Invited Paper
Modeling pattern dependencies in the micron-scale embossing of polymeric layers Hayden Taylor1,a, Ciprian Iliescub, Ming Nib, Chen Xingc,d, Yee Cheong Lamc, and Duane Boninga a
Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA. USA b Institute of Bioengineering and Nanotechnology, 31 Biopolis Way, The Nanos #04-01, Singapore 138669 c School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798 d Singapore-MIT Alliance, N2-B2C-15, 50 Nanyang Avenue, Singapore 639798 ABSTRACT
We describe a highly computationally efficient method for calculating the topography of a thermoplastic polymeric layer embossed with an arbitrarily patterned stamp. The approach represents the layer at the time of embossing as a linear-elastic material, an approximation that is argued to be acceptable for the embossing of thermoplastics in their rubbery regime. We extend the modeling approach to represent the embossing of layers with thicknesses comparable to the characteristic dimensions of the pattern on the stamp. We present preliminary experimental data for the embossing of such layers, and show promising agreement between simulated and measured topographies. Where the thickness of the embossed layer is larger than the characteristic dimensions of the pattern being embossed, the stamp–layer contact pressure exhibits peaks at the edges of regions of contact, and material fills stamp cavities with a single central peak. In contrast, when the layer thickness is smaller than the characteristic dimensions of the features being embossed, contact pressures are minimal at the edges of contact regions, and material penetrates cavities with separate peaks at their edges. These two apparently distinct modes of behavior, and mixtures of them, are well described by the simple and general model presented here. Keywords: hot embossing, micro-embossing, polymethylmethacrylate, polysulfone, thermoplastic polymers, simulation
1. INTRODUCTION 1.1 Hot thermoplastic embossing Being transparent, inexpensive and mechanically tough in comparison with silicon or glass, thermoplastics are well suited to the volume-manufacture of microfluidic devices. The hot embossing of thermoplastic polymers is a promising means of forming the microstructures required in such devices: it offers processing cycle times on the order of a minute, and can be deployed with substrates ranging from the size of an individual chip to continuous reels of material. A typical embossing process for device- or wafer-sized polymeric layers is illustrated in Fig 1. Customarily, the material is heated above its glass-transition temperature and the embossing load is then applied in order to transfer a microstructure from a hard stamp to the softened polymer. The polymer is then usually cooled to below its glass-transition temperature, and the load is then removed and the part separated from the stamp.
1
[email protected]; telephone +1 617 253–0075 Micro- and Nanotechnology: Materials, Processes, Packaging, and Systems IV edited by Jung-Chih Chiao, Alex J. Hariz, David V. Thiel, Changyi Yang, Proc. of SPIE Vol. 7269, 726909 · © 2008 SPIE · CCC code: 0277-786X/08/$18 · doi: 10.1117/12.810732 Proc. of SPIE Vol. 7269 726909-1
2008 SPIE Digital Library -- Subscriber Archive Copy
When hot embossing is used for the fabrication of microelectromechanical systems (MEMS) or microfluidics, it is usually performed on homogeneous polymeric sheets that are much thicker than the characteristic feature sizes of the patterns being embossed. These embossed layers then constitute the body of the device being manufactured. We have previously put forward a highly computationally efficient simulation approach that can provide an approximation to the topography of a thick polymeric layer after embossing with an arbitrarily micro-patterned stamp1.
(a)
applied load heated platen elastomeric gasket rigid backing plate substrate polymeric layer stamp heated platen attached to load frame
(b) loading duration applied load temperature Tg time
Fig. 1. Illustration of the hot embossing process. (a) The polymeric layer to be embossed is placed in contact with a micropatterned stamp and both are inserted between two flat, heated platens. The polymeric layer may be self-contained or alternatively may have been deposited or bonded on to a substrate such as a silicon wafer. (b) The temperature of the polymer/stamp stack is increased above the glass-transition temperature of the polymer, and a load is subsequently applied and held for some time, usually ~1 minute. The materials are then typically cooled to below the glass transition temperature of the polymer, before the load is removed.
