PROGRAM

XV Ukrainian-Polish Symposium

Theoretical and Experimental Studies of Interfacial Phenomena and Their Technological Applications simultaneously with

2nd NANOBIOMAT Conference

Nanostructured Biocompatible/Bioactive Materials

September 12-15, 2016 Lviv, Ukraine

PROGRAM

Symposium Organised by: Professor Mykola T. Kartel. Professor Volodymyr V. Brei, Professor Yuri I. Tarasevich, National Academy of Sciences of Ukraine; Professor Roman Leboda, Professor Jolanta Narkiewicz-Michałek, Faculty of Chemistry, Maria Curie-Skłodowska University, Poland and by: Chemical Division of the National Academy of Sciences of Ukraine A.V. Dumanski Institute of Colloid Chemistry and Chemistry of Water NASU, Kyiv O.O. Chuiko Institute of Surface Chemistry NASU, Kyiv Institute for Sorption and Problems of Endoecology NASU, Kyiv Faculty of Chemistry, Ivan Franko National University in Lviv Lviv University of Trade and Economics Faculty of Chemistry, Maria Curie-Skłodowska University in Lublin Lublin Division of the Polish Chemical Society Polish Academy of Sciences Scientific Center in Kyiv Polish Academy of Sciences Scientific Co-Chairmen of the Symposium: Professor Yuri I. Tarasevich, Corresponding Member of the National Academy of Sciences of Ukraine, A.V. Dumanski Institute of Colloid Chemistry and Chemistry of Water Professor dr. hab. Roman Leboda, Faculty of Chemistry, Maria CurieSkłodowska University Honorary Committee of the Symposium: Professor P. Kutsyk the Rector for the Lviv University of Trade and Economics Professor V. Melnyk the Rector for the Ivan Franko National University in Lviv Professor S. Michalowski the Rector for the Maria Curie-Skłodowska University in Lublin

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Scientific Committee of the Symposium: Prof. J. Błażejowski (Poland) Corr. Member of NASU V. Brei (Ukraine) Prof. B. Buszewski (Poland) Prof. S. Chibowski (Poland) Prof. A. Dąbrowski (Poland) Prof. A. Derylo-Marczewska (Poland) Prof. B. Gawdzik (Poland) Prof. A. Gierak (Poland) Corr. Member of NASU R. Gladyshevskii Prof. M. Glikin (Ukraine) Full Member of NASU V. Goncharuk (Ukraine) Prof. V. Gun’ko (Ukraine) Prof. W. Janusz (Poland) Prof. Ya. Kalychak (Ukraine) Full Member of NASU M. Kartel (Ukraine) Prof. I. Kocemba (Poland) Full Member of NASU V. Koshechko (Ukraine)

Dr. hab. A. Marczewski (Poland) Dr. L. Mikhalovska (UK) Prof. J. Narkiewicz-Michałek (Poland) Corr. Member of NASU S. Orlyk (Ukraine) Prof. W. Rudzinski (Poland) Prof. J. Ryczkowski (Poland) Prof. J. Rynkowski (Poland) Prof. Z. Rzączyńska (Poland) Dr. hab. J. Skubiszewska-Zięba (Poland) Prof. H. Sobczuk (Poland) Prof. М. Soltys (Ukraine) Full Member of NASU V. Strelko (Ukraine) Prof. V. Tertykh (Ukraine) Corr. Member of NASU V. Turov (Ukraine) Prof. A. Voelkel (Poland) Prof. Z. Yaremko (Ukraine) Prof. О. Zaporozhets (Ukraine) Corr. Member of NASU V. Zazhygalov (Ukraine)

Organising Committee: Assoc. Prof. V. Vasylechko (Co-chair), Assoc. Prof. V. Rohovyk (Co-chair) Dr. E. Aksenenko (Secretary), Prof. L. Pelyk, Dr. B. Charmas, Dr. hab. J. Skubiszewska-Zięba, Assoc. Prof. L. Dubenska, Assoc. Prof. L. Bojchyshyn, Assoc. Prof. О. Korkuna, Sc. Fellow. G. Gryshchouk Sponsor: SYSTEMA OPTYMUM – Supplies for Laboratories and Industry Andrij Volodymyrovych MAJEVSKI; http://www.systopt.com.ua 3

September 12 (Monday) Main University Building, 1 Universytets’ka Str. Foyer at the Assembly Hall: 09:00-17:00 Arrival and registration of participants Assembly Hall (Aula): 17:00-17:50 Concert Scientist’s Assembly (form. Kasyno Szlacheckie), 6 Lystopadovogo Chynu Str. 18:00

Welcome Party

September 13 (Tuesday) Main University Building, 1 Universytets’ka Str. Assembly Hall (Aula): 09:00-9:30

Opening of the Symposium

09:30-11:00 Plenary Session; Chair: Prof. M. Kartel 09:30-09:50 Mechanochemistry in catalytic technologies V.A. Zazhigalov, K. Wieczorek-Ciurowa ............................................................ 199 09:50-10:10 Investigation of adsorption equilibria and kinetics in various systems: porous material – organic solute A. Deryło-Marczewska, A.W. Marczewski, M. Błachnio, A. Chrzanowska, M. Sęczkowska ..................................................................................................... 26 10:10-10:30 The features of double electric layer in biological systems M.M. Soltys, Z.M. Yaremko, R.S. Petryshyn ....................................................... 153 10:30-11:00 Coffee Break; Poster Session 1 Theoretical and General 1.1

Langmuir films of polyaminoarene composites with poly(methylmetacrylate) and (styrene–maleic anhydride) copolymer O. Aksimentyeva, Yu. Horbenko, I. Opaynych, V. Dutka ............................................ 1

1.2

On reduction mechanism of lanthanide complex compounds with kalces on the mercury dropping electrode surface L.O. Dubenska, S.I. Tvorynska, S.V. Pysarevska ...................................................... 31

1.3

Silica-chitosan particles for controlled drug delivery applications: adsorption properties of doxorubicin hydrochloride K.O. Filatova, T.V. Krupska, V.V. Turov, V. Sedlarik ............................................... 35 4

1.4

Nonlinear dynamics at electrode/electrolyte interface O. Gichan .................................................................................................................. 43

1.5

Two-dimensional porous matrices with programmable architecture as enantioselective adsorbents – results from computer simulations A. Kasperski, P. Szabelski ......................................................................................... 67

