Safety data sheet according to Regulation (EC) No 1907 ... - Adama

Page 1 of 19 Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 11.02.2015 / 0002 Replaces revision of / Version: 12.07.2013 / 0001 Valid from: 11.02.2015 PDF print date: 13.02.2015 Legion

Safety data sheet according to Regulation (EC) No 1907/2006, Annex II SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier

Legion 125 g/l Quinmerac 375 g/l Metazachlor 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses of the substance or mixture: Herbicide

Uses advised against: Not applicable

1.3 Details of the supplier of the safety data sheet Adama Agricultural Solutions UK Ltd Limited, Unit 15, Thatcham Business Village Colthrop Way, Thatcham Berkshire RG19 4LW, UK Telephone: 01635 860555, Fax: 01635 861555 [email protected] Qualified person's e-mail address: [email protected], [email protected] Please DO NOT use for requesting Safety Data Sheets.

1.4 Emergency telephone Emergency information services / official advisory body: National Chemical Emergency Centre (UK): 01865 407333 (24 hours)

Telephone number of the company in case of emergencies: Tel.: --

SECTION 2: Hazards identification 2.1 Classification of the substance or mixture 2.1.1 Classification according to Regulation (EC) 1272/2008 (CLP) Hazard class Hazard category Hazard statement Carc. 2 H351-Suspected of causing cancer. Aquatic Acute 1 H400-Very toxic to aquatic life.


Aquatic Chronic

1

H410-Very toxic to aquatic life with long lasting effects.

2.1.2 Classification according to Directives 67/548/EEC and 1999/45/EC (including amendments) Carc. Cat. 3, Carcinogen, R40 N, Dangerous for the environment, R50/53

2.2 Label elements 2.2.1 Labeling according to Regulation (EC) 1272/2008 (CLP)

Warning H351-Suspected of causing cancer.

H410-Very toxic to aquatic life with long lasting effects.

P102-Keep out of reach of children. P201-Obtain special instructions before use. P280-Wear protective gloves/protective clothing and eye protection/face protection. P501-Dispose of contents/container to an approved waste disposal plant. EUH208-Contains 1,2-benzisothiazol-3(2H)-one, Metazachlor. May produce an allergic reaction. EUH401-To avoid risks to human health and the environment, comply with the instructions for use. SP 1 Do not contaminate water with the product or its container (Do not clean application equipment near surface water/Avoid contamination via drains from farmyards and roads).

2.3 Other hazards The mixture does not contain any vPvB substance (vPvB = very persistent, very bioaccumulative) or is not included under XIII of the regulation (EC) 1907/2006. The mixture does not contain any PBT substance (PBT = persistent, bioaccumulative, toxic) or is not included under XIII of the regulation (EC) 1907/2006. May produce an allergic reaction.

SECTION 3: Composition/information on ingredients Formulation: Suspension concentrate

3.1 Substance n.a.


3.2 Mixture Metazachlor Registration number (REACH) Index EINECS, ELINCS, NLP CAS content % Classification according to Directive 67/548/EEC

Classification according to Regulation (EC) 1272/2008 (CLP)

Quinmerac Registration number (REACH) Index EINECS, ELINCS, NLP CAS content % Classification according to Directive 67/548/EEC Classification according to Regulation (EC) 1272/2008 (CLP) 1,2-benzisothiazol-3(2H)-one Registration number (REACH) Index EINECS, ELINCS, NLP CAS content % Classification according to Directive 67/548/EEC

Classification according to Regulation (EC) 1272/2008 (CLP)

-616-205-00-9 266-583-0 CAS 67129-08-2 30-40 Carcinogen, R40, Carc.Cat.3 Sensitizising, R43 Dangerous for the environment, N, R50 Dangerous for the environment, R53 Skin Sens. 1, H317 Aquatic Acute 1, H400 (M=100) Aquatic Chronic 1, H410 (M=100) Carc. 2, H351

