MSDS - Devcon

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MSDS Name Manufacturer Name Stock No.: Kit MSDS Revision Date

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DEVCON® Plastic Steel® Liquid (B) ITW Polymers Adhesives, North America 10210 12/30/2012

Components PLASTIC STEEL LIQUID (B) RESIN PLASTIC STEEL LIQUID (B) HARDENER ITW Polymers Adhesives, North America Product Code : 10210 SECTION 1 : PRODUCT AND COMPANY IDENTIFICATION Product Nam e: Manufacturer Nam e: Address: General Phone Num ber: Em ergency Phone Num ber: CHEMTREC: MSDS Revision Date:

PLA STIC STEEL LIQUID (B) RESIN ITW Polym ers Adhesives, North Am erica 30 Endicott Street Danvers, MA 01923 (978) 777-1100 (800) 424-9300 For em ergencies in the US, call CHEMTREC: 800-4249300 12/30/2012

HMIS Health Hazard

2*

Fire Hazard

1

Reactivity

1

Personal Protection

x

*

Chronic Health Effects

SECTION 2 : COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name

CA S#

Ingredient Percent

Iron

7439-89-6

30 - 60 by weight

Bisphenol A diglycidyl ether resin

25068-38-6

30 - 60 by weight

Titanium

7440-32-6

1 - 5 by weight

Silicon

7440-21-3

10 - 30 by weight

Fillers

N/A

1 - 5 by weight

SECTION 3 : HAZARDS IDENTIFICATION Em ergency O verview: Route of Ex posure: Potential Health Effects: Eye:

Sk in:

Inhalation:

Ingestion: Chronic Health Effects: Signs/Sym ptom s: Target O rgans: Aggravation of Pre-Ex isting Conditions:

W ARNING! Potential Sensitizer. Irritant. Eyes. Sk in. Inhalation. Ingestion. Can cause m oderate irritation, burning sensation, tearing, redness, and swelling. O verex posure m ay cause lacrim ation, conjunctivitis, corneal dam age and perm anent injury.. Can cause sk in irritation; itching, redness, rashes, hives, burning, and swelling. Allergic reactions are possible. May cause sk in sensitization, an allergic reaction, which becom es evident on reex posure to this m aterial. Respiratory tract irritant. High concentration m ay cause dizziness, headache, and anesthetic effects. May cause respiratory sensitization with asthm a-lik e sym ptom s in susceptible individuals. Causes irritation, a burning sensation of the m outh, throat and gastrointestinal tract and abdom inal pain. Prolonged sk in contact m ay lead to burning associated with severe reddening, swelling, and possible tissue destruction. O verex posure can cause headaches, dizziness, nausea, and vom iting. Eyes. Sk in. Respiratory system . Digestive system . Individuals with pre-ex isting sk in disorders, asthm a, allergies or k nown sensitization m ay be m ore susceptible to the effects of this product.

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SECTION 4 : FIRST AID MEASURES Eye Contact:

Sk in Contact:

Inhalation: Ingestion:

Im m ediately flush eyes with plenty of water for at least 15 to 20 m inutes. Ensure adequate flushing of the eyes by separating the eyelids with fingers. Get im m ediate m edical attention. Im m ediately wash sk in with plenty of soap and water for 15 to 20 m inutes, while rem oving contam inated clothing and shoes. Get m edical attention if irritation develops or persists. If inhaled, rem ove to fresh air. If not breathing, give artificial respiration or give ox ygen by trained personnel. Seek im m ediate m edical attention. If swallowed, do NO T induce vom iting. Call a physician or poison control center im m ediately. Never give anything by m outh to an unconscious person.

SECTION 5 : FIRE FIGHTING MEASURES Flash Point: Flash Point Method: Auto Ignition Tem perature: Lower Flam m able/Ex plosive Lim it: Upper Flam m able/Ex plosive Lim it: Fire Fighting Instructions:

Ex tinguishing Media: Unsuitable Media: Protective Equipm ent: Unusual Fire Hazards:

>400°F (204.4°C) Pensk y-Martens Closed Cup Not determ ined. Not determ ined. Not determ ined. Evacuate area of unprotected personnel. Use cold water spray to cool fire ex posed containers to m inim ize risk of rupture. Do not enter confined fire space without full protective gear. If possible, contain fire run-off water. Use carbon diox ide (CO 2) or dry chem ical when fighting fires involving this m aterial. Water or foam m ay cause frothing. As in any fire, wear Self-Contained Breathing Apparatus (SCBA), MSHA/NIO SH (approved or equivalent) and full protective gear. Sealed containers at elevated tem peratures m ay rupture ex plosively and spread fire due to polym erization.. Heating above 300 deg F in the presence of air m ay cause slow ox idative decom position and above 500 deg F m ay cause polym erization.