1.6

Segregation of chiral molecules in adsorbed overlayers: results from lattice Monte Carlo simulations A. Woszczyk, P. Szabelski ....................................................................................... 192

1.7

Non-Arrhenius form of the adsorption equation on inhomogeneous substrate: the role of frozen fluctuations V.N. Bondarev, V.V. Kutarov, Е. Schieferstein ......................................................... 15

1.8

Thermodynamics of irreversible adsorption of water vapours by montmorillonite V.V. Kutarov, Yu.I. Tarasevich, E.V. Aksenenko, R.M. Dlubovskiy .......................... 88

1.9

Adsorption equilibrium in a limited space. Open cylindrical micropores V.V. Kutarov, Yu.L. Zub, V.N. Shevchenko, A.I. Iorgov, R.M. Dlubovskiy .............. 89

1.10 Multi-centered hydrogen bonds in the first solvation shell of perchlorate anion K. Nieszporek, P. Podkościelny, J. Nieszporek ....................................................... 108 1.11 Polyparametric equations for studying surface phenomenon by chromatographic method V.Y. Rohovyk ........................................................................................................... 133 1.12 Optical properties of cationic benzethonium chloride mixtures with surfactants of different nature A.V. Sachko, V.P. Zakordonskiy .............................................................................. 136 1.13 Structure and phase transitions of diblock copolymer monolayers E. Słyk, W. Rżysko, P. Bryk ..................................................................................... 149 1.14 Wetting behaviour of water on well defined surfaces. Computer simulation and experiment K. Terpiłowski, P. Bryk, M. Chodkowski ................................................................. 171 1.15 Intermolecular interaction in aqueous binary solutions of surfactants of different nature C.V. Tupys, M.M. Soltys, O.A. Burka ...................................................................... 176 1.16 Morphology of the droplet settled onto grooved surface M. Dokowicz, W. Nowicki ......................................................................................... 28 1.17 Optical characteristics of Fe3O4-Rh6G-SiO2 interaction within hybrid films in a weak magnetic field G. Telbiz, E. Leonenko, V. Grebennikov, N. Kobylinska, О. Shulzhenko, P. Manorik .............................................................................................................. 169 5

1.18 Temperature dependence of dendritic growth of surfactant monolayers at the air/water interface assessed by the quantum chemical approach O.S. Kartashynska, Yu.B. Vysotsky, D. Vollhardt ..................................................... 66 Nanobiomat and related 1.19 Synthesis and structural characteristics of Ni- and Co-doped carbon composites V. Bogatyrov, M. Galaburda, O. Oranska, W. Tomaszewski, J. Skubiszewska-Zięba, M. Borysenko, V. Gun’ko .................................................... 10 1.20 Solid phase extraction of explosives on resorcinol–formaldehyde resin/carbon nanocomposites and their carbonization products V. Bogatyrov, M. Galaburda, O.A. Vyshnevskyy, J. Skubiszewska-Zięba, W. Tomaszewski ........................................................................................................ 11 1.21 Thermal and calorimetric investigations of titania-silica composites B. Charmas, J. Skubiszewska-Zięba .......................................................................... 18 1.22 Surface characterization of amine-functionalized magnetic nanoparticles K. Gdula, I.V. Melnik, A. Dąbrowski, Y.L. Zub, E. Skwarek, P. Borowski ............... 39 1.23 Adsorption of silver ions onto bi-functionalized silica nanoparticles with magnetic core K. Gdula, E. Skwarek, A. Dąbrowski ........................................................................ 40 1.24 Electrochemical properties of bi-functionalized magnetic nanoparticles with silica shell K. Gdula, E. Skwarek, A. Dąbrowski ........................................................................ 41 1.25 Multi-layer graphene oxide alone and in a composite with nanosilica V.M. Gun’ko, V.V. Turov, V.I. Zarko, O.V. Goncharuk, A.K. Matkovsky, G.P. Prykhod’ko, Yu.M. Nychiporuk, E.M. Pakhlov, T.V. Krupska, D.Yu. Balakin, J. Skubiszewska-Zięba, B. Charmas, A.I. Marynin, V.V. Olishevskyi, M.T. Kartel ................................................................................................................ 53 1.26 Hydrothermal and mechanochemical synthesis of crystalline CaCO3 and CaF2 J. Skubiszewska-Zięba, B. Charmas ........................................................................ 146 1.27 The influence of selected anions and cations present at the hydroxyaptite/electrolyte solution interface on the electrical double layer structure E. Skwarek, W. Janusz ............................................................................................ 148 1.28 The study of tartaric acid adsorption at the hydroxyapatite/aqueous electrolyte interface W. Janusz, E. Skwarek, O. Mitrus ............................................................................. 58 1.29 Water state in differently hydrated kefir grains T.V. Krupska, V.M. Gun'ko, V.V. Turov, J. Skubiszewska-Zięba, B. Charmas ......... 85