---402-790-6 CAS 90717-03-6 1-20 Dangerous for the environment, R52 Dangerous for the environment, R53 Aquatic Chronic 3, H412

-613-088-00-6 220-120-9 CAS 2634-33-5 0,005-= 480 The breakthrough times determined in accordance with EN 374 Part 3 were not obtained under practical conditions. The recommended maximum wearing time is 50% of breakthrough time. Protective hand cream recommended. Skin protection - Other: Protective working garments (e.g. safety shoes EN ISO 20345, long-sleeved protective working garments) Respiratory protection: Normally not necessary. Thermal hazards: Not applicable Additional information on hand protection - No tests have been performed. In the case of mixtures, the selection has been made according to the knowledge available and the information about the contents. Selection of materials derived from glove manufacturer's indications. Final selection of glove material must be made taking the breakthrough times, permeation rates and degradation into account. Selection of a suitable glove depends not only on the material but also on other quality characteristics and varies from manufacturer to manufacturer. In the case of mixtures, the resistance of glove materials cannot be predicted and must therefore be tested before use.

Page 8 of 19 Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 11.02.2015 / 0002 Replaces revision of / Version: 12.07.2013 / 0001 Valid from: 11.02.2015 PDF print date: 13.02.2015 Legion The exact breakthrough time of the glove material can be requested from the protective glove manufacturer and must be observed.

8.2.3 Environmental exposure controls No information available at present.

SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Physical state: Colour: Odour: Odour threshold: pH-value: Melting point/freezing point: Initial boiling point and boiling range: Flash point: Evaporation rate: Flammability (solid, gas): Lower explosive limit: Upper explosive limit: Vapour pressure: Vapour density (air = 1): Density: Bulk density: Solubility(ies): Water solubility: Partition coefficient (n-octanol/water): Partition coefficient (n-octanol/water): Auto-ignition temperature: Decomposition temperature: Viscosity: Viscosity: Explosive properties: Oxidising properties:

Liquid Beige Characteristic Not determined 3,8 (1 %, CIPAC MT 75.3) Not determined Not determined n.a. Not determined Not determined n.a. n.a. Not determined Not determined 1,139 g/ml (Regulation (EC) 440/2008 A.3. (RELATIVE DENSITY)) Not determined Not determined Suspension 2,5 (22°C, Metazachlor, pH 7 ) 2000 mg/kg Rat Acute toxicity, by dermal route: Acute toxicity, by inhalation:

LD50

>2000

mg/kg

Rat

LC50

>5

mg/l/4h

Rat

Skin corrosion/irritation:

Rabbit

Serious eye damage/irritation:

Rabbit

Respiratory or skin sensitisation: Germ cell mutagenicity: Carcinogenicity: Reproductive toxicity: Specific target organ toxicity single exposure (STOT-SE): Specific target organ toxicity repeated exposure (STOTRE): Aspiration hazard:

Guinea pig

Test method OECD 423 (Acute Oral Toxicity - Acute Toxic Class Method) OECD 402 (Acute Dermal Toxicity) OECD 403 (Acute Inhalation Toxicity) OECD 404 (Acute Dermal Irritation/Corrosion) OECD 405 (Acute Eye Irritation/Corrosion) OECD 406 (Skin Sensitisation)

Notes

Mist Not irritant Not irritant No (skin contact) n.d.a. n.d.a. n.d.a. n.d.a. n.d.a. n.d.a.

Page 10 of 19 Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 11.02.2015 / 0002 Replaces revision of / Version: 12.07.2013 / 0001 Valid from: 11.02.2015 PDF print date: 13.02.2015 Legion Respiratory tract irritation: Repeated dose toxicity: Symptoms: Other information:

Metazachlor Toxicity/effect Acute toxicity, by oral route: Acute toxicity, by dermal route: Acute toxicity, by inhalation: Skin corrosion/irritation: Serious eye damage/irritation: Respiratory or skin sensitisation: Germ cell mutagenicity: Reproductive toxicity: Other information: Quinmerac Toxicity/effect Acute toxicity, by oral route: Acute toxicity, by dermal route: Acute toxicity, by inhalation: Skin corrosion/irritation: Serious eye damage/irritation: Respiratory or skin sensitisation: Germ cell mutagenicity: Carcinogenicity: Reproductive toxicity:

n.d.a. n.d.a. n.d.a. Classification according to calculation procedure.

