Supporting information for: Automatic fitting of binary interaction parameters for multi-fluid Helmholtz-energy-explicit mixture models† Ian H. Bell∗ and Eric W. Lemmon∗ National Institute of Standards and Technology, Boulder, CO, USA E-mail:
[email protected];
[email protected]
This supplemental material includes the following components as hyperlinked below: • • • •
Information on the pure fluids used in the binary pairs The set of obtained interaction parameters for mixtures in Tier # 1 and Tier #2 The complete listing of the references used for the experimental data A set of figures comparing the pressures calculated with the new interaction parameters with those from the experimental measurements • The python code required to carry out the fitting (also provided in text-based code form, with some other necessary files, including some sample data).
Contents 1 Pure fluid information
S2
2 The obtained values for βT,ij and γT,ij for the binary pairs
S5
3 Deviation plots for the binary pairs
S28
4 Listing of experimental data used
S93
5 Python code S202 5.1 binary fitter.py . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . S202 Literature Cited
† Contribution
S207
of the National Institute of Standards and Technology, not subject to copyright in the US
S1
1
Pure fluid information
Table S1: Information on the pure fluids (short fluid name is compatible with both REFPROP and CoolProp) Short name 1BUTENE ACETONE AMMONIA ARGON BENZENE BUTANE C11 C12 C14 C1CC6 C2BUTENE C3CC6 C4F10 C5F12 CF3I CHLORINE CO CO2 COS CYCLOHEX CYCLOPEN CYCLOPRO D2 D2O D4 DECANE DEE DMC DME EBENZENE ETHANE ETHANOL ETHYLENE H2S HCL HELIUM HEPTANE HEXANE HYDROGEN IBUTENE IHEXANE IOCTANE IPENTANE ISOBUTAN KRYPTON MDM METHANE
IUPAC name but-1-ene propan-2-one azane argon benzene butane undecane dodecane tetradecane methylcyclohexane (Z)-but-2-ene propylcyclohexane 1,1,1,2,2,3,3,4,4,4-decafluorobutane 1,1,1,2,2,3,3,4,4,5,5,5-dodecafluoropentane trifluoroiodomethane molecular chlorine carbon monoxide carbon dioxide sulfanylidenemethanone cyclohexane cyclopentane cyclopropane deuterium deuterium oxide 2,2,4,4,6,6,8,8-octamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane decane ethoxyethane dimethyl carbonate methoxymethane ethylbenzene ethane ethanol ethene hydrogen sulfide hydrogen chloride helium heptane hexane hydrogen 2-methylprop-1-ene 2-methylpentane 2,2,4-trimethylpentane 2-methylbutane 2-methylpropane krypton dimethyl-bis(trimethylsilyloxy)silane methane
S2
CAS Number Reference S1 106-98-9 S2 67-64-1 S3 7664-41-7 S4 7440-37-1 S5 71-43-2 S6 106-97-8 S7 1120-21-4 S8 112-40-3 S9 629-59-4 S10 108-87-2 S1 590-18-1 S11 1678-92-8 S12 355-25-9 S13 678-26-2 S14 2314-97-8 S15 7782-50-5 S2 630-08-0 S16 124-38-9 S2 463-58-1 S17 110-82-7 S18 287-92-3 S19 75-19-4 S20 7782-39-0 S21 7789-20-0 S22 556-67-2 S2 124-18-5 S23 60-29-7 S24 616-38-6 S25 115-10-6 S26 100-41-4 S27 74-84-0 S28 64-17-5 S29 74-85-1 S2 7783-06-4 S30 7647-01-0 S31 7440-59-7 S32 142-82-5 S32 110-54-3 S33 1333-74-0 S1 115-11-7 S2 107-83-5 S34 540-84-1 S2 78-78-4 S6 75-28-5 S2 7439-90-9 S35 107-51-7 S36 74-82-8 Continued on next page...
Table S1 – continued from previous page Short name METHANOL MLINOLEA MM MOLEATE MPALMITA MSTEARAT MXYLENE N2O NEON NEOPENTN NITROGEN NONANE NOVEC649 OCTANE OXYGEN OXYLENE PENTANE PROPANE PROPYLEN PROPYNE PXYLENE R11 R113 R114 R115 R116 R12 R1216 R123 R1234YF R1234ZE R124 R125 R13 R134A R14 R141B R142B R143A R152A R161 R21 R218 R22 R227EA R23 R236EA R236FA R245FA
IUPAC name methanol methyl (9Z,12Z)-octadeca-9,12-dienoate trimethyl-trimethylsilyloxysilane methyl (Z)-octadec-9-enoate methyl hexadecanoate methyl octadecanoate 1,3-dimethylbenzene nitrous oxide neon 2,2-dimethylpropane molecular nitrogen nonane 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone octane molecular oxygen 1,2-dimethylbenzene pentane propane prop-1-ene prop-1-yne 1,4-dimethylbenzene trichloro-fluoromethane 1,1,2-trichloro-1,2,2-trifluoroethane 1,2-dichloro-1,1,2,2-tetrafluoroethane 1-chloro-1,1,2,2,2-pentafluoroethane 1,1,1,2,2,2-hexafluoroethane dichloro-difluoromethane 1,1,2,3,3,3-hexafluoroprop-1-ene 2,2-dichloro-1,1,1-trifluoroethane 2,3,3,3-tetrafluoroprop-1-ene (1E)-1,3,3,3-tetrafluoro-1-propene 2-chloro-1,1,1,2-tetrafluoroethane 1,1,1,2,2-pentafluoroethane chloro-trifluoromethane 1,1,1,2-tetrafluoroethane tetrafluoromethane 1,1-dichloro-1-fluoroethane 1-chloro-1,1-difluoroethane 1,1,1-trifluoroethane 1,1-difluoroethane fluoroethane dichloro-fluoromethane 1,1,1,2,2,3,3,3-octafluoropropane chloro-difluoromethane 1,1,1,2,3,3,3-heptafluoropropane fluoroform 1,1,1,2,3,3-hexafluoropropane 1,1,1,3,3,3-hexafluoropropane 1,1,1,3,3-pentafluoropropane
S3
CAS Number Reference S37 67-56-1 S38 112-63-0 S22,S39 107-46-0 S38 112-62-9 S38 112-39-0 S38 112-61-8 S26 108-38-3 10024-97-2 S2 S40 7440-01-9 S2 463-82-1 S41 7727-37-9 S2 111-84-2 S42 756-13-8 S32 111-65-9 S43,S44 7782-44-7 S26 95-47-6 S32 109-66-0 S45 74-98-6 S46 115-07-1 S19 74-99-7 S26 106-42-3 S47 75-69-4 S48 76-13-1 S49 76-14-2 S14 76-15-3 S2 76-16-4 S48 75-71-8 S50 116-15-4 S51 306-83-2 S52 754-12-1 29118-24-9 S53 S54 2837-89-0 S55 354-33-6 S56 75-72-9 S57 811-97-2 S49 75-73-0 S2 1717-00-6 S2 75-68-3 S58 420-46-2 S59 75-37-6 S60 353-36-6 S49 75-43-4 S2 76-19-7 S61 75-45-6 S14 431-89-0 S62 75-46-7 S63 431-63-0 S64 690-39-1 S65 460-73-1 Continued on next page...
Table S1 – continued from previous page Short name R32 R365MFC R40 R41 RC318 RE143A RE347MCC SF6 SO2 T2BUTENE TOLUENE WATER XENON
IUPAC name difluoromethane 1,1,1,3,3-pentafluorobutane chloromethane fluoromethane 1,1,2,2,3,3,4,4-octafluorocyclobutane trifluoro-methoxymethane 1,1,1,2,2,3,3-heptafluoro-3-methoxypropane sulfur hexafluoride sulfur dioxide (E)-but-2-ene methylbenzene oxidane xenon
S4
CAS Number 75-10-5 406-58-6 74-87-3 593-53-3 115-25-3 421-14-7 375-03-1 2551-62-4 7446-09-5 624-64-6 108-88-3 7732-18-5 7440-63-3
Reference S66 S14 S23 S2 S49 S67 S68 S69 S70 S1 S2 S71 S2
2
The obtained values for βT,ij and γT,ij for the binary pairs
Table S2: Tier #1 data for binary coefficients, including the coefficients βT,ij and γT,ij (MARE: median absolute relative error, N : number of bubble point experimental datapoints) Fluid 1 1BUTENE 1BUTENE 1BUTENE 1BUTENE 1BUTENE 1BUTENE 1BUTENE 1BUTENE 1BUTENE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE AMMONIA AMMONIA AMMONIA AMMONIA AMMONIA AMMONIA AMMONIA
Fluid 2 ACETONE BUTANE C4F10 CO2 DME ETHYLENE PROPYLEN R1216 R32 BENZENE BUTANE C12 C14 C2BUTENE CO2 CYCLOHEX DECANE DEE DMC ETHANE ETHANOL ETHYLENE H2S HEPTANE HEXANE IBUTENE IOCTANE ISOBUTAN METHANOL NONANE PENTANE PROPYLEN PXYLENE R113 R22 SO2 T2BUTENE TOLUENE WATER ARGON BENZENE BUTANE HEXANE KRYPTON MXYLENE OCTANE
βT,ij 1.01475 1.00154 1.06345 0.98059 0.99767 1.00327 1.00018 1.01733 0.98014 0.99820 0.98364 1.03220 1.02803 0.98583 1.01322 0.99120 1.02395 0.99001 0.99700 0.96779 1.00350 0.99223 0.95958 1.01173 1.00129 0.98616 1.00451 0.98302 0.99906 1.01457 0.99450 0.98047 1.00070 0.99630 1.04656 1.01070 0.98504 0.99846 0.98238 1.03498 1.03065 1.05871 1.09995 0.98832 1.04250 1.04331
S5
γT,ij MARE (%) N 0.95623 0.74 49 0.99777 0.36 44 0.86402 1.30 36 0.96751 1.73 61 0.98081 0.44 37 1.05570 2.25 63 1.00725 0.11 19 0.92312 0.46 34 0.85398 1.31 35 0.98198 1.15 480 0.93303 1.47 89 0.99897 2.93 30 1.02375 2.21 23 0.95209 0.64 49 1.08050 2.64 739 0.92123 0.94 249 0.96708 3.97 88 0.97127 2.02 156 0.99989 0.85 34 1.01420 2.45 9 0.97390 0.92 309 1.10077 3.69 35 1.04871 0.01 2 0.92544 1.37 61 0.91955 1.27 188 0.95994 0.67 47 0.93534 4.53 83 0.93551 0.92 48 0.97135 0.64 792 0.94280 2.26 36 0.92363 1.53 69 0.99014 2.40 33 0.97520 2.27 26 0.95086 0.51 44 1.07981 2.51 40 1.10455 3.52 73 0.95011 0.68 46 0.97643 1.12 130 0.91970 4.27 780 1.06504 4.14 65 0.92822 3.33 23 0.80552 2.90 18 0.86636 3.38 9 0.92419 2.66 8 0.95719 3.70 138 0.62644 1.30 10 Continued on next page...
Table S2 – continued from previous page Fluid 1 AMMONIA AMMONIA AMMONIA AMMONIA AMMONIA AMMONIA ARGON ARGON ARGON ARGON ARGON ARGON ARGON ARGON ARGON ARGON ARGON ARGON BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE
Fluid 2 PENTANE PROPANE PROPYLEN PROPYNE R125 R13 BENZENE BUTANE CO2 CYCLOPEN ETHANE HEXANE KRYPTON METHANE NEOPENTN NITROGEN OXYGEN R22 BUTANE C12 C14 C1CC6 CO CO2 CYCLOHEX D4 DECANE DEE DMC EBENZENE ETHANE ETHANOL H2S HEPTANE HEXANE IHEXANE IOCTANE METHANE METHANOL MXYLENE NONANE OCTANE OXYLENE PENTANE PROPANE PROPYLEN PXYLENE R113 R114
βT,ij 1.09752 1.04145 1.02533 1.00696 1.04548 1.03859 1.00291 0.98975 1.00206 0.97980 1.00215 0.97276 1.00020 1.00330 1.00019 1.00288 1.00218 0.98668 0.99022 1.00717 0.99866 1.00452 1.02875 0.99261 1.00212 1.01222 1.00678 1.00092 1.00156 0.99807 0.99662 1.02907 1.00564 1.00775 1.00430 1.00643 1.00861 1.00180 1.02351 0.99896 1.00489 1.00796 1.01414 1.00187 1.00170 0.99730 1.00112 1.00372 1.00118
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γT,ij MARE (%) N 0.84450 4.65 9 0.79017 2.31 49 0.84826 4.00 58 0.94154 0.78 32 0.96866 2.00 230 0.76464 1.06 20 1.40461 1.71 74 1.30400 3.63 35 1.05884 1.08 169 1.36013 3.00 25 1.09498 1.84 58 1.46735 1.02 186 1.00460 0.44 254 0.98974 1.42 196 1.28707 2.33 30 0.99261 0.59 551 0.98992 0.29 657 1.20531 1.81 33 0.99834 1.40 3 1.02547 2.50 61 1.04969 1.56 258 0.98159 0.68 149 1.47254 0.69 87 1.03295 2.69 249 0.97982 0.52 1147 0.98954 2.33 40 0.99831 1.19 22 1.00226 0.60 104 0.98361 0.19 203 1.01425 3.88 54 1.08163 0.93 139 0.91640 2.26 1062 1.06015 0.43 24 0.97482 0.60 794 0.97222 0.54 890 0.97119 0.53 54 0.96998 0.36 103 1.29314 3.43 423 0.90254 3.09 903 1.00464 0.82 53 0.97411 0.59 57 0.98037 0.89 135 1.00329 1.58 30 0.97605 0.64 155 1.01942 1.16 98 1.02876 4.90 85 1.00639 0.80 79 0.97215 0.51 69 0.95788 0.38 12 Continued on next page...
Table S2 – continued from previous page Fluid 1 BENZENE BENZENE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE C11 C11 C11 C11 C11 C11 C12 C12 C12 C12 C12 C12 C12 C12 C12 C12 C14
Fluid 2 R22 TOLUENE C14 C2BUTENE CO2 CYCLOHEX DECANE DME ETHANE ETHYLENE H2S HCL HEPTANE HEXANE IBUTENE ISOBUTAN METHANE MPALMITA OCTANE PENTANE PROPANE R113 R125 R13 R134A R143A R152A R227EA R23 R245FA R32 T2BUTENE CO2 ETHANE METHANOL MXYLENE OXYLENE PXYLENE CO CYCLOHEX DECANE ETHANE H2S HEPTANE METHANOL N2O OCTANE TOLUENE METHANOL
βT,ij 1.01060 1.00015 0.97985 0.99880 0.98681 1.00719 0.98937 0.99621 1.00553 1.02263 0.97552 0.97018 1.00222 0.99847 1.00062 1.00096 1.01187 0.93827 0.96619 0.99658 0.99915 1.00290 0.99482 0.99730 1.00409 1.00093 1.00243 1.01441 0.97624 1.01634 0.98166 0.99911 0.99389 1.06034 0.90438 1.00090 0.99810 0.99981 1.06881 1.00450 0.99870 1.05041 1.01731 0.99911 0.90111 1.03545 1.00166 0.99508 0.90474
S7
γT,ij MARE (%) N 1.03496 3.64 29 1.00176 0.58 215 1.15977 2.54 134 0.99538 0.11 20 0.94861 4.55 1367 1.02834 1.01 3 1.08164 0.81 265 0.96541 0.37 141 1.03769 1.03 308 1.05892 3.39 88 0.93208 2.14 180 0.94381 3.00 33 1.02861 0.69 134 1.01678 0.45 231 0.99703 0.05 15 1.00082 0.17 251 1.20439 3.14 402 1.21149 1.43 76 1.07287 1.12 4 1.00295 0.45 181 1.00548 0.77 254 0.99168 0.17 12 0.90412 0.68 66 0.98279 0.54 49 0.89057 0.85 134 0.91912 0.87 112 0.91179 0.47 112 0.90171 0.77 60 0.89836 2.00 37 0.90319 0.36 23 0.86990 1.02 159 0.99609 0.04 19 1.19119 3.25 42 1.27938 2.01 19 0.95529 1.17 9 1.00198 0.10 13 0.99825 0.14 13 1.00180 0.14 12 1.92729 3.52 26 1.04292 0.50 32 1.00382 0.28 27 1.32514 4.29 168 1.17814 2.63 33 1.03014 1.96 18 0.79118 0.60 52 1.27360 4.99 58 1.02170 1.35 26 1.01727 0.82 19 1.82083 3.98 39 Continued on next page...
Table S2 – continued from previous page Fluid 1 C14 C1CC6 C1CC6 C1CC6 C1CC6 C1CC6 C1CC6 C1CC6 C1CC6 C1CC6 C1CC6 C1CC6 C2BUTENE C2BUTENE C3CC6 C3CC6 C3CC6 C3CC6 C4F10 C4F10 C4F10 C4F10 C4F10 C4F10 C4F10 C5F12 CF3I CF3I CF3I CF3I CF3I CHLORINE CO CO CO CO CO CO CO CO CO CO CO CO2 CO2 CO2 CO2 CO2 CO2
Fluid 2 PROPANE CYCLOHEX EBENZENE ETHANE ETHANOL HEPTANE HEXANE OXYLENE PENTANE PROPANE PXYLENE TOLUENE ETHANOL METHANOL ETHANE H2S NITROGEN PROPANE CO2 DME ETHANE ETHYLENE METHANE PROPANE R365MFC PENTANE ISOBUTAN NITROGEN PROPANE R1234ZE R152A HCL CO2 CYCLOHEX DECANE ETHANE ETHANOL ETHYLENE METHANE MXYLENE NITROGEN OCTANE PXYLENE COS CYCLOPEN DEE DME EBENZENE ETHANE
βT,ij 1.06681 0.99923 1.00104 1.00973 1.02569 0.99972 1.00014 1.00132 1.00254 0.99917 1.00133 0.99987 1.02589 1.02664 1.01912 1.00425 1.01206 1.00516 0.96003 0.95275 0.97199 0.96014 0.98649 0.97499 0.99786 0.97304 1.00200 1.00123 0.99452 1.00346 0.99875 0.99601 0.98414 0.99244 0.95682 0.99829 0.91325 0.96489 0.99378 0.98439 1.00908 0.94829 0.98181 1.00023 1.01592 1.01217 0.99723 1.00091 0.99986
S8
γT,ij MARE (%) N 1.15580 1.83 35 0.99987 0.25 21 0.99289 0.34 81 1.12773 3.21 27 0.90130 4.44 103 0.99780 0.12 167 0.99759 0.21 32 0.99508 0.21 44 1.00312 0.71 45 1.05400 3.06 25 0.99463 0.25 60 0.98708 0.39 349 0.94964 3.88 36 0.90617 4.04 47 1.19500 3.76 26 1.10114 3.40 35 1.69332 4.34 31 1.10943 0.97 27 0.95201 2.49 83 0.86921 1.16 92 0.97003 1.31 84 0.97341 1.63 50 1.12365 3.75 34 0.90987 0.45 37 0.93067 0.65 75 0.89140 1.76 78 0.98459 0.06 28 1.30226 1.28 24 0.98807 0.26 24 0.96604 0.13 44 0.96404 0.30 28 0.96115 1.14 32 1.11798 3.25 105 1.46342 0.89 39 1.79272 2.53 21 1.10196 4.70 53 1.69985 1.75 8 1.09111 0.88 83 0.98372 1.99 108 1.59750 4.78 49 0.99697 1.49 235 1.68304 0.43 43 1.62153 1.19 30 0.94450 0.61 56 0.98308 3.39 263 1.03241 1.61 61 1.03116 1.18 254 1.09145 1.99 95 0.90037 1.09 986 Continued on next page...
Table S2 – continued from previous page Fluid 1 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 COS COS COS CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX
Fluid 2 ETHYLENE H2S HEXANE IPENTANE ISOBUTAN METHANE MSTEARAT NEOPENTN NITROGEN NONANE NOVEC649 OXYGEN OXYLENE PROPANE PROPYLEN PXYLENE R116 R12 R1216 R123 R1234YF R1234ZE R124 R125 R134A R142B R143A R152A R22 R227EA R23 R32 R41 SO2 TOLUENE H2S METHANE PROPANE DMC EBENZENE ETHANE ETHANOL ETHYLENE H2S HEPTANE HEXANE IOCTANE METHANE MXYLENE
βT,ij 1.00402 0.99372 1.02374 1.01718 1.02492 0.98558 0.90151 1.02674 1.01015 1.00033 1.04359 1.00362 1.00114 1.01659 1.01217 1.00340 1.03808 1.01811 1.01687 0.98639 1.01128 1.00219 0.99517 1.01150 1.01036 1.01196 1.02027 1.00224 1.00394 1.00608 1.00402 1.00312 0.99603 1.00511 1.00502 0.99425 1.01619 0.99601 1.00826 1.00430 1.00539 1.02513 1.00126 0.98291 1.00116 1.00102 1.00190 1.01565 1.00315
S9
γT,ij MARE (%) N 0.95576 0.30 268 0.92776 0.86 334 1.01142 4.36 323 0.97686 4.91 372 0.93399 3.33 422 0.97606 2.23 851 1.45262 4.01 26 0.95430 3.31 265 1.12253 1.76 540 1.13485 4.03 98 1.03509 3.66 26 1.04841 2.79 282 1.10292 3.93 102 0.91679 2.25 757 0.93465 2.83 144 1.10430 2.98 119 0.89857 0.28 77 0.95760 0.93 25 0.98477 0.76 28 1.05886 1.26 18 0.98477 1.21 71 1.02234 0.33 8 1.01028 0.56 19 0.96741 3.34 37 1.01129 1.85 137 1.00776 0.68 17 0.98474 0.63 61 1.00646 0.86 164 1.01254 1.14 429 1.00235 0.40 224 0.98470 0.17 245 0.99971 0.75 114 1.00300 0.99 46 1.01070 0.46 22 1.06677 5.00 558 0.94407 0.84 106 1.08482 1.93 22 0.99200 1.06 50 0.92848 0.34 205 0.99414 0.99 51 1.09921 0.80 141 0.90252 4.91 593 1.12037 3.62 83 1.01006 4.75 24 0.99502 0.24 229 0.99297 0.41 205 0.99375 0.21 113 1.32339 3.34 255 0.99328 0.80 53 Continued on next page...