There is, however, growing interest in micro-patterning polymeric layers whose thickness is comparable to the feature dimensions being embossed. Embossed thermoplastic films with thicknesses in the approximate range 10–100 µm could be used to construct multi-layer disposable microfluidic devices — especially if the layers could be pierced with interlayer fluidic conduits or ‘vias’. Such devices could perhaps be made flexible and could adopt a ‘smart-card’ format. Polymeric films with thicknesses in this range are already being industrially embossed with micron-scale patterns2, 3 — often having optical applications — although there is not yet, to our knowledge, a computationally affordable way of simulating the hot embossing of arbitrary, complex patterns in finite-thickness layers. Such a capability would provide device designers with an estimate of the stamp-average pressure that would need to be applied at a certain temperature to fill the cavities of a specific stamp with the polymeric material. Equipped with this capability, device designers would be able rapidly to refine new designs, making them more easily manufacturable. In this work we propose an approximate way of modeling the embossing of finite-thickness thermoplastic layers in a rubbery regime. We show preliminary experimental results, against which the modeling approach is evaluated.
2. THEORY AND SIMULATION APPROACH 2.1 Material model The thermoplastic polymeric materials used in microfabrication are usually of a sufficiently large average molecular weight and processed sufficiently far below their melting temperature that their behavior when embossed can adequately be described as rubbery. This means that when compressed with a patterned stamp, the layer rapidly approaches a limiting topography governed by the elastic component of the material’s behavior. Such temperature-and time-dependent behavior has been studied in detail for polymethylmethacrylate (PMMA), for example4. For the purposes of our approximate simulation method, we capture this rubbery behavior with a linear Kelvin-Voigt model of the material, illustrated in Fig 2. Both the elasticity, E, and the strength of intermolecular resistance to flow — signified by a viscosity, η — are assumed to be decreasing functions of temperature, T, exhibiting reductions of perhaps several orders of magnitude as the temperature increases through the glass-transition temperature, Tg. In a range of temperatures from slightly above the glass-transition to several tens of degrees above it, we regard the intermolecular resistance to flow as being small in relation to the elasticity. As a result, the time taken for the embossed material to
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approach its limiting topography is reduced to perhaps only a few tens of seconds, which is a substantially shorter time than typical loading durations for hot embossing. For embossing processes performed in this rubbery temperature range and with loading durations more than a few times the material’s time constant, it follows that an approximation to the embossed topography can be obtained by modeling the material as a purely elastic layer whose elasticity is E(T). The topography is assumed to be ‘frozen’ in place when it is subsequently cooled under load and the intermolecular resistance to flow increases. Embossing cases in which the material’s flow time constant is comparable with the loading duration can be modeled moderately well by a simple scaling of the effective elastic modulus of the material. In our previous work1 we showed how this might be done for embossing temperatures only slightly above Tg, and a more comprehensive approach is laid out in work to be published separately.
log |modulus|
applied load
storage modulus melt loss modulus
η(T)
E(T)
rubbery behavior
Tg
(a)
temperature, T
(b)
Fig. 2. Material model assumed for approximate simulations of the embossing of thermoplastic polymeric layers. A KelvinVoigt material model (a) is assumed, with temperature-sensitive elasticity E and intermolecular resistance, or viscosity, η. We confine our attention to simulating embossing in the rubbery regime of the material’s behavior (b), in which, when embossed, the layer quickly approaches a limiting topography governed by the elastic component of the material’s behavior. When cooled, the viscosity increases substantially, and is assumed to ‘freeze’ this topography in place.
The use of a linear model ignores the non-linear stress–strain relationship typical of true rubbers; this simplification is a sacrifice that is made to enhance computational speed and it requires that strains in a sufficiently large proportion of the volume of the embossed layer are sufficiently small that a linear stress–strain relationship remains an acceptable approximation. 2.2 Simulation basis In previous work we used a linear-elastic approximation to the behavior of a heated thermoplastic layer to develop a simulation approach for the embossing of thick layers1. Assuming small deflections, and no friction between the stamp and polymer, the out-of-plane surface displacement w(x, y) of an elastic half-space whose surface is exposed to a normal contact pressure distribution p(x, y) is given by:
w( x, y )=
1 −ν 2 πE
p(x′, y′)
∫ ∫ (x − x′) + ( y − y′) 2
2
dx′dy′
(1)
where v is Poisson’s ratio and E is Young’s modulus5. To build a simulation, the elastic layer is discretized on a square grid composed of N × N regions each having diameter d. We index these regions using m and n, where x = md and y = nd. The response, c[m, n], of the layer’s surface deformation to unit pressure applied across a d × d region centered at (m = 0, n = 0) is, via evaluation of (1):
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c [ m, n ] =
1 −ν 2 [ f (x2 , y2 ) − f (x1 , y2 ) − f (x2 , y1 ) + f (x1 , y1 )] πE
(2)
where
(
)
(
)
f ( x, y ) = y ln x + x 2 + y 2 + x ln y + x 2 + y 2 .
