WATTYL ESTAPOL 7008 (PART A ) - FloorSandingSupplies

63 downloads 277 Views 100KB Size Report
Jul 22, 2004 ... Chemwatch Material Safety Data Sheet ... ChemWatch MSDS ..... the outer packaging is a close fitting moulded plastic box and the substances.
ChemWatch MSDS

Page 1 of 12

WATTYL ESTAPOL 7008 (PART A ) Chemwatch Material Safety Data Sheet Issue Date: Thu 22-Jul-2004

CHEMWATCH 15232

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME WATTYL ESTAPOL 7008 (PART A ) SYNONYMS "Polyurethane two pack floor coating", "base component" PROPER SHIPPING NAME PAINT PRODUCT USE Part A or Base of a 2 pack. urethane coating system. Requires that the two parts be mixed by hand or mixer before use, in accordance with manufacturers directions. Mix only as much as is required. Do not return the mixed material to the original containers. CONTAINS free organic isocyanate. Mixing and application requires special precautions and use of personal protective gear [APMF]. For the protection of interior timber surfaces. SUPPLIER

! " ( )

#

%$$% & *

&%

% ''

Section 2 - HAZARDS IDENTIFICATION STATEMENT OF HAZARDOUS NATURE HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code. POISONS SCHEDULE S5 RISK

SAFETY

Flammable. May form explosive peroxides. Harmful by inhalation and in contact with skin. Irritating to eyes and skin. HARMFUL-May cause lung damage if swallowed. Ingestion may produce health damage*. Cumulative effects may result following exposure*. May produce discomfort of the respiratory system*. Limited evidence of a carcinogenic effect*. Possible respiratory and skin sensitiser*. May be harmful to the foetus/ embryo*. Vapours potentially cause drowsiness and dizziness*. * (limited evidence). Keep container in a well ventilated place. Avoid exposure - obtain special instructions before use. To clean the floor and all objects contaminated by this material, use water and detergent. Keep container tightly closed. Keep away from food, drink and animal feeding stuffs. Take off immediately all contaminated clothing.

file://T:\Lab\HTML\15232.HTM

7/11/2005

ChemWatch MSDS

Page 2 of 12

In case of contact with eyes, rinse with plenty of water and contact Doctor or Poisons Information Centre. If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre. (show this container or label). If you feel unwell contact Doctor or Poisons Information Centre. (Show the label if possible).

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS NAME polyol/polyester resin xylene ethyl-3-ethoxypropionate additives contains less than 0.1% benzene

CAS RN

% 30-60 10-30 10-30

.

#

#

.5

5

#

1 0

.

0 .

# + ? .

#

3

0

0

/ @9 9,@ "# ) C E

2

0 0 . #

5 . # # # ?A 9 !B? @ C?A # # ?) @

#

#

-

) 1' / 4/

2 1/1

. #

3

# #

# 1 @ # #

/ )1

0

1

?@ .

5

0 2?

?

0

/4

#

#

" D3

/ " # 0 #

0

# 0 1 ( .- # # ) + "# . 5 # + 0 ) / 1 + = 5 / . + + 5 + / 6 0 ) 1 E 5 + " 0 # F G . 3 + 5 # 2 /4 /3 . 0 0 / 1 + E / 0 . 1 + "# 00 5 # F? # )> E 9"? @ 0 # # # # # / / 0 # FH I J ( E

# # 5

5

.

5

#

0

0 /# .

#

1

2

#

0 / 00 #

. .

5

)

3

1

.

1 1 # #

5

5

) /

1 #

#

2

#

1 #

2

.

/

. 0

3

2

3

.