Endpoi nt LD50 LD50

Value

Unit

Organism

3480 >2000

mg/kg mg/kg

Mouse Rat

LC50

>34,5

mg/l/4h

Test method

Notes

Dust Not irritant Not irritant Yes (skin contact) No

NOAEL

15-20

Rat

0,036

mg/kg bw/d mg/kg

ADI

Endpoi nt LD50 LD50

Value

Unit

Organism

>5000 >2000

mg/kg mg/kg

Rat Rabbit

LC50

>5.4

mg/l/4h

Rat Rabbit Rabbit

1,2-benzisothiazol-3(2H)-one Toxicity/effect Endpoi nt Acute toxicity, by oral route: LD50 Acute toxicity, by oral route: ATE Acute toxicity, by dermal LD50 route:

Test method

Notes

Not irritant Not irritant Not sensitizising No No No

Value

Unit

Organism

375 500 4115

mg/kg mg/kg mg/kg

Rat Rat

Test method

Notes

Page 11 of 19 Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 11.02.2015 / 0002 Replaces revision of / Version: 12.07.2013 / 0001 Valid from: 11.02.2015 PDF print date: 13.02.2015 Legion Acute toxicity, by inhalation:

LC50

0,25

mg/l/4h

Skin corrosion/irritation: Serious eye damage/irritation: Respiratory or skin sensitisation: Germ cell mutagenicity: Symptoms:

Propane-1,2-diol Toxicity/effect Acute toxicity, by oral route: Acute toxicity, by dermal route: Acute toxicity, by inhalation: Skin corrosion/irritation: Serious eye damage/irritation: Respiratory or skin sensitisation: Respiratory or skin sensitisation: Germ cell mutagenicity: Germ cell mutagenicity:

Rat

Dust, Does not conform with EU classification. Irritant Intensively irritant

Guinea pig

Sensitizing (skin contact) Negative vomiting, headaches, gastrointestinal disturbances, nausea

Endpoi nt LD50 LD50

Value

Unit

Organism

>2000 >2000

mg/kg mg/kg

Rat Rabbit

LC50

317,042

mg/l/2h

Rabbit Rabbit Rabbit

Test method

Notes

(Draize-Test) OECD 405 (Acute Eye Irritation/Corrosion)

Not irritant Not irritant

Guinea pig

Not sensitizising

Human being

Not sensitizising OECD 471 (Bacterial Reverse Mutation Test) OECD 476 (In Vitro Mammalian Cell Gene Mutation Test)

Symptoms:

Negative Negative eyes, reddened, mucous membrane irritation, dizziness, watering eyes, nausea

SECTION 12: Ecological information Possibly more information on environmental effects, see Section 2.1 (classification). Legion Toxicity/effect Endpoint Time Value Unit Organism Toxicity to fish: EC50 96h 12,7 mg/l Oncorhynchus mykiss Toxicity to daphnia: EC50 48h 83 mg/l Daphnia magna

Test method

Notes

Page 12 of 19 Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 11.02.2015 / 0002 Replaces revision of / Version: 12.07.2013 / 0001 Valid from: 11.02.2015 PDF print date: 13.02.2015 Legion Toxicity to algae:

ErC50

72h

0,076 7

mg/l

Pseudokirchnerie lla subcapitata

Toxicity to algae:

EbC50

72h

0,028 5

mg/l

Pseudokirchnerie lla subcapitata

Persistence and degradability: Bioaccumulative potential: Mobility in soil: Results of PBT and vPvB assessment Other adverse effects: Other organisms:

ErC50

72h

56,1

Lemna gibba

Other organisms:

EbC50

72h

12

Lemna gibba

Metazachlor Toxicity/effect Toxicity to fish: Toxicity to fish:

Endpoint LC50 LC50

Time 96h 96h

Value 12,3 4

Unit mg/l mg/l

Toxicity to fish:

LC50

96h

8,9

mg/l

Toxicity to fish: Toxicity to fish:

LC50 NOEC/NO EL NOEC/NO EL NOEC/NO EL EC50 EC50 NOEC/NO EL EC10 EC50 DT50

28d 96h

>8 4,8

mg/l mg/l

96h

8,3

mg/l

28d

2,5

mg/l

48h 21d 21d

33 17 0,1

mg/l mg/l mg/l

48h 96h

27 1,63 4

mg/l mg/l d

DT90

23

d

DT50 DT90

4 23

Toxicity to fish: Toxicity to fish: Toxicity to daphnia: Toxicity to daphnia: Toxicity to daphnia: Toxicity to daphnia: Toxicity to algae: Persistence and degradability: Persistence and degradability: Mobility in soil: Mobility in soil:

OECD 201 (Alga, Growth Inhibition Test) OECD 201 (Alga, Growth Inhibition Test) n.d.a. n.d.a. n.d.a. n.d.a. n.d.a.

Organism Cyprinus caprio Oncorhynchus mykiss Oncorhynchus mykiss Oncorhynchus mykiss Cyprinus caprio

OECD 221 (Lemna sp. Growth Inhibition Test) OECD 221 (Lemna sp. Growth Inhibition Test)

Test method

Notes

Page 13 of 19 Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 11.02.2015 / 0002 Replaces revision of / Version: 12.07.2013 / 0001 Valid from: 11.02.2015 PDF print date: 13.02.2015 Legion Toxicity to birds: Toxicity to insects:

LD50

>2000

mg/kg

Japanese quail Negative

Apis mellifera

Quinmerac Toxicity/effect Toxicity to fish:

Endpoint LC50

Time 96h

Value 86,8

Unit mg/l

Toxicity to daphnia: Toxicity to algae: Other information:

LC50 EC50 DT50

48h 72h

mg/l mg/l d

Toxicity to birds:

LD50

>100 >100 10,4 17,4 >2000

mg/l

Colinus virginianus

Unit mg/l

Organism Salmo gairdneri

Test method

mg/l

Oncorhynchus mykiss

OECD 203 (Fish, Acute Toxicity Test)

Lepomis macrochirus Daphnia magna

Organism Oncorhynchus mykiss Daphnia magna

Test method

Notes

Soil

1,2-benzisothiazol-3(2H)-one Toxicity/effect Endpoint Toxicity to fish: LC50

Time 96h

Toxicity to fish:

LC50

96h

Value 1,31,6 2,18

Toxicity to fish:

LC50

96h

3,4

mg/l

Toxicity to daphnia:

EC50

48h

1,53,3

mg/l

Toxicity to algae: Toxicity to algae:

EC50 EC50

72h 96h

0,15 0,055

mg/l mg/l

Toxicity to algae:

ErC50

72h

0,11

mg/l

Bioaccumulative potential:

Log Pow

Toxicity to bacteria:

EC50

16h

0,4

mg/l

Pseudomonas putida

Propane-1,2-diol Toxicity/effect Toxicity to fish:

Endpoint LC50

Time 96h

Value >1000

Unit mg/l

Organism Pimephales promelas

Chlorella vulgaris Pseudokirchnerie lla subcapitata Pseudokirchnerie lla subcapitata

Notes

OECD 202 (Daphnia sp. Acute Immobilisation Test)

OECD 201 (Alga, Growth Inhibition Test)

1,11

A notable biological accumulation potential is not to be expected (LogPow 1-3).