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1.30 Surface functionalization of polymeric porous GMA-EGDMA microspheres by use of maleic anhydride P. Pączkowski, M. Grochowicz, B. Gawdzik ........................................................... 115 1.31 Synthesis and characterization of new hybrid microspheres with amide functionalization B. Podkościelna ...................................................................................................... 120 1.32 Study of synthesis and properties of the polymeric carriers for immobilization of biomolecules B. Podkościelna, G. Demirci, B. Gawdzik, A. Bartnicki, M. Maciejewska, J. Nowak ................................................................................................................. 121 1.33 Effect of cryogenic treatment on physicochemical properties of clays D. Sternik, A. Deryło-Marczewska, V.M. Gun’ko, V.I. Zarko ................................ 156 1.34 Effect of plasma treatment on surface properties of carbon nanotubes I.Ya. Sulym, Yu.I. Sementsov, M.T. Kartel, M.V. Borysenko, K. Terpiłowski, D. Sternik, A. Deryło-Marczewska .......................................................................... 162 1.35 Sorption of silver on Transcarpathian zeolite and antibacterial properties of the clinoptilolite–Ag composite V.O. Vasylechko, V.O. Fedorenko, O.M. Gromyko, G.V. Gryshchouk, Ya.M. Kalychak, M.T. Lototska ............................................................................... 180 1.36 Stable aqueous nanosilica suspensions: preparation and characterization E.F. Voronin, L.V. Nosach, V.M. Gun’ko, K. Terpiłowski, E. Skwarek, W. Janusz ................................................................................................................ 186 1.37 Effect of adsorption modification of the nanoscale silica with polydimethylsiloxane on its properties E.F. Voronin, D. Rymuszka, K. Terpiłowski, E.M. Pakhlov, L.V. Nosach, O.V. Goncharuk, V.M. Gun’ko, J. Skubiszewska-Zięba, B. Charmas ..................... 187 1.38 Application of silica-alumina oxides of different composition for removal of C.I. Reactive Black 5 dye from wastewaters M. Wawrzkiewicz, M. Wiśniewska, S. Chibowski, Z. Hubicki, V.M. Gun’ko, V.I. Zarko ................................................................................................................ 189 1.39 Comparison of electrokinetic properties of mixed alumina-silica-titania oxides in the presence of poly(vinyl alcohol) M. Wiśniewska, K. Terpiłowski, V.I. Zarko, V.M. Gun’ko ...................................... 191 1.40 Studies on the synthesis and physco-chemical properties of new polymeric ion exchangers with sulfur groups B. Podkościelna, M. Gil, A. Bartnicki ..................................................................... 122 1.41 Thermal decomposition and luminescence of naphthalene-2,7-diol diester derivatives with different methacrylic substituents B. Podkościelna, A. Lipke, A. Bartnicki, M. Majdan, B. Gawdzik .......................... 123 7

1.42 Modification of titania surface with organoselenium compound via PAMAM dendrimer L.R. Azizova, O. Dudik, B.B. Palyanytsya, J. Cunningham, L. Mikhalovska .............. 2 1.43 Effect of temperature in adsorption equilibrium and kinetics studies in the system: dye – chitosan-silica hybrid composites M. Błachnio, M. Zienkiewicz-Strzałka, T.M. Budnyak, A. DeryłoMarczewska, A.W. Marczewski, V.A. Tertykh ............................................................. 7 1.44 Studies of thermal behavior of adsorbed herbicide on activated carbon RIB M. Błachnio, M. Zienkiewicz-Strzałka, A. Deryło-Marczewska, A.W. Marczewski ......................................................................................................... 8 1.45 Biogel based on 2-hydroxyethyl methacrylate and functionalized silica Yu. Bolbukh, V. Tertykh, P. Pissis, P. Klonos ........................................................... 13 1.46 Chitosan-cellulose composites as potential drug delivery systems R.B. Kozakevych, V.V. Galysh, M.T. Kartel, Yu.M. Bolbukh, V.A. Tertykh, M. Zienkiewicz-Strzałka ............................................................................................ 78 1.47 Temperature-responsive properties of poly(4-vinylpyridine) coatings: Influence of temperature on wettability, morphology, and protein adsorption J. Raczkowska, Y. Stetsyshyn, K. Awsiuk, J. Zemla, A. Kostruba, K. Harhay, M. Marzec, A. Bernasik, O. Lishchynskyi, H. Ohar, A. Budkowski ........................ 128 1.48 Application of various types of silica as supports for nanostructures M. Zienkiewicz-Strzałka, M. Błachnio, R.B. Kozakevich, Y.M. Bolbukh, A. Deryło-Marczewska, V.A. Tertykh ...................................................................... 202 1.49 Thermal analysis of colloidal silver/pyrogenic silica nanocomposites M. Zienkiewicz-Strzałka, M. Błachnio, R.B. Kozakevich, Y.M. Bolbukh, A. Deryło-Marczewska, V.A. Tertykh ...................................................................... 204 11:00-12:20

Oral session 1: Adsorption and Ion Exchange

Chair: Prof. A. Deryło-Marczewska 11:00-11:20 Study on the adsorption of nitrate, nitrite and ammonium ions on carbon adsorbents A. Gierak, I. Łazarska .......................................................................................... 44 11:20-11:40 Polymeric sorption materials for rare earth ions extraction from aqueous solutions Z.Yu. Bunina, K.Yu. Bryleva, K.M. Belikov .......................................................... 17 11:40-12:00 Characterization of a solid surface via surface free energy calculated from contact angle hysteresis E. Chibowski ........................................................................................................ 19 8

12:00-12:20 Temperature and mixing effect on adsorption kinetics of selected organics on active carbons A.W. Marczewski, M. Sęczkowska, A. Deryło-Marczewska ............................... 100 12:20-13:00 Coffee Break; Poster Session 2 Adsorption and Ion Exchange 2.1 Effect of anionic polyacrylamide adsorption on the stability mechanism of aqueous suspension of zirconium(IV) oxide S. Chibowski, M. Wiśniewska, T. Urban, K. Terpiłowski .......................................... 20 2.2

Study of nanozirconia suspension stability in the presence of cationic polyacrylamide S. Chibowski, M. Wiśniewska, T. Urban, K. Terpiłowski, A. Nosal-Wiercińska ................................................................................................. 21

2.3

Controlling the pore size and structural properties of mesoporous silicas for protein adsorption A. Chrzanowska, A. Deryło-Marczewska, A.W. Marczewski, M. Sęczkowska .......... 24

2.4

Lysozyme adsorption on mesocellular silica foam: analysis of morphology and micro-nanostructure of the surface A. Chrzanowska, A. Deryło-Marczewska, A.W. Marczewski, M. Sęczkowska .......... 25

2.5

Polypyrrole-based nanoporous carbons prepared in the presence of organic potassium salts A. Dziura, A. Drzewińska J. Choma, M. Jaroniec .................................................... 33

2.6

Sorption of heavy metals by natural biopolymers N.V. Efimova, A.P. Krasnopyorova, G.D. Yuhno, А.A. Scheglovskaya .................... 34

2.7

Adsorption-desorption dynamics of alcohols on cationite Amberlyst-15 A.P. Filippov, P.E. Strizhak, N.V. Vlasenko, Yu.N. Kochkin, T.G. Serebrii .............. 37

2.8

Modified fly ash and zeolites as effective adsorbents for Cd(II), Pb(II) and Cr(III) removal from aqueous solution P. Gęca, D. Kołodyńska, A. Góźdź, M. Gęca, Z. Hubicki ......................................... 42

2.9

A comparison of the parameters of the chromatographic separation of the mixture of dyes obtained by caLC on the adsorbents type RP-8 and RP-18 A. Gierak, A. Skorupa ............................................................................................... 45