and
(3)
x1 = md – d/2; x2 = md + d/2; y1 = nd – d/2; y2 = nd + d/2.
(4)
We discretize our representation of the stamp’s topography on a grid of the same dimensions: each region of the grid is assigned one topographical height representing the design of the stamp. We then iteratively find the distribution of stamp–polymer contact pressures that is consistent with the stamp remaining rigid while the polymer deforms. The solution is further constrained by the requirement that the spatial average of contact pressures must equal the specified average pressure applied to the stamp by the embossing apparatus. At each step of the iterative process, the forward computation of the polymer’s topography is performed by convolving the response of the elastic surface to unit pressure in one grid cell (Equation 2) with the candidate pressure distribution p[m, n]. This convolution is implemented using fast Fourier transforms, and since the problem is solved discretely there is an implicit assumption that the pressure distribution — and hence the surface deformation of the elastic layer — is periodic in space, with period Nd in both x and y directions. Since we anticipate our approach being used to simulate the embossing of large arrays of identical microfluidic devices on a single polymeric layer, for example, we see this assumption of periodicity as being an advantage. The iterative solution process must also establish which regions of the stamp are in contact with the polymer when the given embossing load is applied — i.e. which cavities are filled with material. Therefore when a solution for the pressure distribution is found, the corresponding polymer topography is computed and any parts of the simulation region in which the polymer would intersect with the stamp are added to the set of cells assumed to be in contact. Any parts of the contact set in which the computed pressure is tensile are removed from the contact set: the stamp is assumed to be unable to stick to the polymer. This iterative process is repeated until either the contact set is unchanged with a new iteration, or a specified maximum number of iterations have been completed. The solutions for contact pressure distribution and polymer topography that exist at the end of this process are returned as the result of the simulation.
(a)
point load
(b)
h polymer: E1, n1 substrate: E2, n2
polymer: E1, n1
Fig. 3. Comparison of the point-load responses of thick and thin polymeric layers. When the layer is much thicker than the characteristic lateral dimensions of the structure being imprinted (a), the layer can be well approximated as an elastic half-space. When the layer thickness is comparable with the dimensions of the pattern being imprinted (b), a different function, dependent on h, is required. Ei are the layers’ Young’s moduli; vi are their Poisson’s ratios.