Table S2 – continued from previous page Fluid 1 CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOPEN CYCLOPEN CYCLOPEN CYCLOPRO CYCLOPRO CYCLOPRO CYCLOPRO D2 D2 D2 D2O D4 DECANE DECANE DECANE DECANE DECANE DECANE DECANE DECANE DECANE DECANE DECANE DECANE DECANE DEE DEE DEE DEE DEE DEE DEE DMC DMC DMC DMC DMC DMC
Fluid 2 NITROGEN NONANE OCTANE OXYLENE PENTANE PROPANE PROPYLEN PXYLENE R12 R22 TOLUENE D4 ETHANOL XENON PROPANE R125 R134A XENON HYDROGEN NEON NITROGEN WATER MDM DMC ETHANE ETHANOL ETHYLENE H2S MXYLENE OCTANE OXYLENE PENTANE PROPANE PROPYLEN PXYLENE TOLUENE ETHANOL ETHYLENE HEXANE METHANOL R12 SO2 WATER ETHANOL HEPTANE HEXANE METHANOL NONANE OCTANE
βT,ij 0.99970 0.99583 1.00125 1.00392 1.00050 0.99740 1.00099 1.00184 0.96292 0.99094 1.00176 0.99608 1.06483 1.04856 0.99757 1.01522 1.01623 1.07035 0.99136 0.98882 1.01561 0.99577 1.00174 0.98375 1.04076 0.99423 1.05317 1.00073 1.00035 0.99914 0.99865 1.00207 1.01974 1.04471 0.99899 0.99290 1.00897 1.01111 0.99773 1.00417 0.99569 0.98788 0.96917 1.00298 1.00844 1.00137 0.99772 1.02118 1.01339
S10
γT,ij MARE (%) N 1.47554 4.08 40 1.00655 1.11 12 0.99972 0.90 95 0.99006 0.73 39 0.99588 0.40 48 1.03578 0.64 26 1.04089 0.57 12 0.99198 0.87 79 0.98900 0.03 2 0.97638 4.75 77 0.98779 0.76 504 1.03293 0.39 33 0.89994 4.47 13 1.17726 1.08 10 0.98041 1.85 13 0.91039 0.37 34 0.91325 0.32 31 0.94711 3.05 15 0.99511 0.87 150 0.83393 1.22 78 1.22898 0.43 7 1.00379 1.52 70 0.99969 0.94 29 0.92470 4.14 21 1.25637 3.60 256 0.89711 3.80 28 1.28576 1.88 13 1.11635 4.01 134 0.99369 2.15 44 1.00801 0.46 27 0.99471 0.41 16 1.04930 0.97 17 1.14808 2.52 86 1.19102 0.24 3 0.99262 0.89 57 0.99245 2.80 39 0.97226 3.25 461 1.10874 0.96 32 0.99035 1.19 30 0.94684 2.00 141 1.02787 0.83 36 1.04115 3.70 22 0.84219 2.02 64 0.94120 0.80 184 0.92607 0.63 161 0.92986 0.69 68 0.93765 0.67 427 0.93384 1.74 37 0.92726 0.46 32 Continued on next page...
Table S2 – continued from previous page Fluid 1 DME DME DME DME DME DME DME DME DME DME DME DME DME DME DME DME DME EBENZENE EBENZENE EBENZENE EBENZENE EBENZENE EBENZENE EBENZENE EBENZENE EBENZENE EBENZENE EBENZENE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE
Fluid 2 ETHANOL HEXANE ISOBUTAN METHANE METHANOL PENTANE PROPANE PROPYLEN R125 R134A R143A R22 R227EA R236EA R236FA R32 R40 ETHANOL HEPTANE HEXANE IOCTANE METHANOL MXYLENE NONANE OCTANE OXYLENE PXYLENE TOLUENE ETHYLENE H2S HCL HEPTANE HEXANE IOCTANE ISOBUTAN KRYPTON METHANE MXYLENE NITROGEN OCTANE PENTANE PROPANE PROPYLEN R116 R1216 R14 R218 R23 TOLUENE
βT,ij 0.99876 1.00984 1.00227 1.00956 1.00406 1.03571 0.99761 0.99733 1.00899 0.99604 1.00012 1.01491 1.01575 0.98075 0.98997 0.99399 0.99969 1.01024 1.00040 0.99974 1.00096 1.00109 1.00012 1.00375 1.00078 1.00153 0.99948 1.00288 1.00375 0.98791 0.99182 0.97796 0.99131 0.90358 0.99675 1.00338 0.99828 0.98799 1.00685 0.97742 0.99548 0.99896 0.99928 1.03539 1.01157 1.01483 1.03147 1.00597 0.99540
S11
γT,ij MARE (%) N 1.03610 1.76 96 0.99219 0.92 48 0.96302 0.14 55 1.14009 2.13 23 1.00554 1.96 367 0.99489 1.03 23 0.96354 0.35 89 0.98909 0.17 80 1.03733 1.81 104 1.01372 0.50 88 0.99059 0.46 54 1.07125 1.85 57 1.05765 1.73 34 1.06804 0.64 34 1.04344 1.27 31 0.99941 0.40 122 1.01217 0.11 65 0.90463 1.38 32 0.98665 0.52 151 0.99383 0.09 33 0.98599 0.40 63 0.89432 3.04 20 0.99939 0.35 125 0.98564 0.21 50 0.98584 0.52 76 0.99924 0.57 48 0.99905 0.38 204 1.00252 0.97 78 0.99401 1.40 220 0.90711 1.02 68 0.90586 0.64 115 1.15197 1.73 135 1.11251 1.36 91 1.22877 4.73 5 1.03350 0.85 75 1.04799 1.87 207 1.05658 0.92 678 1.17616 2.32 34 1.10465 3.89 292 1.17986 1.82 88 1.07312 1.20 74 1.01483 1.43 542 1.00560 1.06 88 0.89844 0.26 60 0.93961 1.02 50 0.89216 1.39 29 0.93581 0.88 41 0.87082 0.47 44 1.12756 2.97 44 Continued on next page...
Table S2 – continued from previous page Fluid 1 ETHANE ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE H2S H2S H2S H2S H2S H2S H2S H2S H2S H2S H2S HCL
Fluid 2 XENON ETHYLENE HEPTANE HEXANE IBUTENE IHEXANE IOCTANE METHANOL MM NITROGEN NONANE OCTANE OXYLENE PXYLENE R113 R114 R125 R134A R152A R21 R22 R23 R32 T2BUTENE TOLUENE WATER HEPTANE HEXANE ISOBUTAN METHANE NITROGEN NONANE OCTANE PROPANE PROPYLEN R1216 XENON HEXANE IOCTANE IPENTANE ISOBUTAN METHANE MXYLENE NEOPENTN NONANE PENTANE PROPANE TOLUENE HEXANE
βT,ij 0.99857 1.02189 0.98096 0.97333 0.97566 0.98557 0.98077 1.00177 0.99498 1.04316 1.00808 0.99103 0.98697 0.97813 0.98820 0.95361 1.00462 0.97178 0.96946 0.97987 0.99373 0.90517 0.97558 0.97419 0.98100 0.98199 0.97975 0.99131 0.99619 0.99352 0.99699 0.96742 0.96920 1.00374 1.00207 1.01864 0.99831 1.02518 1.02296 1.02775 1.01810 1.00164 0.97237 1.02548 0.99597 1.03760 1.02326 0.98283 1.01481
S12
γT,ij MARE (%) N 1.00960 0.25 164 1.17065 4.01 50 0.89810 4.97 597 0.90746 4.62 489 0.96241 4.45 54 0.90538 2.82 21 0.89163 3.96 127 0.99902 0.68 569 0.91176 4.90 85 1.63914 4.20 43 0.89624 2.07 35 0.89471 3.52 203 0.90681 0.93 14 0.90590 3.86 190 0.90301 0.78 6 0.93497 3.63 6 1.05044 3.47 11 0.98183 1.85 15 0.97677 1.94 13 0.90692 0.41 4 1.05058 2.59 76 1.05138 2.50 9 1.01657 3.97 22 0.95288 4.01 38 0.90682 1.92 492 0.92479 2.70 3130 1.17970 1.56 162 1.13008 2.86 162 1.05868 0.53 30 1.02333 3.68 166 1.05100 2.06 80 1.26048 2.88 12 1.21808 3.37 35 1.01236 0.72 34 1.01552 1.06 128 0.99653 1.34 46 0.98039 0.10 148 1.00351 4.76 27 1.01015 2.81 19 0.95259 1.54 35 0.93303 1.54 90 0.97750 3.09 225 1.10582 3.33 30 0.93089 1.85 60 1.09406 0.93 30 0.96527 2.86 141 0.90945 0.83 315 1.08325 2.46 27 1.01449 0.93 6 Continued on next page...
Table S2 – continued from previous page Fluid 1 HCL HCL HCL HCL HCL HCL HCL HCL HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE HEXANE HEXANE HEXANE HEXANE HEXANE HEXANE HEXANE HEXANE HEXANE HEXANE HEXANE HEXANE HEXANE HEXANE HEXANE HEXANE HYDROGEN IBUTENE IBUTENE IBUTENE IBUTENE IBUTENE IBUTENE IBUTENE IBUTENE IHEXANE IHEXANE
Fluid 2 METHANOL PROPANE R142B R32 R40 R41 SO2 XENON HEXANE IHEXANE MXYLENE NONANE OCTANE OXYLENE PENTANE PROPANE PROPYLEN PXYLENE R113 R114 R12 TOLUENE IHEXANE IOCTANE IPENTANE MM MXYLENE OCTANE OXYLENE PENTANE PROPANE PROPYLEN PXYLENE R113 R114 R22 TOLUENE XENON NEON ISOBUTAN OCTANE PROPANE R143A R152A R227EA R40 SO2 METHANOL PROPANE
βT,ij 0.90069 1.02143 1.00828 1.00252 0.98451 0.98722 0.99420 0.98264 0.99970 1.00097 0.99846 1.00700 0.99971 0.99904 1.00254 0.99939 0.99114 0.99936 0.99577 0.99215 0.98822 0.99684 0.99954 1.00668 1.00040 0.99500 1.01308 0.98656 1.00096 0.99361 1.00499 1.01641 1.00071 0.99940 0.99629 0.98925 0.99876 1.01959 1.00124 1.00019 0.99296 1.00734 1.00220 1.00080 1.01295 1.00052 0.98640 1.00691 1.00112
S13
γT,ij MARE (%) N 1.65053 1.08 138 0.91760 1.52 150 1.00217 0.56 34 0.99760 0.19 40 1.08265 0.94 12 1.10901 2.51 27 1.05144 1.17 31 0.90579 1.92 23 1.00398 1.27 128 1.00472 0.13 42 0.98960 0.37 48 1.00377 0.30 14 1.00028 0.78 118 0.98672 0.27 71 1.01148 0.51 62 1.07072 1.95 109 1.06264 3.44 63 0.98957 0.25 124 0.99057 0.34 12 0.99663 0.24 12 1.03388 0.43 4 0.98136 0.46 430 0.99860 0.11 53 1.00427 0.83 6 1.00502 0.36 33 1.00697 0.13 18 0.99672 0.42 11 1.02501 2.88 75 1.00154 1.30 12 0.99686 1.93 40 1.04332 0.78 77 1.03815 4.69 9 0.99711 0.28 27 0.98509 0.27 50 0.98179 0.20 12 0.99579 0.90 56 0.98316 0.56 206 1.16656 0.81 21 0.83639 3.21 228 0.99644 0.06 15 1.05350 0.92 13 0.99305 0.56 51 0.94375 0.31 54 0.93949 0.41 67 0.92836 0.41 60 0.97922 0.40 18 0.94224 0.72 53 0.88008 0.97 5 1.03496 0.40 62 Continued on next page...
Table S2 – continued from previous page Fluid 1 IOCTANE IOCTANE IOCTANE IOCTANE IOCTANE IOCTANE IOCTANE IPENTANE IPENTANE IPENTANE IPENTANE IPENTANE IPENTANE ISOBUTAN ISOBUTAN ISOBUTAN ISOBUTAN ISOBUTAN ISOBUTAN ISOBUTAN ISOBUTAN ISOBUTAN ISOBUTAN ISOBUTAN ISOBUTAN ISOBUTAN ISOBUTAN KRYPTON KRYPTON KRYPTON METHANE METHANE METHANE METHANE METHANE METHANE METHANE METHANE METHANOL METHANOL METHANOL METHANOL METHANOL METHANOL METHANOL METHANOL METHANOL METHANOL METHANOL
Fluid 2 MXYLENE NITROGEN OCTANE OXYLENE PROPYLEN PXYLENE TOLUENE NITROGEN PROPANE R23 R245FA R365MFC TOLUENE METHANE PROPANE PROPYLEN R1234YF R1234ZE R125 R13 R134A R143A R152A R227EA R23 R245FA R32 METHANE OXYGEN PROPYLEN N2O NEOPENTN NITROGEN OXYGEN PENTANE PROPANE PROPYLEN SO2 MM MXYLENE OXYGEN R134A R152A R21 R22 R32 SO2 T2BUTENE TOLUENE
βT,ij 0.99628 1.00895 1.00129 0.99859 1.03677 0.99929 0.99502 1.01504 0.99358 0.97157 0.98838 1.01335 1.01022 1.01317 1.00324 1.03014 1.00730 1.00591 0.98858 0.99553 1.00145 1.00047 0.99318 1.01326 0.97853 1.01357 0.97650 0.99962 0.99555 0.99711 0.98876 0.98554 1.00034 1.09752 0.98333 0.99403 0.99563 1.03694 1.02619 0.99745 1.07547 1.00779 1.01147 1.03177 1.00262 0.99300 0.97373 0.97890 0.98203
S14
γT,ij MARE (%) N 1.00160 1.19 22 1.55448 3.32 39 1.00412 1.15 40 0.98905 2.15 37 1.11387 0.36 7 0.99104 2.29 34 0.97790 0.59 438 1.40675 1.92 47 1.00863 1.22 125 0.93001 3.02 26 0.90433 1.01 71 0.92380 0.31 47 0.99749 2.08 17 1.18856 2.86 163 1.00375 1.21 275 1.01260 1.00 33 0.93536 0.16 49 0.92820 0.18 32 0.90644 1.48 130 0.98045 0.48 35 0.89668 1.06 100 0.91950 0.16 16 0.91845 0.73 64 0.90916 0.57 37 0.89794 1.41 25 0.90803 0.58 78 0.86238 1.19 71 0.99368 0.32 177 0.98848 1.89 140 1.08746 3.10 51 1.02354 3.36 49 1.22513 2.64 34 0.97792 1.11 890 2.02364 0.07 3 1.27815 3.95 291 1.13418 2.67 582 1.11748 2.81 81 1.07082 3.52 5 0.90636 1.54 15 0.88973 4.08 11 1.50180 1.81 40 0.98889 3.08 14 0.98828 1.76 15 0.91282 0.74 4 1.03751 2.44 19 1.01175 3.41 17 1.02388 0.96 34 0.90748 4.95 47 0.89100 2.43 236 Continued on next page...
Table S2 – continued from previous page Fluid 1 METHANOL METHANOL MLINOLEA MM MOLEATE MPALMITA MXYLENE MXYLENE MXYLENE MXYLENE MXYLENE MXYLENE N2O NEOPENTN NEOPENTN NITROGEN NITROGEN NITROGEN NITROGEN NITROGEN NONANE NONANE NONANE NONANE NOVEC649 NOVEC649 OCTANE OCTANE OCTANE OCTANE OCTANE OCTANE OCTANE OXYGEN OXYGEN OXYLENE PENTANE PENTANE PENTANE PENTANE PENTANE PENTANE PENTANE PENTANE PENTANE PENTANE PENTANE PROPANE PROPANE
Fluid 2 WATER XENON MPALMITA TOLUENE MSTEARAT PROPANE NONANE OCTANE OXYLENE PROPANE PROPYLEN TOLUENE R125 PENTANE PROPANE OXYGEN PXYLENE R13 R14 R227EA OXYLENE PROPYLEN PXYLENE TOLUENE PENTANE RE347MCC OXYGEN OXYLENE PENTANE PROPANE PXYLENE R12 TOLUENE PROPANE SO2 TOLUENE PROPANE R114 R1234ZE R141B R152A R22 R23 R245FA RE347MCC SF6 TOLUENE PROPYLEN R113
βT,ij 0.99676 0.93558 0.99740 0.99910 0.99882 1.08514 1.00227 1.00031 1.00073 1.00346 1.00655 0.99650 0.97626 1.00050 1.02028 0.99847 0.99471 0.97523 0.97005 0.97134 0.99710 1.01604 1.00061 0.99448 0.96690 0.98723 1.04392 0.99933 0.99572 1.01998 0.99788 0.99653 0.99664 1.00316 0.98436 0.99826 0.99575 0.99646 0.98894 1.00270 0.98932 0.98621 0.96622 1.00687 1.00983 0.97466 1.00052 0.99978 1.00470
S15
γT,ij MARE (%) N 0.96774 3.09 1843 0.77335 0.63 13 0.99543 1.17 8 0.97446 0.75 54 0.99836 0.51 5 1.21332 2.01 83 0.98031 0.26 12 0.99296 0.56 24 0.99997 0.25 78 1.08363 0.88 25 1.09811 2.30 16 0.99601 1.35 70 0.77302 4.72 16 1.00236 0.22 50 1.05910 3.11 84 0.99377 0.85 592 1.63462 4.99 265 1.24069 3.87 78 1.10991 2.77 92 1.40945 0.89 24 0.98501 0.15 40 1.11698 2.06 9 0.99387 0.22 11 0.98072 1.91 13 0.90539 0.21 22 0.97915 0.71 20 1.58412 1.95 42 0.99245 0.84 36 1.02288 2.40 34 1.09275 0.91 12 0.98651 0.20 51 1.06084 0.02 2 0.98036 2.01 236 1.15528 0.81 28 1.18081 2.15 26 1.00209 1.16 67 1.01256 0.87 153 0.97011 0.12 12 0.93824 0.81 28 0.97700 0.12 20 0.92023 1.06 39 0.96034 0.80 29 0.94007 3.01 26 0.89534 1.25 35 0.92810 0.71 25 0.92912 4.96 53 0.99282 0.85 116 0.99350 0.33 348 1.01447 0.22 11 Continued on next page...
Table S2 – continued from previous page Fluid 1 PROPANE PROPANE PROPANE PROPANE PROPANE PROPANE PROPANE PROPANE PROPANE PROPANE PROPANE PROPANE PROPANE PROPANE PROPANE PROPANE PROPANE PROPANE PROPYLEN PROPYLEN PROPYLEN PROPYLEN PROPYLEN PROPYLEN PROPYLEN PROPYLEN PROPYLEN PROPYLEN PROPYLEN PROPYLEN PROPYLEN PROPYLEN PROPYLEN PXYLENE R11 R11 R11 R11 R113 R113 R113 R113 R113 R113 R113 R114 R114 R114 R115
Fluid 2 R114 R116 R1216 R1234ZE R125 R134A R143A R152A R227EA R23 R236EA R236FA R245FA R32 RC318 SO2 TOLUENE XENON PXYLENE R114 R115 R116 R12 R1216 R125 R13 R134A R142B R152A R22 R23 R32 XENON TOLUENE R12 R13 R22 R23 R114 R13 R142B R152A R22 R23 SF6 R12 R22 R23 R125
βT,ij 1.00332 1.01661 1.01214 1.01336 1.00883 1.01148 1.00987 1.01223 1.02125 0.98814 1.02233 1.02204 1.02121 1.00067 1.02377 0.99024 1.00576 1.00491 0.99082 1.01235 1.01487 1.01401 1.00271 1.01903 1.00733 0.99688 1.01360 1.00653 1.01177 1.00095 0.99184 0.99634 0.99031 0.99915 1.00726 0.99697 0.99960 0.97898 0.99859 0.99941 0.99666 0.98806 0.98836 0.97121 1.07569 1.00164 1.00300 0.97633 0.99972
S16
γT,ij MARE (%) N 0.98055 0.17 12 0.89173 0.70 61 0.92233 0.29 35 0.93387 0.39 30 0.89892 0.69 316 0.89674 0.75 179 0.91581 0.46 86 0.92009 1.86 133 0.91449 0.55 188 0.87585 0.77 32 0.92015 0.50 37 0.91493 0.68 43 0.92286 0.55 28 0.86421 0.71 446 0.92320 0.17 55 0.87281 0.68 8 1.04281 2.98 39 1.04133 0.41 22 1.09426 2.66 16 0.97683 0.82 14 0.94167 0.10 19 0.87937 0.25 13 0.98830 0.12 42 0.93686 0.57 127 0.92944 0.34 47 0.95923 0.15 16 0.93494 0.42 23 0.99250 0.52 23 0.94791 1.09 46 0.97836 0.11 35 0.91810 0.70 13 0.90627 0.36 80 1.01223 2.04 51 0.99999 0.54 53 1.00102 0.71 46 1.01419 1.96 130 0.97759 0.98 14 0.94638 1.44 11 1.00476 1.33 29 1.05033 1.02 48 0.98837 0.18 12 0.95473 0.25 12 0.99757 0.47 12 0.98801 1.88 14 1.06961 4.14 22 0.99126 2.40 96 0.96580 3.64 247 0.96230 0.75 12 0.96147 0.16 60 Continued on next page...
Table S2 – continued from previous page Fluid 1 R115 R116 R116 R116 R116 R12 R12 R12 R12 R12 R12 R12 R12 R12 R1216 R1216 R1216 R123 R123 R123 R123 R1234YF R1234YF R1234YF R1234YF R1234YF R1234YF R1234YF R1234ZE R1234ZE R124 R124 R125 R125 R125 R125 R125 R125 R125 R125 R125 R125 R125 R13 R13 R134A R134A R134A R134A
Fluid 2 R22 R134A R143A R22 R23 R1216 R13 R134A R142B R143A R152A R22 R23 RC318 R123 R22 RC318 R134A R22 R32 WATER R125 R134A R143A R152A R161 R227EA R32 R152A R32 R134A R142B R134A R143A R152A R161 R227EA R23 R236EA R236FA R245FA R32 RE143A R14 R23 R141B R142B R143A R152A
βT,ij 1.01422 1.01284 1.01003 0.99671 0.99695 0.99964 0.99071 1.00750 1.01193 0.98590 1.01876 0.99654 0.99206 1.00226 1.00494 0.99593 1.00387 0.99393 0.99482 0.98824 1.09996 0.99915 0.99972 1.00024 0.99630 0.99781 0.99938 0.99143 0.99902 0.99587 0.99881 0.99802 1.00056 0.99911 0.99429 1.01043 1.00101 0.99685 0.99947 0.99960 0.99836 0.99450 1.00105 0.99884 1.00234 1.00716 1.00176 0.99930 0.99979
S17
γT,ij MARE (%) N 0.94989 1.35 189 0.93618 0.69 83 0.93499 0.38 78 0.91302 1.58 12 0.91114 0.56 65 0.97942 0.89 15 0.97345 3.17 151 0.94100 0.06 24 0.97650 1.16 16 0.95199 1.28 48 0.94387 1.03 67 0.96477 1.76 585 0.93086 3.10 36 0.96907 0.76 61 0.97467 0.75 11 0.96186 0.70 69 1.00433 0.85 31 0.98277 1.18 31 1.01277 1.67 56 0.98194 0.80 21 0.95847 0.05 4 0.99876 0.11 56 0.98643 0.20 42 0.99523 0.20 35 0.98112 0.13 50 0.98828 0.23 50 0.99916 0.27 40 0.95802 0.21 73 0.99579 0.21 36 0.97118 2.55 10 0.98961 0.60 17 1.00320 0.12 19 1.00037 0.50 204 1.00558 0.49 100 1.00282 1.40 93 0.99311 1.27 63 1.00302 0.47 38 1.00309 0.42 19 1.01046 0.06 23 1.01028 0.07 14 1.01325 0.17 17 0.98147 0.54 455 1.00517 0.23 21 0.99334 0.68 84 0.93027 0.50 90 0.96823 0.96 38 0.98544 0.11 26 1.00188 0.68 167 1.00246 0.13 91 Continued on next page...
