diazepine Monohydrate

K. L E W I N S K I , W. N I T E K , B. J. O L E K S Y N CII Ci2 Ni3 CI4 Ci5 CI6 C17 C18 C19 020 C21 022 C26 027 028 C29 C30

0.8944 (2) 0.9798 (2) 1.0007 (2) 0.9521 (2) 0.8899 (3) 0.8067 (2) 0.7868 (2) 0.8479 (2) 0.9344 (2) 0.7504 (2) 0.6583 (3) 0.78629 ( 1 3 ) 0.2602 (2) 0.2900 (2) 0.2032 (2) 0.1717 (3) 0.0219 (3)

0.9763 (2) 0.29332 (11) 1.0694 (2) 0.26900 (12) 1.09721 ( 1 3 ) 0.19693(10) 1.0614 (2) 0.06480 (13) 0.9985 (2) 0.00826 (12) 0.8995 (2) 0.02591 (10) 0.86631 ( 1 5 ) 0.10045(9) 0.93167 (14) 0.16128(10) 1.02994 (15) 0.14293(11) 0.84474 (14) -0.03643 (7) 0.7478 (2) -0.02329 (12) 0.76352(11) 0.34025(7) 0.9395 (2) 0.37587 (11) 1.03828 (15) 0.39006(10) 0.86660 ( 1 5 ) 0.42692(9) 0.9094 (3) 0.50414 (13) 0.9510 (3) 0.5082 (2)

0.0443 (4) 0.0495 (4) 0.0490 (4) 0.0564 (5) 0.0601 (6) 0.0463 (4) 0.0389 (3) 0.0363 (3) 0.0427 (4) 0.0590(4) 0.0647 (6) 0.0469(3) 0.0467 (4) 0.0808 (5) 0.0685 (4) 0.0688 (7) 0.0787 (8)

Table 2. Selected geometric parameters ( * , o) N1----C2 NI---C8 NI---C6 C2---C3 C3--C26 C3---C4 C4~C5 C4---C7 C5