2.3 Extension to finite-thickness substrates The procedure described in 2.2 was derived for infinitely thick substrates. For micro-embossed polymeric layers on the order of 1 mm in thickness, such a model has been seen to represent experimental results well. For thinner layers, however, a more general approach is needed (Fig 3). We begin by confining ourselves to cases in which, although the layer may be thin in comparison with the diameters of the largest features on the stamp, the average thickness of the
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layer is reduced, during embossing, by only a small proportion of its original thickness. Such an assumption would presumably be valid when modeling a process in which a stamp with a patterned relief of, say, 10 µm was embossed into a layer of thickness 100 µm. All that needs to change in our simulation approach is our description of how the material’s surface deforms when exposed to unit pressure across one element of the discretized polymer surface. We use an approach described by O’Sullivan and King 6, and later employed by Peng and Bhusan7 and by Nogi and Kato8, in which an analytical solution is found for the Papkovich-Neuber potentials in the upper layer, 1. The stresses and displacements in the layer are then found for the application of unit pressure to a central d × d region of the surface. The solution is performed in the spatial frequency domain and the inverse Fourier transform is subsequently computed numerically to give a spatial representation of the kernel function. The Fourier transform of the surface deflection of layer 1 is given by:
⎡1 − ν 1 ⎤ C (ξ ,η ) = − ⎢ ⎥ [1 + 4αhκ exp(− 2αh ) − λκ exp(− 4αh )]αR ⎣ µ1 ⎦
(5)
where ξ and η are spatial frequencies and
α = k f ξ 2 +η 2 ; λ = 1−
[ (
µ1 µ 2 − 1 4(1 −ν 1 ) ; κ= 1 + (µ1 µ 2 )(3 − 4ν 2 ) µ1 µ 2 + (3 − 4ν 1 )
(6)
]
)
R = − 1 − λ + κ + 4κα 2 h 2 exp(− 2αh ) + λκ exp(− 4αh ) α −2 . −1
The thickness of layer 1 (as defined in Fig 3) is denoted as h and layer 2 is assumed infinite in thickness; µi are the layers’ shear moduli, equal to Ei/[2(1+νi)]. The factor kf is introduced here as a way of ‘tuning’ the model to experimental results. It has no physical basis at present but has been found to be needed to model some of the results that will be presented in Section 4. In the absence of ‘tuning’, kf is set to 1. In this implementation, C[ξm, ηn] are computed over a range of 2N for m and n, where ξm = mkfπ/Nd and ηn = nkfπ/Nd. The value of C[0, 0] is undefined according to (5); however, since most thermoplastics above their glass transition temperature are almost incompressible, we set C[0, 0] to zero, with the result that the average value of the function in the spatial domain will be zero — consistent with conservation of the layer’s volume. After inverse Fourier transformation of C[ξm, ηn] and scaling up by the empirical factor kf, the central N × N region of the resulting matrix is taken as the kernel function, c[m, n], for use in simulation (Fig 4). This approach to constructing the kernel function has been found necessary in order to give accurate simulations of long-range pattern interactions. (In the subsequent simulation, c[m, n] is again Fourier-transformed as part of the forward convolution with trial pressure distributions.) h
y
x
2N
inverse Fourier transform
N
x
× kf kf π / Nd (a) frequency domain
simulation d domain (b) spatial domain
Fig. 4. Illustration of the relationship between frequency and spatial domains in the construction of the point-load response kernel function. Coefficients in the frequency domain are calculated across a matrix with four times as many elements as are in the spatial representation of the region to be simulated. The additional empirical factor kf is introduced to allow the characteristic length of the kernel function to be ‘tuned’ to experimental results if necessary. After inverse Fourier transformation and scaling by kf, the central N × N elements of the resulting matrix are used as the kernel function. After Nogi and Kato8.
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The substrate would usually be expected to be much harder than the polymeric layer, although its stiffness and Poisson’s ratio can be appropriately specified. The substrate is also assumed in this formulation to be bonded to the polymeric layer. If the substrate is genuinely attached to the layer — as it would be if the polymer had been spun on to a silicon wafer prior to embossing — we would almost certainly be comfortable with this assumption. If, however, the polymer layer is self-contained (e.g. an extruded film), the assumption may be less valid. It would be possible to derive kernel functions for various polymer–substrate coefficients of friction. The kernel function was evaluated and is plotted in Fig 5 for three values of h. In the functions plotted here, the layer is assumed to have a Young’s modulus of 2 MPa and a Poisson’s ratio of 0.5, and each function is discretized at a 1 µm pitch and evaluated over a 512 µm × 512 µm region. For h = 1 mm, the function produced by evaluating and inverse Fourier-transforming (5) is almost indistinguishable from the analytical function of (2) for an elastic half-space. For h = 75 µm, the diameter of the kernel function has tightened somewhat but retains largely the same shape. For h = 2.2 µm, however, the function has changed radically to a two-peak form in which material is displaced upwards around the region of application of pressure.
surface displacement (µm)
h = 2.2 µm h = 2.2 µm
h = 75 µm h = 1 mm and elastic half-plane
h = 75 µm
h = 1 mm
Elastic half-plane radial position (µm)
radial position (µm)
Fig. 5. Comparison of kernel functions generated for three different layer thicknesses. The functions are discretized with pitch d = 1 µm and describe the displacement of an elastic material’s surface in response to unit pressure applied downwards across a region of size d × d, centered at (0, 0). The layer, of thickness h, is assumed to have a Young’s modulus of 2 MPa and a Poisson’s ratio of 0.5. The three function instances for which h is defined were generated following the method described by Nogi and Kato8. For h = 1 mm, the finite layer-thickness function is virtually indistinguishable from the analytical function for the surface displacement of an elastic half-space5. For h = 75 µm, the shape is appreciably changed, and for h = 2.2 µm, the function has morphed into one with two peaks, indicating upwards displacement of material around the point of loading.