2.10 Application of modified clay for removal of phenol and PO43- ions from aqueous solutions A. Gładysz-Płaska ..................................................................................................... 47 2.11 Simultaneous adsorption of lanthanides and PO43- ions on natural red clay modified by HDTMA A. Gładysz-Płaska, M. Majdan ................................................................................. 48 9

2.12 Filler’s impact on structure-relaxation processes in polyester-resin oxide nanocomposites B.M. Gorelov, A.M. Gorb, O.I. Polovina, S. Wacke, Z. Czapla, M. Kostrzewa, A. Ingram .......................................................................................... 49 2.13 Assessment of swelling kinetics by microscopic studies J. Goworek, P. Krasucka, R. Zaleski, K. Skrzypiec ................................................... 50 2.14 Zeolite modified by chitosan as an adsorbent for environmental applications A. Góźdź, D. Kołodyńska, P. Gęca, M. Gęca, Z. Hubicki ......................................... 51 2.15 Graphene oxide: preparation, properties, applications N.A. Havryliuk .......................................................................................................... 54 2.16 Adsorption of methylene blue and malachite green on micro-mesoporous carbon materials K. Jedynak, M. Repelewicz ....................................................................................... 61 2.17 Removal of selected phthalates from aqueous solution by mesoporous ordered carbon adsorbents K. Jedynak, D. Wideł, J. Oszczudłowski ................................................................... 62 2.18 Dyes catalytic degradation using modified tin(IV) oxide and hydroxide powder S.V. Khalameida, M.M. Samsonenko, J. Skubiszewska-Zięba, O. Zakutevsky .......... 68 2.19 Bioactive carbon sorbents in ecology A.V. Khokhlov, A.A. Bychenko .................................................................................. 70 2.20 Sorption properties of hybrid organic-silica materials towards 137Cs, 90Sr, 90Y radionuclides A.P. Krasnopyorova, I.V. Khristenko, G.D. Yuhno, E.V. Ostapenko, A.C. Levishko ............................................................................................................ 80 2.21 Sorption extraction of 137Cs and 90Sr radionuclides from aqueous solutions by MnO(OH) nanoparticles A.P. Krasnopyorova, D.S. Sofronov, A.M. Odnovolova, N.V. Efimova, G.D. Yuhno, O.S. Kogol ..................................................................................................... 81 2.22 Study of sorption of heavy metal ions using synthetic carbonaceous adsorbents J. Krukowska, P. Gęca, D. Kołodyńska, Z. Hubicki .................................................. 83 2.23 The use of biochar as a sorbent in the removal of heavy metal ions from waters and wastewaters J. Krukowska, A. Góźdź, D. Kołodyńska ................................................................... 84 2.24 The influence of chemical modification on adsorption properties of natural zeolites A.D. Kustovska .......................................................................................................... 87 2.25 Sorption of polycyclic aromatic hydrocarbons on clays A. Lipke, A. Gładysz-Płaska, M. Majdan .................................................................. 92 10

2.26 Microporous lanthanide 2,6-naphthalenedicarboxylates – sorption investigations R. Łyszczek, A. Gładysz-Płaska, A. Ostasz ................................................................ 94 2.27 Lanthanide metal-organic frameworks – structural, thermal and sorption properties R. Łyszczek, L. Mazur, A. Ostasz, A. Bartyzel, H. Głuchowska ................................ 95 2.28 Using azo coupling reaction to determine the 3-bromoaniline as tryazene I.M. Maga ................................................................................................................. 96 2.29 Ion-exchange sorption of some metals on clinoptilolite. Theoretical calculations and experimental research S.S. Milyovich, V.I. Gomonaj, M.M. Fizer .............................................................. 102 2.30 Application of SBA-15 type mesoporous silica with thiourea ligand for removal of toxic Cd (II) ions from aqueous solutions G.I. Nazarchuk, I.V. Melnyk, M. Vaclavikova, Yu.L. Zub ........................................ 106 2.31 The application of modified layered materials for the purification of waste water M. Motak, I. Hnat, B. Samojeden ........................................................................... 103 2.32 The effect of homocysteine and homocystine protonation on double layer parameters at the electrode/chlorates (VII) interface A. Nosal-Wiercińska, M. Wiśniewska, M. Grochowski, W. Kaliszczak, S. Skrzypek, M. Brycht ................................................................................................ 111 2.33 Characteristics of amino acids adsorption on the surface-modified carbon sorbents A.M. Oleksiievets, I.A. Farbun, V.V. Strelko ........................................................... 112 2.34 Adsorption of NOx over supported Ag-, Cu- and Fe- oxide catalysts in presence of oxygen M. Pietraszek, K. Soja, D. W Worch, W. Suprun, B. Samojeden, R. Gläser ........... 119 2.35 Adsorption of phenolic compounds from aqueous solutions on original and oxidized multiwalled carbon nanotubes P. Podkościelny, A. Dąbrowski, K. Nieszporek ....................................................... 124 2.36 Gd3+ and Gd-DTPA adsorption on magnetite/chitosan nanocomposites Ie.V. Pylypchuk, D. Kolodynska, P.P. Gorbyk ........................................................ 127 2.37 Water vapor adsorption with nanostructured polyphase compositions based on the solid component of welding aerosol T.L. Rakyts’ka, A.S. Truba, A.A. Ennan, R.M. Dlubovskiy, V.Y. Volkova ............... 130