Table S2 – continued from previous page Fluid 1 R134A R134A R134A R134A R134A R134A R134A R134A R134A R14 R14 R142B R142B R143A R143A R143A R143A R143A R152A R152A R152A R152A R161 R161 R218 R218 R22 R22 R227EA R227EA R23 R23 R23 R236EA R236FA R32 R32 R32 R40 R40 R41 R41 SF6 SO2
Fluid 2 R161 R218 R22 R227EA R23 R236FA R245FA R32 RE143A R23 TOLUENE R22 R32 R152A R161 R23 R236FA R32 R22 R227EA R23 R32 R227EA R32 R22 RC318 R23 RC318 R23 R32 R32 SF6 TOLUENE R32 R32 SF6 SO2 TOLUENE R41 XENON TOLUENE XENON XENON TOLUENE
βT,ij 1.00101 0.99885 0.99975 1.00135 1.00246 0.99958 0.99918 0.99493 0.99957 1.01673 0.92032 1.00430 0.98803 0.99955 0.99931 0.99197 0.99911 0.99734 1.00239 1.00880 1.00035 0.99966 1.00966 1.00239 0.98269 1.00386 0.99569 1.05268 0.98860 0.98611 1.00116 0.99445 0.96909 0.99812 0.99365 0.99830 1.00238 1.01598 0.99518 0.96464 0.97539 0.97753 0.96469 1.01133
S18
γT,ij 1.00619 0.92280 0.99196 0.98915 1.02190 1.00198 1.00657 0.99503 0.99594 0.94295 1.18828 1.00646 0.97510 0.99038 0.99556 1.00381 1.01834 0.97488 1.01169 0.99527 1.02378 0.99709 1.02456 0.98909 0.91598 1.04248 0.98752 0.96966 1.00208 0.97064 1.00385 0.91843 1.07054 1.01165 0.99661 0.86502 0.99968 0.98173 0.99810 1.03491 1.09707 0.91395 0.92846 1.02114
MARE (%) 0.29 0.50 0.37 0.21 2.42 0.03 0.14 0.96 0.06 2.61 1.69 1.71 0.92 0.33 0.55 0.72 0.12 0.70 0.99 0.13 1.14 0.92 0.85 0.68 0.71 2.47 1.03 2.24 2.56 0.73 0.36 0.51 0.65 0.38 0.25 0.48 0.20 1.49 0.48 0.83 1.19 2.08 0.61 2.74
N 31 28 102 71 67 15 25 550 24 86 8 320 18 25 109 16 21 143 150 16 16 46 57 96 63 47 92 6 16 62 16 9 9 25 15 12 52 9 11 15 9 31 81 27
Table S3: Tier #2 data for binary coefficients, including the coefficients βT,ij and γT,ij (MARE: median absolute relative error, N : number of bubble point experimental datapoints) Fluid 1 1BUTENE 1BUTENE 1BUTENE 1BUTENE 1BUTENE 1BUTENE 1BUTENE 1BUTENE 1BUTENE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE ACETONE AMMONIA AMMONIA AMMONIA AMMONIA AMMONIA AMMONIA AMMONIA AMMONIA AMMONIA AMMONIA AMMONIA ARGON ARGON ARGON ARGON ARGON ARGON ARGON ARGON ARGON ARGON ARGON ARGON ARGON ARGON
Fluid 2 BENZENE CO CYCLOHEX ETHANOL HYDROGEN ISOBUTAN METHANOL PXYLENE WATER AMMONIA C1CC6 CO EBENZENE HYDROGEN IPENTANE METHANE NITROGEN OCTANE OXYGEN OXYLENE PROPANE PROPYNE R12 CYCLOHEX ETHANOL HELIUM HYDROGEN METHANE METHANOL NEON NITROGEN TOLUENE WATER XENON C11 C12 C14 CO D2O DECANE ETHANOL HELIUM HEPTANE HYDROGEN IOCTANE IPENTANE METHANOL NEON
βT,ij 1.00000 0.99447 1.00000 1.00000 0.98675 1.00007 1.02340 0.96008 0.95073 1.10000 1.00000 1.00000 1.00000 0.97057 1.00000 1.01177 1.06037 1.00000 1.00000 1.00000 0.99404 0.99950 1.00000 0.98531 0.97142 0.88018 1.01569 0.99640 0.90292 1.01445 0.99729 1.00000 0.99441 1.00000 1.00000 1.00000 1.00000 1.05707 0.92822 1.00000 0.90008 0.98293 1.00000 1.00212 1.00000 1.00000 1.01531 0.99735
S19
γT,ij MARE (%) N 1.00448 0.29 4 1.30617 11.00 22 1.01232 0.09 4 0.97263 11.16 21 2.64151 25.75 18 0.99600 0.05 54 0.92118 5.03 25 1.10251 7.44 12 0.72540 64.16 60 1.32348 70.91 3 0.91927 1.08 16 1.41494 7.04 5 0.98023 1.02 15 2.86813 10.75 21 0.91514 0.00 1 1.27000 9.41 27 1.51478 12.52 62 0.93376 4.93 19 1.34127 4.90 9 0.98076 0.56 14 1.02526 6.19 19 1.04116 6.02 18 2.58901 96.47 9 1.52702 98.12 31 1.08108 22.58 117 2.38481 284.37 38 2.67385 70.12 124 2.01940 93.99 62 1.17664 26.00 98 3.47870 83.84 71 2.10058 63.66 57 0.96557 3.34 8 1.15251 7.70 1260 0.98409 7.31 4 1.70314 0.02 1 1.75957 0.00 1 1.84219 0.01 1 0.98564 5.53 43 1.52666 21.20 6 1.65984 0.01 1 1.92336 90.73 5 2.98819 41.21 596 1.50288 0.00 1 1.38790 13.56 196 1.49136 0.00 1 1.19610 0.30 1 1.41701 5.15 4 1.10782 8.95 264 Continued on next page...
Table S3 – continued from previous page Fluid 1 ARGON ARGON ARGON ARGON ARGON BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BENZENE BUTANE BUTANE BUTANE BUTANE BUTANE BUTANE C11 C11 C11 C11 C11 C11 C11 C11 C11 C12 C12 C12 C12 C12 C12 C12 C12 C12
Fluid 2 NONANE OCTANE PENTANE WATER XENON CYCLOPEN DME ETHYLENE HYDROGEN IBUTENE ISOBUTAN NEOPENTN NITROGEN OXYGEN R116 R12 R13 R14 R218 R23 R32 R41 RC318 SO2 WATER ETHANOL HYDROGEN METHANOL NITROGEN RC318 WATER ETHANOL HEXANE KRYPTON METHANE NEON NITROGEN OXYGEN R14 SF6 CO2 DME ETHYLENE HCL HEXANE HYDROGEN KRYPTON METHANE NEON
βT,ij 1.00000 1.00000 1.00000 0.97549 1.00000 1.02703 1.00000 1.01223 1.06573 1.00000 1.00000 1.00000 0.99831 1.00000 1.00000 1.10000 1.07658 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 0.94531 1.02906 0.98381 1.02433 1.01353 1.00000 1.07481 0.98498 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.01109 1.00000 1.05664 1.01007 1.00000 1.02298 1.00000 1.09987 1.00000
S20
γT,ij MARE (%) N 1.61334 0.00 1 1.55673 0.01 1 1.11232 0.30 1 2.90981 82.95 181 0.97846 0.00 1 0.99631 5.35 50 1.03150 0.24 34 1.11992 6.55 235 3.32586 39.79 229 1.00264 0.50 5 0.99187 0.06 4 0.97847 0.58 6 1.49708 30.00 220 1.36875 1.62 19 0.90406 0.36 2 1.43751 672.59 3 1.14419 3686.94 4 1.02989 4.19 14 0.83955 0.78 2 0.99967 2.66 9 0.97041 3.95 9 1.03976 1.65 9 0.84205 7.71 2 0.99383 3.00 19 0.87764 24.41 88 0.94462 6.82 422 2.66756 22.54 107 0.89655 6.71 188 1.36266 18.21 227 0.90716 1.83 8 1.73393 89.12 229 0.91441 5.93 34 1.03982 2.51 12 1.48444 0.01 1 1.54101 0.01 1 2.95915 0.00 1 1.80655 0.00 1 1.66613 0.01 1 1.30785 0.01 1 1.13925 0.01 1 1.22502 8.57 140 1.14655 0.58 34 1.38081 7.72 75 1.23510 6.03 63 1.05477 3.56 12 3.95734 36.01 12 1.52782 0.00 1 1.72946 16.18 108 2.98618 0.00 1 Continued on next page...
Table S3 – continued from previous page Fluid 1 C12 C12 C12 C12 C12 C12 C12 C14 C14 C14 C14 C14 C14 C14 C14 C14 C14 C14 C1CC6 C1CC6 C1CC6 C1CC6 C1CC6 C1CC6 C1CC6 C1CC6 C1CC6 C2BUTENE C3CC6 C3CC6 C4F10 C4F10 C5F12 CHLORINE CHLORINE CHLORINE CHLORINE CO CO CO CO CO CO CO CO CO CO2 CO2 CO2
Fluid 2 NITROGEN OXYGEN PENTANE PROPANE R14 SF6 WATER CO2 CYCLOHEX ETHANE HYDROGEN KRYPTON METHANE NEON NITROGEN OXYGEN R14 SF6 CO2 DMC H2S HYDROGEN IOCTANE METHANE METHANOL MXYLENE NITROGEN T2BUTENE CO2 METHANE CO H2S SF6 R12 R22 R32 SO2 DMC DME H2S HELIUM HEXANE HYDROGEN METHANOL PROPANE WATER CYCLOHEX DECANE DMC
βT,ij 1.03336 1.00000 1.01552 1.01745 1.00000 1.00000 0.90720 1.01370 1.00000 1.07063 0.95187 1.00000 1.09625 1.00000 1.06181 1.00000 1.00000 1.00000 0.98184 1.00000 0.98380 1.03638 0.99997 1.02340 1.02549 1.00000 0.98362 1.00007 0.97991 1.03053 1.04476 0.90282 1.00000 1.00000 1.00000 1.00000 0.99754 1.02533 1.06654 0.99141 1.07911 0.96184 1.01766 1.02074 0.97444 0.99960 1.02425 1.00603 0.98071
S21
γT,ij MARE (%) N 1.95902 17.81 219 1.72104 0.01 1 1.12132 7.91 19 1.19551 7.02 50 1.35629 0.01 1 1.17939 0.01 1 0.75043 11.28 18 1.29496 11.18 79 1.06540 8.47 25 1.37752 5.97 21 3.99221 128.94 12 1.59389 0.00 1 1.89180 52.06 95 2.97044 0.00 1 2.06637 5.76 85 1.80207 0.00 1 1.42750 0.01 1 1.23877 0.01 1 1.02091 6.15 286 0.92695 0.52 7 1.01544 5.12 29 3.26948 20.85 36 0.99637 0.17 42 1.37940 10.49 122 0.86633 6.32 36 0.99602 0.26 26 1.54211 13.35 62 0.99965 0.07 19 1.10417 8.18 43 2.03219 79.23 31 1.40248 6.81 39 0.81372 6.18 45 1.02466 0.00 1 0.96364 0.93 20 0.94418 1.30 21 0.88811 1.73 20 0.94546 7.36 78 1.57948 24.07 24 1.24185 5.78 49 1.03093 8.34 50 3.27919 36.90 55 1.52699 7.03 57 1.44750 34.46 225 1.96092 75.76 59 1.21891 11.26 130 1.35428 53.39 18 1.01294 6.47 273 1.16065 6.44 578 1.12373 6.81 275 Continued on next page...
Table S3 – continued from previous page Fluid 1 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 CO2 COS CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOHEX CYCLOPEN CYCLOPEN D2 D2O D2O D2O D2O D2O D2O D2O D2O DECANE DECANE DECANE DECANE DECANE DECANE DECANE DECANE DECANE DECANE DECANE DECANE
Fluid 2 ETHANOL HELIUM HEPTANE HYDROGEN IOCTANE KRYPTON METHANOL MLINOLEA MOLEATE MPALMITA MXYLENE NEON OCTANE PENTANE WATER METHANOL CYCLOPEN D4 DEE HYDROGEN IBUTENE METHANOL NEOPENTN OXYGEN R13 WATER NITROGEN R245FA HELIUM ETHANE KRYPTON METHANE METHANOL NITROGEN OXYGEN R14 SF6 DME EBENZENE HEXANE HYDROGEN KRYPTON METHANE METHANOL NEON NITROGEN OXYGEN R14 SF6
βT,ij 0.99635 0.92922 1.01291 1.04927 1.02888 1.00000 1.00279 0.90685 0.90396 0.92034 1.00597 1.00000 1.00683 1.01522 0.93681 1.01230 1.00000 1.00000 1.00000 1.09092 1.00000 1.03084 1.00000 1.00000 1.00000 1.09967 1.00346 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.03408 1.00000 1.07874 0.90650 1.00000 1.04491 1.00000 1.00000 1.00000
S22
γT,ij MARE (%) N 1.10179 6.21 1163 3.96147 33.31 130 1.06281 6.43 535 2.18929 30.01 512 1.05408 6.89 156 0.95429 0.12 91 1.06981 5.33 1133 1.47603 7.50 47 1.45725 7.23 95 1.42798 5.46 38 1.10431 5.13 180 1.88142 0.97 89 1.09502 8.75 345 0.98595 5.63 450 1.06104 46.77 1188 1.00647 8.12 53 1.00270 0.02 9 1.00540 1.37 26 0.98399 0.30 14 3.33104 29.53 192 1.01007 0.14 5 0.87262 9.03 263 1.00695 1.06 4 1.39137 5.74 7 1.03637 2.91 3 0.86292 11.27 4 1.41712 6.88 31 0.88879 0.28 12 1.24485 4.73 26 0.93445 34.01 6 1.22034 34.42 7 1.23470 39.30 8 0.97835 2.79 11 1.45932 25.18 8 1.37763 25.67 8 0.93211 20.16 2 0.77427 56.58 9 1.09217 0.58 36 0.98963 1.59 16 1.02897 1.36 12 3.75803 19.59 86 1.45044 0.01 1 1.59681 10.26 267 0.91194 7.70 94 2.88374 0.00 1 1.83158 7.09 270 1.62228 0.01 1 1.27286 0.01 1 1.11345 0.00 1 Continued on next page...
Table S3 – continued from previous page Fluid 1 DECANE DEE DEE DEE DEE DEE DEE DEE DMC DMC DMC DMC DMC DME DME DME DME DME DME EBENZENE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANE ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHANOL ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE ETHYLENE H2S
Fluid 2 WATER ETHANE IPENTANE ISOBUTAN METHANE PENTANE PROPYLEN TOLUENE DME METHANE OXYGEN TOLUENE WATER HYDROGEN NITROGEN SO2 TOLUENE WATER XENON WATER ETHANOL HELIUM HYDROGEN METHANOL MPALMITA MSTEARAT WATER HYDROGEN IPENTANE ISOBUTAN KRYPTON METHANE MXYLENE OXYGEN PENTANE PROPANE PROPYLEN R115 R41 SO2 XENON HYDROGEN IOCTANE KRYPTON METHANOL N2O TOLUENE WATER HEPTANE
βT,ij 0.96728 1.00000 0.99995 1.00000 1.01187 1.00000 1.00000 1.00606 0.98740 1.00000 1.02493 1.00000 0.95516 1.01255 1.09283 0.98570 1.00000 0.99213 1.00000 1.00000 0.99594 0.93671 1.04624 0.95541 0.90842 0.90220 0.93313 1.08611 0.98376 0.97773 1.09023 1.04298 0.98708 1.00000 0.97716 0.99435 1.00926 1.00000 1.00000 1.00000 1.00000 0.96678 0.98713 1.00000 0.98742 1.00000 0.99104 0.95427 1.01322
S23
γT,ij MARE (%) N 0.75477 17.01 22 1.07416 0.28 6 0.98986 0.19 18 0.99791 0.05 47 1.28353 5.89 31 0.98727 0.39 12 1.02643 0.85 12 0.99002 12.27 26 0.99774 9.75 26 1.34015 7.47 6 1.52724 25.63 24 0.97534 0.25 8 0.85447 5.10 23 2.55017 7.29 44 1.30375 10.37 74 1.13935 8.62 130 1.04750 0.59 35 0.95827 29.41 421 1.01975 4.41 8 3.11944 74.78 9 1.10845 6.03 28 3.60074 82.46 124 2.39576 76.37 304 1.09336 24.83 104 1.26613 10.64 20 1.10379 33.33 16 2.39844 95.39 180 3.48931 18.74 60 0.93185 6.00 11 0.96089 7.07 91 1.65665 99.88 12 1.40455 6.00 79 0.91201 8.68 17 1.46023 96.09 7 0.92417 7.37 118 1.01596 12.42 82 1.02194 8.31 52 0.98413 5.64 4 1.06923 3.38 9 1.02995 10.76 16 1.14113 5.20 4 2.44725 90.28 223 1.16674 7.38 15 1.00073 3.36 7 1.11834 9.22 174 0.98020 0.30 9 1.16986 6.54 94 1.00980 54.89 165 1.02333 7.00 124 Continued on next page...
Table S3 – continued from previous page Fluid 1 H2S H2S H2S H2S HCL HCL HCL HCL HCL HCL HCL HELIUM HELIUM HELIUM HELIUM HELIUM HELIUM HELIUM HELIUM HELIUM HELIUM HELIUM HELIUM HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE HEXANE HEXANE HEXANE HEXANE HEXANE HEXANE HEXANE HEXANE HEXANE HEXANE HEXANE HYDROGEN HYDROGEN HYDROGEN HYDROGEN
Fluid 2 HYDROGEN METHANOL NITROGEN WATER HEPTANE IOCTANE N2O OCTANE PENTANE R14 WATER HYDROGEN ISOBUTAN METHANE MXYLENE NEON NITROGEN OXYGEN PROPANE R12 R22 TOLUENE WATER HYDROGEN IOCTANE KRYPTON METHANE METHANOL NEON NITROGEN OXYGEN R13 R14 SF6 HYDROGEN KRYPTON METHANE METHANOL NEON NITROGEN OXYGEN R14 R245FA SF6 WATER IOCTANE ISOBUTAN METHANE METHANOL
βT,ij 0.95369 1.00974 0.95384 0.96408 1.00000 1.00000 1.00000 1.00000 1.00000 1.08347 0.90820 1.00453 1.11102 1.06900 1.12462 0.97780 1.05837 0.96374 1.10594 0.94099 1.08391 1.14744 1.12101 1.01390 1.00005 1.00000 1.04281 0.98493 1.00000 1.04893 1.00000 1.00000 1.00000 1.00000 1.03163 1.00000 1.03231 1.00521 1.00000 1.00739 1.00000 1.00000 1.00000 1.00000 0.93299 1.02765 1.00975 1.05598 0.97956
S24
γT,ij MARE (%) N 2.07954 19.91 11 1.03824 5.08 73 0.95256 6.96 72 1.01399 36.01 156 1.06484 0.00 1 0.84343 0.00 1 0.97917 0.20 23 1.09939 0.01 1 0.99423 0.00 1 0.92749 21.54 8 3.11534 11.52 146 0.96138 12.65 173 2.99315 216975.50 37 3.43642 53.15 701 1.99456 18893.92 20 1.64856 19.22 58 2.85932 37.78 859 3.62583 65.52 159 3.10440 12750.14 62 3.74933 5.60 36 3.00677 63.84 8 2.19219 21581.51 20 3.26831 51.93 86 3.15086 6.34 50 1.00073 0.04 31 1.33007 0.01 1 1.43174 10.81 216 0.86767 11.11 166 2.57547 0.00 1 1.72180 36.51 315 1.46300 3.44 2 1.08559 0.40 2 1.14517 0.00 1 1.02113 0.01 1 3.13449 20.32 173 1.18219 0.00 1 1.35094 7.54 457 0.86981 8.09 559 2.44826 0.00 1 2.91931 90.23 142 1.45076 31.82 3 1.14268 0.00 1 0.89567 2.65 12 0.86243 0.00 1 1.39191 89.79 37 3.08168 11.05 75 2.42731 6.73 22 1.51528 15.09 491 3.21871 30.28 179 Continued on next page...
Table S3 – continued from previous page Fluid 1 HYDROGEN HYDROGEN HYDROGEN HYDROGEN HYDROGEN HYDROGEN HYDROGEN HYDROGEN HYDROGEN IBUTENE IBUTENE IHEXANE IHEXANE IOCTANE IOCTANE IOCTANE IOCTANE IOCTANE IOCTANE IOCTANE IOCTANE IPENTANE IPENTANE ISOBUTAN ISOBUTAN ISOBUTAN ISOBUTAN KRYPTON KRYPTON KRYPTON KRYPTON KRYPTON KRYPTON METHANE METHANE METHANE METHANE METHANE METHANE METHANE METHANE METHANE METHANOL METHANOL METHANOL METHANOL METHANOL METHANOL METHANOL
Fluid 2 MPALMITA MXYLENE NITROGEN OCTANE PENTANE PROPANE PROPYLEN TOLUENE WATER METHANOL WATER OCTANE R245FA KRYPTON METHANE METHANOL NEON OXYGEN R14 SF6 SO2 METHANE METHANOL METHANOL NITROGEN R236FA WATER METHANOL NEON NONANE OCTANE WATER XENON METHANOL MXYLENE NONANE OCTANE R12 R14 R22 TOLUENE WATER MOLEATE NITROGEN NONANE OCTANE OXYLENE PENTANE PROPANE
βT,ij 1.09627 1.04758 1.02625 1.00443 0.98907 1.01245 0.99826 1.02377 1.00140 1.02859 1.00000 0.99993 1.00000 1.00000 1.00000 1.01748 1.00000 1.00000 1.00000 0.97613 1.00000 1.09077 1.00381 1.03092 1.00265 1.00000 0.92291 0.93986 0.92749 1.00000 1.00000 0.94451 0.99998 0.96013 0.96144 0.94146 0.94646 0.90422 1.00000 0.90227 0.98181 0.93570 1.05710 1.03264 1.09794 1.05273 0.98125 0.99709 0.98590
S25
γT,ij MARE (%) N 3.96775 436.52 60 3.18976 14.40 119 1.36379 26.37 254 3.31767 13.86 138 2.89007 18.98 30 2.42846 30.56 139 2.34534 18.54 46 3.18126 17.04 102 3.45786 79.62 72 0.91943 5.18 61 0.71977 0.00 1 1.00943 1.11 71 0.89887 0.44 12 1.31855 0.00 1 1.35899 0.00 1 0.86272 5.35 8 2.54963 0.00 1 1.45674 1.95 5 1.13271 0.00 1 1.15212 91.23 7 0.92492 15.79 9 1.29129 9.55 50 0.90155 6.15 29 0.90255 5.67 142 1.29294 5.86 141 0.90682 1.65 13 0.86893 30.91 12 1.34404 6.84 8 2.42520 90.01 128 1.41323 0.01 1 1.37093 0.00 1 2.39986 89.18 49 1.00805 1.25 132 1.35227 16.81 208 1.46468 7.51 54 1.54436 10.84 173 1.47424 5.64 125 2.02698 162.59 35 0.91301 3.05 13 1.26415 29.09 56 1.39271 16.11 205 1.29757 46.74 284 1.09443 10.94 20 1.55286 5.59 150 0.89380 5.56 103 0.87538 8.94 123 0.90694 6.48 30 0.88892 10.18 92 0.95671 11.93 105 Continued on next page...