1 " )

/ G 5

5 0

. " )

# (?D /

) 5

# # 1 "# 1

/ 5

'%-%

1

&& G1

Section 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA · Foam. · Dry chemical powder. · BCF (where regulations permit). · Carbon dioxide. · Water spray or fog - Large fires only. FIRE FIGHTING · Alert Fire Brigade and tell them location and nature of hazard. · May be violently or explosively reactive. · Wear breathing apparatus plus protective gloves. · Prevent, by any means available, spillage from entering drains or water course. · If safe, switch off electrical equipment until vapour fire hazard removed. · Use water delivered as a fine spray to control fire and cool adjacent area. · Avoid spraying water onto liquid pools. · DO NOT approach containers suspected to be hot. · Cool fire exposed containers with water spray from a protected location. · If safe to do so, remove containers from path of fire. When any large container (including road and rail tankers) is involved in a fire, consider evacuation by 500 metres in all directions. FIRE/EXPLOSION HAZARD · Liquid and vapour are flammable. · Moderate fire hazard when exposed to heat or flame. · Vapour forms an explosive mixture with air. · Moderate explosion hazard when exposed to heat or flame. · Vapour may travel a considerable distance to source of ignition. · Heating may cause expansion or decomposition leading to violent rupture of

file://T:\Lab\HTML\15232.HTM

7/11/2005

ChemWatch MSDS

Page 4 of 12

containers. · On combustion, may emit toxic fumes of carbon monoxide (CO)., Combustion products include. other pyrolysis products typical of burning organic material. WARNING: Long standing in contact with air and light may result in the formation of potentially explosive peroxides. FIRE INCOMPATIBILITY Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result. HAZCHEM

3[Y]

Personal Protective Equipment PERSONAL PROTECTION EQUIPMENT Breathing apparatus. Gas tight chemical resistant suit. Limit exposure duration to 1 BA set - 30 mins.

Section 6 - ACCIDENTAL RELEASE MEASURES EMERGENCY PROCEDURES MINOR SPILLS · Remove all ignition sources. · Clean up all spills immediately. · Avoid breathing vapours and contact with skin and eyes. · Control personal contact by using protective equipment. · Contain and absorb small quantities with vermiculite or other absorbent material. · Wipe up. · Collect residues in a flammable waste container. MAJOR SPILLS · Clear area of personnel and move upwind. · Alert Fire Brigade and tell them location and nature of hazard. · May be violently or explosively reactive. · Wear breathing apparatus plus protective gloves. · Prevent, by any means available, spillage from entering drains or water course. · No smoking, naked lights or ignition sources. · Increase ventilation. · Stop leak if safe to do so. · Water spray or fog may be used to disperse / absorb vapour. · Contain spill with sand, earth or vermiculite. · Use only spark-free shovels and explosion proof equipment. · Collect recoverable product into labelled containers for recycling. · Absorb remaining product with sand, earth or vermiculite. · Collect solid residues and seal in labelled drums for disposal. · Wash area and prevent runoff into drains. · If contamination of drains or waterways occurs, advise emergency services. PROTECTIVE ACTIONS FOR SPILL

( @?B, 2 @ C C @?B, .

4

3

' *77

C

(99" 9"? B9"? "@D? "@9 0 # 0 ) 0 # 5

K9 ? 1 "#

0

#

L

# # #

# #

*7

/

/

# 5

/ 6 # B9"? "@D? # 1 ) .

5 "@9

#

#

# /

#

5

)

.

0 L

file://T:\Lab\HTML\15232.HTM

4

. /

#

/

#

#

5

0 5 .

/ 5

#

1

.

#

0

/

/ 5

.

7/11/2005

ChemWatch MSDS

# # @ @"@

*

00 @ 9

Page 5 of 12

1 "@9 #

K9 ? # #

/ # /#

) E

@

#

#

/ . )

77 M

B,?

5

0

77

2'' ! / 31 /

0

#

! 0

5

/

/

C9"

M

/

/

!"?

.

.

5

.

5

)

/ #

#

#

# 77 77

@ / D B'7 B' #

#

5

/

#

/4 N

. .

#

# 0 #

1 #

00

77 7 /4 N

# ) ; /

2 @; 3 /

" )

/

'7 %7 /4 N

# )

) @

#

0

# -*-

5

)

00

/

) #

1

5

) #

M

/4 N

5

-*-

. @";9!"