While the method for computing the kernel function for a finite-thickness layer produces a smooth result when h >> d, the kernel function is noticeably rough when d ~ h. Although, as will be seen in Section 4, the rough function is still able to provide smooth and realistic simulated topographies, it may prove desirable to smooth the kernel function, perhaps by evaluating C[ξm, ηn] over a larger range of frequencies and downsampling the inverse-transformed function.
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3. EXPERIMENTAL METHOD 3.1 Test-pattern design The test-pattern illustrated in Fig 6 was used to conduct embossing experiments against which to compare simulation results. The pattern comprises a 30 mm square array of identical cells, with each cell having diameter 0.85 mm. The cell design, when transferred to an embossing stamp, incorporates square holes and trenches with diameters and separations ranging from 10 to 100 µm. The design of the pattern is deliberately periodic, to allow for convenient simulation using the method described above.
polymer sample
A
A’
B
B’
silicon stamp
0.85 mm stamp cavity stamp surface
Fig. 6. Test-pattern for embossing polymeric layers. The design of one unit of the pattern contains square holes, trenches and ridges ranging from 10 to 100 µm in diameter. The relief of the pattern on the test stamp is ~ 30 µm. The stamp is patterned with a square, homogeneous array of these units at a pitch of 850 µm. The array of patterns extends beyond the edges of the polymeric sample. Two sections through the pattern are defined for the analysis of results: A–A’, which is through embossed ridges/trenches, and B–B’, which is through square posts on the embossed part.
3.2 Test stamp fabrication The test-pattern illustrated was etched into a silicon wafer using deep reactive ion etching to a depth of approximately 30 µm. The etch mask was a 10 µm-thick layer of AZ4620 photoresist and after etching this was removed from the wafer by a 30-minute oxygen plasma exposure followed by a 15-minute immersion in a hydrogen peroxide/sulfuric acid ‘pirahna’ mixture. 3.3 Embossing of 75 µm-thick PMMA film Sheets of 75 µm-thick Rohaglas 99845 PMMA were obtained as a gift from Degussa HPP Technical Films (Madison, WI). Two preliminary 15 mm square samples were cut from the film and embossed with the silicon test stamp under the following conditions: (i) 75 °C, with a sample-average pressure of c. 4 MPa; (ii) 80 °C, with a sample-average pressure of 13 MPa. In both cases the load was held for 2 minutes before cooling to 40 °C and unloading. The embossing apparatus used was a Carver (Wabash, IN) 4386 manual hydraulic press equipped with electrically heated platens and water-assisted cooling. A 1.5 mm-thick polycarbonate plate served as the ‘rigid backing plate’ of Fig 1a: since the embossing temperature was well below polycarbonate’s glass-transition temperature of ~137 °C, it was assumed that the Young’s modulus of the backing plate was 3 GPa and with a Poisson’s ratio of 0.3. 3.4 Embossing of spun-on 2.2 µm-thick polysulfone film Polysulfone (BASF, Florham Park, NJ) was dissolved at a concentration of 15 wt% in N-Methylpyrrolidone, and was spun at 1000 r.p.m. on to silicon wafers on to which had first been deposited a silicon nitride layer using the process detailed by Iliescu et al.9: it was found that the nitride layer promoted the adhesion of the polysulfone to the wafer’s surface. After spinning, the wafers were baked on a hotplate at 110 °C for 1 minute. A wafer coated in this way was
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diced into pieces c. 15 mm square. As a preliminary test, one of these pieces was embossed at 205 °C with a sampleaverage pressure of 30 MPa that was held for 2 minutes before cooling. The embossing temperature was 20 °C above the published value of polysulfone’s glass-transition temperature. Because of the high temperature of embossing, it would not have been safe to use the water-cooling capability of the press, and the platens were instead allowed to cool, via radiation and the convection of air, at a much slower rate, taking ~20 minutes to reach the unloading temperature of ~130 °C. 3.5 Measurement The pre-embossing thickness of the spun-on polysulfone film was measured by scratching the film from part of a fragment of a film-coated wafer, sputtering the fragment with ~50 nm gold, and profiling the surface with a Zygo (Middlefield, CT) NewView scanning white-light interferometer. The PMMA film’s thickness, meanwhile, was measured with a micrometer screw gauge. The polysulfone sample, post-embossing, was scratched in a small region to reveal the underlying substrate. These samples, and the embossed PMMA films, were sputtered with ~50 nm gold and their surfaces were profiled with the white-light interferometer. Using this interferometer, the area of a single cell could be scanned at a lateral resolution of ~0.5 µm in ~2 minutes. Measurement is quick enough that several measurements can efficiently be made at various positions on a sample, giving an impression of the spatial uniformity of the embossed pattern or of the frequency of defect occurrence. The topography of the etched silicon stamp was also measured by white-light interferometry.