Table S3 – continued from previous page Fluid 1 METHANOL METHANOL METHANOL METHANOL METHANOL METHANOL METHANOL METHANOL MPALMITA MXYLENE MXYLENE MXYLENE MXYLENE MXYLENE MXYLENE MXYLENE MXYLENE N2O N2O N2O N2O N2O NEON NEON NEON NEON NEON NEON NEON NEON NEOPENTN NEOPENTN NITROGEN NITROGEN NITROGEN NITROGEN NITROGEN NITROGEN NITROGEN NITROGEN NITROGEN NITROGEN NONANE NONANE NONANE NONANE OCTANE OCTANE OCTANE
Fluid 2 PROPYLEN PXYLENE R113 R115 R125 R23 R40 R41 MSTEARAT NITROGEN PXYLENE R14 R23 R32 R41 SO2 WATER NITROGEN OXYGEN R41 WATER XENON NITROGEN NONANE OCTANE OXYGEN R13 R14 WATER XENON NITROGEN WATER NONANE OCTANE PENTANE PROPANE PROPYLEN R12 R22 SO2 TOLUENE WATER OXYGEN PROPANE R14 SF6 PROPYLEN PROPYNE R13
βT,ij 0.99720 0.98739 1.00000 1.00000 1.07314 0.98394 0.97078 1.00000 0.99015 1.01001 1.00006 1.00000 1.00000 1.00000 1.00000 0.99622 1.04669 1.09449 1.03393 1.00000 0.97502 1.00000 0.94761 1.00000 1.00000 0.96269 1.02019 1.01237 1.06887 0.95939 1.08037 1.00000 0.98671 0.99756 0.95563 0.98478 0.97087 0.98951 0.94217 1.02736 0.98492 1.00887 1.00000 1.00000 1.00000 1.00000 1.00345 0.97259 1.00000
S26
γT,ij MARE (%) N 0.98606 8.34 60 0.89529 7.01 60 0.90186 2.17 22 0.92338 5.12 4 1.07688 7.10 14 1.08852 7.23 67 0.97914 5.57 43 1.03903 8.17 8 0.98959 7.86 48 1.62786 6.40 53 0.99957 0.48 44 1.15525 0.62 9 0.97871 6.30 9 1.02930 1.25 9 1.10305 0.96 9 1.04288 6.59 27 0.87383 6.62 21 1.15194 10.87 63 1.09127 5.88 53 0.99435 0.79 28 1.02227 6.68 14 0.93739 1.24 14 1.23021 23.31 175 2.79941 0.00 1 2.68761 11.71 2 1.18582 9.72 225 2.12890 20.90 26 2.28862 38.99 27 2.22412 42.77 28 2.67561 93.42 122 1.32541 60.08 121 0.59742 0.00 1 1.75784 13.06 83 2.80226 87.81 113 1.47427 7.56 115 1.22231 5.98 196 1.24370 12.47 59 1.32449 13.84 20 1.30233 6.27 119 1.20420 5.55 51 1.55881 10.37 75 2.69483 97.52 259 1.57413 0.01 1 1.14177 4.87 5 1.23337 0.00 1 1.08530 0.01 1 1.11158 5.98 17 1.01908 7.69 26 1.11600 0.61 3 Continued on next page...
Table S3 – continued from previous page Fluid 1 OCTANE OCTANE OCTANE OXYGEN OXYGEN OXYGEN OXYLENE OXYLENE OXYLENE PENTANE PENTANE PROPANE PROPANE PROPANE PROPANE PROPYLEN PROPYLEN PROPYLEN PROPYNE PXYLENE R114 R116 R116 R116 R12 R1216 R124 R134A R14 R14 R14 R141B R142B R143A R152A R152A R152A R161 R22 R22 R23 R32 R40 R41 SF6 SO2 WATER
Fluid 2 R14 SF6 WATER PENTANE TOLUENE WATER PXYLENE R22 WATER R12 WATER PROPYNE R115 R22 WATER R14 TOLUENE WATER WATER WATER R115 R1216 R32 XENON R32 TOLUENE RC318 WATER R41 WATER XENON R142B R152A R22 R218 R245FA WATER TOLUENE R32 WATER WATER R40 WATER WATER WATER WATER XENON
βT,ij 1.00000 1.06769 1.02749 1.00000 1.00565 1.07118 0.99994 1.02143 1.00000 1.00000 0.90984 1.00000 1.00000 1.00000 0.91995 1.08723 1.00738 0.92795 0.98126 0.90162 0.98910 0.90029 1.00000 1.00000 1.00000 0.98327 1.00000 0.95817 1.00000 1.06743 1.00000 1.00000 1.00000 1.00000 0.98904 0.99996 0.93514 1.00500 1.00000 0.98492 0.91677 1.00000 0.99270 1.02127 0.90722 1.04687 0.97080
S27
γT,ij 1.18894 1.11392 0.82231 1.43446 1.43578 2.69181 0.99975 1.11123 3.14024 3.21270 1.19213 0.90121 0.94333 0.94236 1.60750 0.97558 1.06479 0.87415 0.89083 0.87970 1.02268 1.03711 0.85639 0.91058 0.90631 0.99024 0.96751 0.83723 0.91470 0.84047 0.86623 0.99702 0.97178 1.00048 0.87645 1.01051 0.91198 1.06506 0.99347 0.89479 1.02714 0.95649 0.98898 0.98472 0.81643 0.89761 2.09846
MARE (%) 1.23 2169.04 9.66 0.00 26.15 88.91 0.21 13.52 59.90 92.58 36.30 3.03 0.00 0.00 81.86 20.35 9.46 70.55 29.46 13.89 5.60 39.26 0.74 9.56 0.26 19.18 0.82 52.57 2.23 14.81 3.07 0.26 0.82 0.02 5.70 0.36 45.71 5.18 0.15 38.64 42.97 0.53 15.76 8.88 32.12 19.27 74.53
N 4 4 22 1 91 132 59 93 10 9 48 3 1 1 499 60 67 313 40 21 18 11 12 7 14 8 11 6 2 3 8 11 8 9 83 28 10 16 11 12 6 11 7 48 14 74 71
3
Deviation plots for the binary pairs
In each of the following figures, the error in the predicted bubble-point pressure (using the binary interaction parameters βT,ij and γT,ij from this work) is plotted against the temperature. The sources of the experimental data are listed in section 4.
S28
1BUTENE+BENZENE
1BUTENE+BUTANE
1BUTENE+CO
1BUTENE+CO2
201BUTENE+CYCLOHEX 10 0 10 20
1BUTENE+DME
1BUTENE+ETHANOL
201BUTENE+ETHYLENE 10 0 10 20
1BUTENE+HYDROGEN
1BUTENE+ISOBUTAN
201BUTENE+METHANOL 10 0 10 20
1BUTENE+PROPYLEN
1BUTENE+PXYLENE
1BUTENE+R1216
1BUTENE+R32
1BUTENE+WATER
260 280 300 320 340 360 380
240 260 280 300 320 340 360 380 400 420
260 280 300 320 340 360 380 400 420
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 1BUTENE+ACETONE 10 0 10 20 20 10 0 10 20
20 10 0 10 20
1BUTENE+C4F10
T (K)
T (K)
S29
T (K)
ACETONE+BENZENE
ACETONE+BUTANE
ACETONE+C14
ACETONE+C1CC6
20ACETONE+C2BUTENE 10 0 10 20
ACETONE+CO
ACETONE+CO2
20ACETONE+CYCLOHEX 10 0 10 20
ACETONE+DECANE
ACETONE+DEE
ACETONE+EBENZENE
ACETONE+ETHANE
20 ACETONE+ETHANOL 10 0 10 20
ACETONE+ETHYLENE
ACETONE+H2S
260 280 300 320 340 360 380 400 420 440
200 250 300 350 400 450 500 550
200 250 300 350 400 450 500
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 ACETONE+AMMONIA 10 0 10 20 20 10 0 10 20
20 10 0 10 20
ACETONE+C12
ACETONE+DMC
T (K)
T (K)
S30
T (K)
ACETONE+METHANE ACETONE+METHANOL
20ACETONE+NITROGEN 10 0 10 20
ACETONE+NONANE
ACETONE+OCTANE
ACETONE+OXYGEN
ACETONE+OXYLENE
ACETONE+PENTANE
20 ACETONE+PROPANE 10 0 10 20
ACETONE+PROPYLEN
ACETONE+PROPYNE
240 260 280 300 320 340 360 380
20 10 0 10 20
T (K)
T (K)
S31
T (K)
450
20ACETONE+ISOBUTAN 10 0 10 20
400
ACETONE+IPENTANE
350
ACETONE+IOCTANE
300
20 ACETONE+IBUTENE 10 0 10 20
250
ACETONE+HYDROGEN
200
ACETONE+HEXANE
200 250 300 350 400 450 500
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 ACETONE+HEPTANE 10 0 10 20
ACETONE+R113
ACETONE+R12
ACETONE+SO2
ACETONE+T2BUTENE
20ACETONE+TOLUENE 10 0 10 20
ACETONE+WATER
AMMONIA+ARGON
20AMMONIA+BENZENE 10 0 10 20
AMMONIA+BUTANE
AMMONIA+CYCLOHEX
20AMMONIA+ETHANOL 10 0 10 20
AMMONIA+HELIUM
AMMONIA+HEXANE
20AMMONIA+HYDROGEN 10 0 10 20
AMMONIA+KRYPTON
AMMONIA+METHANE
200 250 300 350 400 450 500 550
250 300 350 400 450 500 550 600
450
T (K)
400
350
300
ACETONE+R22
250
20 10 0 10 20
200
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 ACETONE+PXYLENE 10 0 10 20
T (K)
S32
T (K)
AMMONIA+PROPYLEN
AMMONIA+PROPYNE
AMMONIA+R125
AMMONIA+R13
AMMONIA+TOLUENE
AMMONIA+WATER
AMMONIA+XENON
ARGON+BENZENE
ARGON+BUTANE
ARGON+C11
ARGON+C12
180 200 220 240 260 280 300 320 340 360
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
T (K)
T (K)
S33
T (K)
450
20AMMONIA+PROPANE 10 0 10 20
400
AMMONIA+PENTANE
350
AMMONIA+OCTANE
300
20AMMONIA+NITROGEN 10 0 10 20
250
AMMONIA+NEON
200
AMMONIA+MXYLENE
100 200 300 400 500 600 700
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20AMMONIA+METHANOL 10 0 10 20
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
ARGON+C14
ARGON+CO
ARGON+CO2
ARGON+CYCLOPEN
ARGON+D2O
ARGON+DECANE
ARGON+ETHANE
ARGON+ETHANOL
ARGON+HELIUM
ARGON+HEPTANE
ARGON+HEXANE
ARGON+HYDROGEN
ARGON+IOCTANE
ARGON+IPENTANE
ARGON+KRYPTON
ARGON+METHANE
ARGON+METHANOL
ARGON+NEON
50 100 150 200 250 300 350 400 450 50 100 150 200 250 300 350 50 100 150 200 250 300 350
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
T (K)
S34
T (K)
ARGON+NITROGEN
ARGON+NONANE
ARGON+OCTANE
ARGON+OXYGEN
ARGON+PENTANE
ARGON+R22
ARGON+WATER
ARGON+XENON
BENZENE+BUTANE
BENZENE+C12
BENZENE+C14
BENZENE+C1CC6
BENZENE+CO
BENZENE+CO2
20BENZENE+CYCLOHEX 10 0 10 20
BENZENE+CYCLOPEN
BENZENE+D4
200 250 300 350 400 450 500
0 100 200 300 400 500 600 700
50 100 150 200 250 300 350 400 450
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 ARGON+NEOPENTN 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
T (K)
T (K)
S35
T (K)
BENZENE+DEE
BENZENE+DMC
BENZENE+DME
BENZENE+EBENZENE
BENZENE+ETHANE
20 BENZENE+ETHANOL 10 0 10 20
BENZENE+ETHYLENE
BENZENE+H2S
20 BENZENE+HEPTANE 10 0 10 20
BENZENE+HEXANE
BENZENE+HYDROGEN
20 BENZENE+IBUTENE 10 0 10 20
BENZENE+IHEXANE
BENZENE+IOCTANE
20BENZENE+ISOBUTAN 10 0 10 20
BENZENE+MEA
BENZENE+METHANE
250 300 350 400 450 500 550 600
150 200 250 300 350 400 450 500 550 600
150 200 250 300 350 400 450 500 550
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
BENZENE+DECANE
20 10 0 10 20 20 10 0 10 20
T (K)
T (K)
S36
T (K)
BENZENE+MXYLENE
BENZENE+NEOPENTN
20BENZENE+NITROGEN 10 0 10 20
BENZENE+NONANE
BENZENE+OCTANE
20 BENZENE+OXYGEN 10 0 10 20
BENZENE+OXYLENE
BENZENE+PENTANE
20 BENZENE+PROPANE 10 0 10 20
BENZENE+PROPYLEN
BENZENE+PXYLENE
BENZENE+R113
BENZENE+R114
BENZENE+R116
BENZENE+R12
BENZENE+R13
BENZENE+R14
250 300 350 400 450 500 550 600
250 300 350 400 450 500 550
250 300 350 400 450 500 550
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20BENZENE+METHANOL 10 0 10 20
20 10 0 10 20 20 10 0 10 20
T (K)
T (K)
S37
T (K)
20 10 0 10 20 20 10 0 10 20
BENZENE+R218
BENZENE+R22
BENZENE+R23
BENZENE+R32
BENZENE+R41
BENZENE+RC318
BENZENE+SO2
BENZENE+TOLUENE
BENZENE+WATER
BUTANE+C14
BUTANE+C2BUTENE
BUTANE+CO2
BUTANE+DECANE
BUTANE+DME
BUTANE+ETHANOL
BUTANE+ETHYLENE
20 BUTANE+CYCLOHEX 10 0 10 20
500
T (K)
450
400
350
BUTANE+ETHANE
300
20 10 0 10 20
200 250 300 350 400 450 500 550 600 200 250 300 350 400 450 500 550 600 650
20 10 0 10 20
250
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
S38
T (K)
20 10 0 10 20 20 10 0 10 20
BUTANE+H2S
BUTANE+HCL
BUTANE+HELIUM
BUTANE+HEPTANE
BUTANE+HEXANE
BUTANE+HYDROGEN
BUTANE+IBUTENE
BUTANE+ISOBUTAN
BUTANE+METHANE
BUTANE+MPALMITA
BUTANE+NITROGEN
BUTANE+OCTANE
BUTANE+PENTANE
BUTANE+PROPANE
BUTANE+R113
BUTANE+R125
BUTANE+R13
20 BUTANE+METHANOL 10 0 10 20 20 10 0 10 20 20 10 0 10 20
150 200 250 300 350 400 450 500 550 600 200 250 300 350 400 450 500 550 100 150 200 250 300 350 400 450
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
T (K)
S39
T (K)
BUTANE+RC318
BUTANE+T2BUTENE
BUTANE+WATER
C11+CO2
C11+ETHANE
C11+ETHANOL
C11+HELIUM
C11+HEXANE
C11+KRYPTON
C11+METHANE
C11+METHANOL
T (K)
S40
T (K)
260 280 300 320 340 360 380 400 420 440
BUTANE+R32
450
BUTANE+R245FA
400
20 10 0 10 20
BUTANE+R23
350
20 10 0 10 20
BUTANE+R227EA
300
20 10 0 10 20
BUTANE+R152A
250
20 10 0 10 20
BUTANE+R143A
200
20 10 0 10 20
BUTANE+R134A
200 300 400 500 600 700 800
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
C12+CYCLOHEX
C12+DECANE
C12+DME
C12+ETHANE
C12+ETHYLENE
C12+H2S
C12+HCL
C12+HELIUM
T (K)
S41
T (K)
150 200 250 300 350 400 450
C12+CO2
400
C12+CO
350
C11+SF6
300
C11+R14
250
C11+PXYLENE
200
C11+OXYLENE
150
20 10 0 10 20
C11+OXYGEN
450
20 10 0 10 20
C11+NITROGEN
400
20 10 0 10 20
C11+NEON
350
20 10 0 10 20
C11+MXYLENE
300
20 10 0 10 20
250
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
C12+HEXANE
C12+HYDROGEN
C12+KRYPTON
C12+METHANE
C12+METHANOL
C12+N2O
C12+NEON
C12+NITROGEN
C12+OCTANE
C12+OXYGEN
C12+PENTANE
C12+PROPANE
C12+R14
C12+SF6
C12+TOLUENE
C12+WATER
C14+CO2
T (K)
250 300 350 400 450 500 550 600 650 250 300 350 400 450 500 550 600
20 10 0 10 20
C12+HEPTANE
200 250 300 350 400 450 500
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
S42
T (K)
C14+SF6
C1CC6+CO2
C1CC6+CYCLOHEX
C1CC6+DMC
C1CC6+EBENZENE
C1CC6+ETHANE
T (K)
S43
T (K)
T (K)
500
C14+R14
450
C14+PROPANE
400
C14+OXYGEN
350
C14+NITROGEN
300
C14+NEON
250
C14+METHANOL
500
C14+METHANE
450
20 10 0 10 20
C14+KRYPTON
400
20 10 0 10 20
C14+HYDROGEN
350
20 10 0 10 20
C14+HELIUM
300
20 10 0 10 20
C14+ETHANE
250
20 10 0 10 20
C14+CYCLOHEX
250 300 350 400 450 500 550
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
C1CC6+H2S
C1CC6+HEPTANE
C1CC6+HEXANE
C1CC6+HYDROGEN
C1CC6+IOCTANE
C1CC6+METHANE
C1CC6+METHANOL
C1CC6+MXYLENE
20 C1CC6+NITROGEN 10 0 10 20
C1CC6+OXYLENE
C1CC6+PENTANE
C1CC6+PROPANE
C1CC6+PXYLENE
C1CC6+TOLUENE
20 10 0 10 20 20 10 0 10 20
S44
250 300 350 400 450 500 550
500
T (K)
450
T (K)
400
C2BUTENE+METHANOL C2BUTENE+T2BUTENE
350
20C2BUTENE+ETHANOL 10 0 10 20
300
20 10 0 10 20
150 200 250 300 350 400 450 500
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
C1CC6+ETHANOL
20 10 0 10 20
T (K)
C4F10+H2S
C4F10+METHANE
C4F10+PROPANE
C4F10+R365MFC
C5F12+PENTANE
C5F12+SF6
CF3I+ISOBUTAN
T (K)
S45
T (K)
T (K)
500
C4F10+ETHYLENE
450
C4F10+ETHANE
400
C4F10+DME
350
C4F10+CO2
300
C4F10+CO
250
C3CC6+PROPANE
500
20 10 0 10 20
C3CC6+NITROGEN
450
20 10 0 10 20
C3CC6+METHANE
400
20 10 0 10 20
C3CC6+H2S
350
20 10 0 10 20
C3CC6+ETHANE
300
20 10 0 10 20
C3CC6+CO2
200 250 300 350 400 450 500 550 600 250
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
CHLORINE+R22
CHLORINE+R32
CHLORINE+SO2
CO+CO2
CO+CYCLOHEX
CO+DECANE
CO+DMC
CO+DME
CO+ETHANE
CO+ETHANOL
CO+ETHYLENE
CO+H2S
T (K)
S46
T (K)
100 150 200 250 300 350 400
CHLORINE+R12
450
20 10 0 10 20
CHLORINE+HCL
400
20 10 0 10 20
CF3I+R152A
350
20 10 0 10 20
CF3I+R1234ZE
300
20 10 0 10 20
CF3I+PROPANE
250
20 10 0 10 20
CF3I+NITROGEN
220 240 260 280 300 320 340 360 380 200
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
CO+HELIUM
CO+HEXANE
CO+HYDROGEN
CO+METHANE
CO+METHANOL
CO+MXYLENE
CO+NITROGEN
CO+OCTANE
CO+PROPANE
CO+PXYLENE
CO+WATER
CO2+COS
CO2+CYCLOHEX
CO2+CYCLOPEN
CO2+CYCLOPRO
CO2+DECANE
CO2+DEE
CO2+DMC
0 100 200 300 400 500 600 200 250 300 350 400 450 500 550 600 50 100 150 200 250 300 350 400 450
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
T (K)
S47
T (K)
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
CO2+EBENZENE
CO2+ETHANE
CO2+ETHANOL
CO2+ETHYLENE
CO2+H2S
CO2+HELIUM
CO2+HEPTANE
CO2+HEXANE
CO2+HYDROGEN
CO2+IOCTANE
CO2+IPENTANE
CO2+ISOBUTAN
CO2+KRYPTON
CO2+METHANE
CO2+METHANOL
CO2+MLINOLEA
CO2+MOLEATE
T (K)
150 200 250 300 350 400 450 500 550 50 100 150 200 250 300 350 400 450 500
20 10 0 10 20
CO2+DME
200 250 300 350 400 450 500
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
S48
T (K)
CO2+NEOPENTN
CO2+NITROGEN
CO2+NONANE
CO2+NOVEC649
CO2+OCTANE
CO2+OXYGEN
CO2+OXYLENE
CO2+PENTANE
CO2+PROPANE
CO2+PROPYLEN
CO2+PXYLENE
CO2+R116
CO2+R12
CO2+R1216
150 200 250 300 350 400 450
200 250 300 350 400 450 500 550 600
T (K)
450
20 10 0 10 20
CO2+NEON
400
20 10 0 10 20
CO2+MXYLENE
350
20 10 0 10 20
CO2+MSTEARAT
300
20 10 0 10 20
CO2+MPALMITA
250
20 10 0 10 20
200
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
S49
T (K)
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
CO2+R123
CO2+R1234YF
CO2+R1234ZE
CO2+R124
CO2+R125
CO2+R134A
CO2+R142B
CO2+R143A
CO2+R152A
CO2+R22
CO2+R227EA
CO2+R23
CO2+R32
CO2+R41
CO2+SO2
CO2+TOLUENE
CO2+WATER
COS+H2S
200 250 300 350 400 450 500 550 600 100 200 300 400 500 600 700 220 240 260 280 300 320 340 360
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
T (K)
S50
T (K)
COS+METHANOL
COS+PROPANE
CYCLOHEX+CYCLOPEN 20 10 0 10 20
CYCLOHEX+D4
CYCLOHEX+DEE
20 10 0 10 20
CYCLOHEX+DMC
CYCLOHEX+H2S
20CYCLOHEX+HEPTANE 10 0 10 20
CYCLOHEX+HEXANE CYCLOHEX+HYDROGEN
20CYCLOHEX+IBUTENE 10 0 10 20
CYCLOHEX+IOCTANE
CYCLOHEX+METHANE
150 200 250 300 350 400 450 500 550
CYCLOHEX+ETHYLENE
100 150 200 250 300 350 400 450
20CYCLOHEX+ETHANOL 10 0 10 20
CYCLOHEX+EBENZENE CYCLOHEX+ETHANE
260 280 300 320 340 360 380
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
COS+METHANE
20 10 0 10 20
T (K)
T (K)
S51
T (K)
10 0 10 20
CYCLOHEX+OCTANE
20CYCLOHEX+OXYGEN 10 0 10 20
CYCLOHEX+OXYLENE
CYCLOHEX+PENTANE
20CYCLOHEX+PROPANE 10 0 10 20
CYCLOHEX+PROPYLEN CYCLOHEX+PXYLENE
CYCLOPEN+D4
T (K)
500
CYCLOHEX+WATER
450
20CYCLOHEX+TOLUENE 10 0 10 20
400
CYCLOHEX+R22
350
CYCLOHEX+R13
20 10 0 10 20
300
CYCLOHEX+R12
200 250 300 350 400 450 500 550
CYCLOHEX+NONANE
250 300 350 400 450 500 550
CYCLOHEX+NITROGEN 20 10 0 10 20
250
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
CYCLOHEX+METHANOL CYCLOHEX+MXYLENE CYCLOHEX+NEOPENTN 20