SECTION 6 : ACCIDENTAL RELEASE MEASURES Spill Cleanup Measures:

Personnel Precautions: Environm ental Precautions: O ther Precautions:

Absorb spill with inert m aterial (e,g., dry sand or earth), then place in a chem ical waste container. Provide ventilation. Clean up spills im m ediately observing precautions in the protective equipm ent section. After rem oval, flush spill area with soap and water to rem ove trace residue. Avoid personal contact and breathing vapors or m ists. Ventilate area. Use proper personal protective equipm ent as listed in section 8. Evacuate area and k eep unnecessary and unprotected personnel from entering the spill area. Avoid runoff into storm sewers, ditches, and waterways. Pum p or shovel to storage/salvage vessels.

SECTION 7 : HANDLING and STORAGE Handling: Storage: Special Handling Procedures:

Hygiene Practices:

Use with adequate ventilation. Avoid breathing vapor, aerosol or m ist. Store in a cool, dry, well ventilated area away from sources of heat and incom patible m aterials. Keep container tightly closed when not in use. Provide appropriate ventilation/respiratory protection against decom position products (see Section 10) during welding/flam e cutting operations and to protect against dust during sanding/grinding of cured product. Wash thoroughly after handling.

SECTION 8 : EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE GUIDELINES Engineering Controls:

Eye/Face Protection:

Sk in Protection Description: Respiratory Protection:

O ther Protective:

Use appropriate engineering control such as process enclosures, local ex haust ventilation, or other engineering controls to control airborne levels below recom m ended ex posure lim its. Good general ventilation should be sufficient to control airborne levels. W here such system s are not effective wear suitable personal protective equipm ent, which perform s satisfactorily and m eets O SHA or other recognized standards. Consult with local procedures for selection, training, inspection and m aintenance of the personal protective equipm ent. Wear appropriate protective glasses or splash goggles as described by 29 CFR 1910.133, O SHA eye and face protection regulation, or the European standard EN 166. Wear appropriate protective gloves and other protective apparel to prevent sk in contact. Consult m anufacturer's data for perm eability data. A NIO SH approved air-purifying respirator with an organic vapor cartridge or canister m ay be perm issible under certain circum stances where airborne concentrations are ex pected to ex ceed ex posure lim its. Protection provided by air purifying respirators is lim ited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, ex posure levels are not k nown, or any other circum stances where air purifying respirators m ay not provide adequate protection. Facilities storing or utilizing this m aterial should be equipped with an eyewash and a deluge shower safety station.

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eyewash and a deluge shower safety station.

EXPO SURE GUIDELINES Silicon: Guideline ACGIH: Guideline O SHA:

Notes :

15 m g/m 3 PEL-TW A: 15 m g/m 3 Total particulate/dust (T) PEL-TW A: 5 m g/m 3 Respirable fraction (R) O nly established PEL and TLV values for the ingredients are listed.

SECTION 9 : PHYSICAL and CHEMICAL PROPERTIES Physical State Appearance: Color: O dor: Boiling Point: Melting Point: Specific Gravity: Solubility: Vapor Density: Vapor Pressure: Percent Volatile: Evaporation Rate: pH: Molecular Form ula: Molecular Weight: Flash Point: Flash Point Method: Auto Ignition Tem perature: VO C Content: Percent Solids by Weight

Viscous. Liquid.. dark grey. Slight. odor. >500°F (260°C) Not determ ined. 2.8 negligible. >1 (air = 1) 0.03 m m Hg @171°F 0 2 gm /k g [Nutritional and Gross Metabolic - O ther changes] RTECS Num ber: XR1700000 Silicon: RTECS Num ber: VW 0400000 Eye: Eye - Rabbit Standard Draize test.: 3 m g Ingestion: O ral - Rat LD50: 3160 m g/k g [Details of tox ic effects not reported other than lethal dose value]

SECTION 12 : ECOLOGICAL INFORMATION Ecotox icity: Environm ental Fate:

No ecotox icity data was found for the product. No environm ental inform ation found for this product.

SECTION 13 : DISPOSAL CONSIDERATIONS Waste Disposal:

RCRA Num ber:

Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the classifications of hazardous waste prior to disposal. Furtherm ore, consult with your state and local waste requirem ents or guidelines, if applicable, to ensure com pliance. Arrange disposal in accordance to the EPA and/or state and local guidelines. None.