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2.38 Some features of Pd(II) and Cu(II) adsorption with bentonites and activity of bentonite based catalysts in the reaction of carbon monoxide oxidation T.L. Rakyts’ka, V.O. Vasylechko, T.O. Kiose, G.M. Dzhyga, G.V. Gryshchouk, V.Y. Volkova .............................................................................. 131 2.39 Synthesis, spectroscopic and thermal studies of new coordination polymers: 1,2-phenylenediacetates of light lanthanides(III) I. Rusinek, J. Sienkiewicz-Gromiuk, A. Bartyzel, Z. Rzączyńska ............................. 134 2.40 The influence of modification of activated carbons by N-containing compounds on sulphur dioxide sorption B. Samojeden, T. Grzybek, W. Suprun .................................................................... 138 2.41 Preparation and characterization of active carbons from natural wastes M. Sęczkowska, M. Galaburda, V.M. Bogatyrov, A. Deryło-Marczewska, A.W. Marczewski, A. Chrzanowska ......................................................................... 141 2.42 Parameters of adenine adsorption at the interface electrode/acetic buffer pH 6 D. Sieńko, D. Gugała-Fekner, J. Nieszporek, K. Nieszporek .................................. 144 2.43 The adsorption of adenosine at the interface electrode/acetic buffer pH 6 D. Sieńko, J. Nieszporek, D. Gugała-Fekner .......................................................... 145 2.44 Optimization of Acid Red adsorption removal on «corn stalks-polyaniline» composite using full experimental design L.M. Soldatkina, M.A. Zavrichko ............................................................................ 152 2.45 Sorption-coagulation treatment of liquid radioactive wastes by using new inorganic coagulants and sorbents V. Strelko, S. Meleshevych, Т. Psareva, І. Zhuravlev, O. Oleksiienko, V. Yakovlev, T. Shaposhnikova ............................................................................... 159 2.46 Effect of surfactant and temperature on the emission spectra of pyrene M. Szaniawska, A. Taraba, K. Szymczyk ................................................................. 163 2.47 UV-Vis study of pyrene in nonionic surfactant solutions M. Szaniawska, A. Taraba, K. Szymczyk ................................................................. 164 2.48 A study of adsorption properties of modified graphene B. Szczęśniak, J.Choma ........................................................................................... 165 2.49 Effect of temperature on the acoustical properties of aqueous solutions of nonionic surfactants A. Taraba, M. Szaniawska, K. Szymczyk ................................................................. 167 2.50 The temperature influence on the pyrene spectra in the surfactant micelle solutions A. Taraba, M. Szaniawska, K. Szymczyk ................................................................. 168

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2.51 Microwave-assisted phosphoric acid activation of dogwood stones for preparation of functionalized carbon adsorbents S.I. Trofymenko, N.V. Sych, O.I. Poddubnaya, M.M. Tsyba, V.M. Vikarchuk, M.F. Kovtun, A.M. Puziy ......................................................................................... 174 2.52 Adsorption properties of activated carbon obtained from cherry stones in relation to low-molecular poly(acrylic acid) M. Wiśniewska, P. Nowicki, A. Nosal-Wiercińska, R. Pietrzak .............................. 190 2.53 Adsorption of aniline and self organization of polyaniline layers on the surface of substrates of different nature M.M. Yatsyshyn, Yu.A. Stetsiv, V.M. Makogon, U.V. Tsiko, M.M. Soltys ............... 194 2.54 The influence of chaotropic effect on retention of fluoroquinolones in reversed phase liquid chromatographic systems M. Kamińska, M. Studziński, K. Pilorz, I.M. Choma ................................................ 63 2.55 Generalization of gas-chromatographic retention times for cyclization products of acrylates with aldehydes and 2,3-dimethylbuta-1,3-diene I.P. Polyuzhyn, O.I. Marshalok, N.M. Vytrykush, H.O. Marshalok ........................ 125 2.56 Synthesis of new advanced Fe-oxide and biologically inspired zeolite-based nano-adsorbents E. Chmielewská ......................................................................................................... 22 13:00-14:00 Oral session 1: Adsorption and Ion Exchange (Continued) Chair: Prof. E. Chibowski 13:00-13:20 Spectroscopic analysis of structural transformation of carbons during pyrolysis of BM-DVB copolymer with phosphoric acid A.M. Puziy, O.I. Poddubnaya, M. Sobiesiak, B. Gawdzik .................................. 126 13:20-13:40 Light scattering and TEM study of aggregation in hematite - anionic surfactant systems M. Kosmulski, E. Maczka, J. Hartmann ............................................................... 75 13:40-14:00 Transcarpathian zeolites in analytical chemistry V.O. Vasylechko, G.V. Gryshchouk, O. Vyviurska, Ch.B. Shabalkina, Ya.M. Kalychak .................................................................................................. 181 14:00-15:30

Lunch time

15:30-16:50 Oral session 2: Catalysis; Chair: Prof. V. Brei 15:30-15:50 Biomass waste: a sustainable platform for the production of chemicals V.O. Yevdokymenko, D.S. Kamenskyh, T.V. Tkachenko, V.I. Kashkovsky, M.M. Filonenko, V.V. Vakhrin ........................................................................... 195 15:50-16:10 Nanophase catalysts for CO and CH4 oxidative conversion G.R. Kosmambetova ............................................................................................. 74 13

16:10-16:30 Electrochemical studies of arenediazonium ions reactivity towards propyl gallate in micellar solutions J. Narkiewicz-Michalek, A. Sienkiewicz, M. Szymula, C. Bravo-Diaz ............... 105 16:30-16:50 Ethanol conversion into 1,3-butadiene over metal-oxide composition based on La2O3-SiO2 O.V. Larina, P.I. Kyriienko, S.O. Soloviev ........................................................... 90 16:50-17:30 Coffee Break; Poster Session 3 Catalysis 3.1 Bentonites and vermiculites modified with iron or silver as catalysts for VOC oxidation A. Basiura, M. Motak, B. Samojeden, P. da Costa ..................................................... 4 3.2

AgxCuy bimetallic nanoparticles as the catalysts of initiated oxidation of cumene L.I. Bazylyak, A.R. Kytsya, O.I. Pobigun, I.O. Opeida ............................................... 5

3.3

Surfactants influence on the kinetics of perhydrolysis reaction of acetylsalicylic acid M. Blazheyevskiy, L. Kryskiw ..................................................................................... 9

3.4

Surface structure and catalytic activity of amorphous and nanocrystalline metallic alloys Fe-Nb-B and Fe-Nb-B-Dy in alkaline solution L.M. Boichyshyn, O.M. Danyliak, B.Ya. Kotur ......................................................... 12

3.5

Influence of cerium (IV) oxide on catalytic properties of Cu-Ni/C compositions in methanol carbonylation process V.S. Borysevych, A.Yu. Kapran, S.M. Orlyk .............................................................. 16

3.6

New applications of 1-[(aryl)alkyl]-3-methylimidazolium chloroaluminates E. Dresler, R. Jasiński, W. Ochędzan-Siodłak, E. Nowakowska-Bogdan, D. Wieczorek ............................................................................................................. 29