T (K)
S52
T (K)
CYCLOPEN+NITROGEN
CYCLOPEN+R245FA
20 CYCLOPEN+XENON 10 0 10 20
CYCLOPRO+PROPANE
CYCLOPRO+R125
CYCLOPRO+R134A
CYCLOPRO+XENON
D2+HELIUM
D2+HYDROGEN
D2+NEON
D2+NITROGEN
D2O+ETHANE
D2O+KRYPTON
D2O+METHANE
D2O+METHANOL
D2O+NITROGEN
D2O+OXYGEN
0 50 100 150 200 250 300 350 400
0 50 100 150 200 250 300 350 400 450
0 50 100 150 200 250 300 350
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20CYCLOPEN+ETHANOL 10 0 10 20
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
T (K)
T (K)
S53
T (K)
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
D2O+R14
D2O+SF6
D2O+WATER
D4+MDM
DEA+MEA
DEA+METHANOL
DEA+SO2
DEA+WATER
DECANE+DMC
DECANE+DME
DECANE+EBENZENE
DECANE+ETHANE
DECANE+ETHANOL
DECANE+ETHYLENE
DECANE+H2S
DECANE+HELIUM
DECANE+HEXANE
DECANE+HYDROGEN
280 300 320 340 360 380 400 420 440 460 150 200 250 300 350 400 450 500 100 200 300 400 500 600 700
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
T (K)
S54
T (K)
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
DECANE+KRYPTON
DECANE+METHANE
DECANE+METHANOL
DECANE+MXYLENE
DECANE+NEON
DECANE+NITROGEN
DECANE+OCTANE
DECANE+OXYGEN
DECANE+OXYLENE
DECANE+PENTANE
DECANE+PROPANE
DECANE+PROPYLEN
DECANE+PXYLENE
DECANE+R14
DECANE+SF6
DECANE+TOLUENE
DECANE+WATER
DEE+ETHANE
280 300 320 340 360 380 400 420 440 460 100 200 300 400 500 600 700 250 300 350 400 450 500 550 600
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
T (K)
S55
T (K)
DEE+R12
DEE+SO2
DEE+TOLUENE
DEE+WATER
DMC+DME
DMC+ETHANOL
DMC+HEPTANE
DMC+HEXANE
DMC+METHANE
T (K)
S56
T (K)
T (K)
360
DEE+PROPYLEN
340
DEE+PENTANE
320
DEE+METHANOL
300
DEE+METHANE
280
20 10 0 10 20
DEE+ISOBUTAN
450
20 10 0 10 20
DEE+IPENTANE
400
20 10 0 10 20
DEE+HEXANE
350
20 10 0 10 20
DEE+ETHYLENE
300
20 10 0 10 20
DEE+ETHANOL
260 280 300 320 340 360 380 400 420 250
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
DME+PROPANE
DME+PROPYLEN
DME+R125
DME+R134A
T (K)
S57
T (K)
T (K)
500
DME+PENTANE
450
DME+NITROGEN
400
DME+METHANOL
350
DME+METHANE
300
DME+ISOBUTAN
250
DME+HYDROGEN
450
DME+HEXANE
400
DME+ETHANOL
350
DMC+WATER
300
DMC+TOLUENE
250
20 10 0 10 20
DMC+OXYGEN
450
20 10 0 10 20
DMC+OCTANE
400
20 10 0 10 20
DMC+NONANE
350
20 10 0 10 20
DMC+METHANOL
300
20 10 0 10 20
250
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
DME+R22
DME+R227EA
DME+R236EA
DME+R236FA
DME+R32
DME+R40
DME+SO2
DME+TOLUENE
DME+WATER
DME+XENON
EBENZENE+ETHANOL
20EBENZENE+HEPTANE 10 0 10 20
EBENZENE+HEXANE
EBENZENE+IOCTANE
EBENZENE+METHANOL EBENZENE+MXYLENE 20
EBENZENE+NONANE
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
S58
450
T (K)
400
350
300
T (K)
250
150 200 250 300 350 400 450
500
T (K)
450
400
350
300
10 0 10 20
250
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
DME+R143A
20 10 0 10 20
ETHANE+H2S
ETHANE+HCL
ETHANE+HEPTANE
ETHANE+HEXANE
ETHANE+IOCTANE
ETHANE+ISOBUTAN
ETHANE+KRYPTON
ETHANE+METHANE
ETHANE+METHANOL
0 100 200 300 400 500 600 700
20 10 0 10 20
ETHANE+HELIUM
20ETHANE+HYDROGEN 10 0 10 20 20 10 0 10 20
T (K)
T (K)
S59
T (K)
450
20 ETHANE+ETHYLENE 10 0 10 20
400
ETHANE+ETHANOL
350
EBENZENE+WATER
300
20EBENZENE+TOLUENE 10 0 10 20
250
EBENZENE+PXYLENE
200
EBENZENE+OXYLENE
50 100 150 200 250 300 350 400 450
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 EBENZENE+OCTANE 10 0 10 20
ETHANE+MSTEARAT
ETHANE+MXYLENE
20 ETHANE+NITROGEN 10 0 10 20
ETHANE+OCTANE
ETHANE+PENTANE
ETHANE+PROPANE
ETHANE+PROPYLEN
ETHANE+R116
ETHANE+R1216
ETHANE+R14
ETHANE+R218
ETHANE+R23
ETHANE+TOLUENE
ETHANE+WATER
ETHANE+XENON
ETHANOL+ETHYLENE
ETHANOL+HEPTANE
50 100 150 200 250 300 350 400
150 200 250 300 350 400 450 500
100 200 300 400 500 600 700
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 ETHANE+MPALMITA 10 0 10 20
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
T (K)
T (K)
S60
T (K)
ETHANOL+IBUTENE
20 ETHANOL+IHEXANE 10 0 10 20
ETHANOL+IOCTANE
ETHANOL+IPENTANE
20ETHANOL+ISOBUTAN 10 0 10 20
ETHANOL+KRYPTON
ETHANOL+MEA
20ETHANOL+METHANE 10 0 10 20
ETHANOL+METHANOL
ETHANOL+MM
20ETHANOL+MXYLENE 10 0 10 20
ETHANOL+NITROGEN
ETHANOL+NONANE
ETHANOL+OCTANE
ETHANOL+OXYGEN
ETHANOL+OXYLENE
250 300 350 400 450 500 550
150 200 250 300 350 400 450 500 550
280 300 320 340 360 380 400 420 440
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
ETHANOL+HYDROGEN
20 10 0 10 20
20 10 0 10 20
ETHANOL+HEXANE
T (K)
T (K)
S61
T (K)
ETHANOL+R115
ETHANOL+R125
ETHANOL+R134A
ETHANOL+R152A
ETHANOL+R21
ETHANOL+R22
ETHANOL+R23
ETHANOL+R32
ETHANOL+R41
ETHANOL+SO2
ETHANOL+T2BUTENE
ETHANOL+TOLUENE
260 280 300 320 340 360 380 400 420 440
280 300 320 340 360 380 400
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
T (K)
500
ETHANOL+R114
450
ETHANOL+R113
400
20 ETHANOL+PXYLENE 10 0 10 20
350
ETHANOL+PROPYLEN
300
ETHANOL+PROPANE
250
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 ETHANOL+PENTANE 10 0 10 20
T (K)
S62
T (K)
ETHYLENE+ISOBUTAN
ETHYLENE+KRYPTON
ETHYLENE+METHANE 20 10 0 10 20
ETHYLENE+METHANOL
ETHYLENE+N2O
ETHYLENE+NITROGEN 20 10 0 10 20
ETHYLENE+NONANE
ETHYLENE+OCTANE
20ETHYLENE+PROPANE 10 0 10 20
ETHYLENE+PROPYLEN
ETHYLENE+R1216
200 250 300 350 400 450 500
T (K)
T (K)
S63
T (K)
350
20ETHYLENE+IOCTANE 10 0 10 20
300
ETHYLENE+HYDROGEN
250
ETHYLENE+HEXANE
200
20ETHYLENE+HEPTANE 10 0 10 20
150
ETHYLENE+HELIUM
100
ETHANOL+XENON
100 200 300 400 500 600 700
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
ETHANOL+WATER
20 10 0 10 20
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
ETHYLENE+WATER
ETHYLENE+XENON
FLUORINE+HELIUM
H2S+HEPTANE
H2S+HEXANE
H2S+HYDROGEN
H2S+IOCTANE
H2S+IPENTANE
H2S+ISOBUTAN
H2S+METHANE
H2S+METHANOL
H2S+MXYLENE
H2S+NEOPENTN
H2S+NITROGEN
H2S+NONANE
H2S+PENTANE
H2S+PROPANE
50 100 150 200 250 300 350 400 450 500 150 200 250 300 350 400 450 500 550 600 150 200 250 300 350 400 450
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 ETHYLENE+TOLUENE 10 0 10 20
T (K)
T (K)
S64
T (K)
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
H2S+TOLUENE
H2S+WATER
HCL+HEPTANE
HCL+HEXANE
HCL+IOCTANE
HCL+METHANOL
HCL+N2O
HCL+OCTANE
HCL+PENTANE
HCL+PROPANE
HCL+R14
HCL+R142B
HCL+R32
HCL+R40
HCL+R41
HCL+SO2
HCL+WATER
HCL+XENON
150 200 250 300 350 400 450 500 150 200 250 300 350 400 450 500 550 600 140 160 180 200 220 240 260 280 300 320
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
T (K)
S65
T (K)
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
HELIUM+HEPTANE
HELIUM+HEXANE
HELIUM+HYDROGEN
HELIUM+IOCTANE
HELIUM+ISOBUTAN
HELIUM+METHANE
HELIUM+MXYLENE
HELIUM+NEON
HELIUM+NITROGEN
HELIUM+NONANE
HELIUM+OCTANE
HELIUM+OXYGEN
HELIUM+PARAHYD
HELIUM+PROPANE
HELIUM+R12
HELIUM+R22
HELIUM+TOLUENE
HELIUM+WATER
0 100 200 300 400 500 600 0 100 200 300 400 500 600 0 100 200 300 400 500 600 700
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
T (K)
S66
T (K)
HEPTANE+IHEXANE
20 HEPTANE+IOCTANE 10 0 10 20
HEPTANE+KRYPTON
HEPTANE+MEA
20HEPTANE+METHANE 10 0 10 20
HEPTANE+METHANOL
HEPTANE+MXYLENE
HEPTANE+NEON
HEPTANE+NITROGEN
HEPTANE+NONANE
HEPTANE+OCTANE
HEPTANE+OXYGEN
HEPTANE+OXYLENE
20 HEPTANE+PENTANE 10 0 10 20
HEPTANE+PROPANE
HEPTANE+PROPYLEN
150 200 250 300 350 400 450 500 550
250 300 350 400 450 500 550
280 300 320 340 360 380 400 420 440
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
HEPTANE+HYDROGEN
20 10 0 10 20
20 10 0 10 20 20 10 0 10 20
HEPTANE+HEXANE
T (K)
T (K)
S67
T (K)
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
HEPTANE+PXYLENE
HEPTANE+R113
HEPTANE+R114
HEPTANE+R12
HEPTANE+R13
HEPTANE+R14
HEPTANE+SF6
HEPTANE+TOLUENE
HEXANE+HYDROGEN
HEXANE+IHEXANE
HEXANE+IOCTANE
HEXANE+IPENTANE
HEXANE+KRYPTON
HEXANE+METHANE
HEXANE+METHANOL
HEXANE+MM
HEXANE+MXYLENE
HEXANE+NEON
280 300 320 340 360 380 400 420 100 150 200 250 300 350 400 450 250 300 350 400 450 500 550
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
T (K)
S68
T (K)
20 HEXANE+PROPYLEN 10 0 10 20
HEXANE+PXYLENE
HEXANE+R113
HEXANE+R114
HEXANE+R14
HEXANE+R22
HEXANE+R245FA
HEXANE+SF6
HEXANE+TOLUENE
HEXANE+WATER
HEXANE+XENON
HYDROGEN+IOCTANE
240 260 280 300 320 340 360 380 400 420
250 300 350 400 450 500 550
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
T (K)
700
HEXANE+PROPANE
600
HEXANE+PENTANE
500
HEXANE+OXYLENE
20 10 0 10 20
400
HEXANE+OXYGEN
300
HEXANE+OCTANE
200
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 HEXANE+NITROGEN 10 0 10 20
T (K)
S69
T (K)
HYDROGEN+MEA
HYDROGEN+METHANE
10 0 10 20
HYDROGEN+METHANOL HYDROGEN+MPALMITA HYDROGEN+MXYLENE 20 10 0 10 20
HYDROGEN+PENTANE 20 10 0 10 20
HYDROGEN+PROPANE HYDROGEN+PROPYLEN
HYDROGEN+R14
HYDROGEN+TOLUENE
20HYDROGEN+WATER 10 0 10 20
IBUTENE+ISOBUTAN
IBUTENE+METHANOL
20 10 0 10 20
HYDROGEN+R13
HYDROGEN+OCTANE
0 100 200 300 400 500 600
HYDROGEN+NITROGEN
50 100 150 200 250 300 350 400 450 500
20 HYDROGEN+NEON 10 0 10 20
0 100 200 300 400 500 600
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
HYDROGEN+ISOBUTAN 20
T (K)
T (K)
S70
T (K)
IHEXANE+PROPANE
IHEXANE+R245FA
20 10 0 10 20
IOCTANE+KRYPTON
IOCTANE+METHANE
IOCTANE+METHANOL
IOCTANE+NEON
IOCTANE+NITROGEN
250
450
T (K)
400
350
300
20 IOCTANE+MXYLENE 10 0 10 20
S71
T (K)
T (K)
500
IHEXANE+OCTANE
450
20 10 0 10 20
400
IHEXANE+METHANOL
350
IBUTENE+WATER
300
IBUTENE+SO2
20 10 0 10 20
250
IBUTENE+R40
500
IBUTENE+R227EA
450
IBUTENE+R152A
20 10 0 10 20
400
IBUTENE+R143A
350
IBUTENE+PROPANE
300
IBUTENE+OCTANE
250
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
IOCTANE+OCTANE
20IOCTANE+PROPYLEN 10 0 10 20 20 10 0 10 20
IOCTANE+SF6
IOCTANE+OXYGEN
IOCTANE+OXYLENE
IOCTANE+PXYLENE
IOCTANE+R14
IOCTANE+SO2
IOCTANE+TOLUENE
ISOBUTAN+METHANE
T (K)
500
IPENTANE+TOLUENE
450
20IPENTANE+R365MFC 10 0 10 20
400
IPENTANE+R245FA
350
IPENTANE+R23
300
20IPENTANE+PROPANE 10 0 10 20
150 200 250 300 350 400 450 500
IPENTANE+METHANOL IPENTANE+NITROGEN
280 300 320 340 360 380 400 420 440 460
20IPENTANE+METHANE 10 0 10 20
250
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
S72
T (K)
ISOBUTAN+R125
ISOBUTAN+R13
ISOBUTAN+R134A
ISOBUTAN+R143A
ISOBUTAN+R152A
ISOBUTAN+R227EA
ISOBUTAN+R23
ISOBUTAN+R236FA
ISOBUTAN+R245FA
ISOBUTAN+R32
ISOBUTAN+WATER
KRYPTON+METHANE
100 150 200 250 300 350 400
100 150 200 250 300 350 400
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
T (K)
450
ISOBUTAN+R1234ZE
400
ISOBUTAN+R1234YF
350
20ISOBUTAN+PROPYLEN 10 0 10 20
300
ISOBUTAN+PROPANE
250
ISOBUTAN+NITROGEN
200
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
ISOBUTAN+METHANOL 20 10 0 10 20
T (K)
S73
T (K)
KRYPTON+NEON
KRYPTON+NONANE
20 KRYPTON+OCTANE 10 0 10 20
KRYPTON+OXYGEN
KRYPTON+PROPYLEN
KRYPTON+WATER
KRYPTON+XENON
MEA+WATER
METHANE+METHANOL 20 10 0 10 20
METHANE+MXYLENE
METHANE+N2O
20METHANE+NEOPENTN 10 0 10 20
METHANE+NITROGEN
METHANE+NONANE
20 METHANE+OCTANE 10 0 10 20
METHANE+OXYGEN
METHANE+PENTANE
100 200 300 400 500 600 700
0 100 200 300 400 500 600
50 100 150 200 250 300 350 400 450
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20KRYPTON+METHANOL 10 0 10 20
20 10 0 10 20
T (K)
T (K)
S74
T (K)
METHANE+PROPYLEN
METHANE+R12
METHANE+R14
METHANE+R22
METHANE+SO2
20METHANE+TOLUENE 10 0 10 20
METHANE+WATER
METHANOL+MM
20 10 0 10 20
METHANOL+MXYLENE METHANOL+NITROGEN
METHANOL+OCTANE
METHANOL+OXYLENE 20 10 0 10 20
METHANOL+PENTANE METHANOL+PROPANE
T (K)
T (K)
S75
METHANOL+OXYGEN
200 250 300 350 400 450 500
20METHANOL+NONANE 10 0 10 20
0 100 200 300 400 500 600 700
METHANOL+MOLEATE 20 10 0 10 20
0 100 200 300 400 500 600
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20METHANE+PROPANE 10 0 10 20
T (K)
METHANOL+PXYLENE
METHANOL+R113
METHANOL+R115
METHANOL+R125
METHANOL+R134A
20 METHANOL+R152A 10 0 10 20
METHANOL+R21
METHANOL+R22
METHANOL+R23
METHANOL+R32
METHANOL+R40
METHANOL+R41
METHANOL+SO2
METHANOL+T2BUTENE
METHANOL+TOLUENE 20 10 0 10 20
METHANOL+WATER
METHANOL+XENON
280 300 320 340 360 380 400
200 250 300 350 400 450 500 550 600
240 260 280 300 320 340 360 380
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
METHANOL+PROPYLEN 20 10 0 10 20 20 10 0 10 20
20 10 0 10 20 20 10 0 10 20
T (K)
T (K)
S76
T (K)
MM+TOLUENE
MOLEATE+MSTEARAT
20MPALMITA+MSTEARAT 10 0 10 20
MPALMITA+PROPANE
MXYLENE+NITROGEN
20 MXYLENE+NONANE 10 0 10 20
MXYLENE+OCTANE
MXYLENE+OXYLENE
20MXYLENE+PROPANE 10 0 10 20
MXYLENE+PROPYLEN
MXYLENE+PXYLENE
MXYLENE+R14
MXYLENE+R23
MXYLENE+R32
MXYLENE+R41
MXYLENE+SO2
MXYLENE+TOLUENE
250 300 350 400 450 500 550
200 250 300 350 400 450 500
250 300 350 400 450 500 550 600
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20MLINOLEA+MPALMITA 10 0 10 20
20 10 0 10 20 20 10 0 10 20
T (K)
T (K)
S77
T (K)
N2O+NITROGEN
N2O+OXYGEN
N2O+R125
N2O+R41
N2O+WATER
N2O+XENON
NEON+NITROGEN
NEON+NONANE
NEON+OCTANE
NEON+OXYGEN
NEON+R13
NEON+R14
NEON+WATER
NEON+XENON
NEOPENTN+NITROGEN 20 10 0 10 20
NEOPENTN+PENTANE
NEOPENTN+PROPANE
100 150 200 250 300 350 400 450
0 100 200 300 400 500 600 700 800
150 200 250 300 350 400 450
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
MXYLENE+WATER
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
T (K)
T (K)
S78
T (K)
NITROGEN+NONANE
NITROGEN+OCTANE
20 NITROGEN+OXYGEN 10 0 10 20
NITROGEN+PENTANE
NITROGEN+PROPANE
20NITROGEN+PROPYLEN 10 0 10 20
NITROGEN+PXYLENE
NITROGEN+R12
NITROGEN+R13
NITROGEN+R14
NITROGEN+R22
NITROGEN+SO2
NITROGEN+TOLUENE
NITROGEN+WATER
NONANE+OXYGEN
NONANE+OXYLENE
0 100 200 300 400 500 600 700
0 100 200 300 400 500 600
0 100 200 300 400 500 600
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 NEOPENTN+WATER 10 0 10 20
20 10 0 10 20
20 NITROGEN+R227EA 10 0 10 20 20 10 0 10 20
T (K)
T (K)
S79
T (K)
NONANE+PROPYLEN
NONANE+PXYLENE
NONANE+SF6
NONANE+TOLUENE
NOVEC649+RE347MCC
OCTANE+OXYGEN
OCTANE+OXYLENE
OCTANE+PENTANE
OCTANE+PROPANE
20 OCTANE+PROPYLEN 10 0 10 20
OCTANE+PROPYNE
OCTANE+PXYLENE
OCTANE+R12
OCTANE+R13
OCTANE+R14
280 300 320 340 360 380 400 420
200 220 240 260 280 300 320 340 360 380
250 300 350 400 450 500 550
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 NONANE+PROPANE 10 0 10 20 20 10 0 10 20
NONANE+R14
20NOVEC649+PENTANE 10 0 10 20 20 10 0 10 20
20 10 0 10 20
T (K)
T (K)
S80
T (K)
OXYGEN+SO2
OXYGEN+TOLUENE
OXYGEN+WATER
OXYLENE+PXYLENE
OXYLENE+R22
OXYLENE+TOLUENE
OXYLENE+WATER
PENTANE+PROPANE
PENTANE+R114
PENTANE+R12
PENTANE+R1234ZE
PENTANE+R141B
PENTANE+R152A
100 200 300 400 500 600 700
300 350 400 450 500 550 600 650 700
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
T (K)
500
OXYGEN+PROPANE
450
OXYGEN+PENTANE
400
20 10 0 10 20
350
OCTANE+WATER
300
OCTANE+TOLUENE
250
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
OCTANE+SF6
20 10 0 10 20
T (K)
S81
T (K)
PENTANE+WATER
PROPANE+PROPYLEN
PROPANE+PROPYNE
20 10 0 10 20
PROPANE+R113
PROPANE+R114
PROPANE+R115
20 10 0 10 20
PROPANE+R116
PROPANE+R1216
PROPANE+R1234ZE
20 10 0 10 20
PROPANE+R125
PROPANE+R134A
PROPANE+R143A
T (K)
S82
T (K)
240 260 280 300 320 340 360 380
20 10 0 10 20
450
PENTANE+TOLUENE
400
PENTANE+SF6
20PENTANE+RE347MCC 10 0 10 20
350
PENTANE+R245FA
300
PENTANE+R23
250
PENTANE+R22
200 250 300 350 400 450 500 550 600 650 200
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
PROPANE+R236EA
PROPANE+R236FA
PROPANE+R245FA
PROPANE+R32
PROPANE+RC318
PROPANE+SO2
PROPANE+TOLUENE
PROPANE+WATER
PROPANE+XENON
PROPYLEN+PXYLENE
PROPYLEN+R114
PROPYLEN+R115
PROPYLEN+R116
PROPYLEN+R12
200 250 300 350 400 450 500
250 300 350 400 450 500 550 600 650 700
T (K)
400
20 10 0 10 20
PROPANE+R23
350
20 10 0 10 20
PROPANE+R227EA
300
20 10 0 10 20
PROPANE+R22
250
20 10 0 10 20
PROPANE+R152A
200
20 10 0 10 20
150
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
S83
T (K)
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