.

# ) 5

#

0 -

1

00 O

# #

/

00

) -*-

#

# &77 '77

5

.

- "

#

0

# )

.

#

/

.

EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG) 0 - # ) # -*-

/

1

0

)

3

/ 0 / /

#

/

"#

/

M1 5 77

#

, @?B,

/ # /

@

/

#

5 0 - #

1

5 5 2=

#

"#

0

0

# 0

' %

. .

2"$3

!( P ! 0 " D . 5 . 6 5 9C 0 " ) # 5 . 0 C P C 5 > B P B 5 > " P " J 5 J1 C (1 / E # 0 9 @ ; / J 'R

6 -

/

5

0 1 9B, 1

0 0

#

#

# / B

%

5

-% & 2 &&%31

INGREDIENT DATA

AS ? ? 9 9"? 5

"# C .

#

D

7 .

0

2

3

-) 1 2 -)

7

2

/

/

) / 5

-)

3 0

7 #

3 A

5

#

.

# /#

1 ?)

00

# /#

) ) #

5 ?)

5 1

/ 77

/

)

9" #

. # #

0 = .

/# 77

5

/ 0

0

#

* " D-"

'

1 "? #

00 1

# /

/# 0

. /

.

.

?";S -*-?";9AS B9 @9 "? ) . ? " '7 *77 /4 N

#

5

9; F?

.

#

# L

>

1

,@;1 G

PERSONAL PROTECTION EYE

+ + +

0 #

/

# / //

#

1

1

file://T:\Lab\HTML\15232.HTM

0

.

.

7/11/2005

ChemWatch MSDS

Page 8 of 12

1 # #

. # 0

5 # 5

. 1 @

.

.

0 . 0

=

5

5 0

#

)

5 5

#

0

/

0

5 @9 ;

0 @

HANDS/FEET #

+ 95 + D + D + ? + ?

/

0

OTHER

5 0

/

.

6

/1 .

D 1 /1 B ..

1

1 5 1

#

0

#

0

> C

0

.

2 3

/

0

#

6

#

#

0

. ) 2E

3

7 ) ?

-0

;

#

#

/

5

0

6

.

3

0

#

/

/-

0

6

1

6

#

S M

M 5

- #

M?)

0-( B - ! B- !

( -

-0

M31 B

- ! B- ! B-

6

0

0

5

6

0

0

3

9

ENGINEERING CONTROLS .

0

1 .

.

0 #

0

0 5

1

"# .

# .

-

77 ) ?

0

#

2

7 ) ?

5

#

# 2 1/1 .

#

B

#

2 3

#

.

RESPIRATOR

U - (

#

0

#

5

/#

(

2 3

.

M

#

#

0 .

M0

0

0

5

# #

#

)

. #

#

)M1

/

/

/

1

1

0 @

0 0

5

5 #

, 5 . 0 M( . / # / 0 @ )M1 "# 00 2 3 0 # 0 / . -/ 5 E @ T1 QQQQQQQQQQQQQQQQQQQQQQQQQQQQQQQQ ?4?D 4 ? D D@"9 "?( 9 DC 4 ?4 DC "!B $ ?9 B? ? ?9 B? ?4 "!B @"B@ ?$ D ;S 9 "$ ?9 B$ @"B@ ? !"S !"S 4 ?9 B? ? @"B@ ? ?9 B? ? D QQQQQQQQQQQQQQQQQQQQQQQQQQQQQQQQ , 5 . 0 M( . / # / 0 @ )M1 "# 00 2 3 0 # 0 / . -/ 5 E @ T1 T @ - # # 0 @ )

9"? 0 T # 0 0 / 1

)

0

, 5 . M( . / # / 0 "# 00 2 3 0 # 0 -/

(

0

1

GLOVE SELECTION INDEX

(

/ 1 "#

'&G1

5

0

# 5

/

#

0 # 0 1 E 0 . 6 # . . / / . 1 # . # . 5 # # # /# 1 F C

)

# #

/

#

6

;

0 5

file://T:\Lab\HTML\15232.HTM

.