3.7

Tris(acetonitrile)chloropalladium tetrafluoroborate synthesis, application and structural analysis I. Dybała, O.M. Demchuk ......................................................................................... 32

3.8

Synthesis of new ternary superacid ZrO2-SiO2-Al2O3 mixed oxide and its activity in tetrahydrofuran oligomerization O.I. Inshina, A.M. Korduban, G.M. Telbiz, V.V. Brei ............................................... 56

3.9

Effect of physical and chemical properties of zirconium-containing oxide catalysts on their catalytic activity in the process of condensation of methyl propionate with formaldehyde V.V. Ivasiv, Yu.V. Nebesna, W.Ya. Suprun, R.V. Nebesnyi ....................................... 57

3.10 Molecular mechanism of asymmetric Suzuki-Miyaura coupling reaction R. Jasiński, O.M. Demchuk ....................................................................................... 59 3.11 New example of extremal push-pull catalyst R. Jasiński, B. Mirosław, O.M. Demchuk, D. Babyuk, A. Łapczuk-Krygier ............. 60 14

3.12 Influence of composition of Ni-containing composites based on Sc- and Cestabilized zirconia on their catalytic performance in the processes of oxidative conversion of C1-C4 alkanes M.R. Kantserova, V.I. Chedryk, S.M. Orlyk .............................................................. 64 3.13 Tailoring porous structure and surface chemistry of carbon-based solid acid catalysts from apricot stones L.Y. Kotynska, O.I. Poddubnaya, M.M. Tsyba, L.A. Kupchyk, A.M. Puziy ............... 76 3.14 Preparation of ethylene in reactor with rotating reaction zone by aerosol nanocatalysis technology A.I. Lugovskoy, M.A. Glikin ...................................................................................... 93 3.15 The influence of Al2O3-supported cobalt nanoparticles size on their catalytic properties in the reaction of CO oxidation V. Marchuk, Ye. Kalishyn, P. Strizhak ...................................................................... 99 3.16 Hydrothermal treatment of catalysts carrier as a way to increase their efficiency in the processes of aldol condensation of carbonyl compounds R.V. Nebesnyi, Z.G. Pikh, V.V. Ivasiv, V.V. Sydorchuk, S.V. Khalameida, I.I. Shpyrka .............................................................................................................. 107 3.17 Voltammetric determination of caffeine in beverage samples using Nafion covered lead film electrode A. Nosal-Wiercińska, K. Tyszczuk-Rotko, I. Sadok, S. Yilmaz, S. Yagmur, G. Saglikogl, S. Yanik ............................................................................................. 110 3.18 Copper oxide containing catalysts for low temperature DeNOx-NH3-SCR M. Pietraszek, M. Kasprick, W. Suprun, B. Samojeden, T. Grzybek, R. Gläser ................................................................................................................................. 118 3.19 The influence of concentration of nitric acid used in clinoptilolite modification on the activity of clinoptilolite based palladium-copper catalysts in the reaction of carbon monoxide oxidation T.L. Rakyts’ka, T.O. Kiose, K.O. Golubchik, V.Y. Volkova ...................................... 129 3.20 Mesoporous zirconium silicate synthesized by sol-gel method as the heatresistant cation exchanger and catalyst support in the dehydrogenation reaction A.V. Redkina, M.V. Kravchenko, V.I. Yakovlev, N.D. Konovalova, V.V. Strelko ............................................................................................................. 132 3.21 Adsorption and activation of ethanol over sulfonated resin catalysts for ethyltert-butyl ether synthesis T.G. Serebrii, N.V. Vlasenko, Yu.N. Kochkin, P.E. Strizhak ................................... 140 3.22 Sonochemistry for environment protection: catalysts synthesis and pollutants degradation V.L. Starchevsky, V.O. Zazhigalov, V.V. Sydorchuk, S.V. Khalameida .................. 155 15

3.23 Influence of composition of MFe2O4 (M = Fe, Mn, Mg, Zn) spinels on their catalytic properties in the steam reforming process I.L. Stolyarchuk, L.Yu. Dolgykh, I.V. Vasylenko, Y.I. Pyatnitsky, P.E. Strizhak ........................................................................................................... 158 3.24 Bentonite modified with ions of transition metals in the reaction of ozone decomposition A.S. Truba, G.M. Dzhyga, T.L. Rakyts’ka, A.V. Nagaevs’ka, V.Y. Volkova ............ 175 3.25 Physicochemical properties of modified carbon fibres with S-containing compounds A.V. Vakaliuk, L.М. Grishchenko, T.M. Bezugla, V.Z. Radkevich .......................... 178 3.26 Selective dehydration of ethyl lactate into ethyl acrylate over NaY, NaX, and NaA zeolites A.M. Varvarin, A.M. Mylin, V.V. Brei ..................................................................... 179 3.27 Benzene in the products of toluene with methanol transformation on basic zeolite catalysts Yu.G. Voloshyna, O.P. Pertko, M.M. Krylova, L.K. Patrylak ................................. 183 3.28 Pt surface complexes as precursors for hydrogen oxidation catalysts O.B. Volovenko, O.A. Zaporozhets, V.V. Lisnyak, O.Yu. Boldyrieva ...................... 184 3.29 Influence of mechanochemical activation on the Zn-Ce-O composition properties V.A. Zazhigalov, O.V. Sachuk, L.S. Kuznetsova ...................................................... 197 3.30 Low temperature implantation as a promising method for nanocatalysts preparation on different supports V.A. Zazhigalov, V.V. Goncharov, I.V. Bacherikova, O.V. Sanzhak ....................... 196 3.31 Titanium containing ceramic supported photocatalysts for environment protection V.A. Zazhigalov, O.V. Sanzhak, D.V. Brazhnyk,V.V. Goncharov ........................... 198 3.32 Selective catalytic reduction of NO with NH3 on mixed alumina – iron (III) oxide pillared montmorillonite “Cheto” Arizona, modified with hexamminecobalt (III) P. Ziemiański, K. Kałahurska, B. Samojeden ......................................................... 201 Human and Environmental 3.33 Double layered hydroxides Mg - La(III) and Mg - Ce(III) as a new phosphate adsorbents for medicine and environmental protection Y.V. Babak, I.Z. Zhuravlev, V.V. Strelko ..................................................................... 3 3.34 Influence of surfactants on chemiluminescence in the system 9-cyano-10-methylacridinium nitrate (NCMA) – H2O2 N.Yu. Bondarenko, M.Ye. Blazheyevskiy ................................................................... 14 16