PROPYLEN+R125
PROPYLEN+R13
PROPYLEN+R134A
PROPYLEN+R14
PROPYLEN+R142B
PROPYLEN+R152A
PROPYLEN+R22
PROPYLEN+R23
PROPYLEN+R32
PROPYLEN+TOLUENE
PROPYLEN+WATER
PROPYLEN+XENON
PROPYNE+WATER
PXYLENE+TOLUENE
PXYLENE+WATER
R11+R12
R11+R13
T (K)
50 100 150 200 250 300 350 400 450 500 200 250 300 350 400 450 500 550 600 650
20 10 0 10 20
PROPYLEN+R1216
100 200 300 400 500 600 700
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
S84
T (K)
R113+R22
R113+R23
R113+SF6
R114+R115
R114+R12
R114+R22
R114+R23
R115+R125
R115+R22
R116+R1216
R116+R134A
R116+R143A
T (K)
S85
T (K)
150 200 250 300 350 400 450
R113+R152A
450
20 10 0 10 20
R113+R142B
400
20 10 0 10 20
R113+R13
350
20 10 0 10 20
R113+R114
300
20 10 0 10 20
R11+R23
250
20 10 0 10 20
R11+R22
260 280 300 320 340 360 380 400 200
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
R12+R142B
R12+R143A
R12+R152A
R12+R22
R12+R23
R12+R32
R12+RC318
R1216+R123
R1216+R22
R1216+RC318
R1216+TOLUENE
T (K)
S86
T (K)
180 200 220 240 260 280 300 320 340
R12+R134A
400
R12+R13
350
20 10 0 10 20
R12+R1216
300
20 10 0 10 20
R116+XENON
250
20 10 0 10 20
R116+R32
200
20 10 0 10 20
R116+R23
150
20 10 0 10 20
R116+R22
100 200 300 400 500 600 700
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
R1234YF+R152A
R1234YF+R161
R1234YF+R227EA
R1234YF+R32
R1234ZE+R152A
R1234ZE+R32
R124+R134A
R124+R142B
R124+RC318
R125+R134A
R125+R143A
T (K)
S87
T (K)
200 220 240 260 280 300 320 340 360
R1234YF+R143A
450
R1234YF+R134A
400
20 10 0 10 20
R1234YF+R125
350
20 10 0 10 20
R123+WATER
300
20 10 0 10 20
R123+R32
250
20 10 0 10 20
R123+R22
200
20 10 0 10 20
R123+R134A
240 260 280 300 320 340 360
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
R13+R23
R134A+R141B
R134A+R142B
R134A+R143A
R134A+R152A
20 10 0 10 20
R134A+R161
R134A+R218
R134A+R22
200
20 10 0 10 20
T (K)
S88
T (K)
240 260 280 300 320 340 360 380
R13+R14
20 10 0 10 20
400
R125+RE143A
350
R125+R32
300
R125+R245FA
250
20 10 0 10 20
200
R125+R236FA
150
R125+R236EA
400
R125+R23
350
R125+R227EA
300
R125+R161
250
R125+R152A
20 10 0 10 20
150
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
R134A+R227EA
R134A+R23
R134A+R236FA
R134A+R245FA
R134A+R32
R134A+RE143A
R134A+WATER
R14+R23
R14+R41
R14+TOLUENE
R14+WATER
R14+XENON
R141B+R142B
R142B+R152A
R142B+R22
R142B+R32
R143A+R152A
R143A+R161
270 280 290 300 310 320 330 340 100 150 200 250 300 350 400 100 150 200 250 300 350 400 450
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
T (K)
S89
T (K)
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
R143A+R23
R143A+R236FA
R143A+R32
R152A+R218
R152A+R22
R152A+R227EA
R152A+R23
R152A+R245FA
R152A+R32
R152A+WATER
R161+R227EA
R161+R32
R161+TOLUENE
R218+R22
R218+RC318
R22+R23
R22+R32
T (K)
200 220 240 260 280 300 320 340 360 240 260 280 300 320 340 360 380 400
20 10 0 10 20
R143A+R22
240 260 280 300 320 340 360
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
S90
T (K)
20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20 20 10 0 10 20
R22+RC318
R22+WATER
R227EA+R23
R227EA+R32
R23+R32
R23+SF6
R23+TOLUENE
R23+WATER
R236EA+R32
R236FA+R32
R32+R40
R32+SF6
R32+SO2
R32+TOLUENE
R40+R41
R40+WATER
R40+XENON
R41+TOLUENE
240 260 280 300 320 340 360 380 400 420 160 180 200 220 240 260 280 300 320 340 140 160 180 200 220 240 260 280 300 320
∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%) ∆p/pcalc × 100 (%)
20 10 0 10 20
T (K)
T (K)
S91
T (K)
220 240 260 280 300 320 340 360 380 400 100 200 300 400 500 600 700 220
∆p/pcalc × 100 (%)∆p/pcalc × 100 (%)∆p/pcalc × 100 (%)
T (K) T (K)
S92
T (K)
R41+WATER R41+XENON SF6+WATER
SF6+XENON SO2+WATER SO2+TOLUENE
SO2+WATER WATER+XENON
320
300
280
20 10 0 10 20
260
20 10 0 10 20
240
20 10 0 10 20
4
Listing of experimental data used Table S4: Experimental data sources used for fitting (N: number of data points) Reference T (K) p (MPa) x1 (-) 1BUTENE & ACETONE S72 323 - 323 0.0824 - 0.596 0.000000 - 1.000000 S73 365 - 365 0.297 - 1.51 0.000000 - 1.000000 1BUTENE & BENZENE S74 298 - 298 0.0406 - 0.102 0.066000 - 0.245000 1BUTENE & BUTANE S75 311 - 411 0.362 - 3.34 0.098200 - 0.931300 S76 311 - 339 0.355 - 0.869 0.000000 - 1.000000 1BUTENE & C4F10 S77 313 - 343 0.493 - 1.48 0.058000 - 0.952000 1BUTENE & CO S78 313 - 383 1.01 - 10.1 0.760000 - 1.000000 1BUTENE & CO2 S79 273 - 273 0.127 - 3.49 0.000000 - 1.000000 S80 311 - 318 0.517 - 7.35 0.129200 - 1.000000 1BUTENE & CYCLOHEX S74 298 - 298 0.0405 - 0.102 0.083000 - 0.287000 1BUTENE & DME S81 284 - 417 0.236 - 4.88 0.043400 - 0.935700 1BUTENE & ETHANOL S82 326 - 326 0.0344 - 0.645 0.000000 - 1.000000 1BUTENE & ETHYLENE S83 273 - 293 0.128 - 5.5 0.000000 - 1.000000 S84 293 - 375 0.6 - 6.64 0.067000 - 0.922000 1BUTENE & HYDROGEN S85 253 - 357 5 - 30 0.713000 - 0.961000 1BUTENE & ISOBUTAN S86 278 - 344 0.162 - 1.09 0.251700 - 0.753600 S87 318 - 318 0.525 - 0.608 0.000000 - 1.000000 1BUTENE & METHANOL S82 326 - 326 0.0635 - 0.67 0.000000 - 1.000000 S74 298 - 298 0.0406 - 0.102 0.009000 - 0.038000 S88 365 - 365 0.267 - 1.51 0.000000 - 1.000000 1BUTENE & PROPYLEN S89 278 - 378 0.241 - 4.1 0.170500 - 0.817400 1BUTENE & PXYLENE S78 313 - 383 0.004 - 2.16 0.000000 - 1.000000 1BUTENE & R1216 S90 313 - 343 0.547 - 2.21 0.061000 - 0.974000 1BUTENE & R32 S90 303 - 333 0.494 - 3.99 0.049000 - 0.980000 1BUTENE & WATER S91 311 - 417 0.183 - 6.83 0.000067 - 0.000728 S92 311 - 417 0.436 - 6.8 0.959020 - 0.998590 S93 311 - 411 0.434 - 3.85 0.000218 - 0.998400 S94 298 - 298 0.101 - 0.101 0.000071 - 0.000071 Continued on next page...
S93
N 26 27 4 17 33 36 24 13 51 4 37 23 45 22 18 30 26 23 4 2 19 20 34 35 28 18 11 1
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 353 - 411 1.2 - 3.79 0.000270 - 0.000580 ACETONE & AMMONIA S96 292 - 292 0.024 - 0.024 0.620000 - 0.620000 S97 263 - 298 0.101 - 0.101 0.809400 - 0.915800 ACETONE & BENZENE S98 329 - 353 0.0976 - 0.0987 0.000000 - 1.000000 S99 328 - 352 0.0976 - 0.0976 0.000000 - 1.000000 S100 329 - 353 0.101 - 0.101 0.000000 - 1.000000 S101 329 - 353 0.101 - 0.101 0.000000 - 1.000000 S102 329 - 352 0.0984 - 0.0984 0.000000 - 1.000000 S103 329 - 353 0.101 - 0.101 0.000000 - 1.000000 S104 329 - 353 0.0995 - 0.101 0.000000 - 1.000000 S105 318 - 318 0.0298 - 0.0684 0.000000 - 1.000000 S106 331 - 350 0.101 - 0.101 0.054000 - 0.869000 S107 298 - 298 0.0127 - 0.0302 0.000000 - 1.000000 S108 373 - 545 0.211 - 4.66 0.093000 - 0.872000 S109 303 - 323 0.0186 - 0.0795 0.041700 - 0.947400 S110 318 - 318 0.0385 - 0.0665 0.130000 - 0.924500 S111 329 - 347 0.1 - 0.1 0.069000 - 0.947000 S112 323 - 323 0.0483 - 0.0771 0.156400 - 0.840200 S113 298 - 298 0.0127 - 0.0307 0.000000 - 1.000000 S114 313 - 313 0.0244 - 0.0566 0.000000 - 1.000000 S115 330 - 345 0.101 - 0.101 0.139000 - 0.883000 S116 330 - 348 0.101 - 0.101 0.076000 - 0.922000 ACETONE & BUTANE S117 283 - 313 0.101 - 0.101 0.772400 - 0.930930 S118 273 - 313 0.0089 - 0.382 0.000000 - 1.000000 S72 330 - 330 0.105 - 0.593 0.000000 - 1.000000 S73 364 - 365 0.297 - 1.29 0.000000 - 1.000000 ACETONE & C12 S119 313 - 333 0.0332 - 0.115 0.168000 - 1.000000 ACETONE & C14 S119 313 - 333 0.036 - 0.115 0.247000 - 1.000000 ACETONE & C1CC6 S120 318 - 318 0.0151 - 0.0687 0.000000 - 1.000000 ACETONE & C2BUTENE S72 332 - 332 0.111 - 0.561 0.000000 - 1.000000 S73 365 - 365 0.303 - 1.21 0.000000 - 1.000000 ACETONE & CO S121 313 - 313 1.75 - 8.45 0.937900 - 0.988900 ACETONE & CO2 S122 213 - 293 0.253 - 2.53 0.070000 - 0.940000 S123 298 - 313 0.396 - 7.41 0.017500 - 0.925000 S124 308 - 333 1.5 - 6.02 0.233000 - 0.809000 S125 298 - 298 2.15 - 3.37 0.427000 - 0.620000 S126 289 - 302 5.39 - 6.92 0.086000 - 0.086000 S127 295 - 401 4.86 - 11.7 0.020000 - 0.206000 S128 291 - 313 0.78 - 7.39 0.065000 - 0.857200 S129 313 - 333 0.987 - 9.5 0.034100 - 0.897900 Continued on next page... S95
S94
N 2 1 2 48 15 43 15 12 15 16 13 12 10 159 36 9 12 23 13 15 17 21 3 50 25 25 32 25 18 26 27 5 55 25 5 4 10 30 76 21
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 291 - 313 0.78 - 7.39 0.063400 - 0.857400 S131 291 - 313 0.78 - 7.39 0.063000 - 0.857000 S132 303 - 333 1.05 - 8.1 0.197900 - 0.849300 S133 318 - 333 1.54 - 9.7 0.067000 - 0.814000 S134 333 - 393 2.36 - 12.4 0.073400 - 0.674600 S135 323 - 323 0.49 - 7.11 0.213000 - 0.944000 S136 333 - 473 6.98 - 11.8 0.100000 - 0.700000 S137 291 - 313 0.72 - 7.88 0.016000 - 0.802000 S138 313 - 313 0.51 - 7.58 0.075000 - 0.940000 S139 298 - 313 0.55 - 7.02 0.050901 - 0.859885 S140 313 - 353 1.93 - 10.8 0.153415 - 0.653072 S141 298 - 298 0.776 - 2.71 0.531900 - 0.872100 S142 298 - 333 0.81 - 5.47 0.104000 - 0.903000 S143 318 - 338 1.54 - 10.1 0.000000 - 0.814000 S144 291 - 313 0.78 - 7.39 0.065000 - 0.857200 S145 303 - 333 1.05 - 8.1 0.000000 - 0.802100 S146 298 - 298 2.15 - 3.37 0.427000 - 0.620000 ACETONE & CYCLOHEX S147 326 - 354 0.101 - 0.101 0.000000 - 1.000000 S148 308 - 354 0.0196 - 0.107 0.000000 - 1.000000 S149 298 - 298 0.0309 - 0.0349 0.207700 - 0.920900 S113 298 - 298 0.013 - 0.0349 0.000000 - 1.000000 S150 298 - 298 0.0257 - 0.0346 0.120000 - 0.949000 S151 323 - 323 0.0363 - 0.0905 0.000000 - 1.000000 S152 273 - 273 0.00363 - 0.0108 0.000000 - 1.000000 S153 313 - 313 0.0246 - 0.0631 0.000000 - 1.000000 S154 293 - 303 0.0103 - 0.0428 0.000000 - 1.000000 S155 324 - 351 0.094 - 0.094 0.000000 - 1.000000 ACETONE & DECANE S156 282 - 321 0.00704 - 0.0743 0.130000 - 0.995600 S157 338 - 338 0.0852 - 0.134 0.345000 - 0.985000 S119 313 - 333 0.00152 - 0.115 0.000000 - 1.000000 S114 313 - 313 0.000488 - 0.0566 0.000000 - 1.000000 ACETONE & DEE S158 308 - 330 0.102 - 0.103 0.000000 - 1.000000 S159 273 - 273 0.00921 - 0.0247 0.000000 - 1.000000 S160 293 - 303 0.0247 - 0.0861 0.000000 - 1.000000 S161 293 - 293 0.0246 - 0.0582 0.000000 - 1.000000 S162 308 - 329 0.101 - 0.101 0.000000 - 1.000000 S163 308 - 329 0.101 - 0.101 0.000000 - 1.000000 S164 308 - 328 0.101 - 0.101 0.002100 - 0.981400 S165 298 - 388 0.0118 - 0.903 0.000000 - 1.000000 S166 333 - 343 0.116 - 0.308 0.000000 - 1.000000 ACETONE & DMC S167 330 - 361 0.101 - 0.101 0.046900 - 0.965500 ACETONE & EBENZENE S114 313 - 313 0.00287 - 0.0566 0.000000 - 1.000000 ACETONE & ETHANE S168 298 - 298 0.48 - 3.94 0.073200 - 0.957300 Continued on next page... S130
S95
N 73 73 15 11 30 12 43 64 15 23 19 7 29 17 76 32 4 22 44 12 25 8 27 12 32 70 21 38 9 25 21 13 9 27 7 11 17 14 45 39 34 17 8
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 309 - 309 4.88 - 4.88 0.050000 - 0.050000 S170 330 - 483 4.38 - 9.27 0.173000 - 0.735000 ACETONE & ETHANOL S171 305 - 321 0.0117 - 0.0763 0.000000 - 1.000000 S172 330 - 349 0.101 - 0.101 0.050000 - 0.900000 S173 330 - 347 0.101 - 0.101 0.081000 - 0.877000 S174 329 - 352 0.101 - 0.101 0.000000 - 1.000000 S175 329 - 351 0.101 - 0.101 0.000000 - 1.000000 S176 329 - 351 0.101 - 0.101 0.000000 - 1.000000 S177 328 - 351 0.0373 - 0.101 0.000000 - 1.000000 S178 331 - 342 0.101 - 0.101 0.200000 - 0.800000 S179 303 - 308 0.0171 - 0.0445 0.100000 - 0.900000 S180 323 - 323 0.0295 - 0.082 0.000000 - 1.000000 S181 288 - 328 0.00767 - 0.0939 0.076500 - 0.910900 S182 323 - 323 0.0295 - 0.082 0.000000 - 1.000000 S183 323 - 323 0.0295 - 0.082 0.000000 - 1.000000 S150 298 - 298 0.0112 - 0.0282 0.075000 - 0.872000 S184 373 - 423 0.223 - 1.14 0.000000 - 1.000000 S185 344 - 363 0.0757 - 0.286 0.000000 - 1.000000 S186 329 - 351 0.101 - 0.101 0.000000 - 1.000000 S187 329 - 351 0.101 - 0.101 0.000000 - 1.000000 S188 329 - 351 0.101 - 0.101 0.000000 - 1.000000 ACETONE & ETHYLENE S189 228 - 248 0.101 - 1.82 0.190000 - 0.974500 S190 298 - 323 1.35 - 7.59 0.146800 - 0.904200 ACETONE & H2S S97 263 - 298 0.101 - 0.101 0.839300 - 0.930200 ACETONE & HEPTANE S191 273 - 323 0.00106 - 0.0819 0.000000 - 1.000000 S192 323 - 323 0.0188 - 0.0829 0.000000 - 1.000000 S193 328 - 338 0.101 - 0.101 0.202000 - 0.886000 S194 338 - 338 0.0775 - 0.137 0.118000 - 0.867000 S195 329 - 360 0.101 - 0.101 0.042200 - 0.893700 S114 313 - 313 0.0123 - 0.0575 0.000000 - 1.000000 ACETONE & HEXANE S196 253 - 318 0.00184 - 0.0853 0.000000 - 1.000000 S197 268 - 293 0.00455 - 0.0319 0.000000 - 1.000000 S193 323 - 331 0.101 - 0.101 0.076000 - 0.753000 S198 308 - 342 0.0305 - 0.121 0.000000 - 1.000000 S199 322 - 331 0.101 - 0.101 0.085000 - 0.885000 S200 308 - 308 0.0292 - 0.0555 0.000000 - 1.000000 S201 283 - 308 0.0103 - 0.059 0.000000 - 1.000000 S202 322 - 331 0.101 - 0.101 0.102000 - 0.954000 S114 313 - 313 0.0373 - 0.0717 0.000000 - 1.000000 S203 323 - 340 0.101 - 0.101 0.010600 - 0.995000 ACETONE & HYDROGEN S204 298 - 373 1.47 - 9.96 0.960860 - 0.995820 S205 298 - 323 0.101 - 0.101 0.999657 - 0.999726 ACETONE & IBUTENE Continued on next page... S169
S96
N 1 130 41 13 9 11 11 11 20 4 10 15 50 15 15 9 36 33 12 21 13 17 18 2 19 11 6 8 9 16 26 29 12 44 8 14 20 10 27 22 19 2
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 323 - 323 0.0818 - 0.608 0.000000 - 1.000000 S73 364 - 365 0.296 - 1.55 0.000000 - 1.000000 ACETONE & IOCTANE S206 303 - 323 0.00893 - 0.08 0.000000 - 1.000000 S207 321 - 321 0.0173 - 0.0722 0.000000 - 1.000000 S187 329 - 372 0.101 - 0.101 0.000000 - 1.000000 ACETONE & IPENTANE S193 299 - 299 0.101 - 0.101 0.173000 - 0.173000 ACETONE & ISOBUTAN S72 319 - 319 0.0696 - 0.611 0.000000 - 1.000000 S73 364 - 365 0.294 - 1.69 0.000000 - 1.000000 ACETONE & METHANE S208 298 - 298 0.101 - 0.101 0.998140 - 0.998140 S190 298 - 323 1.06 - 11.8 0.771300 - 0.984700 S209 298 - 298 0.101 - 8 0.860000 - 0.998128 ACETONE & METHANOL S158 329 - 338 0.102 - 0.102 0.000000 - 1.000000 S210 328 - 337 0.0968 - 0.0973 0.000000 - 1.000000 S211 328 - 335 0.101 - 0.101 0.055344 - 0.926382 S212 293 - 293 0.0128 - 0.0239 0.000000 - 1.000000 S213 281 - 291 0.0133 - 0.0133 0.110000 - 1.000000 S214 329 - 336 0.101 - 0.101 0.060000 - 0.940000 S172 328 - 336 0.101 - 0.101 0.048000 - 0.982000 S215 329 - 336 0.101 - 0.101 0.043200 - 0.999100 S216 373 - 373 0.352 - 0.403 0.047000 - 0.977000 S173 329 - 337 0.101 - 0.101 0.036000 - 0.683000 S217 329 - 338 0.101 - 0.101 0.000000 - 1.000000 S175 329 - 338 0.101 - 0.101 0.000000 - 1.000000 S218 328 - 336 0.1 - 0.1 0.058000 - 0.921000 S148 308 - 338 0.0272 - 0.101 0.000000 - 1.000000 S219 328 - 328 0.0723 - 0.101 0.028700 - 0.944800 S220 293 - 313 0.0175 - 0.0567 0.154000 - 0.893000 S178 329 - 335 0.101 - 0.101 0.080000 - 0.900000 S221 328 - 336 0.101 - 0.101 0.050000 - 0.950000 S222 328 - 338 0.101 - 0.101 0.000000 - 1.000000 S223 329 - 338 0.103 - 0.103 0.000000 - 1.000000 S224 328 - 335 0.101 - 0.101 0.101000 - 0.872000 S225 323 - 323 0.0604 - 0.084 0.051400 - 0.952800 S180 323 - 323 0.0556 - 0.084 0.000000 - 1.000000 S181 288 - 328 0.0109 - 0.0969 0.051200 - 0.930200 S226 329 - 341 0.101 - 0.101 0.000000 - 1.000000 S227 328 - 338 0.101 - 0.101 0.000000 - 1.000000 S228 328 - 338 0.101 - 0.101 0.000000 - 1.000000 S202 329 - 335 0.101 - 0.101 0.083000 - 0.984000 S229 298 - 298 0.017 - 0.0308 0.000000 - 1.000000 S230 328 - 335 0.0987 - 0.0987 0.100000 - 0.900000 S231 328 - 337 0.101 - 0.101 0.024000 - 0.930000 S232 313 - 323 0.0355 - 0.0839 0.000000 - 1.000000 S233 305 - 328 0.042 - 0.101 0.785000 - 0.883000 Continued on next page... S72
S97
N 25 26 49 23 21 1 25 27 1 22 4 19 13 9 11 7 13 7 19 11 15 17 11 13 52 28 23 5 13 12 10 12 4 27 50 16 20 14 9 14 9 23 32 5