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SECTION 14 : TRANSPORT INFORMATION DO T DO T DO T DO T

Shipping Nam e: UN Num ber: Hazard Class: Pack ing Group:

Non regulated. N/A Not applicable. Not applicable.

SECTION 15 : REGULATORY INFORMATION Iron : TSCA Inventory Status: Listed Canada DSL: Listed Bisphenol A diglycidyl ether resin : TSCA Inventory Status: Listed Canada DSL: Listed Titanium : TSCA Inventory Status: Listed Canada DSL: Listed Silicon : TSCA Inventory Status: Listed Massachusetts: Listed Pennsylvania: Listed Canada DSL: Listed Canadian Regulations. W HMIS Hazard Class(es): D2B All com ponents of this product are on the Canadian Dom estic Substances List.

SECTION 16 : ADDITIONAL INFORMATION HMIS Fire Hazard: HMIS Health Hazard: HMIS Reactivity: HMIS Personal Protection: MSDS Revision Date: MSDS Author:

1 2* 1 x 12/30/2012 Actio Corporation

Copyright� 1996-2011 Actio Software Corporation. All Rights Reserved.

SECTION 1 : PRODUCT AND COMPANY IDENTIFICATION Product Nam e: Manufacturer Nam e: Address: General Phone Num ber: Em ergency Phone Num ber: CHEMTREC: MSDS Creation Date: MSDS Revision Date:

PLA STIC STEEL LIQUID (B) HA RDENER ITW 30 Endicott Street Danvers, MA 01923 (978) 777-1100 (800) 424-9300 For em ergencies in the US, call CHEMTREC: 800-4249300 6/22/2012 06/30/2012

HMIS Health Hazard

3*

Fire Hazard

1

Reactivity

0

Personal Protection

X

*

Chronic Health Effects

SECTION 2 : COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name

CA S#

Triethylenetetram ine

112-24-3

2-Propenenitrile, reaction products with ethylenediam ine, 68909-99-9 hydrogenated

Ingredient Percent

< 5 by weight >25 by weight

SECTION 3 : HAZARDS IDENTIFICATION Em ergency O verview: Route of Ex posure: Potential Health Effects: Eye: Sk in:

DANGER! Corrosive. Harm ful. Potential Sensitizer Irritant. Eyes. Sk in. Inhalation. Ingestion. Corrosive. W ill cause eye burns, perm anent tissue dam age, and blindness. Contact causes severe sk in irritation and possible burns. m ay cause perm anent sk in dam age. If absorbed through the sk in, m ay cause central nervous system effects, such as headache, nausea, dizziness, confusion, breathing difficulties. Harm ful in contact with sk in. Allergic reactions are possible. May cause sk in sensitization, an allergic reaction, which becom es evident

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Inhalation:

Ingestion: Chronic Health Effects: Signs/Sym ptom s:

Target O rgans: Aggravation of Pre-Ex isting Conditions:

on reex posure to this m aterial. May cause severe respiratory system irritation. May cause central nervous system effects, such as headache, nausea, dizziness, confusion, breathing difficulties. Severe cases of overex posure can result in respiratory failure. Pulm onary edem a m ay be delayed up to 24 hours. This product presents an elevated inhalation health risk when used in spray or aerosol applications. Harm ful if swallowed. Corrosive to the gastrointestinal tract. Prolonged sk in contact causes burns. Repeated or prolonged inhalation m ay cause tox ic effects. Depending on solution concentration, m aterial m ay be corrosive to sk in, m ucous m em branes and eyes. Vapors m ay cause respiratory irritation. Sym ptom s of overex posure m ay be headache, dizziness, tiredness, nausea and vom iting. Eyes. Sk in. Respiratory system . Digestive system . Individuals with pre-ex isting sk in disorders, asthm a, allergies or k nown sensitization m ay be m ore susceptible to the effects of this product.

SECTION 4 : FIRST AID MEASURES Eye Contact:

Sk in Contact:

Inhalation: Ingestion:

O ther First Aid:

Im m ediately flush eyes with plenty of water for at least 15 to 20 m inutes. Ensure adequate flushing of the eyes by separating the eyelids with fingers. Get im m ediate m edical attention. Im m ediately wash sk in with plenty of soap and water for 15 to 20 m inutes, while rem oving contam inated clothing and shoes. Get m edical attention if irritation develops or persists. If inhaled, rem ove to fresh air. If not breathing, give artificial respiration or give ox ygen by trained personnel. Seek im m ediate m edical attention. If swallowed, do NO T induce vom iting. Call a physician or poison control center im m ediately. Never give anything by m outh to an unconscious person. Due to possible aspiration into the lungs, DO NO T induce vom iting if ingested. Provide a glass of water to dilute the m aterial in the stom ach. If vom iting occurs naturally, have the person lean forward to reduce the risk of aspiration.

