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AEROSPACE REPORT NO. TR-2007(8555)-5

The Rubidium Atomic Clock and Basic Research December 10,2007

James C. Camparo Electronics and Photonics Laboratory Physical Sciences Laboratories

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This report was submitted by The Aerospace Corporation, El Segundo, CA 90245-4691, under Contract No. FA8802-04-C-0001 with the Space and Missile Systems Center, 483 N. Aviation Blvd., El Segundo, CA 90245. It was reviewed and approved for The Aerospace Corporation by B. Jaduszliwer, Principal Director, Electronics and Photonics Laboratory; and D. C. Marvin, Principal Director, Research and Program Development Office. Michael Zambrana was the project officer for the Mission-Oriented Investigation and Experimentation (MOIE) program. This report has been reviewed by the Public Affairs Office (PAS) and is releasable to the National Technical Information Service (NTIS). At NTIS, it will be available to the general public, including foreign nationals. This technical report has been reviewed and is approved for publication. Publication of this report does not constitute Air Force approval of the report's findings or conclusions. It is published only for the exchange and stimulation of ideas.

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The Rubidium Atomic Clock and Basic Research

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J. C. Camparo

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The vapor-cell atomic clock finds application today in the global positioning system and telecommunications. To improve and miniaturize the humble device for future applications will require a deeper understanding of atomic and chemical physics.

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Atomic clocks, Rubidium atomic clock 16. SECURITY CLASSIFICATION OF:

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This work was supported under The Aerospace Corporation's Mission-Oriented Investigation and Experimentation program, funded by U.S. Air Force Space and Missile Systems Center under Contract No. FA8802-04-C-0001. This report is a reprint of a feature article in Physics Today. Reprinted with permission of The American Institute of Physics.

in

The rubidium atomic clock and basic research James Camparo The vapor-cell atomic clock finds application today in the global positioning system and telecommunications. To improve and miniaturize the humble device for future applications will require a deeper understanding of atomic and chemical physics. James Camparo is a senior scientist at The Aerospace Corporation in Los Angeles.

You're returning home from a conference, in a rental car on a dark, rainy road 50 miles from the airport; you're running out of time to catch your flight, and you're lost. As little as 10 years ago, this would have been the stuff of travel nightmares, to be shared with colleagues during a coffee break between conference sessions. Today it is less of a nightmare and more of an inconvenience. You pull your car to the side of the road, program your desired destination into the rental car's navigation system, and let it calculate a direct route to the airport from your present location using signals from orbiting GPS (global positioning system) satellites. Thankfully, you make it home without an exciting but harrowing story to tell family and friends. Unseen and forgotten in this now-routine use of GPS are the atomic clocks. The propagation times of signals traveling 20 000 km from space to Earth are measured at the nanosecond level, and from those measurements, positions are calculated to within, in some cases, a few centimeters. More generally, modern systems ranging from cell-phone communications to satellite navigation take advantage of atomic clocks, in particular the capabilities of small, lowpower, rubidium vapor-cell clocks. How the vapor-cell clock came to play such an important role in modern timekeeping is a story that goes back half a century, and one that highlights the close interplay between basic science and technological innovation.

The vapor-cetf atomic clock The vapor-cell atomic clock is an unpretentious device. Light from a small discharge lamp passes through a vapor of rubidium atoms housed in a glass cell and is detected by a photodiode. The light intensity transmitted by the vapor is used to lock the frequency of an RF signal to an atomic transition. The RF signal can then be down-converted to generate a train of one-second pulses for timekeeping. Given its conceptual simplicity, the extent to which the vapor-cell clock's realization relies on basic atomic and chemical physics is quite striking. Since time intervals are defined as the elapsed phase of some stable oscillation, all clocks are, at heart, frequency standards. Just like in your wristwatch, the timekeeping signal in an atomic clock is derived from a quartz crystal oscillator. ©2007 American Institute ol Physics, S-0031-9228-0711-010-3

However, a crystal oscillator's RF frequency vxt1, depends on a number of environmental factors, such as humidity, vibration, and radiation, that can cause the clock to either speed up or slow down. In the vapor-cell atomic clock, -i\till is electronically tied to an atomic resonance, thereby transferring the stability of atomic structure to the clock's tick rate. The atomic resonance that forms the basis of the Rb clock's operation is the transition between two hyperfine states of 87Rb. As in hydrogen, the ground state of Rb is split into two hyperfine levels by the magnetic-dipole interaction between the single valence electron and the nucleus. Those states are labeled by the total-angular-momentum quantum number F, as shown in figure la. Each hyperfine state is further split into Zeeman sublevels, characterized by the quantum number mF. The mF = 0 sublevels are unaffected to first order by stray magnetic fields, which can arise in devices from a host of internal and environmental sources. The socalled 0-0 transition between the F = 2, mF = 0 and F = 1, mF = 0 states, with frequency vhts = 6.8347 GHz, is unaffected by such fields and is ideal for stabilizing \\U1|. Figure lb shows the means by which vxlll is electronically tied to vhls. The first step is to multiply the output of a voltagecontrolled crystal oscillator (VCXO) by a factor M to create a microwave field with a frequency near vhrbr + can be expanded in terms of the unperturbed eigenstates—that is,

* = X cn|n>e-;^'.

