Isoprene. 34 10208-80-7 Alpha-muurolene. Monoterpenes. 35 39029-41-9 Gamma-cadinene. 2 508-32-7 Tricyclene. 36 24406-05-1 Alpha-cadinene. 3 80-56-8.
SUPPLEMENTARY DATA Aydin, Y.M., Yaman, B., Koca, H., Dasdemir, O., Kara, M., Altiok, H., Dumanoglu, Y., Bayram, A., Tolunay, D., Odabasi, M., Elbir, T., 2014. Biogenic volatile organic compound (BVOC) emissions from forested areas in Turkey: Determination of specific emission rates for thirty-one tree species. Science of the Total Environment 490, 239–253. Table SM1. Analyzed BVOCs #
Compound Isoprene 78-79-5 Isoprene Monoterpenes 508-32-7 Tricyclene 80-56-8 Alpha-Pinene 471-84-1 Alpha-Fenchene 79-92-5 Camphene 3387-41-5 Sabinene 127-91-3 Beta-Pinene 123-35-3 Beta-Myrcene 99-83-2 l-Phellandrene 13466-78-9 Delta 3-Carene 99-86-5 Alpha-Terpinene 535-77-3 m-Cymene 138-86-3 Limonene 555-10-2 Beta-Phellandrene 08-10-6874 cis-Ocimene 3779-61-1 trans-beta-Ocimene 99-85-4 Gamma-Terpinene 586-62-9 Terpinolene 673-84-7 Alloocimene 2,6-Dimethyl-1,3,5,7460-01-5 octatetraene, E
# 33 34 35 36 37
CAS No 17066-67-0 10208-80-7 39029-41-9 24406-05-1 17627-44-0
38 39 40 41 42 43 44 45 46 47 48 49 50 51 52
78-93-3 534-22-5 115-18-4 4170-30-3 5780-40-5 470-67-7 104-93-8 470-82-6 111-87-5 53219-21-9 586-81-2 7787-20-4 15186-51-3 78-69-3 78-70-6
Compound Beta-selinene Alpha-muurolene Gamma-cadinene Alpha-cadinene Cis-Alpha-Bisabolene Oxygenated Compounds 2-Butanone Furan, 2-methyl2-Methyl-3-buten-2-ol Crotonaldehyde Butyl aldoxime, 3-methyl-, synIsocineole p-Methylanisole Eucalyptol 1-Octanol Dihydromyrcenol Gamma-Terpineol L-Fenchone Rosefuran Tetrahydrolinalool Linalool L
53
1632-73-1
D-Fenchyl alcohol
21
99-87-6
54
460-01-5
2-Methyl-6-methylene-1,7octadien-3-one
22
51911-82-1
55
1728-46-7
2-tert-Butylcyclohexanone
56 57 58 59 60 61 62
3901-93-7 76-22-2 124-76-5 34413-88-2 13491-79-7 562-74-3 98-55-5
63 64 65
93-15-2 77171-55-2 489-86-1
trans-Dihydro-beta-terpineol Camphor Isoborneol d-Pinocarvone 2-(1,1-dimethylethyl)-cyclohexanol 4-Terpineol Alpha-Terpineol Oxygenated Sesquiterpenes Methyl Eugenol (-)-Spathulenol Guaiol
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
23 24 25 26 27 28 29 30 31 32
CAS No
3856-25-5 13744-15-5 1135-66-6 469-61-4 87-44-5 6753-98-6 18794-84-8 23986-74-5 17699-05-7 502-61-4
p-isopropyl toluene (p-Cymene) (E)-4,8-Dimethyl-1,3,7nonatriene Sesquiterpenes Copaene Beta-cubebene Isolongifolene Alpha-cedrene trans-Caryophyllene Alpha-humulene Beta-farnesene Germacrene-D Alpha-Bergamotene E,E-Alpha-Farnesene
1
Figure SM1. Forest lands in Turkey.