#

6 " ; 5

;?E 0

/

)# .

6

1 2 0 1

5 1 D

6

7/11/2005

ChemWatch MSDS

#

Page 9 of 12

.

)

-

1

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE

# /#

0 5

#

.

6

>

)

#

1

1

PHYSICAL PROPERTIES Liquid. Does not mix with water. Sinks in water. E E

/ B

/

/# 2V 3

.

. 5 2/4 3

; 2 8 D B

3

1 .

@

. 1 3 7-'7 C 2 P 3 < 283 17 2V 3 *%& 285

5 D ?) /

5 "

/ B 1

0 .

/ ,

; 2 )

D ?5 ( ! C

# ?)

5

2V 3 2 3 2

B 2V 3 5 "

'- %' P 3 3

< 5

17 . .

& 283 2V 3

R17

6

Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION CONDITIONS CONTRIBUTING TO INSTABILITY · Presence of incompatible materials. · Product is considered stable. · Hazardous polymerisation will not occur.

Section 11 - TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS ACUTE HEALTH EFFECTS SWALLOWED Accidental ingestion of the material may be damaging to the health of the individual. Considered an unlikely route of entry in commercial/industrial environments. The liquid may produce gastrointestinal discomfort and may be harmful if swallowed. Ingestion may result in nausea, pain and vomiting. Vomit entering the lungs by aspiration may cause potentially lethal chemical pneumonitis. EYE

SKIN

This material can cause eye irritation and damage in some persons. The liquid produces a high level of eye discomfort and is capable of causing pain and severe conjunctivitis. Corneal injury may develop, with possible permanent impairment of vision, if not promptly and adequately treated. The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. This material can cause inflammation of the skin on contact in some persons. The material may accentuate any pre-existing dermatitis condition. Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected. Exposure limits with "skin" notation indicate that vapour and liquid may be absorbed through intact skin. Absorption by skin may readily exceed vapour inhalation exposure. Symptoms for skin absorption are the same as for inhalation. Contact with eyes and mucous membranes may also contribute to overall exposure and may also invalidate the exposure standard. Toxic effects may result from skin absorption. The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin.

file://T:\Lab\HTML\15232.HTM

7/11/2005

ChemWatch MSDS

Page 10 of 12

INHALED Inhalation of aerosols (mists, fumes), generated by the material during the course of normal handling, may be harmful. There is some evidence to suggest that the material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lung damage. Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by narcosis, drowsiness, reduced alertness, loss of reflexes, lack of coordination and vertigo. Xylene is a central nervous system depressant. Headache, fatigue, tiredness, irritability and digestive disturbances (nausea, loss of appetite and bloating) are the most common symptoms of xylene overexposure. Injury to the heart, liver, kidneys and nervous system has also been noted amongst workers. Temporary memory loss, kidney impairment, temporary confusion and some evidence of disturbance of liver function was reported in workers grossly exposed to xylene (1%). One death was noted, with autopsy revealing lung congestion, oedema and local bleeding of alveoli. Inhaling xylene at 100 ppm for 5-6 hours can increase reaction time and cause slight inco-ordination. Tolerance developed during the work week, but was lost over the weekend. Physical exercise may reduce tolerance. About 4-8% of total absorbed xylene accumulates in fat. If exposure to highly concentrated solvent atmosphere is prolonged this may lead to narcosis, unconsciousness, even coma and possible death. CHRONIC HEALTH EFFECTS Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure. There has been some concern that this material can cause cancer or mutations but there is not enough data to make an assessment. There is some evidence that human exposure to the material may result in developmental toxicity. This evidence is based on animal studies where effects have been observed in the absence of marked maternal toxicity, or at around the same dose levels as other toxic effects but which are not secondary non-specific consequences of the other toxic effects. Exposure to the material for prolonged periods may cause physical defects in the developing embryo (teratogenesis). Women exposed to xylene in the first 3 months of pregnancy showed a slightly increased risk of miscarriage and birth defects. Evaluation of workers chronically exposed to xylene has demonstrated lack of genetic toxicity. Exposure to xylene has been associated with increased rates of blood cancer, but this may be complicated by exposure to other substances, including benzene. Animal testing found no evidence of cancer-causing activity. Chronic solvent inhalation exposures may result in nervous system impairment and liver and blood changes. [PATTYS]. TOXICITY AND IRRITATION 5