Test method OECD 203 (Fish, Acute Toxicity Test)

Notes

Page 14 of 19 Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 11.02.2015 / 0002 Replaces revision of / Version: 12.07.2013 / 0001 Valid from: 11.02.2015 PDF print date: 13.02.2015 Legion Toxicity to daphnia:

EC50

48h

>1000

mg/l

Daphnia magna

Toxicity to algae:

EC50

72h

>1000

mg/l

Selenastrum capricornutum

Persistence and degradability:

28d

81

%

Persistence and degradability:

28d

87-92

%

Bioaccumulative potential: Results of PBT and vPvB assessment Toxicity to bacteria: Toxicity to bacteria:

BCF

Other information: Water solubility:

COD

OECD 202 (Daphnia sp. Acute Immobilisation Test) OECD 201 (Alga, Growth Inhibition Test) OECD 301 F (Ready Biodegradability - Manometric Respirometry Test) OECD 301 C (Ready Biodegradability - Modified MITI Test (I))

1000 >1000

mg/l mg/l

1,585

mg/g

activated sludge activated sludge

OECD 209 (Activated Sludge, Respiration Inhibition Test (Carbon and Ammonium Oxidation)) Mixable

SECTION 13: Disposal considerations 13.1 Waste treatment methods For the substance / mixture / residual amounts EC disposal code no.: The waste codes are recommendations based on the scheduled use of this product. Owing to the user's specific conditions for use and disposal, other waste codes may be allocated under certain circumstances. (2001/118/EC, 2001/119/EC, 2001/573/EC) 02 01 08 agrochemical waste containing dangerous substances 07 04 01 aqueous washing liquids and mother liquors 20 01 19 pesticides Recommendation:

Page 15 of 19 Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 11.02.2015 / 0002 Replaces revision of / Version: 12.07.2013 / 0001 Valid from: 11.02.2015 PDF print date: 13.02.2015 Legion Pay attention to local and national official regulations E.g. suitable incineration plant. E.g. dispose at suitable refuse site.

For contaminated packing material Pay attention to local and national official regulations Empty container completely. Uncontaminated packaging can be recycled. Dispose of packaging that cannot be cleaned in the same manner as the substance. Recommended cleaner: Water

SECTION 14: Transport information General statements UN number:

3082

Transport by road/by rail (ADR/RID) UN proper shipping name: UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (METAZACHLOR) Transport hazard class(es): 9 Packing group: III Classification code: M6 LQ (ADR 2013): 5L LQ (ADR 2009): 7 Environmental hazards: environmentally hazardous Tunnel restriction code: E

Transport by sea (IMDG-code) UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (METAZACHLOR) Transport hazard class(es): 9 Packing group: III EmS: F-A, S-F Marine Pollutant: Yes Environmental hazards: environmentally hazardous

Transport by air (IATA) UN proper shipping name: Environmentally hazardous substance, liquid, n.o.s. (METAZACHLOR) Transport hazard class(es): 9 Packing group: III Environmental hazards: environmentally hazardous

Special precautions for user Persons employed in transporting dangerous goods must be trained. All persons involved in transporting must observe safety regulations. Precautions must be taken to prevent damage.

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Freighted as packaged goods rather than in bulk, therefore not applicable. Minimum amount regulations have not been taken into account.

Page 16 of 19 Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 11.02.2015 / 0002 Replaces revision of / Version: 12.07.2013 / 0001 Valid from: 11.02.2015 PDF print date: 13.02.2015 Legion Danger code and packing code on request. Comply with special provisions.

SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture National rules/regulation for the compliance with maximum quantities with regard to phosphates and or phosphorous compounds must be observed and complied with. For classification and labelling see Section 2. Observe restrictions: Comply with trade association/occupational health regulations. Observe youth employment law (German regulation). Observe law on protection of expectant mothers (German regulation). Observe plant protection medium law.