4. RESULTS AND DISCUSSION 4.1 75 µm-thick PMMA layer We consider first the results of embossing the 75 µm-thick PMMA film. Cross-sections through the measured topographies are plotted in Fig 7. For the sample processed at 75 °C with a sample-average pressure of 4 MPa (Fig 7a and 7b), penetration of the stamp cavities was everywhere less than 2 µm. A finite-thickness linear-elastic model of the embossed layer was fit to these experimental results, and the red solid lines in Fig 7a and 7b correspond to an effective elastic modulus of 163 MPa. The effective modulus was the only fitting parameter; the factor kf was kept equal to 1. The shape and magnitude of the simulated topographies match the measurements closely. We also plot, as a dashed green line, the topography predicted by an infinite-thickness layer model having an effective Young’s modulus of 163 MPa. Interestingly, the infinite-thickness model under-predicts by as much as 30% the degree of penetration of the narrower cavities, but substantially overestimates the degree of penetration of the 100 µm-wide cavity. In other words, for a given applied embossing pressure, cavities narrower than the layer thickness are penetrated further than they would be if the layer were infinitely thick, while cavities wider than the layer thickness are penetrated less far than they would be for a thicker layer. This result is worth noting, because it suggests that for a given stamp pattern there may be a finite polymeric layer thickness that is ‘optimal’ for embossing in the sense that it requires a minimal pressure to fill all its cavities. For the sample embossed at 80 °C with a sample-average pressure of 13 MPa, the finite-thickness substrate model tracks well the peak cavity penetration depths when an effective layer modulus of 10.7 MPa is chosen (Fig 8b). That this modulus is more than a decade smaller than the modulus fit for the sample embossed at 75 °C indicates that these samples were processed in the glass-transition region of the polymer, in which the viscoelastic parameters vary rapidly with temperature. Extensive further investigation would be needed to place fully in context these point-estimates of effective modulus. Yet the point that can be taken from this experiment is that a linear-elastic material representation, using an appropriately scaled modulus, can provide a good prediction of embossed topography. Although the peak depth of cavity penetration is well captured by the model, the shape of the material penetrating each cavity is not very closely represented: the simulation implies that material penetrating the narrow cavities adopts a parabolic shape, while a scanning electron micrograph of the embossed part (Fig 8c) indicates a more rectangular shape for the ‘plug’ of material penetrating each cavity. A modified kernel function shape might better capture the embossed topography, although the ability of this simulation technique to establish the necessary embossing pressure for nearcomplete stamp filling may well prove to be adequate as it stands.
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75 °C 4 MPa
topography (µm)
(a) Section A–A’
(b) Section B–B’
80 °C 13 MPa
topography (µm)
(c) Section A–A’
(d) Section B–B’
lateral position (µm) simulation: finite-thickness model
measured tops of Si stamp cavities
simulation: infinite-thickness model
experiment
Fig. 7. Results of embossing two samples of Rohrglas 99845 PMMA. One was embossed at 75 °C and a sample-average pressure of c. 4 MPa, and the other at 80 °C and c. 13 MPa. The loading duration was 2 minutes in each case. Measured topographies through sections A–A’ (ridges) and B–B’ (posts), as defined in Fig. 6, are shown for each sample (black circles), along with the equivalent simulated topographies (red solid lines) and the measured locations of the tops of the stamp cavities (blue dashed lines). In (a) and (b), green dashed lines also show the prediction of an infinite-thickness model of the polymeric layer.