SECTION 5 : FIRE FIGHTING MEASURES Flam m able Properties: Flash Point: Flash Point Method: Auto Ignition Tem perature: Lower Flam m able/Ex plosive Lim it: Upper Flam m able/Ex plosive Lim it: Fire Fighting Instructions:

Ex tinguishing Media: Unsuitable Media: Protective Equipm ent:

Class III B. >230°F (110°C) Pensk y-Martens Closed Cup Not determ ined. Not determ ined. Not determ ined. Evacuate area of unprotected personnel. Use cold water spray to cool fire ex posed containers to m inim ize risk of rupture. Do not enter confined fire space without full protective gear. If possible, contain fire run-off water. Use carbon diox ide (CO 2) or dry chem ical when fighting fires involving this m aterial. Water or foam m ay cause frothing. As in any fire, wear Self-Contained Breathing Apparatus (SCBA), MSHA/NIO SH (approved or equivalent) and full protective gear.

SECTION 6 : ACCIDENTAL RELEASE MEASURES Spill Cleanup Measures:

Personnel Precautions: Environm ental Precautions: O ther Precautions:

Absorb spill with inert m aterial (e,g., dry sand or earth), then place in a chem ical waste container. Provide ventilation. Clean up spills im m ediately observing precautions in the protective equipm ent section. After rem oval, flush spill area with soap and water to rem ove trace residue. Corrosive. Avoid personal contact and breathing vapors or m ists. Ventilate area. Use proper personal protective equipm ent as listed in section 8. Evacuate area and k eep unnecessary and unprotected personnel from entering the spill area. Avoid runoff into storm sewers, ditches, and waterways. Pum p or shovel to storage/salvage vessels.

SECTION 7 : HANDLING and STORAGE Handling:

Storage:

Special Handling Procedures:

Hygiene Practices:

Use with adequate ventilation. Avoid breathing vapor, aerosol or m ist. Avoid contact with eyes and sk in. Do not reuse containers without proper cleaning or reconditioning. Store in a cool, dry, well ventilated area away from sources of heat and incom patible m aterials. Keep container tightly closed when not in use. Do not store in reactive m etal containers. Keep away from acids, ox idizers. Provide appropriate ventilation/respiratory protection against decom position products (see Section 10) during welding/flam e cutting operations and to protect against dust during sanding/grinding of cured product. Do not use sodium nitrite or other nitrosating agents in form ulations containing this product. Suspected cancer-causing nitrosam ines could be form ed. Avoid contact with sk in and eyes. Wash thoroughly after handling.

Page 5 of 7

SECTION 8 : EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE GUIDELINES Engineering Controls:

Eye/Face Protection:

Sk in Protection Description:

Hand Protection Description:

Respiratory Protection:

O ther Protective:

Use appropriate engineering control such as process enclosures, local ex haust ventilation, or other engineering controls to control airborne levels below recom m ended ex posure lim its. Good general ventilation should be sufficient to control airborne levels. W here such system s are not effective wear suitable personal protective equipm ent, which perform s satisfactorily and m eets O SHA or other recognized standards. Consult with local procedures for selection, training, inspection and m aintenance of the personal protective equipm ent. Wear appropriate protective glasses or splash goggles as described by 29 CFR 1910.133, O SHA eye and face protection regulation, or the European standard EN 166. Chem ical-resistant gloves and chem ical goggles, face-shield and synthetic apron or coveralls should be used to prevent contact with eyes, sk in or clothing. Butyl rubber. Nitrile rubber. Neoprene gloves. Polyvinyl Alcohol Gloves (PVA). Im pervious gloves. PVC disposable gloves. A NIO SH approved air-purifying respirator with an organic vapor cartridge or canister m ay be perm issible under certain circum stances where airborne concentrations are ex pected to ex ceed ex posure lim its. Protection provided by air purifying respirators is lim ited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, ex posure levels are not k nown, or any other circum stances where air purifying respirators m ay not provide adequate protection. Facilities storing or utilizing this m aterial should be equipped with an eyewash and a deluge shower safety station.

EXPO SURE GUIDELINES Notes :

O nly established PEL and TLV values for the ingredients are listed.