15.2 Chemical safety assessment A chemical safety assessment is not provided for mixtures.

SECTION 16: Other information These details refer to the product as it is delivered. Revised sections:

2, 3, 8, 11, 12

Classification and processes used to derive the classification of the mixture in accordance with the ordinance (EG) 1272/2008 (CLP): Classification in accordance with regulation (EC) No. 1272/2008 (CLP) Carc. 2, H351 Aquatic Acute 1, H400 Aquatic Chronic 1, H410

Evaluation method used Classification according to calculation procedure. Classification based on toxicological analyses. Classification based on toxicological analyses.

The following phrases represent the posted R phrases / H phrases, Hazard Class and Risk Category Code (GHS/CLP) of the product and the constituents (specified in Section 2 and 3). 22 Harmful if swallowed. 38 Irritating to skin. 40 Limited evidence of a carcinogenic effect. 41 Risk of serious damage to eyes. 43 May cause sensitization by skin contact. 50 Very toxic to aquatic organisms. 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 52 Harmful to aquatic organisms. 53 May cause long-term adverse effects in the aquatic environment. H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction.

Page 17 of 19 Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 11.02.2015 / 0002 Replaces revision of / Version: 12.07.2013 / 0001 Valid from: 11.02.2015 PDF print date: 13.02.2015 Legion H318 Causes serious eye damage. H351 Suspected of causing cancer. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. Carc. — Carcinogenicity Aquatic Acute — Hazardous to the aquatic environment - acute Aquatic Chronic — Hazardous to the aquatic environment - chronic Skin Sens. — Skin sensitization Acute Tox. — Acute toxicity - oral Skin Irrit. — Skin irritation Eye Dam. — Serious eye damage

Any abbreviations and acronyms used in this document: AC Article Categories acc., acc. to according, according to ACGIH American Conference of Governmental Industrial Hygienists ADR Accord européen relatif au transport international des marchandises Dangereuses par Route (= European Agreement concerning the International Carriage of Dangerous Goods by Road) AOEL Acceptable Operator Exposure Level AOX Adsorbable organic halogen compounds approx. approximately Art., Art. no. Article number ATE Acute Toxicity Estimate according to Regulation (EC) 1272/2008 (CLP) BAM Bundesanstalt für Materialforschung und -prüfung (Federal Institute for Materials Research and Testing, Germany) BAuA Bundesanstalt für Arbeitsschutz und Arbeitsmedizin (= Federal Institute for Occupational Health and Safety, Germany) BCF Bioconcentration factor BGV Berufsgenossenschaftliche Vorschrift (= Accident Prevention Regulation) BHT Butylhydroxytoluol (= 2,6-Di-t-butyl-4-methyl-phenol) BMGV Biological monitoring guidance value (EH40, UK) BOD Biochemical oxygen demand BSEF Bromine Science and Environmental Forum bw body weight CAS Chemical Abstracts Service CEC Coordinating European Council for the Development of Performance Tests for Fuels, Lubricants and Other Fluids CESIO Comité Européen des Agents de Surface et de leurs Intermédiaires Organiques CIPAC Collaborative International Pesticides Analytical Council CLP Classification, Labelling and Packaging (REGULATION (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures) CMR carcinogenic, mutagenic, reproductive toxic COD Chemical oxygen demand CTFA Cosmetic, Toiletry, and Fragrance Association DMEL Derived Minimum Effect Level DNEL Derived No Effect Level DOC Dissolved organic carbon

