textural, geochemical and leaching study of volcanic

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Apr 23, 2015 - FEI Quanta 2000 ESEM FEG. Laser Difractometer LS230 Beckman Coulter in. FRX , LOI (950ºC) and ICP-MS/OES. The leaching test is used as ...
TEXTURAL, GEOCHEMICAL AND LEACHING STUDY OF VOLCANIC ASH: ENVIRONMENTAL IMPACT OF THE VOLCANO CALBUCO ERUPTION, APRIL 2015 1*

1

1

Benet D. , Carrazana A. , Gimeno D. , Kalmbach R.

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1

Departament de Mineralogia, Petrologia i Geologia Aplicada. Universitat de Barcelona, Spain. Carrer Martí i Franquès s/n, 08028, Barcelona. 2 Grupo de Estudios Ambientales (GEA). Centro Regional Universitario Bariloche. Universidad Nacional del Comahue, Argentina. *E-mail: [email protected]

I N T R O D U C T I O N RD

1. THE ERUPTION OF APRIL 23

2015

2. GEOLOGY OF CALBUCO VOLCANO

3. VOLCANIC ASH SAMPLING N

SAM-2 SAM-1

675m

4. OBJECTIVES The aims are (1) to characterize geochemically and texturally the ash samples and (2) to assess the geochemical impact of ash in the local balance.

R E S U L T S 5. TEXTURAL CHARACTERIZATION

7. LEACHING TEST

5.1 GSA: Frequency curves and accumulate frequency curves Accumulate Vol. %

Volume % 100

10

100

SAM-1

SAM-2

9

90

9

90

8

80

8

80

7

70

7

70

6

60

6

60

5

50

5

50

4

40

4

40

3

30

3

30

2

20

2

20

1

10

1

10

0

0

0 0.01

0.10

1.00

10.00

100.00

0 0.01

1000.00

The histogram has bimodal distribution. The main peak at 110 µm diameter and the secondary at 15 µm.

The leaching test is used as a proxy of short-term weathering on ash deposits, e.g. rainfall. The ratio between bulk composition and leachate composition, called RML(%), is indicative of the mobility for each element: leachate composition shows whether is suitable for human consumption comparing to the drinking guideline values.

0.10

1.00

Grain-size (μm)

10.00

100.00

1000.00

Grain-size (μm)

Mobility

RML

Elements

High

>5%

Te

Moderate

5-0,5%

Tl, Mo, Cd, Ni,As, Th, Sb, K, Na, Cu, Sn, Zn, W, Ca, Li, Pb, Rb.

Low

200

9.39 6.70

Fraction (Horwell 2007)

0.25 0.09

Respirable