3.35 A modeling analysis for the assessment of Cu2+ adsorption onto activated carbons for detoxification of industrial effluents L.M. Gryschenko, V.E. Diyuk, R.T. Maryichuk, V.O. Kozhanov, V.V. Lisnyak ........ 52 3.36 Effect of the modified silica on the conductivity and water stability of sensor elements based on nanocomposites of conjugated polymers Yu. Horbenko, O. Aksimentyeva, V. Bohatyrev, B. Tsizh, I. Olenych, M. Pavlyk, M. Olhova .................................................................................................... 55 3.37 The use of surfactants for intensification of cleaning soil O.V. Karpenko, A.R. Bania, O.Z. Komarovska-Porokhniavets, O.Y. Karpenko, V.I. Lubenets, V.P. Novikov, M.M. Soltys ........................................ 65 3.38 Tactical anti-microbial gelous coatings for wound treatment M.M. Konoplya, U.A. Antonenko, M.V. Shabanov, M.A. Grebeniuk ........................ 72 3.39 New trends in the coagulation technology of water treatment and purification M.V. Shabanov, M.M. Konoplya, U.A. Antonenko, M.A. Grebeniuk ...................... 143 3.40 Ion-pair complex formation between fluoroquinolone antibiotics and methyl red and their use in the extraction-spectrophotometric analysis O.Ya. Korkuna, T.V. Zhak, M.Ya. Smolinska ............................................................ 73 3.41 Textile materials with silver incorporated polymeric coating for wound treatment G.I. Kovtun ................................................................................................................ 77 3.42 Bioactive compositions based on zeolite and polymeric derivatives of guanidine O.P. Kozar, Yu.V. Hrechanyk ................................................................................... 79 3.43 Drug release improvement via in situ TEOS transformation P. Krasucka, A. Kierys, J. Goworek .......................................................................... 82 3.44 Thermogravimetric analysis of nanocomposite materials based on poly(2-hydroxyethyl methacrylate) O.S. Kukolevska, I.I. Gerashchenko, M.V. Borysenko .............................................. 86 3.45 The role of bacteria and their secondary metabolites in the process of bioremediation D. Mańko, A. Zdziennicka, B. Jańczuk ...................................................................... 97 3.46 Supramolecular complexes of sulfamethazine A. Ostasz, R. Łyszczek, L. Mazur ............................................................................ 113 3.47 Supramolecular complexes of trimethoprim A. Ostasz, R. Łyszczek, L. Mazur ............................................................................ 114 3.48 Arselon-based filter material for industrial cleaning from dust and gas L.V. Pelyk, V.O. Vasylechko .................................................................................... 116 17

3.49 Reduction of chromium oxoanions by immobilized chromium-resistant sulphate-reducing bacteria T.B. Peretyatko, S.O. Hnatush, N.R. Kordupel, K.V. Sholyak ................................. 117 3.50 Phenols extraction to water phase in the ‘oil–water’ system I.I. Sakhnyuk, Yu.Z. Borutska .................................................................................. 137 3.51 Effect of substituent upon the antioxidant activity of phenolic acids in TX-100 micellar solutions M. Szymula, J. Narkiewicz-Michalek ...................................................................... 166 3.52 Application of screen-printed carbon electrode modified with bismuth in stripping analysis K. Tyszczuk-Rotko, K. Domańska, K. Vytřas, R. Metelka, A. Nosal-Wiercińska ............................................................................................... 177 3.53 2,6-Diamino-N-methylpyrimidine as new fluorescent probe for palladium(II) determination using hyphenated technique O.B. Volovenko, T.Ie. Keda, N.P. Skreminska, D.S. Milokhov, O.V. Khilya, O.A. Zaporozhets .................................................................................................... 184 3.54 Physico-mathematical model of sedimentation process of iron-containing particles in the magnetized porous nozzle M.V. Yatskov, O.I. Mysina ...................................................................................... 193 3.55 Universal disposable filter for water purification and disinfection in the field conditions I.Z. Zhuravlev, V.V. Strelko, V.A. Trychlib, V.E. Goba, Y.V. Isaieva ...................... 200 3.56 Analysis of alcoholic beverages with multidimensional gas chromatography O. Vyviurska, L. Bulavová, I. Špánik ...................................................................... 188 17:30-18:50 Oral session 2: Catalysis (Continued); Chair: Prof. V. Zazhigalov 17: 30-17:50 New insights into the preparation of iron molybdate catalysts for methanol oxidation V. Nikolenkо, Yu.V. Kalashnykov, I.S. Samchileyev, A.O. Kostyniuk, H. Bayahia, I.V. Kozhevnikov ............................................................................ 109 17:50-18:10 Selective conversion of glycerol - ethanol mixture into ethyl lactate over СеO2/Al2O3 catalyst A.M. Mylin, V.V. Brei ......................................................................................... 104 18:10-18:30 Activation of nanoparticle surface caused by the collision in the catalyst aerosol I.M. Glikina .......................................................................................................... 46 18:30-18:50 Flue gas toxicants sorption process under sorbent mechanoactivation M.G. Serdyukova, S.A. Kudryavtsev, I.M. Glikina ............................................. 139 18

2d NANOBIOMAT Conference Nanostructured Biocompatible/Bioactive Materials This session is simultaneous to Oral Session 2 Location to be announced 15:30-16:50 Plenary Session Nanobiomat Chair: Prof. J. Skubiszewska-Zięba 15:30-15:50 The study of the glutamic acid adsorption at the hydroxyapatite/aqueous electrolyte interface E. Skwarek .......................................................................................................... 147 15:50-16:10 The study of sorption and thermal properties of alginates D. Sternik, D. Filipiuk, M. Majdan, L. Fuks, A. Deryło-Marczewska ................ 157 16:10-16:30 Superhydrophobic layers deposited on plasma activated glass K. Terpiłowski, D. Rymuszka, O. Goncharuk, L. Davydenko ............................ 172 16:30-16:50 Blood contacting materials with NO-generating surface L. Mikhalovska, J. Cunningham, K. Kulyk, L. Azizova, S. Mikhalovsky ............ 101 16:50-17:30 Coffee Break; Poster Session 3 17:30-18:30 Plenary Session Nanobiomat (Continued); Chair: Prof. L. Mikhalovska 17:30-17:50 Application of chitosan-silica hybrid composites for the removal of dyes from aqueous solutions M. Błachnio, M. Zienkiewicz-Strzałka, T.M. Budnyak, A. Deryło-Marczewska, A.W. Marczewski, V.A. Tertykh ....................................... 6 17:50-18:10 Synthesis and structure elucidation of various carbon and silica materials containing magnetic iron oxides M. Studziński, Y.M. Bolbukh, R.B. Kozakevich, V.A. Tertykh ............................ 161 18:10-18:30 Synthesis and characterization of silver nanocomposites based on pyrogenic silica and diamine silver ions M. Zienkiewicz-Strzałka, M. Błachnio, R.B. Kozakevich, Y.M. Bolbukh, A. Deryło-Marczewska, V.A. Tertykh ................................................................. 203 19:30