.

1 B 0

# 0

5

0

#

)

1 B"?

0

- B /

0 " )

?00

.

AS ? "9A@ 9 9 @ # @ # @ # B "# 9" ?5

? @"S 2# 3 C '7 2 3 C'7 *77 2# 3 " 2 3 2 3 '7 5 00 . 0 . 0 /

?";S "9A@ 9 9 C C @ # T ! TT ?

-*-?";9AS B9 @9 "? @"S 2 3 C'7 '777 /4 / 2 3 C'7 ' 7 /4 / 2 .. 3 C'7 7777 /4 / 2 .. 3 C'7 7R% /4 / 2 3 '7 '7 4 # . E 0 /

/4 / /4 / 77 7777 '777 0

@BB@" "@9 2 .. 3 '77 /4 # E ? 2# 3 77 ? 2 .. 3 R / E ? 2 .. 3 ' /4 # ?D?B?

4%# 4 # .

@ B

,

*

/ .

#

1

6

/1 @BB@" "@9 2 .. 3 7 /4 ? 2 .. 3 '77 /4

# # - E

E

Section 12 - ECOLOGICAL INFORMATION C9

9"

#

/

file://T:\Lab\HTML\15232.HTM

1

7/11/2005

ChemWatch MSDS

B 0 AS ? ? ( # '7 (: 77 / H 2 ; 0- 0 ; 0- 0 ; 0- 0 ; 0- 0 ; 0- 0 ; 0- 0 ; 0- 0 ; 0- 0 6 . 6 . 6 . 6 . # # # ) # ) # ) # )

Page 11 of 12

0

/

#

# 0

2&%# 13 2 /4 3 *1' 1 - 1 7 / &&'3 *1 -*1 7 - ; /# 2# 3 %R 2# 3 % - ; /# 2# 3 2# 3 1% 0 - ; /# 2# 3 %R 0 2# 3 % , - ; /# 2# 3 % 7 , 2# 3 **% / . - ; /# 2# 3 %R / . 2# 3 % / . - ; /# 2# 3 % 7 / . 2# 3 * 7 ) /# . - ; /# 2 - 3 %&1' ) /# . 2 - 3 %' # 0- 0 - ; /# 2# 3 1R7?$7 # 0- 0 2# 3 *1&7?$7' # 0- 0 - ; /# 2# 3 # 0- 0 2# 3 1%

?";S -*-?";9AS B9 @9 "? / H 1 ' 6 00 " ) 20 # 3 '72&%#3 %' 14 1> 9? 7 14 1 " ) 20 3 '7 2&%#3 * 14 1> 9? 7 14 1 " ) 2 3 '72&%3 < 77 14 1> 9? 77 14 1 " ) 2 # 3 '72&%3 < 77 14 1> 9? 77 14 1 " ) 2 . /3 '72&%3 < 77 14 1> 9? 77 14 1 " ) 2 6 # 3 '72&%3 < 77 14 1> 9? 77 14 1 " ) 2 3 '72&%3 < 77 14 1> 9? 77 14 1 / 0 . / . / / # *8 / . 0 5 / . 9) / "#9C 1&R / ) / 4/ 9C 1& / ) / 4/ 9C-' W 7 4 1 71*R / ) / 4 9C- 7 W 7 4 1 71'% / ) / 4 00 '# @ -'7