Proc. of SPIE Vol. 7269 726909-9
(a) simulated contact pressure (MPa)
(b) simulated topography (pm)
150
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Fig. 8. Simulation vs. experiment for the embossing of Rohrglas 99845 PMMA at 80 °C and a sample-average pressure of c. 13 MPa for 2 minutes. The simulated contact pressure distribution (a) indicates that the contact pressure peaks at the edges of the stamp–substrate contact regions. A 3-D plot of the simulated topography (b) shows that wider features have been penetrated more deeply by polymer. A scanning electron micrograph of a region of the sample (c) demonstrates the reasonable fidelity of the simulation.
4.2 2.2 µm-thick polysulfone layer We now consider the embossing of the polysulfone film. Fig 9 shows topographies measured at two separate sites on the same sample, which was embossed at 205 °C for 2 min under 30 MPa. Whereas, with the 75 µm-thick film, the wider cavities on the stamp filled more readily, in the case of this thinner film the depth of cavity penetration is larger for the smaller cavities, and especially for those cavities surrounded by large regions of the stamp without cavities (Fig 10a). Moreover, the topography of material penetrating each cavity wider than 10 µm now exhibits separate peaks at the cavity edges, in place of the single central peak seen with layers that are thicker than the cavity widths. This dual-peak filling mode is similar to that observed at the considerably smaller scales of thermal nanoimprint lithography10–12. The finite-thickness kernel function generated for the measured film thickness of 2.2 µm yielded a simulated topography with peaks that were rather too sharp and too close to the edges of the cavities. By tuning the scaling factor kf to 2.5, the characteristic diameter of the kernel function is increased by that factor and the shapes of most peaks are now well represented. The only exception is the very tall peak at the right hand side of the traces in Fig 9, which the scanning electron micrograph of Fig 10c indicates has in reality curled over towards the substrate, reducing its height. A corresponding effective elastic modulus of 4 MPa was fit for the layer.
Proc. of SPIE Vol. 7269 726909-10
topography (µm)
measurement site 1
(a) Section A–A’
posts broken
(b) Section B–B’
topography (µm)
measurement site 2
(c) Section A–A’
(d) Section B–B’
lateral position (µm) simulation
experiment
measured tops of Si stamp cavities
Fig. 9. Comparison of experimental results and simulation for the embossing of a 2.2 µm-thick spun-on film of polysulfone. The sample was embossed at 205 °C with a sample-average pressure of 30 MPa held for approximately 2 minutes before cooling to ~130 °C over ~10 minutes and unloading. Measurements from two separate locations on the sample are shown. Measured topographies through sections A–A’ (ridges) and B–B’ (posts), as defined in Fig. 6, are shown for each location (black circles), along with the equivalent simulated topographies (red solid lines) and the measured locations of the tops of the stamp cavities (blue dashed lines).
Proc. of SPIE Vol. 7269 726909-11
(a)
surface position (µm)
(b)
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H
200 o0
10
H
LL h
300
02 500
20 µm
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Fig. 10. Simulation vs. experiment for the embossing of a 2.2 µm-thick spun-on film of polysulfone. A 3-D plot of the simulated topography (b) indicates that the narrower cavities, and especially those surrounded by few other cavities, have filled the most deeply. Scanning electron micrographs of the sample (a, c) verify this behavior.
As the thickness of the polymeric layer reduces, the nature of the simulated pressure distribution also changes substantially. With the 75 µm-thick layer, contact pressure exhibits peaks at the boundaries of cavities (Fig 8a), while for the 2.2 µm-thick layer, contact pressure is minimal at cavity edges and increases with distance from a cavity (Fig 11a). The location of the peak of the simulated pressure distribution for the 2.2 µm-thick layer corresponds to some interesting artifacts in a portion of the sample (Fig 11b). Profiling of one of these artifacts showed that the layer thickness had apparently sprung back to its original value at the center of the artifact. Further investigation of the causes of these defects is needed.
