open loop systems are highly complex structures containing multiple variables and numerous opportunities for the failure of PGM recovery. Consequently, open loops are inherently inefficient and recycling falls a long way short of its potential.

Recycling of old jewellery items is also conducted through open loop systems. Due to its high and very obvious value, levels of recovery are high. However, with an indeterminate lifecycle, jewellery is uniquely different and falls largely beyond the scope of this study.

6

Improving PGM recycling

Although it may be possible to further optimise PGM recycling within Germany’s already efficient closed loop systems, the incremental benefits are likely to be relatively modest. The real challenge lies in finding ways to improve the performance of open loop systems, principally in respect of endof-life vehicles and to a lesser extent, electronic hardware. In order to define the potential benefits the research partners have evaluated the impact of different scenarios through to 2020.

6.1 Autocatalyst recycling Even assuming continued open loop recycling and no improvements in recycling rates, PGMs recovered from used autocatalysts will treble by 2020. This will be a natural function of an increasing proportion of vehicles scrapped each year that will be autocatalyst equipped, and the rising profile of PGM consumption in respect of newly registered vehicles. However, with recycling rates remaining low and the available volume of PGMs rising, the quantity escaping the net will increase steeply and become irretrievably lost. By 2020 it is estimated that annual losses from the autocatalyst lifecycle could top 10 tonnes of PGMs or reach US-$ 290 million (at June 2005 PGM prices) respectively. By contrast, a progressive conversion of existing open loop recycling systems into more efficient closed loops would drive up recycling rates. The partners estimate that closed loop recycling would more than double the recovery of PGMs from used autocatalysts by 2020 and slash losses. End of Life Vehicle (ELV) recycling legislation has been adopted in Germany and should be supportive of such a conversion taking place. This legislation assigns responsibility for recycling to the original manufacturer or importer of the vehicle. As a consequence, vehicle manufacturers are establishing reception and dismantling centres where “own marque” ELVs may be returned. Although this is a helpful development, the partners conclude that such legislation will need to be supplemented by other initiatives if PGM recycling from used autocatalysts is to reach its full potential. These include: -

Increasing the awareness of PGM value and the benefits of recycling. Proceedings of EMC 2005

Material Flows of PGMs

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Improving cooperation between participants in the recycling chain with a view to enhancing transparency and rationalising the system.

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The optimisation of dismantling and recovery procedures together with improved decanning techniques.

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Greater attention to improving logistics in order to optimise material flow.

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Action by competent authorities to certify and monitor recycling participants, eliminate informal sector participation and to regulate and control ELV exports.

Ca. 1.000 dismantlers + 60.000 workshops

Sources for spent catalysts from end-of-live vehicles (ELV) І from cat exchange (workshops) cat-converter

< 100 catalyst collectors (including subcollectors)

Collection logistic

Catalyst-cars

cat-converter

< 10 decanners

decanning

Catalytic converters

cat-ceramic Catalyst ceramic < 10 refiners globally (2 in Europe)

PGM-Refining

Green numbers refer to Germany

Figure 11: Recycling chain for autocatalysts with numbers of participants in Germany

6.2 Recycling of electronic hardware In many respects the issues relating to end-of-life electronic goods are similar to those described for used autocatalysts. However, there are key differences which relate both to the low and declining levels of PGMs contained (in other words, grade) and the absolute decline in PGM usage (specifically of palladium) over recent years. The two most important application areas for PGMs in electronics are hard disk drives (HDDs) and multi layer ceramic capacitors (MLCCs). -

In HDDs, tiny amounts of platinum and more recently ruthenium are applied to the disks (creating high density memory layers) and to disk read heads. The disks are typically made of aluminium. At end-of-life, the value of the aluminium far outweighs that of the platinum and so disks are channelled - also driven by established separation techniques - to aluminium smelters where the platinum is lost.

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Palladium is an ingredient of MLCCs that are used in a variety of applications including mobile phones and computer peripherals. Since 2001, when the price of palladium reached $1,000 per ounce, there has been a substantial shift away from palladium and to nickel based MLCCs. Consequently, the palladium contained in end-of-life electronic goods will decline sharply in future

Proceedings of EMC 2005, Vol. 4, Dresden, Germany, Sept. 18-21, 2005, pp 1697-1712

Hagelüken, Ryan years. At the same time, ongoing miniaturisation and economy of use raise questions over the future viability of recycling such materials for their palladium value.