Conference Dinner (Hetman restraunt in Vynnyky suburb of Lviv)

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September 14 (Wednesday) Off-site Sessions – Zhovkva (Żółkiew) 09:00

Departure from Main University Building

10:00-11:40 Oral Session 3; Chair: Prof. J. Narkiewicz-Michalek 10:00-10:20 Solid phase extraction of explosives on Ni-doped carbosils prepared by mechanochemistry W. Tomaszewski, B. Charmas, J. Skubiszewska-Zięba ....................................... 173 10:20-10:40 Activated carbons obtained from agriculture by-products and their role in environment protection D. Mańko, M. Barczak, A. Zdziennicka ................................................................ 97 10:40-11:00 Characterization and adsorptive properties of saponite clay G.M. Sokol-Deichuk, M. Sprynskyy, A.Y. Ganziuk, B. Buszewski ...................... 150 11:00-11:20 Individual and composite ionites based on highly dispersed TiO2 O.P. Kobulei, T.S. Psareva, V.V. Strelko ............................................................. 71 11:20-11:40 3D structured biosilica obtained under cultivation of unicellular diatom microalgaes M. Sprynskyy, M. Hornowska, P. Pomastowski, B. Buszewski .......................... 154 11:40-12:00

Coffee Break

12:00-14:00 Oral Session 4; Chair: Prof. M. Nikolenkо 12:00-12:20 Factors controlling catalytic activity of zeolites for liquid-phase synthesis of ethyl tert-butyl ether N.V. Vlasenko ..................................................................................................... 182 12:20-13:00 Adsorption and diffusion of methanol and ethanol on Cationite Amberlyst-15: the temperature dependence A.P. Filippov, P.E. Strizhak, N.V. Vlasenko, Yu.N. Kochkin, T.G. Serebrii ......... 36 13:00-13:20 The fractal approach to study kinetics of the heterogeneous reactions on the bulk porous and nanostructured catalysts O.Z. Didenko, A.I. Trypolskyi, G.R. Kosmambetova, P.E. Strizhak ..................... 27 13:20-13:40 Production of motor fuel components from black oil via aerosol nanocatalysis technology S.V. Leonenko, S.A. Kudryavtsev, I.M. Glikina .................................................... 91 13:40-14:00 A new low-temperature method for methanol synthesis from syngas at atmospheric pressure N.Yu. Khimach, S.L. Melnykova, I.V. Polunkin .................................................... 69 14:00-15:00 Lunch Sightseeing; Excursion, Return to Lviv 20

September 15 (Thursday) Main University Building, 1 Universytets’ka Str.

Mirror Hall

09:00-10:20 Oral Session 5; Chair: Prof. B. Gawdzik 09:00-09:20 Adsorption of anthocyanins from berry extracts using bentonite: factorial design analysis L.M. Soldatkina, V.O. Novotna .......................................................................... 151 09:20-09:40 Study of the effect of pH on the adsorption of selected organics on active carbon M. Sęczkowska, A.W. Marczewski, A. Deryło-Marczewska, A. Chrzanowska ................................................................................................. 141 09:40-10:00 Thin-layer chromatography hyphenated with bioassays as a tool for searching bioactive compounds in plants I.M. Choma, W. Jesionek ..................................................................................... 23 10:00-10:20 Nanospectroscopy and proton transport phenomena of nanocomposites based on doped titanium dioxide G. Telbiz, E. Leonenko, A. Stronsky, P. Manorik ............................................... 170 10:20-10:40

Coffee Break

10:40-12:00 Oral Session 6; Chair: Prof. S. Orlyk 10:40-11:00 Plasma polymerization process for polymer layer deposition on the glass surface D. Rymuszka, K. Terpiłowski, J. Wlosowska ...................................................... 135 11:00-11:20 The unidirectional droplet motion induced by a symmetric stimulation B. Gątarski, W. Nowicki ....................................................................................... 38 11:20-11:40 Reaction of tertiary phosphine-boranes with trimethylphosphine D. Strzelecka, O.M. Demchuk ............................................................................ 160 11:40-12:00 Determination of lidocaine and its metabolite in saliva L.O. Dubenska, S.I. Plotycya, M.E. Blazheyevskіy, O.M. Sarahman ................... 30 12:00-12:30 12:30

Coffee Break

Round Table

Closing of the Symposium

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Notes

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Програма ХV Українсько-польського симпозіуму ТЕОРЕТИЧНІ І ЕКСПЕРИМЕНТАЛЬНІ ДОСЛІДЖЕННЯ МІЖФАЗНИХ ЯВИЩ ТА ЇХ ТЕХНОЛОГІЧНІ ЗАСТОСУВАННЯ, СПІЛЬНО З 2-Ю КОНФЕРЕНЦІЄЮ NANOBIOMAT – НАНОСТРУКТУРОВАНІ БІОСУМІСНІ/БІОАКТИВНІ МАТЕРІАЛИ

Технічний редактор С. Сеник Комп’ютерне верстання Є. Аксененко Формат 60×84/16. Умовн. друк. арк. . Зам. Тираж 200 прим. Зам. Видавець та виготовлювач: Львівський національний університет імені Івана Франка, вул. Університетська, 1, м. Львів, 79000 Свідоцтво про внесення суб’єкта видавничої справи до Державного реєстру видавців, виготівників і розповсюджувачів видавничої продукції. Серія ДК № 3059 від 13.12.2007 р.

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