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Lateral position (mm) Fig. 11. (a) Simulation of stamp–polymer contact pressure distribution in the embossing of a 2.2 µm-thick spun-on film of polysulfone. The simulated pressure increases with distance from the edges of the contact region. An optical micrograph of several copies of the test pattern in part of the embossed sample (b) indicates defects in the compressed region of the polysulfone film, corresponding in shape to that of the simulated pressure distribution. Profilometry of one of these defects (c, d) indicates that the compressed layer has ‘sprung back’ to approximately its original thickness in the center of the defect region.
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Fig. 12. Scanning electron micrographs of the embossed polysulfone sample. (a) Close-up of 10, 20 and 30 µm-diameter posts and ridges, showing the edge-peaks in the topographies of incompletely filled features and the places where 10 µm-diameter posts had been torn from the film during separation of the stamp from the layer. (b) Oblique view of three copies of the test pattern, showing the topography of the embossed layer. (c) Close-up of the ends of two embossed ridges, in a region where part of the film has been scratched away, revealing the SiN substrate and showing the thickness of the compressed layer of polysulfone.
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Our current modeling approach is based on the assumption that, while the layer may be thin, it is compressed by only a small proportion of its thickness. In fact, the minimum post-embossing layer thickness of polysulfone was measured as 1.6 µm, which is around 70% of the starting layer thickness. This is a substantial reduction, and to be modeled properly we might need to consider finding the true final pressure distribution as the superposition of a series of pressure distributions associated with progressively thinner layers. We do not, however, anticipate that such a refinement would deal with the modeling problem that the scaling factor kf is designed to overcome: thinner layers are associated with narrower load-response kernel functions, while in contrast we found that we needed a broader kernel function than was directly predicted by the 2.2 µm initial thickness. 4.3 Simulation speed The test pattern was discretized for simulation on a 1µm-pitch grid of 850 × 850 elements. In cases where the initial guess for the contact set was accurate, the simulation, which was implemented in MatLab (The Mathworks, Natick, MA), completed in between 30 and 90 s using a desktop computer equipped with two 3.2 GHz Intel Pentium 4 processors and 2 GB of RAM. In the case where material had touched the tops of some of the cavities (PMMA embossed at 80 °C), additional iterations to find the contact set extended the simulation time to up to ten minutes. In comparison with full three-dimensional finite-element modeling of such a structure, we anticipate that our simulation approach will be shown to be approximately two orders of magnitude faster.
5. CONCLUSION We have outlined a computationally inexpensive way of simulating the hot-embossing of thermoplastic layers of finite thickness. A simulation in which the embossed layer is discretized on a grid of size 850 × 850 takes between one and ten minutes to run. The results of such simulations have been shown to capture the key topographical features of real embossed thermoplastic layers having two markedly different layer thicknesses. The thickness of one of these layers, 75 µm, was larger than most of the feature dimensions of the embossed pattern, while the other, at 2.2 µm, was substantially thinner than all feature dimensions. There remains much work to be done to establish the extent of validity of this modeling approach, but it appears to offer a promising means by which to select appropriate processing parameters for the successful embossing of a given pattern. The insights offered by this modeling approach could also be used to guide the design of embossed patterns — for example, by informing the introduction of ‘dummy’ features on embossing stamps to relieve contact pressure concentrations. Ongoing work aims to refine the simulation method to deal with cases in which parts of a finite-thickness layer are reduced, during embossing, to a small proportion of the initial layer thickness. When this refinement is accomplished, the computationally efficient simulation of nanoimprint lithography will be an avenue along which this work can be extended.
6. ACKNOWLEDGEMENTS We thank N. Ames, L. Anand, B. Anthony, M. Dirckx, D. Hardt, and Y. Hirai for helpful discussions. We acknowledge the support of the Singapore–MIT Alliance as well as the use of MIT’s Microsystems Technology Laboratories in the course of this work.
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7. REFERENCES [1] [2] [3] [4] [5] [6] [7] [8] [9] [10] [11] [12]
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