H NMR spectrum for compound I (DMSO-d6, 500 MHz)

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F-7-(108-124) #197 RT: 0.66 AV: 1 NL: 1.57E7. T: FTMS + p ESI Full ms [350.0000-550.0000]. 360. 380. 400. 420. 440. 460. 480. 500. 520. 540 m/z. 0. 5. 10. 15.
Figure S1: 1H NMR spectrum for compound I (DMSO-d6, 500 MHz)

Figure S2: 13C NMR spectrum for compound I (DMSO-d6, 125 MHz)

Figure S3: DEPT spectrum for compound I (DMSO-d6, 125 MHz)

Figure S4: HSQC spectrum for compound I (DMSO-d6, 500 MHz)

Figure S5: HMBC spectrum for compound I (DMSO-d6, 500 MHz)

Figure S6: COSY spectrum for compound I (DMSO-d6, 500 MHz)

Relative Abundance

F-7-(108-124) #197 RT: 0.66 AV: 1 NL: 1.57E7 T: FTMS + p ESI Full ms [350.0000-550.0000] 413.2127 z=?

100 95 90 85 80 75 70 65 60 55 50 45 40 35

461.1584 z=1

30

389.1578 z=1

25

421.2332 z=1

20 15 10

362.1919 z=2

384.2050 z=2 375.2510 z=1

5

481.2632 491.1690 z=1 z=1

441.2985 z=1

437.2366 z=1

406.2182 z=2

525.2896 z=1 539.1906 z=1

447.1637 z=1

521.1798 z=1

494.2711 z=1

549.1747 z=?

0 360

380

400

420

440

460

480

m/z

Figure S7: FT-MS spectrum for compound I

500

520

540

Figure S8: 1H NMR spectrum for compound II (DMSO-d6, 500 MHz)

Figure S9: 13C NMR spectrum for compound II (DMSO-d6, 125 MHz)

Figure S10: DEPT spectrum for compound II (DMSO-d6, 125 MHz)

Figure S11: HSQC spectrum for compound II (DMSO-d6, 500 MHz)

Figure S12: HMBC spectrum for compound II (DMSO-d6, 500 MHz)

Relative Abundance

F-7-3-4 #285 RT: 0.97 AV: 1 NL: 2.66E5 T: FTMS - p ESI Full ms [350.0000-550.0000] 451.1415 z=?

100 95 90

451.0898 z=?

85 80 75 70 65 60 55 50 45 40 35 30 25 20 15 10

451.1783 z=?

451.0534 z=?

5

451.4521 z=?

0 450.6

450.7

450.8

450.9

451.0

451.1 m/z

451.2

451.3

Figure S13: FT-MS spectrum for compound II

451.4

451.5

451.6

Figure S14: 1H NMR spectrum for compound III (DMSO-d6, 500 MHz)

Figure S15: 13C NMR spectrum for compound III (DMSO-d6, 125 MHz)

Figure S16: DEPT spectrum for compound III (DMSO-d6, 125 MHz)

Figure S17: HSQC spectrum for compound III (DMSO-d6, 500 MHz)

Figure S18: HMBC spectrum for compound III (DMSO-d6, 500 MHz)

Relative Abundance

F-7-8 #83 RT: 0.27 AV: 1 NL: 7.49E7 T: FTMS + p ESI Full ms [200.0000-600.0000] 421.1649 z=1

100 95 90 85 80 75 70 65 60 55 50 45

443.1469 z=1

40 35 30 25 20 15 10 5 0 200

231.1206 z=1

253.1648 275.1468 z=1 z=1 303.1417 z=1 250

300

359.2041 z=1 350

413.2126 z=1

400 m/z

463.3038 z=1 450

507.3303 z=1 500

Figure S19: FT-MS spectrum for compound III

551.3569 z=1 550

595.3831 z=1 600

Figure S20: 1H NMR spectrum for compound IV (DMSO-d6, 400 MHz)

Figure S21: 13C NMR spectrum for compound IV (DMSO-d6, 100 MHz)

Figure S22: DEPT spectrum for compound IV (DMSO-d6, 100 MHz)

Figure S23: HSQC spectrum for compound IV (DMSO-d6, 400 MHz)

Figure S24: HMBC spectrum for compound IV (DMSO-d6, 400 MHz)

Figure S25: COSY spectrum for compound IV (DMSO-d6, 400 MHz)

Figure S26: NOESY spectrum for compound IV (DMSO-d6, 400 MHz)

Relative Abundance

F-7-3-3 #128 RT: 0.61 AV: 1 NL: 9.38E6 T: FTMS - p ESI Full ms [200.0000-600.0000] 590.2055 z=1

100 95 90 85

527.1816 z=1

311.1635 z=1

80 75

580.1399 z=1

70 65 60 519.1331 z=1

55 50 297.1481 z=1

45

325.1789 z=1

465.1466 z=1

563.1562 z=1

40 331.1131 z=?

35

455.1468 z=1

30 25 20

283.2598 z=1

15 10 5 0 200

226.9750 z=1

351.1024 z=1

263.0522 z=1

250

383.1279 z=1 300

350

400 m/z

437.1161 z=1

450

499.1512 z=1

546.1472 z=1

471.0817 z=?

500

Figure S27: FT-MS spectrum for compound IV

550

600