Although the available market may be shrinking in terms of PGMs, the recycling of redundant electronic goods is a high profile subject. Germany has adopted legislation which is similar to its ELV laws. Whilst this will be supportive of creating more efficient recycling systems, such legislation is not a solution in itself. The issues the partners have highlighted for autocatalyst recycling are equally valid if recycling from electronic goods is also to be optimised.

7

Environmental benefits

The extraction of PGMs from recycled materials results in significantly lower emissions than from equivalent amounts of PGMs generated by mining. -

In recycling, basis the total amounts of PGM resulting from recycling and mine production, emission levels of carbon dioxide (equivalent) were calculated to be only 7% of those evolved during mine production. Sulphur dioxide emissions were assessed as negligible.

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In 2001 Germany’s demand for newly mined PGMs equated to emissions in mine production of 300,000 tonnes of carbon dioxide and 20,000 tonnes of sulphur dioxide (both equivalents).

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Germany consumed only 5% of global PGM mine production in 2001. 300,000 tonnes of carbon dioxide is equivalent to that emitted in production of 168,000 tonnes of steel.

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Optimising PGM recycling offers clear environmental benefits. The potential conversion of open loop recycling systems to closed loops would serve to increase the supply of secondary PGMs and reduce dependence on mine production. Were this to be achieved, the increased supply of secondary PGMs would represent reduced emissions in mine production of 90,000 tonnes of carbon dioxide and 7,000 tonnes of sulphur dioxide by 2020.

8

Conclusion

The platinum group metals (PGMs) are an indispensable part of our 21st century lifestyle. The use of platinum in high quality, high fashion jewellery is long established and the use of palladium, its sister element, is increasingly evident in white gold and high purity palladium jewellery. However, whilst jewellery represents the visible face of the PGMs, it is behind the scenes and in more subtle ways that these rare and valuable metals make a real difference to every day lives. Last year over 50% of the world’s newly mined PGMs were consumed in the production of autocatalysts, making use of their unique catalytic properties. Other important applications where the catalytic properties of PGMs play an essential role include the production of nitric acid, used Proceedings of EMC 2005

Material Flows of PGMs primarily in nitrogen based fertilisers for food production, the catalytic reforming of naphtha into high octane vehicle fuels, the production of silicone compounds used as sealants and adhesives and in the synthesis of pharmaceutical compounds and speciality chemicals. Beyond catalysis the PGMs also play a central role in electronic components, including hard disk drives and ceramic capacitors, the manufacturing of fibreglass and liquid crystal displays and as important constituents of dental alloys. PGMs are scarce, non-renewable natural resources. They are extremely durable and invariably survive both the industrial processes they are used in as well as the life cycle of the consumer products they are contained within. Because of their value and durability the PGMs are eminently recyclable. Because of their scarcity it is essential they are efficiently recovered from industrial processes and redundant products and recycled into new PGM products. The research conducted by Umicore and Öko-Institute has examined PGM-lifecycles in considerable depth. Although the published report is a case study of the situation in Germany, it also serves as an invaluable reference for the PGM industry worldwide. The results of its analysis and its discussion of the issues will find resonance in many other countries and in numerous industries. In particular, its insights into the whole subject of PGM recycling shed new light on this highly complex area and will be of key importance to all market participants from mining companies and industrial users to refiners, fabricators, banks and traders.

References [1] Hagelüken, C., M. Buchert, H. Stahl: Stoffströme der Platingruppenmetalle, Clausthal-Zellerfeld 2005 (ISBN 3-935797-20-6) [2] GFMS, Umicore, Öko-Institut: Materials flow of platinum group metals, London 2005 (ISBN 09543293-7-6) [3] Hagelüken, C., M. Buchert, H. Stahl: Substantial outflows of PGMs identified, Erzmetall 56 (2003), No. 9, 529-540 [4] Johnson Matthey (Ed): Platinum 2004, London 2004 [5] GFMS: Platinum & Palladium Survey 2005, London 2005.

Proceedings of EMC 2005, Vol. 4, Dresden, Germany, Sept. 18-21, 2005, pp 1697-1712