2
Figure SM2. Several overall views from the dynamic enclosure samplings
3
(a)
(b)
(c)
(d)
Figure SM3. Views from (a) ambient air purification system, (b) pumps, (c) enclosure chamber, (d) computer systems
4
Sessile Oak
Other SQs 34%
Turkey Oak
Betafarnesene 37%
transCaryophyll ene 16%
Isolongifol ene 13%
Isolongifol ene 26%
Other SQs 35%
transCaryophyll ene 25%
Alphacadinene 14%
Eastern Cottonwood
European Aspen Other SQs 15%
Other SQs 18%
Alphahumulene 7%
Alphahumulene 9%
transCaryophyll ene 73%
transCaryophyll ene 78%
Western Australian Golden Wattle
Black Locust
transCaryophyll ene Other SQs 24% 39%
Other SQs 40%
Isolongifol ene 22%
Alphamuurolene 22%
Isolongifol ene 15%
Betacubebene 12%
Orieantal Horbeam
Other SQs 32%
European Hornbeam
Isolongifol ene 34%
Isolongifol ene 19% Germacre ne-D 9%
Copaene 15%
Copaene 11%
South European Flowering Ash
European Ash
Other SQs 29%
transCaryophyll ene 23%
Other SQs 38%
transCaryophyll ene 19%
Cis-AlphaBisabolen e 15%
transCaryophyll ene 26%
transCaryophyll ene 32%
Other SQs 20% Alphahumulene 10%
Isolongifol ene 24%
transCaryophyll ene 70%
Figure SM4. Sesquiterpene compositions of broad-leaved species (Other SQs: Other Sesquiterpenes). 5
Orieantal Plane
The River Red Gum Other SQs 8%
Other SQs 17%
Alphahumulene 8% transCaryophyll ene 69%
Cis-AlphaBisabolen e 14%
transCaryophyll ene 84%
Silver Lime
Sweet Chestnut Other SQs 13%
transCaryophyll ene 35%
Other SQs 28%
Isolongifol ene 10%
transCaryophyll ene 77%
Isolongifol ene 28%
Copaene 9%
Oriental Beech
Other SQs 36%
Alphamuurolene 10%
European Alder transCaryophyll ene 19%
transCaryophyll ene 38%
Other SQs 39%
Isolongifol ene 16%
Isolongifol ene 12%
Figure SM4. Continued.
6
Copaene 18%
Alphahumulene 12%
Sessile Oak
Turkey Oak
Other Oxy. C. 12%
Other Oxy. C. 14%
1-Octanol 10%
Eucalyptol 7% Furan, 2methyl19%
Crotonald ehyde 59%
Crotonald ehyde 69%
Furan, 2methyl10%
Eastern Cottonwood
European Aspen Other Oxy. C. 18%
Crotonald ehyde 26%
Other Oxy. C. 36%
Isoborneol 10% Crotonald ehyde 20%
Isoborneol 15% Furan, 2methyl11%
Other Oxy. C. 16%
Crotonald ehyde 14%
Black Locust Other Oxy. C. 31%
AlphaTerpineol 34%
Eucalyptol 15%
Camphor 13%
European Hornbeam Butyl aldoxime, 3-methyl-, syn15%
Other Oxy. C. 17%
Crotonald ehyde 52%
1-Octanol 9% Crotonald ehyde 77%
Dihydromy rcenol 11%
Furan, 2methyl13%
South European Flowering Ash Other
European Ash Other Oxy. C. 10%
Oxy. C. 10%
1-Octanol 7% Furan, 2methyl11%
Crotonald ehyde 28%
Linalool L 13%
1-Octanol 28%
Oriental Hornbeam Furan, 2methyl6%
AlphaTerpineol 26%
1-Octanol 12%
Western Australian Golden Wattle GammaTerpineol 8%
Eucalyptol 26%
1-Octanol 10% Crotonald ehyde 72%
Furan, 2methyl22%
Crotonald ehyde 58%
Figure SM5. Oxygenated compound compositions of broad-leaved species (Other Oxy.C.: Other Oxygenated Compounds). 7
Oriental Plane Other Oxy. C. 17%
River Red Gum 4Terpineol Crotonald 1% ehyde 2%
1-Octanol 37%
Linalool L 17% 2-Methyl3-buten-2ol 29%
Eucalyptol 93%
Silver Lime
Sweet Chestnut
Other Oxy. C. 8% Crotonald ehyde 14%
Other Oxy. C. 11% AlphaTerpineol 8%
Camphor 32% Linalool L 18% Eucalyptol 28%
GammaTerpineol 24%
European Alder Other Oxy. C. 14%
Other Oxy. C. 16%
Dihydromy rcenol 7% Furan, 2methyl9%
Eucalyptol 47%
Linalool L 10%
Oriental Beech AlphaTerpineol 6%
Other Oxy. C. 4%
AlphaTerpineol 9% Crotonald ehyde 62% Linalool L 22%
Figure SM5. Continued.