SECTION 9 : PHYSICAL and CHEMICAL PROPERTIES Physical State Appearance: Color: O dor: Boiling Point: Melting Point: Density: Specific Gravity: Solubility: Vapor Pressure: Percent Volatile: Evaporation Rate: pH: Molecular Form ula: Molecular Weight: Viscosity: Flash Point: Flash Point Method: Auto Ignition Tem perature: VO C Content: Percent Solids by Weight

Liquid. Am ber. No data available >473°F (245°C) Not determ ined. 0.97 g/cm 3 (60.555 lb/ft3) at 21 °C ( 70 °F) Not determ ined. Slightly soluble 2.8 m m Hg @70°F Not determ ined. Not determ ined. alk aline Mix ture Mix ture 350 m Pa.s at 77 °F (25 °C) >230°F (110°C) Pensk y-Martens Closed Cup Not determ ined. Not determ ined. Not determ ined.

SECTION 10 : STABILITY and REACTIVITY Chem ical Stability: Hazardous Polym erization: Conditions to Avoid:

Incom patible Materials:

Stable under norm al tem peratures and pressures. Not reported. Ex trem e heat, spark s, and open flam e. Incom patible m aterials, ox idizers and ox idizing conditions. Product m ay slowly corrode copper, alum inum , zinc and galvanized surfaces. O x idizers, acids, and chlorinated organic com pounds. Reactive m etals (e.g. sodium , calcium , zinc). Sodium /calcium hypochlorite. Nitrous acid/ ox ide, nitrites. Perox ides. Materials reactive with hydrox yl com pounds. Do not use sodium nitrite or other nitrosating agents in form ulations containing this product. Suspected cancer-causing nitrosam ines could be form ed. Avoid contact with sk in and eyes. Reaction with perox ides m ay result in violent decom position of perox ide possibly creating an ex plosion.

SECTION 11 : TOXICOLOGICAL INFORMATION Triethylenetetramine: RTECS Num ber: Eye:

YE6650000 Eye - Rabbit Standard Draize test.: 49 m g Eye - Rabbit Standard Draize test.: 20 m g/24H

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Sk in:

Adm inistration onto the sk in - Rabbit LD50: 805 m g/k g [Details of tox ic effects not reported other than lethal dose value] Adm inistration onto the sk in - Rabbit O pen irritation test: 490 m g Adm inistration onto the sk in - Rabbit Standard Draize test.: 5 m g/24H Adm inistration onto the sk in - Guinea pig TDLo: 3667 m g/k g [Reproductive - Effects on Em bryo or Fetus - Fetal death] O ral - Rat LD50: 2500 m g/k g [Details of tox ic effects not reported other than lethal dose value] O ral - Mouse LD50: 38.5 m g/k g [Details of tox ic effects not reported other than lethal dose value]

Ingestion:

SECTION 12 : ECOLOGICAL INFORMATION Ecotox icity: Environm ental Fate:

No ecotox icity data was found for the product. No environm ental inform ation found for this product.

SECTION 13 : DISPOSAL CONSIDERATIONS Waste Disposal:

Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the classifications of hazardous waste prior to disposal. Furtherm ore, consult with your state and local waste requirem ents or guidelines, if applicable, to ensure com pliance. Arrange disposal in accordance to the EPA and/or state and local guidelines.

SECTION 14 : TRANSPORT INFORMATION DO T Shipping Nam e: DO T UN Num ber:

Refer to Bill of Lading Refer to Bill of Lading

SECTION 15 : REGULATORY INFORMATION Triethylenetetramine : TSCA Inventory Status: Listed Massachusetts: Listed Pennsylvania: Listed Canada DSL: Listed 2-Propenenitrile, reaction products with ethylenediamine, hydrogenated : TSCA Inventory Status: Listed Canada DSL: Listed Canadian Regulations. W HMIS Hazard Class(es): D2B; E All com ponents of this product are on the Canadian Dom estic Substances List.

WHMIS Pictograms

SECTION 16 : ADDITIONAL INFORMATION HMIS Fire Hazard: HMIS Health Hazard: HMIS Reactivity: HMIS Personal Protection: MSDS Creation Date: MSDS Revision Date: MSDS Author:

1 3* 0 X 6/22/2012 06/30/2012 Actio Corporation

Disclaim er:

This Health and Safety Inform ation is correct to the best of our k nowledge and belief at the date of its publication but we cannot accept liability for any loss, injury or dam age which m ay result from its use. The inform ation given in the Data Sheet is designed only as a guidance for safe handling, storage and the use of the substance. It is not a specification nor does it guarantee any specific properties. All chem icals should be handled only by com petent personnel, within a controlled environm ent. Copyright� 1996-2011 Actio Software Corporation. All Rights Reserved.

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