Page 18 of 19 Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 11.02.2015 / 0002 Replaces revision of / Version: 12.07.2013 / 0001 Valid from: 11.02.2015 PDF print date: 13.02.2015 Legion DT50 Dwell Time - 50% reduction of start concentration DVS Deutscher Verband für Schweißen und verwandte Verfahren e.V. (= German Association for Welding and Allied Processes) dw dry weight e.g. for example (abbreviation of Latin 'exempli gratia'), for instance EC European Community ECHA European Chemicals Agency EEA European Economic Area EEC European Economic Community EINECS European Inventory of Existing Commercial Chemical Substances ELINCS European List of Notified Chemical Substances EN European Norms EPA United States Environmental Protection Agency (United States of America) ERC Environmental Release Categories ES Exposure scenario etc. et cetera EU European Union EWC European Waste Catalogue Fax. Fax number gen. general GHS Globally Harmonized System of Classification and Labelling of Chemicals GWP Global warming potential HET-CAM Hen's Egg Test - Chorionallantoic Membrane HGWP Halocarbon Global Warming Potential IARC International Agency for Research on Cancer IATA International Air Transport Association IBC Intermediate Bulk Container IBC (Code) International Bulk Chemical (Code) IC Inhibitory concentration IMDG-code International Maritime Code for Dangerous Goods incl. including, inclusive IUCLID International Uniform ChemicaL Information Database LC lethal concentration LC50 lethal concentration 50 percent kill LCLo lowest published lethal concentration LD Lethal Dose of a chemical LD50 Lethal Dose, 50% kill LDLo Lethal Dose Low LOAELLowest Observed Adverse Effect Level LOEC Lowest Observed Effect Concentration LOEL Lowest Observed Effect Level LQ Limited Quantities MARPOL International Convention for the Prevention of Marine Pollution from Ships n.a. not applicable n.av. not available n.c. not checked n.d.a. no data available NIOSH National Institute of Occupational Safety and Health (United States of America) NOAEC No Observed Adverse Effective Concentration NOAEL No Observed Adverse Effect Level

Page 19 of 19 Safety data sheet according to Regulation (EC) No 1907/2006, Annex II Revised on / Version: 11.02.2015 / 0002 Replaces revision of / Version: 12.07.2013 / 0001 Valid from: 11.02.2015 PDF print date: 13.02.2015 Legion NOEC No Observed Effect Concentration NOEL No Observed Effect Level ODP Ozone Depletion Potential OECD Organisation for Economic Co-operation and Development org. organic PAH polycyclic aromatic hydrocarbon PBT persistent, bioaccumulative and toxic PC Chemical product category PE Polyethylene PNEC Predicted No Effect Concentration POCP Photochemical ozone creation potential ppm parts per million PROC Process category PTFE Polytetrafluorethylene REACH Registration, Evaluation, Authorisation and Restriction of Chemicals (REGULATION (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals) REACH-IT List-No. 9xx-xxx-x No. is automatically assigned, e.g. to pre-registrations without a CAS No. or other numerical identifier. List Numbers do not have any legal significance, rather they are purely technical identifiers for processing a submission via REACH-IT. RID Règlement concernant le transport International ferroviaire de marchandises Dangereuses (= Regulation concerning the International Carriage of Dangerous Goods by Rail) SADT Self-Accelerating Decomposition Temperature SAR Structure Activity Relationship SU Sector of use SVHC Substances of Very High Concern Tel. Telephone ThOD Theoretical oxygen demand TOC Total organic carbon TRGS Technische Regeln für Gefahrstoffe (=Technical Regulations for Hazardous Substances) UN RTDG United Nations Recommendations on the Transport of Dangerous Goods VbF Verordnung über brennbare Flüssigkeiten (= Regulation for flammable liquids (Austria)) VOC Volatile organic compounds vPvB very persistent and very bioaccumulative WEL-TWA, WEL-STEL WEL-TWA = Workplace Exposure Limit - Long-term exposure limit (8-hour TWA (= time weighted average) reference period), WEL-STEL = Workplace Exposure Limit - Short-term exposure limit (15-minute reference period) (EH40, UK). WHO World Health Organization wwt wet weight The statements made here should describe the product with regard to the necessary safety precautions - they are not meant to guarantee definite characteristics - but they are based on our present up-to-date knowledge. No responsibility. These statements were made by:

Chemical Check GmbH, Chemical Check Platz 1-7, D-32839 Steinheim, Tel.: +49 5233 94 17 0, Fax: +49 5233 94 17 90 © by Chemical Check GmbH Gefahrstoffberatung. The copying or changing of this document is forbidden except with consent of the Chemical Check GmbH Gefahrstoffberatung.