8
Eucalyptol 33%
Crotonald ehyde 22%
Turkish Red Pine
Black Pine
Other SQs 8%
Other SQs 16%
Cis-AlphaBisabolen e 7%
Alphahumulene 14%
transCaryophyl lene 73%
Alphahumulene 12%
Scots Pine
Alphahumulene 9%
Other SQs 27%
Stone Pine
Isolongifol ene 30%
Other SQs 32%
transCaryophyl lene 51%
transCaryophyll ene 29%
Alphahumulene 9%
Isolongifol ene 13%
Aleppo Pine
Maritime Pine
Other SQs 22% Alphahumulene 11%
transCaryophyll ene 70%
Other SQs 35% transCaryophyll ene 67%
Isolongifol ene 36%
Cis-AlphaBisabolen e 9%
Radiata Pine
transCaryophyll ene 20%
Nordmann Fir Other SQs 15%
Alphahumulene 7%
Other SQs 25% Isolongifol ene 54%
Betafarnesene 38%
transCaryophyll ene 14%
Oriental Spruce Other SQs 14%
Alphahumulene 47%
Mediterranean Cypress
transCaryophyll ene 31%
Gammacadinene 11%
Betafarnesene 26% Alphahumulene 29%
transCaryophyll ene 19%
Other SQs 21%
Alphahumulene 28% Germacre ne-D 21%
Figure SM6. Sesquiterpene compositions of coniferous species (Other SQs: Other Sesquiterpenes). 9
Greek Juniper
Other SQs 30%
Prickly Juniper
Other SQs 19% Alphacedrene 50%
Alphamuurolene 12%
Germacre ne-D 20%
Phoenicean Juniper
Other SQs 31%
Alphamuurolene 8%
transCaryophyll ene 42%
Alphahumulene 27%
Foetid Juniper
transCaryophyll ene 40%
Other SQs 35%
Alphacedrene 9% Gammacadinene 10%
Alphahumulene 21%
Lebanon Cedar
Other SQs 29% Germacre ne-D 12%
transCaryophyll ene 39%
Cis-AlphaBisabolen e 20%
Figure SM6. Continued.
10
Alphahumulene 25%
transCaryophyll ene 21%
Turkish Red Pine
Black Pine Other Oxy. C. 9%
Other Oxy. C. 3% GammaTerpineol 13% AlphaTerpineol 15%
AlphaTerpineol 9%
Eucalyptol 36%
Eucalyptol 82% Linalool L 33%
Scots Pine
Stone Pine
Other Oxy. C. 2%
AlphaTerpineol 18%
Other Oxy. C. 9%
Linalool L 8% Linalool L 24%
Eucalyptol 83%
Aleppo Pine
Maritime Pine
Other Oxy. C. 17%
Other Oxy. C. 18% 1-Octanol 27%
Eucalyptol 56%
Eucalyptol 25%
D-Fenchyl alcohol 55%
Radiata Pine
Linalool L 58%
Nordmann Fir
Other Oxy. C. 14%
Other Oxy. C. 15%
Linalool L 10%
Isoborneol 7%
2-Methyl3-buten-2ol 76%
Linalool L 28%
Mediterranean Cypress
Orieantal Spruce
Other Oxy. C. 14%
Other Oxy. C. 32%
GammaTerpineol 39%
Eucalyptol 50%
4Terpineol 47%
Linalool L 31% GammaTerpineol 19%
Eucalyptol 18%
Figure SM7. Oxygenated compound compositions of coniferous species (Other Oxy.C.: Other Oxygenated Compounds). 11
Greek Juniper
Other Oxy. C. 41%
D-Fenchyl alcohol 11%
Prickly Juniper Other Oxy. C. 22%
GammaTerpineol 36%
Eucalyptol 10% 1-Octanol 12%
Camphor 12%
Phoenicean Juniper
Foetid Juniper
Other Oxy. C. 17% AlphaTerpineol 13%
Linalool L 47%
GammaTerpineol 9%
Other Oxy. C. 31%
1-Octanol 35% Linalool L Gamma16% Terpineol 19%
Dihydromy rcenol 8% 1-Octanol 10%
Lebanon Cedar Other Oxy. C. 16%
GammaTerpineol 9%
4Terpineol 44%
Linalool L 13% AlphaTerpineol 18%
Figure SM7. Continued.
12
Crotonald ehyde 29%
Eucalyptol 22%