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 373 - 423 0.349 - 1.4 0.000000 - 1.000000 S235 373 - 373 0.371 - 0.405 0.100200 - 0.900400 S236 328 - 338 0.101 - 0.101 0.000000 - 1.000000 S237 329 - 334 0.101 - 0.101 0.135000 - 0.675000 S238 328 - 337 0.101 - 0.101 0.024000 - 0.930000 S239 329 - 338 0.101 - 0.101 0.000000 - 1.000000 S154 293 - 303 0.013 - 0.0384 0.000000 - 1.000000 S240 328 - 336 0.0998 - 0.1 0.041000 - 0.938000 S241 323 - 323 0.0552 - 0.083 0.000000 - 1.000000 S242 328 - 336 0.101 - 0.101 0.033800 - 0.894300 S243 329 - 338 0.101 - 0.101 0.000000 - 1.000000 S244 328 - 337 0.1 - 0.1 0.000000 - 1.000000 S245 328 - 337 0.1 - 0.1 0.000000 - 1.000000 S246 313 - 313 0.101 - 0.101 0.050000 - 0.050000 S247 328 - 338 0.101 - 0.101 0.000000 - 1.000000 S248 328 - 337 0.101 - 0.101 0.000000 - 1.000000 S249 323 - 323 0.0591 - 0.0835 0.034300 - 0.878800 ACETONE & NITROGEN S250 298 - 298 0.101 - 0.101 0.999452 - 0.999452 S251 293 - 308 0.101 - 0.101 0.999430 - 0.999464 S252 223 - 400 1.98 - 12 0.937000 - 0.989000 S253 396 - 483 8.43 - 41.5 0.560000 - 0.898000 ACETONE & NONANE S191 302 - 324 0.0008 - 0.0857 0.000000 - 1.000000 S114 313 - 313 0.00141 - 0.0566 0.000000 - 1.000000 ACETONE & OCTANE S114 313 - 313 0.00415 - 0.0566 0.000000 - 1.000000 ACETONE & OXYGEN S252 253 - 283 0.108 - 0.753 0.994400 - 0.999300 S254 298 - 298 0.101 - 0.101 0.999129 - 0.999129 ACETONE & OXYLENE S114 313 - 313 0.00206 - 0.0566 0.000000 - 1.000000 ACETONE & PENTANE S197 238 - 298 0.00106 - 0.0778 0.000000 - 1.000000 S255 305 - 323 0.101 - 0.102 0.047000 - 0.979000 S256 373 - 423 0.366 - 1.8 0.000000 - 1.000000 ACETONE & PROPANE S257 325 - 425 0.397 - 4.67 0.249000 - 0.897000 S170 378 - 493 3.54 - 5.84 0.221000 - 0.862000 ACETONE & PROPYLEN S258 293 - 333 0.311 - 0.702 0.576000 - 0.944000 S259 293 - 333 0.294 - 0.686 0.650000 - 0.959000 S260 298 - 298 0.0306 - 1.16 0.000000 - 1.000000 ACETONE & PROPYNE S261 203 - 248 0.000467 - 0.0554 0.367000 - 0.911000 ACETONE & PXYLENE S114 313 - 313 0.00265 - 0.0566 0.000000 - 1.000000 S262 313 - 353 0.0026 - 0.211 0.000000 - 1.000000 ACETONE & R113 Continued on next page... S234
S98
N 35 10 20 13 23 21 33 18 7 11 11 23 29 1 18 30 9 1 4 33 24 19 23 21 8 1 16 37 11 33 19 93 9 12 14 18 16 16
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 308 - 308 0.0465 - 0.0733 0.000000 - 1.000000 S264 293 - 313 0.0286 - 0.0881 0.055000 - 0.946000 ACETONE & R12 S235 353 - 353 0.122 - 0.234 0.093100 - 0.882800 ACETONE & R22 S265 293 - 293 0.0973 - 0.0973 0.823200 - 0.823200 S266 309 - 407 0.986 - 0.986 0.257100 - 0.974500 S267 363 - 400 1.29 - 5.53 0.051000 - 0.832500 ACETONE & SO2 S220 293 - 313 0.0256 - 0.0924 0.687000 - 0.967500 S268 293 - 313 0.0256 - 0.0924 0.687000 - 0.967500 S269 228 - 250 0.000533 - 0.0546 0.000000 - 1.000000 S270 268 - 298 0.0998 - 0.1 0.166000 - 0.559000 ACETONE & T2BUTENE S72 332 - 332 0.112 - 0.606 0.000000 - 1.000000 S73 364 - 365 0.297 - 1.27 0.000000 - 1.000000 ACETONE & TOLUENE S271 330 - 383 0.1 - 0.1 0.000000 - 1.000000 S272 330 - 381 0.101 - 0.101 0.010000 - 0.981000 S120 318 - 318 0.00989 - 0.0682 0.000000 - 1.000000 S109 308 - 328 0.0135 - 0.0918 0.035600 - 0.925700 S114 313 - 313 0.00789 - 0.0566 0.000000 - 1.000000 S273 303 - 303 0.00723 - 0.0371 0.031500 - 0.969200 ACETONE & WATER S158 330 - 373 0.103 - 0.103 0.000000 - 1.000000 S274 311 - 373 0.0123 - 0.116 0.000000 - 1.000000 S275 328 - 372 0.0968 - 0.0968 0.000000 - 1.000000 S276 298 - 298 0.00316 - 0.0306 0.000000 - 1.000000 S277 333 - 376 0.101 - 0.101 0.003000 - 0.941000 S278 330 - 365 0.101 - 0.101 0.003596 - 0.950189 S279 295 - 373 0.0267 - 0.101 0.000000 - 1.000000 S280 330 - 450 0.101 - 1.38 0.005000 - 0.966000 S214 332 - 346 0.101 - 0.101 0.082000 - 0.715000 S172 330 - 347 0.101 - 0.101 0.050000 - 0.930000 S216 373 - 373 0.111 - 0.369 0.003300 - 0.971000 S281 330 - 503 0.101 - 3.45 0.010000 - 0.950000 S282 327 - 373 0.101 - 0.101 0.000000 - 1.000000 S283 293 - 323 0.00234 - 0.0821 0.000000 - 1.000000 S221 329 - 357 0.101 - 0.101 0.020000 - 0.950000 S222 329 - 373 0.101 - 0.101 0.000000 - 1.000000 S284 329 - 361 0.1 - 0.199 0.100000 - 0.900000 S179 303 - 308 0.0226 - 0.0451 0.100000 - 0.900000 S224 330 - 349 0.101 - 0.101 0.049000 - 0.940000 S285 283 - 313 0.0106 - 0.0531 0.317500 - 0.736300 S286 288 - 318 0.00168 - 0.0679 0.000000 - 1.000000 S287 298 - 298 0.00666 - 0.0267 0.015150 - 0.554794 S288 308 - 308 0.00563 - 0.0465 0.000000 - 1.000000 S183 323 - 323 0.0124 - 0.082 0.000000 - 1.000000 S289 298 - 328 0.00319 - 0.0976 0.000000 - 1.000000 Continued on next page... S263
S99
N 22 24 9 1 9 30 22 22 33 2 25 25 8 28 20 44 14 22 14 66 12 5 13 18 49 47 7 9 21 71 27 29 15 12 43 10 13 16 52 12 21 17 75
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 330 - 367 0.101 - 0.101 0.008400 - 0.965900 S291 329 - 373 0.101 - 0.101 0.000000 - 0.999500 S292 293 - 313 0.0132 - 0.0531 0.100200 - 0.802300 S293 290 - 369 0.02 - 0.101 0.004000 - 0.999000 S294 330 - 347 0.101 - 0.101 0.050800 - 0.945000 AMMONIA & ARGON S295 298 - 374 2.53 - 82.4 0.658200 - 0.998540 S296 273 - 323 5.08 - 20 0.958550 - 0.994390 S297 298 - 313 10.5 - 21.2 0.961650 - 0.983360 S298 298 - 423 2.31 - 16.7 0.360000 - 0.508000 AMMONIA & BENZENE S299 273 - 293 0.137 - 0.845 0.046000 - 0.978000 AMMONIA & BUTANE S300 273 - 323 0.104 - 2.41 0.000000 - 1.000000 S301 316 - 420 2.07 - 10.3 0.000000 - 1.000000 AMMONIA & CYCLOHEX S96 292 - 292 0.000533 - 0.000533 0.290000 - 0.290000 S302 429 - 551 3.55 - 8.71 0.083000 - 0.869000 S303 429 - 551 3.55 - 8.71 0.083000 - 0.869000 S299 273 - 293 0.113 - 0.852 0.025000 - 0.983000 AMMONIA & ETHANOL S96 291 - 291 0.0052 - 0.0052 0.490000 - 0.490000 S304 293 - 303 0.109 - 0.109 0.204321 - 0.258187 S305 277 - 328 0.013 - 0.716 0.014300 - 0.560500 S306 277 - 318 0.0021 - 0.404 0.000000 - 0.405406 AMMONIA & HELIUM S307 373 - 413 6.28 - 600 0.831000 - 1.000000 S298 298 - 423 1.4 - 14.6 0.405000 - 0.585000 S308 228 - 283 2.07 - 4.83 0.000080 - 0.000900 AMMONIA & HEXANE S309 300 - 327 1.06 - 2.27 0.288500 - 0.975400 AMMONIA & HYDROGEN S310 298 - 373 5.01 - 101 0.772230 - 0.996620 S311 273 - 273 10.1 - 101 0.963560 - 0.994940 S312 240 - 294 14.5 - 19.1 0.986000 - 0.997000 S297 298 - 298 2.89 - 20.2 0.984500 - 0.998300 S313 211 - 295 0.764 - 2.18 0.990417 - 0.997906 S314 278 - 394 0.505 - 41.7 0.000000 - 1.000000 AMMONIA & KRYPTON S315 253 - 268 2.54 - 20.3 0.967000 - 0.993800 AMMONIA & METHANE S316 298 - 313 5.52 - 78.5 0.854000 - 0.983100 S298 298 - 423 1.16 - 17.5 0.572000 - 0.611000 S317 273 - 373 7.5 - 100 0.796000 - 0.979000 AMMONIA & METHANOL S96 291 - 291 0.0115 - 0.0115 0.540000 - 0.540000 S304 293 - 303 0.109 - 0.109 0.243366 - 0.315937 S318 313 - 333 0.12 - 2.44 0.166000 - 0.936000 S319 303 - 363 0.022 - 5.03 0.000000 - 1.000000 Continued on next page... S290
S100
N 20 29 25 75 9 38 12 4 11 23 22 130 1 5 5 20 1 3 68 50 27 12 30 9 27 6 5 4 25 111 8 27 12 23 1 3 14 41
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 314 - 395 0.123 - 4.23 0.000000 - 0.680101 S321 298 - 298 0.101 - 0.101 0.283833 - 0.283833 AMMONIA & MXYLENE S322 281 - 293 0.2 - 0.85 0.093000 - 1.000000 AMMONIA & NEON S323 298 - 413 1.01 - 91.2 0.677000 - 1.000000 AMMONIA & NITROGEN S324 278 - 394 0.505 - 31.4 0.060500 - 1.000000 S298 298 - 423 1.77 - 23.8 0.427000 - 0.562000 S308 200 - 283 2.07 - 4.83 0.000260 - 0.003530 AMMONIA & OCTANE S309 318 - 341 1.73 - 3.11 0.408400 - 0.978400 AMMONIA & PENTANE S309 297 - 319 0.973 - 1.92 0.295800 - 0.977300 AMMONIA & PROPANE S325 218 - 248 0.0299 - 0.225 0.000000 - 1.000000 S326 273 - 293 0.43 - 1.64 0.000000 - 1.000000 AMMONIA & PROPYLEN S326 263 - 293 0.291 - 1.59 0.000000 - 1.000000 AMMONIA & PROPYNE S327 203 - 229 0.00773 - 0.0664 0.000000 - 1.000000 AMMONIA & R125 S328 254 - 323 0.199 - 2.53 0.000000 - 1.000000 S329 205 - 248 0.023 - 0.229 0.049300 - 0.929200 AMMONIA & R13 S330 288 - 298 2.16 - 3.92 0.017000 - 0.989000 AMMONIA & TOLUENE S331 398 - 398 0.2 - 0.34 0.002700 - 0.015900 AMMONIA & WATER S332 190 - 454 0.002 - 1.89 0.000000 - 1.000000 S333 364 - 420 0.101 - 0.448 0.000940 - 0.042480 S334 313 - 414 0.202 - 1.02 0.031600 - 0.614900 S335 313 - 414 0.202 - 1.02 0.031600 - 0.614900 S336 403 - 503 1.33 - 7.17 0.076000 - 0.696000 S337 372 - 373 0.101 - 0.101 0.000009 - 0.001980 S338 313 - 589 0.00738 - 21.8 0.000000 - 1.000000 S339 303 - 619 0.005 - 22.5 0.000000 - 1.000000 S318 333 - 333 0.16 - 2.07 0.197000 - 0.832000 S340 373 - 473 0.191 - 3.12 0.041800 - 0.318100 S341 389 - 614 1.29 - 21.5 0.189000 - 0.800000 S342 293 - 413 0.00636 - 3.1 0.046400 - 0.960200 S343 313 - 353 0.0315 - 0.253 0.097942 - 0.177473 S319 293 - 353 0.0023 - 5.03 0.000000 - 1.000000 S344 305 - 379 1.01 - 5.45 0.836000 - 0.905700 S345 310 - 400 0.0312 - 4.5 0.101600 - 0.895200 S346 293 - 353 0.0121 - 0.961 0.104982 - 0.412846 S305 293 - 313 0.012 - 0.315 0.119200 - 0.428200 S347 293 - 333 0.071 - 0.599 0.103000 - 0.741000 AMMONIA & XENON Continued on next page... S320
S101
N 52 1 145 77 50 12 32 10 9 21 38 62 38 75 163 20 8 207 22 29 29 18 7 227 348 6 40 111 115 6 36 9 51 35 10 27
Table S4 – continued from previous page Reference S348
ARGON S349
ARGON S350 S351
ARGON S352
ARGON S352
ARGON S352
ARGON ARGON S353 S354 S355
ARGON S356 S357 S358 S359 S360 S361 S362
ARGON S351 S363
ARGON S364
ARGON S365
ARGON S352
ARGON S366 S367 S368 S369
ARGON S370 S371 S372
ARGON S373 S374 S375 S376 S377
T (K) p (MPa) x1 (-) 195 - 195 0.00608 - 0.357 0.890900 - 1.000000 & BENZENE 283 - 333 1.52 - 7.74 0.012900 - 0.067800 & BUTANE 340 - 380 0.745 - 18.5 0.000000 - 0.550000 366 - 366 1.34 - 14.7 0.000000 - 0.564000 & C11 298 - 298 0.101 - 0.101 0.002559 - 0.002559 & C12 298 - 298 0.101 - 0.101 0.002607 - 0.002607 & C14 298 - 298 0.101 - 0.101 0.002743 - 0.002743 & C5F12 & CO 84 - 84 0.0689 - 0.128 0.000000 - 1.000000 123 - 137 1.52 - 3.78 0.062000 - 0.921000 123 - 137 1.52 - 3.78 0.079000 - 0.938000 & CO2 233 - 273 4.38 - 13.2 0.033000 - 0.350000 288 - 288 7.51 - 9.78 0.060000 - 0.167000 233 - 299 1.52 - 14 0.005600 - 0.411700 278 - 300 4.7 - 7.93 0.025500 - 0.056000 233 - 299 1.52 - 14 0.005600 - 0.411700 233 - 273 2.57 - 13.2 0.000000 - 0.350000 288 - 288 5.69 - 9.78 0.000000 - 0.207000 & CYCLOPEN 366 - 410 0.358 - 31 0.000000 - 0.548000 87 - 87 0.101 - 0.101 1.000000 - 1.000000 & D2 87 - 120 2.18 - 9.07 0.873000 - 0.970200 & D2O 278 - 303 0.101 - 0.101 0.000025 - 0.000043 & DECANE 298 - 298 0.101 - 0.101 0.002479 - 0.002479 & ETHANE 81 - 114 0.041 - 0.691 0.312000 - 0.660000 90 - 90 0.0979 - 0.136 0.220100 - 1.000000 91 - 91 0.0312 - 0.143 0.062000 - 1.000000 116 - 116 0.17 - 0.918 0.069000 - 0.981300 & ETHANOL 298 - 298 0.101 - 0.101 0.000618 - 0.000618 298 - 298 0.101 - 0.101 0.034600 - 0.034600 283 - 313 0.101 - 0.101 0.000560 - 0.000623 & HELIUM 93 - 148 1.72 - 13.8 0.862000 - 0.998500 91 - 115 0.981 - 21.6 0.937900 - 0.999500 150 - 199 351 - 1.05e+03 0.276000 - 0.730000 68 - 108 2.02 - 12.2 0.000000 - 0.998580 85 - 140 0.507 - 12.2 0.971400 - 0.999940 Continued on next page...
S102
N 5 74 25 13 1 1 1
13 16 16 15 4 62 11 62 19 12 26 1 31 6 1 6 5 12 38 1 1 3 29 66 81 354 187
Table S4 – continued from previous page Reference S378 S379 S380
ARGON S352
ARGON S349 S352
ARGON S312 S381 S382 S376 S383 S364
ARGON S384
ARGON S363
ARGON S385 S386 S387 S388 S389 S390 S391 S392
ARGON S393 S394 S395 S396 S354 S397 S398 S399 S400 S401 S402 S403
ARGON S370 S372
ARGON S404 S405 S406 S407
T (K) p (MPa) x1 (-) 91 - 91 0.583 - 2.54 0.997610 - 0.999550 98 - 160 9.63 - 422 0.000000 - 0.977100 91 - 148 1.42 - 68.9 0.000000 - 0.998500 & HEPTANE 298 - 298 0.101 - 0.101 0.002518 - 0.002518 & HEXANE 283 - 333 1.32 - 8.15 0.032200 - 0.185000 298 - 298 0.101 - 0.101 0.004000 - 0.004000 & HYDROGEN 87 - 87 11.6 - 18.4 0.813000 - 0.897000 83 - 141 0.08 - 51.4 0.375400 - 1.000000 100 - 100 0.641 - 4.62 0.936300 - 0.996400 68 - 105 2.03 - 12.2 0.000000 - 0.978570 86 - 113 0.507 - 4.05 0.930500 - 0.999600 87 - 140 1.7 - 10.2 0.870100 - 0.981100 & IOCTANE 298 - 298 0.101 - 0.101 0.003076 - 0.003076 & IPENTANE 87 - 87 0.101 - 0.101 0.999999 - 0.999999 & KRYPTON 88 - 88 0.0827 - 0.1 0.646800 - 0.892800 88 - 88 0.0923 - 0.0999 0.866700 - 0.960100 104 - 116 0.0237 - 0.952 0.000000 - 1.000000 116 - 116 0.519 - 0.83 0.493800 - 0.880000 120 - 193 0.101 - 5 0.000000 - 1.000000 138 - 193 0.35 - 5.98 0.000000 - 1.000000 120 - 200 0.106 - 5.98 0.000000 - 1.000000 125 - 189 0.152 - 5.01 0.000000 - 1.000000 & METHANE 92 - 124 0.0161 - 0.387 0.010500 - 0.380000 91 - 91 0.0117 - 0.143 0.000000 - 1.000000 115 - 137 0.185 - 1.83 0.040300 - 0.953100 116 - 116 0.14 - 0.952 0.000000 - 1.000000 151 - 178 1.17 - 5.1 0.024000 - 0.935000 115 - 115 0.189 - 0.888 0.055100 - 0.956100 91 - 91 0.0117 - 0.143 0.000000 - 1.000000 112 - 133 0.203 - 2.23 0.027000 - 0.958000 131 - 131 0.38 - 2.09 0.000000 - 1.000000 123 - 123 0.335 - 1.34 0.072900 - 0.946800 123 - 164 1.01 - 3.55 0.000000 - 0.688000 105 - 126 0.0564 - 1.67 0.000000 - 1.000000 & METHANOL 298 - 298 0.101 - 0.101 0.000415 - 0.000415 283 - 313 0.101 - 0.101 0.000412 - 0.000457 & NEON 84 - 130 0.383 - 7.24 0.910200 - 0.998000 96 - 130 7.52 - 62.1 0.429000 - 0.907500 91 - 120 0.981 - 21.6 0.000000 - 0.992100 87 - 94 6.38 - 103 0.000000 - 0.945800 Continued on next page...
S103
N 5 202 56 1 185 1 2 136 14 311 55 122 1 1 3 4 21 3 40 156 61 45 17 11 66 10 34 6 9 31 7 12 36 92 1 3 58 36 88 54
Table S4 – continued from previous page Reference S408
ARGON S409 S351
ARGON S410 S411 S412 S413 S394 S397 S367 S382 S401 S414 S415 S416 S417 S418 S419 S420 S421 S422
ARGON S352
ARGON S352
ARGON S423 S424 S425 S426 S427 S428 S429 S412 S416 S430 S431 S421 S432
ARGON S363
ARGON S433 S434
ARGON S435
ARGON
T (K) p (MPa) x1 (-) 93 - 138 0.176 - 101 0.000000 - 1.000000 & NEOPENTN 323 - 323 1.11 - 25.1 0.024900 - 0.653100 367 - 411 0.997 - 15.1 0.000000 - 0.516000 & NITROGEN 85 - 85 0.0804 - 0.232 0.000000 - 1.000000 79 - 103 0.122 - 0.405 0.000000 - 1.000000 84 - 84 0.0689 - 0.204 0.000000 - 1.000000 80 - 120 0.132 - 2.5 0.000000 - 1.000000 84 - 84 0.0689 - 0.204 0.000000 - 1.000000 100 - 100 0.394 - 0.737 0.100100 - 0.861100 85 - 85 0.0748 - 0.219 0.000000 - 1.000000 100 - 100 0.349 - 0.736 0.078600 - 0.885400 123 - 123 1.48 - 2.84 0.029500 - 0.949400 95 - 121 0.214 - 2.66 0.000000 - 1.000000 112 - 112 0.838 - 1.51 0.000000 - 0.889300 72 - 136 0.101 - 2.63 0.000000 - 0.959500 81 - 88 0.122 - 0.122 0.097000 - 0.670000 82 - 120 0.133 - 2.25 0.037300 - 0.779000 81 - 92 0.133 - 0.133 0.004100 - 0.926900 90 - 90 0.101 - 0.102 0.000300 - 0.029000 80 - 100 0.0429 - 0.773 0.000000 - 1.000000 81 - 115 0.125 - 1.06 0.086100 - 0.903000 & NONANE 298 - 298 0.101 - 0.101 0.002505 - 0.002505 & OCTANE 298 - 298 0.101 - 0.101 0.002439 - 0.002439 & OXYGEN 82 - 82 0.04 - 0.056 0.000000 - 0.927000 87 - 95 0.0741 - 0.211 0.039500 - 0.858000 87 - 96 0.0972 - 0.206 0.185000 - 0.867000 90 - 110 0.0993 - 0.666 0.000000 - 1.000000 89 - 96 0.121 - 0.204 0.211000 - 0.832000 90 - 120 0.104 - 1.21 0.000000 - 1.000000 90 - 96 0.119 - 0.223 0.020000 - 0.998000 84 - 90 0.0492 - 0.128 0.000000 - 1.000000 87 - 139 0.101 - 2.63 0.003500 - 0.978500 85 - 118 0.064 - 1.02 0.098500 - 0.905500 89 - 92 0.101 - 0.129 0.000200 - 0.755500 95 - 100 0.16 - 0.321 0.000000 - 1.000000 92 - 115 0.124 - 0.94 0.016700 - 0.923500 & PENTANE 87 - 87 0.101 - 0.101 1.000000 - 1.000000 & PROPYLEN 74 - 91 0 - 0.125 0.005000 - 0.993000 100 - 150 0.139 - 4.74 0.028000 - 1.000000 & R22 273 - 348 1.52 - 19.4 0.014600 - 0.587000 & WATER Continued on next page...
