Is the unexpected behaviour of the resolved K3[Crin(C20 4)3] in aqueous solution responsible for the formation of pure chiral solid phase of a two-dimensional (2D) [MnnCrni(C204)3 NEt(7i-Pr)(n-Bu)(n-C5Hn )] network? Michel Gruselle,*0 Cyrille Train,0 Nikolai S. Ovanesyan,6 Viktor D. Makhaev* and Christine Cordier “ Laboratoire de Chimie lnorganique et Materiaux Moleculaires, CNRS, Universite Pierre et Marie Curie, 75252 Paris Cedex 05, France. Fax: +33 14 427 3841; e-mail:
[email protected] b Institute o f Problems o f Chemical Physics, Russian Academy o f Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation c Itodys, UMR CNRS 7086, Universite Paris 7 - Denis Diderot, 75005 Paris, France DOI: 10.l070/M C 20()4vni-ln06A M ;,!lfl