Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is © The Royal Society of Chemistry 2014
Triptycene Based Organometallic Complexes: A New Class of Acceptor Synthons for Supramolecular Ensembles Sourav Chakraborty,1 Snehasish Mondal,1 Sourav Bhowmick,1 Jianqiu Ma,2 Hongwei Tan,2 Subhadip Neogi,3 and Neeladri Das1* 1 2
Department of Chemistry, Indian Institute of Technology Patna, Patna 800 013, Bihar, India
Department of Chemistry, Beijing Normal University, Beijing 100050, People's Republic of China 3
Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India
E-mail:
[email protected]; Tel. +91 612 2552023; Fax +91 612 2277383.
Table of contents 1. 1H and 31P NMR spectra of compound 1................................................................. S2 2. 1H and 31P NMR spectra of compound 2................................................................. S3 3. 1H and 31P NMR spectra of compound 3................................................................. S4 4. 1H and 31P NMR spectra of compound 4................................................................. S5 5. 1H and 31P NMR spectra of compound 5................................................................. S6 6. 1H and 31P NMR spectra of compound 6................................................................. S7 7. ESI-MS data of compound 2 and 3...........................................................................S8 8. ESI-MS data of compound 4.....................................................................................S9 9. ESI-TOF-MS data of compound 5 and 6........................................................S9 & S10 10. DOSY NMR spectrum of compound 5 and 6..........................................................S10
S1
1
H NMR spectrum of 1: PEt3 Pt Et 3P Br
PEt 3 Br Pt PEt 3
Et 3P
Pt PEt3 Br
31
P NMR spectrum of 1:
S2
1
H NMR spectrum of 2: PMe3 Pt Me 3P Br
PMe3 Br Pt PMe3
31
Me3 P
Pt PMe 3 Br
P NMR spectrum of 2:
S3
1
H NMR spectrum of 3: PEt3 Pt Et3P
O3 N
PEt 3 O3 N Pt PEt 3
31
Et3 P
Pt PEt3 NO3
P NMR spectrum of 3:
S4
1
H NMR spectrum of 4:
PMe3 Pt Me 3P O3N
PMe3 O 3N Pt PMe3
1
H NMR spectrum of 4:
S5
Me 3P
Pt PMe 3 NO3
1
H NMR spectrum of 5:
31
P NMR spectrum of 5:
S6
1
H NMR spectrum of 6:
31
P NMR spectrum of 6:
S7
ESI-MS dataof 2:
ESI-MS data of 3:
S8
ESI-MS data of 4:
ESI-TOF-MS data of 5:
S9
ESI-TOF-MS data of 6:
1
H DOSY NMR spectrum of 5 in CD3OD:
1
H DOSY NMR spectrum of 6 in CD3OD:
S10