(1!

n= 1

Shortly after the field is turned on, c, = Cj = 1 /\/2~j and it can be shown by time-dependent perturbation theory that

C-K- ~

ieE0 (r + r e'>), 31 32

(2)

V2*

If the phase of the field's b mode varies rapidly and randomly with respect to the a mode, then the cosine term of equation 4 averages to zero, and each excitation pathway acts independently. Alternatively, if

. 89, 472 (1953). 7. D. K. Walter, W. M. Griffith, W. Happer, Phys. Rev. Lett. 88, 093004 (2002); P. Oreto et al., Phys. Rev. A 69, 042716 (2004). 8. J. C. Camparo, S. B. Delcamp, Opt. Commun. 120, 257 (1995). 9. R. Frueholz, M. Wun-Fogle, /. Am. Ceram. Soc. 66, 605 (1983); R. Cook, R. Frueholz, Proceedings of the 42nd Annual Frequency Control Symposium, IEEE, Piscataway, NJ (1988), p. 525. 10. J. Camparo, C. Klimcak, S. Herbulock, IEEE Trans. Instrum. Meas. 54, 1873 (2005); I. Coffer, B. Sickmiller, J. Camparo, IEEE Trans. Ultrason. Ferroelectr. Freq. Control 51,139 (2004); J. Camparo, IEEE Ultrason. Ferroelectr. Freq. Control 52, 1075 (2005). 11. I. Camparo, I. Coffer, Phys. Rev. A 59, 728 (1999); J. Coffer, M. Anderson, J. Camparo, Phys. Rev. A 65, 033807 (2002). 12. J. ]. Townsend, J. G. Coffer, I. C. Camparo, Phys. Rev. A 72, 033807 (2005); M. Huang, J. G. Coffer, J. C. Camparo, Opt. Commun. 265, 187 (2006). 13. }. Vanier, Appl. Phys. B 81, 421 (2005). 14. S. Knappe et al., Appl. Phys. Lett. 85, 1460 (2004). 15. J. Vanier, C. Audoin, The Quantum Physics of Atomic Frequency Standards, Adam Hilger/IOP, Bristol, UK (1989), chap. 3. 16. J. Bjorkholm, P. Liao, Lecture Notes in Physics: Volume 43, Springer, Berlin (1975), p. 176. 17. A. Kastler, /. Opt. Soc. Am. 53, 902 (1963). 18. J. Camparo, P. Lambropoulos, /. Opt. Soc. Am. B 19,1169 (2002). • November 2007

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The Aerospace Corporation functions as an "architect-engineer" for national security programs, specializing in advanced military space systems. The Corporation's Physical Sciences Laboratories support the effective and timely development and operation of national security systems through scientific research and the application of advanced technology. Vital to the success of the Corporation is the technical staffs wide-ranging expertise and its ability to stay abreast of new technological developments and program support issues associated with rapidly evolving space systems. Contributing capabilities are provided by these individual organizations: Electronics and Photonics Laboratory: Microelectronics, VLSI reliability, failure analysis, solid-state device physics, compound semiconductors, radiation effects, infrared and CCD detector devices, data storage and display technologies; lasers and electro-optics, solid-state laser design, micro-optics, optical communications, and fiber-optic sensors; atomic frequency standards, applied laser spectroscopy, laser chemistry, atmospheric propagation and beam control, LIDAR/LADAR remote sensing; solar cell and array testing and evaluation, battery electrochemistry, battery testing and evaluation. Space Materials Laboratory: Evaluation and characterizations of new materials and processing techniques: metals, alloys, ceramics, polymers, thin films, and composites; development of advanced deposition processes; nondestructive evaluation, component failure analysis and reliability; structural mechanics, fracture mechanics, and stress corrosion; analysis and evaluation of materials at cryogenic and elevated temperatures; launch vehicle fluid mechanics, heat transfer and flight dynamics; aerothermodynamics; chemical and electric propulsion; environmental chemistry; combustion processes; space environment effects on materials, hardening and vulnerability assessment; contamination, thermal and structural control; lubrication and surface phenomena. Microelectromechanical systems (MEMS) for space applications; laser micromachining; laser-surface physical and chemical interactions; micropropulsion; micro- and nanosatellite mission analysis; intelligent microinstruments for monitoring space and launch system environments. Space Science Applications Laboratory: Magnetospheric, auroral and cosmic-ray physics, wave-particle interactions, magnetospheric plasma waves; atmospheric and ionospheric physics, density and composition of the upper atmosphere, remote sensing using atmospheric radiation; solar physics, infrared astronomy, infrared signature analysis; infrared surveillance, imaging and remote sensing; multispectral and hyperspectral sensor development; data analysis and algorithm development; applications of multispectral and hyperspectral imagery to defense, civil space, commercial, and environmental missions; effects of solar activity, magnetic storms and nuclear explosions on the Earth's atmosphere, ionosphere and magnetosphere; effects of electromagnetic and paniculate radiations on space systems; space instrumentation, design, fabrication and test; environmental chemistry, trace detection; atmospheric chemical reactions, atmospheric optics, light scattering, state-specific chemical reactions, and radiative signatures of missile plumes.