S104
N 67 16 16 11 56 12 108 19 7 8 18 13 46 14 1610 14 115 41 60 44 68 1 1 6 27 12 55 24 63 35 24 200 140 58 16 24 1 76 65 33
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 278 - 303 0.101 - 0.101 0.000023 - 0.000038 S372 283 - 313 0.101 - 0.101 0.000020 - 0.000034 S436 477 - 663 10.4 - 337 0.020000 - 0.800000 S437 283 - 298 0.101 - 0.101 0.000025 - 0.000034 ARGON & XENON S388 116 - 116 0.845 - 0.845 0.875300 - 0.875300 BENZENE & BUTANE S117 283 - 313 0.101 - 0.101 0.409600 - 0.832800 BENZENE & C12 S438 313 - 353 6e-05 - 0.101 0.000000 - 1.000000 S439 298 - 323 2.1e-05 - 0.0362 0.000000 - 1.000000 BENZENE & C14 S440 313 - 353 0.00905 - 0.101 0.202000 - 1.000000 S441 298 - 323 1e-06 - 0.0362 0.000000 - 1.000000 S442 308 - 308 9e-06 - 0.0198 0.000000 - 1.000000 S443 283 - 373 4e-07 - 0.18 0.000000 - 1.000000 S444 298 - 313 0.00343 - 0.0216 0.236270 - 0.873460 BENZENE & C1CC6 S445 353 - 374 0.101 - 0.101 0.000000 - 1.000000 S446 353 - 374 0.101 - 0.101 0.000000 - 1.000000 S447 313 - 313 0.0122 - 0.0244 0.000000 - 1.000000 S448 303 - 323 0.0078 - 0.0362 0.000000 - 1.000000 S449 348 - 348 0.0488 - 0.0848 0.044500 - 0.919100 S450 353 - 369 0.101 - 0.101 0.138000 - 0.981500 BENZENE & CO S451 283 - 373 3.04 - 5.07 0.959300 - 0.979000 S452 323 - 433 1.41 - 9.26 0.936300 - 0.990100 S453 433 - 533 0.71 - 6.89 0.932290 - 1.000000 BENZENE & CO2 S454 298 - 313 0.894 - 7.75 0.067300 - 0.893700 S455 313 - 393 0.105 - 13.3 0.052000 - 1.000000 S456 313 - 313 0.758 - 0.758 0.944000 - 0.944000 S457 313 - 393 0.496 - 6.27 0.339000 - 0.983000 S458 344 - 414 2.29 - 15.4 0.270000 - 0.857000 S459 273 - 303 0.826 - 6.31 0.071800 - 0.876200 S460 344 - 344 6.89 - 10.9 0.154000 - 0.547000 S461 293 - 308 1.7 - 7.31 0.021000 - 0.821000 S462 333 - 333 4.1 - 8.27 0.363000 - 0.717000 S463 293 - 313 3.43 - 7.42 0.092000 - 0.490000 S464 313 - 393 0.496 - 6.27 0.339000 - 0.983000 S465 344 - 344 6.89 - 11.1 0.154000 - 0.547000 S466 313 - 313 0.758 - 5.17 0.469000 - 0.944000 BENZENE & CYCLOHEX S467 349 - 352 0.0957 - 0.0957 0.000000 - 0.573000 S468 352 - 352 0.0948 - 0.104 0.000000 - 1.000000 S469 303 - 343 0.0182 - 0.08 0.118600 - 0.865900 S470 351 - 353 0.101 - 0.101 0.045000 - 0.928000 S445 351 - 354 0.101 - 0.101 0.000000 - 1.000000 S471 351 - 353 0.101 - 0.101 0.127000 - 0.920000 Continued on next page... S365
S105
N 6 3 168 4 1 3 38 33 61 34 28 145 21 24 30 20 32 29 24 4 21 73 17 44 1 29 14 28 16 29 3 25 29 16 6 15 5 17 16 17 9
Table S4 – continued from previous page Reference S472 S473 S474 S475 S476 S477 S478 S479 S480 S481 S482 S483 S484 S485 S486 S487 S488 S489 S490 S491 S492 S493 S494 S495 S496 S497 S498 S499 S500 S501 S502 S113 S503 S504 S150 S505 S506 S507 S508 S509 S510 S511 S185 S512 S513 S514 S515 S516 S517
T (K) 392 - 392 351 - 353 351 - 353 410 - 494 312 - 354 351 - 353 350 - 352 351 - 353 351 - 352 283 - 333 323 - 354 343 - 343 318 - 328 351 - 353 351 - 352 351 - 353 351 - 354 343 - 343 313 - 313 293 - 323 298 - 298 313 - 313 274 - 299 343 - 353 238 - 293 232 - 280 313 - 313 343 - 354 313 - 313 281 - 293 313 - 313 298 - 298 313 - 313 313 - 313 298 - 298 298 - 328 351 - 353 313 - 313 303 - 313 303 - 313 298 - 298 403 - 423 343 - 343 313 - 313 343 - 343 323 - 333 313 - 313 313 - 313 323 - 354
p (MPa) x1 (-) 0.295 - 0.307 0.192000 - 0.853500 0.101 - 0.101 0.088000 - 0.953000 0.101 - 0.101 0.088000 - 0.953000 0.46 - 1.85 0.000000 - 1.000000 0.0229 - 0.101 0.000000 - 1.000000 0.101 - 0.101 0.088000 - 0.953000 0.101 - 0.101 0.178000 - 0.938000 0.101 - 0.101 0.101000 - 0.945000 0.101 - 0.101 0.212199 - 0.811665 0.00607 - 0.0576 0.000000 - 1.000000 0.0358 - 0.101 0.000000 - 1.000000 0.0751 - 0.0795 0.125000 - 0.875000 0.0315 - 0.0485 0.100800 - 0.892100 0.101 - 0.101 0.077000 - 0.865000 0.101 - 0.101 0.141000 - 0.825000 0.101 - 0.101 0.077000 - 0.865000 0.101 - 0.101 0.000000 - 1.000000 0.0754 - 0.0801 0.139800 - 0.943200 0.026 - 0.0275 0.128200 - 0.865600 0.0114 - 0.0396 0.750200 - 0.750400 0.0127 - 0.0146 0.000000 - 1.000000 0.0244 - 0.0246 0.000000 - 1.000000 0.00398 - 0.0147 0.077000 - 0.898000 0.0726 - 0.101 0.000000 - 1.000000 0.000489 - 0.0112 0.020000 - 0.938000 0.00028 - 0.00533 0.000000 - 1.000000 0.0243 - 0.0275 0.000000 - 1.000000 0.0687 - 0.101 0.000000 - 1.000000 0.0261 - 0.0274 0.273000 - 0.852100 0.00555 - 0.0117 0.022100 - 0.984700 0.0244 - 0.0275 0.000000 - 1.000000 0.0127 - 0.0145 0.000000 - 1.000000 0.0244 - 0.0274 0.000000 - 1.000000 0.0243 - 0.0274 0.000000 - 1.000000 0.0133 - 0.0146 0.098000 - 0.930000 0.0136 - 0.0485 0.119300 - 0.920200 0.101 - 0.101 0.095000 - 0.967000 0.025 - 0.0275 0.073700 - 0.957900 0.0159 - 0.0275 0.000000 - 1.000000 0.0159 - 0.0275 0.000000 - 1.000000 0.0127 - 0.0147 0.000000 - 1.000000 0.372 - 0.604 0.098400 - 0.882700 0.076 - 0.0807 0.133600 - 0.881100 0.0244 - 0.0275 0.000000 - 1.000000 0.0722 - 0.0799 0.000000 - 1.000000 0.0369 - 0.0576 0.034000 - 0.944000 0.0244 - 0.0275 0.000000 - 1.000000 0.0271 - 0.0271 0.295400 - 0.700800 0.04 - 0.101 0.000000 - 1.000000 Continued on next page...
S106
N 4 13 10 44 15 10 11 11 4 23 21 7 10 23 8 23 21 12 7 4 8 2 49 31 58 48 9 16 12 36 17 12 14 11 9 41 24 20 27 39 13 31 7 22 14 60 24 2 26
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 313 - 313 0.0271 - 0.0272 0.300300 - 0.701200 S519 331 - 353 0.0533 - 0.0987 0.000000 - 1.000000 S520 323 - 350 0.04 - 0.0933 0.053500 - 0.946600 S521 403 - 403 0.363 - 0.397 0.000000 - 1.000000 BENZENE & CYCLOPEN S446 322 - 353 0.101 - 0.101 0.000000 - 1.000000 S522 298 - 318 0.0197 - 0.0816 0.065500 - 0.586200 BENZENE & D4 S523 298 - 333 0.00179 - 0.0454 0.119950 - 0.855800 BENZENE & DECANE S524 364 - 414 0.101 - 0.101 0.150000 - 0.700000 S525 313 - 313 0.00048 - 0.0244 0.000000 - 1.000000 S526 298 - 323 0.000173 - 0.0362 0.000000 - 1.000000 BENZENE & DEE S527 308 - 353 0.101 - 0.102 0.000000 - 1.000000 S528 293 - 303 0.00987 - 0.0862 0.000000 - 1.000000 S529 273 - 343 0.00359 - 0.308 0.000000 - 1.000000 S530 293 - 293 0.00997 - 0.0588 0.000000 - 1.000000 BENZENE & DMC S531 283 - 373 0.00317 - 0.18 0.000000 - 1.000000 S532 283 - 375 0.00368 - 0.187 0.078300 - 0.871900 S533 313 - 338 0.0165 - 0.0622 0.035000 - 0.916000 BENZENE & DME S534 323 - 323 0.0355 - 1.14 0.000000 - 1.000000 BENZENE & EBENZENE S535 353 - 409 0.101 - 0.101 0.000000 - 1.000000 S536 356 - 404 0.102 - 0.102 0.076700 - 0.910100 S537 453 - 553 0.345 - 4.23 0.063000 - 0.955000 BENZENE & ETHANE S538 274 - 528 0.689 - 9.31 0.051900 - 0.848000 S168 298 - 298 0.776 - 3.8 0.070100 - 0.879900 S539 180 - 265 0.075 - 0.988 0.010900 - 0.764800 S540 303 - 303 0.101 - 0.101 0.986040 - 0.986040 BENZENE & ETHANOL S541 323 - 323 0.042 - 0.0541 0.114000 - 0.912000 S542 341 - 341 0.101 - 0.101 0.551557 - 0.551557 S543 299 - 353 0.0133 - 0.104 0.067200 - 1.000000 S162 341 - 353 0.101 - 0.101 0.000000 - 1.000000 S544 341 - 353 0.101 - 0.101 0.000000 - 1.000000 S545 293 - 293 0.00584 - 0.013 0.000000 - 1.000000 S546 341 - 351 0.101 - 0.101 0.740000 - 0.987000 S547 341 - 345 0.101 - 0.101 0.121000 - 0.860000 S548 293 - 293 0.00596 - 0.013 0.000000 - 1.000000 S549 313 - 333 0.0179 - 0.0757 0.000000 - 1.000000 S550 318 - 318 0.0271 - 0.0413 0.040900 - 0.962600 S551 341 - 351 0.101 - 0.101 0.008000 - 0.985000 S552 341 - 353 0.101 - 0.101 0.000000 - 1.000000 S553 341 - 353 0.101 - 0.101 0.000000 - 1.000000 S554 306 - 336 0.024 - 0.0533 0.000000 - 1.000000 Continued on next page... S518
S107
N 2 67 109 14 34 18 40 3 21 42 13 22 77 14 88 104 27 36 13 15 28 113 7 18 1 8 1 130 10 14 20 7 4 14 40 12 15 11 15 20
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 410 - 533 0.689 - 6.21 0.250000 - 0.750000 S556 405 - 534 0.689 - 6.25 0.250000 - 0.750000 S557 341 - 462 0.101 - 1.48 0.016000 - 0.990000 S558 328 - 328 0.0478 - 0.0628 0.084000 - 0.943000 S482 317 - 353 0.0296 - 0.101 0.000000 - 1.000000 S559 328 - 328 0.0478 - 0.0628 0.084000 - 0.943000 S560 323 - 323 0.0296 - 0.0513 0.000000 - 1.000000 S561 483 - 558 2.79 - 6.04 0.000000 - 1.000000 S562 339 - 351 0.0933 - 0.0933 0.016000 - 1.000000 S563 338 - 347 0.0933 - 0.0933 0.090000 - 0.975000 S564 328 - 353 0.0363 - 0.101 0.000000 - 1.000000 S565 298 - 298 0.00787 - 0.0166 0.000000 - 1.000000 S194 341 - 347 0.101 - 0.101 0.076000 - 0.914000 S181 288 - 328 0.0068 - 0.0611 0.071200 - 0.932100 S566 298 - 298 0.00784 - 0.0165 0.000000 - 1.000000 S567 298 - 298 0.0124 - 0.0165 0.100000 - 0.900000 S568 298 - 298 0.0106 - 0.0169 0.057000 - 0.935000 S569 318 - 318 0.0231 - 0.0413 0.000000 - 1.000000 S150 298 - 298 0.00978 - 0.0166 0.041000 - 0.910000 S570 341 - 350 0.101 - 0.101 0.036000 - 0.960000 S233 323 - 341 0.0499 - 0.101 0.552000 - 0.603000 S571 313 - 313 0.0179 - 0.0334 0.000000 - 1.000000 S572 341 - 440 0.101 - 0.811 0.000000 - 1.000000 S508 303 - 313 0.0105 - 0.0334 0.000000 - 1.000000 S573 341 - 342 0.1 - 0.1 0.267000 - 0.739000 S574 328 - 333 0.0374 - 0.0754 0.002400 - 0.998700 S575 294 - 347 0.0128 - 0.104 0.089700 - 0.903700 BENZENE & ETHYLENE S576 303 - 423 2.19 - 10.9 0.101900 - 0.802200 S577 303 - 423 1.01 - 12.2 0.170000 - 0.982000 S578 272 - 563 2.03 - 9.12 0.000000 - 1.000000 S258 293 - 333 0.277 - 3.13 0.498000 - 0.982000 S579 160 - 270 0.0588 - 1.44 0.009120 - 0.851000 S580 298 - 298 0.0836 - 0.132 0.985210 - 0.991234 S581 353 - 433 3-9 0.328000 - 0.931000 S582 513 - 533 3.5 - 6.5 0.847000 - 0.992000 BENZENE & H2S S583 323 - 423 0.455 - 9.8 0.064000 - 0.944100 BENZENE & HELIUM BENZENE & HEPTANE S584 353 - 370 0.101 - 0.101 0.052000 - 0.955000 S445 326 - 372 0.04 - 0.101 0.000000 - 1.000000 S585 323 - 358 0.0289 - 0.101 0.017890 - 0.979340 S586 353 - 353 0.0606 - 0.0998 0.046400 - 0.897200 S546 355 - 369 0.101 - 0.101 0.062000 - 0.778000 S587 353 - 372 0.101 - 0.101 0.000000 - 1.000000 S554 313 - 351 0.024 - 0.0533 0.000000 - 1.000000 S588 353 - 371 0.101 - 0.101 0.015000 - 0.935000 S589 348 - 348 0.0525 - 0.0858 0.074100 - 0.937800 Continued on next page... S555
S108
N 24 27 48 9 21 9 15 64 16 16 16 11 11 47 27 9 11 13 9 14 6 24 75 35 6 34 221 14 56 93 15 12 5 30 16 24
14 80 32 10 8 38 22 18 11
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 293 - 293 0.00507 - 0.0101 0.028000 - 0.972000 S591 333 - 333 0.0317 - 0.0518 0.087000 - 0.908000 S592 352 - 369 0.101 - 0.101 0.039000 - 0.970000 S593 353 - 372 0.101 - 0.101 0.000000 - 1.000000 S490 333 - 333 0.0289 - 0.0522 0.045400 - 0.979000 S594 351 - 369 0.096 - 0.101 0.071000 - 0.960000 S595 328 - 328 0.0231 - 0.0445 0.000000 - 1.000000 S596 333 - 353 0.028 - 0.101 0.000000 - 1.000000 S597 353 - 371 0.101 - 0.101 0.023000 - 0.940000 S598 383 - 488 0.158 - 1.77 0.070700 - 0.878000 S599 318 - 318 0.0169 - 0.03 0.060400 - 0.977900 S600 298 - 313 0.006 - 0.0241 0.000000 - 1.000000 S495 353 - 353 0.057 - 0.101 0.000000 - 1.000000 S601 313 - 348 0.0146 - 0.0853 0.099000 - 0.925000 S602 328 - 328 0.0231 - 0.0436 0.000000 - 1.000000 S603 341 - 368 0.0667 - 0.101 0.100000 - 0.900000 S604 340 - 372 0.0648 - 0.101 0.000000 - 1.000000 S605 353 - 372 0.101 - 0.101 0.000000 - 1.000000 S572 353 - 461 0.101 - 0.811 0.000000 - 1.000000 S511 413 - 413 0.35 - 0.441 0.197200 - 0.673100 S525 313 - 313 0.0123 - 0.0244 0.000000 - 1.000000 S606 298 - 320 0.0129 - 0.0328 0.970600 - 0.993000 S607 298 - 313 0.0061 - 0.0244 0.000000 - 1.000000 S608 313 - 313 0.0123 - 0.0244 0.000000 - 1.000000 S609 313 - 313 0.0183 - 0.023 0.296400 - 0.700200 S516 313 - 313 0.0183 - 0.023 0.296800 - 0.702000 S610 313 - 313 0.0183 - 0.023 0.299500 - 0.699100 BENZENE & HEXANE S611 340 - 354 0.102 - 0.102 0.000000 - 1.000000 S612 340 - 353 0.0965 - 0.101 0.000000 - 1.000000 S587 341 - 353 0.101 - 0.101 0.000000 - 1.000000 S475 393 - 454 0.405 - 1.01 0.080000 - 1.000000 S613 342 - 353 0.101 - 0.101 0.016000 - 0.976000 S614 342 - 353 0.101 - 0.101 0.016000 - 0.976000 S615 342 - 353 0.101 - 0.101 0.000000 - 1.000000 S616 342 - 342 0.101 - 0.101 0.000000 - 0.060000 S617 341 - 341 0.00667 - 0.101 0.049962 - 0.150000 S618 304 - 333 0.0267 - 0.0533 0.063000 - 0.970000 S558 328 - 328 0.0495 - 0.0648 0.123000 - 0.915000 S619 342 - 351 0.101 - 0.101 0.053000 - 0.927000 S483 343 - 343 0.0828 - 0.106 0.125000 - 0.875000 S559 328 - 328 0.0495 - 0.0648 0.123000 - 0.915000 S620 333 - 333 0.0522 - 0.0767 0.000000 - 1.000000 S485 342 - 352 0.101 - 0.101 0.080000 - 0.972000 S591 342 - 351 0.101 - 0.101 0.060000 - 0.945000 S487 342 - 352 0.101 - 0.101 0.080000 - 0.972000 S621 298 - 313 0.0161 - 0.037 0.000000 - 0.832000 S565 298 - 298 0.0127 - 0.0206 0.000000 - 1.000000 S597 342 - 351 0.101 - 0.101 0.080000 - 0.921000 Continued on next page... S590
S109
N 18 12 13 11 13 58 20 25 22 74 15 24 9 22 13 20 45 19 62 15 14 4 49 27 2 2 2 11 38 38 34 23 23 15 6 7 31 14 13 7 14 12 18 16 18 52 10 10
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 298 - 340 0.0157 - 0.0846 0.000000 - 1.000000 S494 274 - 298 0.00464 - 0.0205 0.090000 - 0.952000 S623 298 - 298 0.0128 - 0.0202 0.010400 - 0.996100 S624 298 - 298 0.0127 - 0.0202 0.000000 - 1.000000 S625 363 - 463 0.147 - 1.51 0.089800 - 0.961300 S626 343 - 343 0.0729 - 0.104 0.000000 - 1.000000 S627 333 - 333 0.0545 - 0.0765 0.027700 - 0.971500 S628 323 - 323 0.0414 - 0.0538 0.190000 - 0.914000 S629 342 - 353 0.101 - 0.101 0.000000 - 1.000000 S525 313 - 313 0.0244 - 0.0374 0.000000 - 1.000000 S630 296 - 350 0.0144 - 0.104 0.078100 - 0.889600 S631 323 - 323 0.0414 - 0.0538 0.190000 - 0.914000 BENZENE & HYDROGEN S632 298 - 423 0.0127 - 294 0.406000 - 1.000000 S633 433 - 533 1.9 - 17.8 0.868250 - 0.992850 S634 339 - 433 0.525 - 68.9 0.757000 - 0.998340 S635 366 - 422 3.32 - 14 0.921500 - 0.985800 S636 323 - 423 2.55 - 15.7 0.941500 - 0.989700 S637 303 - 303 0.989 - 4.6 0.987320 - 0.997327 S638 298 - 298 0.101 - 0.101 0.999780 - 0.999780 S639 150 - 320 0.525 - 68.9 0.000000 - 0.998340 S453 433 - 533 0.71 - 20.7 0.776790 - 1.000000 BENZENE & IBUTENE S640 298 - 298 0.0271 - 0.102 0.769000 - 0.970000 BENZENE & IHEXANE S641 283 - 323 0.00608 - 0.0723 0.000000 - 1.000000 S642 313 - 333 0.0244 - 0.1 0.000000 - 1.000000 BENZENE & IOCTANE S445 353 - 372 0.101 - 0.101 0.000000 - 0.988000 S643 298 - 298 0.00653 - 0.0132 0.000000 - 1.000000 S644 308 - 348 0.0122 - 0.0865 0.079300 - 0.988400 S645 313 - 313 0.013 - 0.0245 0.000000 - 1.000000 S646 351 - 368 0.094 - 0.094 0.044000 - 1.000000 BENZENE & ISOBUTAN S647 298 - 298 0.0405 - 0.102 0.855000 - 0.962000 BENZENE & METHANE S648 311 - 378 9.87 - 16.5 0.714912 - 0.820137 S649 311 - 311 10.5 - 35.8 0.239900 - 0.805400 S650 339 - 339 0.689 - 33.1 0.305000 - 0.986000 S208 298 - 298 0.101 - 0.101 0.997910 - 0.997910 S651 273 - 333 4.9 - 43.6 0.240000 - 0.914000 S652 421 - 501 1.99 - 24.3 0.505300 - 0.974800 S653 165 - 278 1.01 - 17.2 0.000110 - 0.981500 S654 313 - 313 14.9 - 37.4 0.312000 - 0.713000 S655 266 - 352 5.11 - 53.7 0.267800 - 0.898300 S656 323 - 423 1.46 - 9.14 0.833500 - 0.972500 S657 323 - 373 14.5 - 35.7 0.310900 - 0.759200 S658 278 - 348 2.18 - 9.62 0.835000 - 0.963000 BENZENE & METHANOL Continued on next page... S622
S110
N 122 48 50 14 60 15 31 6 15 17 159 6 27 49 20 4 18 9 1 28 96 5 24 42 25 9 34 18 23 4 6 11 17 1 35 18 22 6 218 24 47 18
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 273 - 373 0.00359 - 0.386 0.000000 - 1.000000 S99 330 - 352 0.0967 - 0.0967 0.000000 - 1.000000 S659 313 - 313 0.0351 - 0.0488 0.000000 - 0.859000 S545 293 - 293 0.01 - 0.019 0.000000 - 1.000000 S660 298 - 328 0.0244 - 0.0905 0.080300 - 0.975800 S661 308 - 308 0.0199 - 0.039 0.000000 - 1.000000 S662 328 - 328 0.0658 - 0.0904 0.401200 - 0.959500 S663 331 - 352 0.098 - 0.098 0.000000 - 1.000000 S552 331 - 353 0.101 - 0.101 0.003500 - 1.000000 S664 363 - 363 0.249 - 0.306 0.143500 - 0.883000 S476 312 - 353 0.0229 - 0.101 0.000000 - 1.000000 S665 331 - 351 0.101 - 0.101 0.005100 - 0.998000 S555 397 - 522 0.689 - 7.58 0.250000 - 0.750000 S561 493 - 553 2.6 - 7.53 0.106400 - 1.000000 S666 330 - 340 0.0973 - 0.0973 0.033500 - 0.980000 S667 373 - 493 0.312 - 5.76 0.047900 - 0.976700 S668 288 - 328 0.0112 - 0.0902 0.053000 - 0.968000 S669 331 - 344 0.101 - 0.101 0.027000 - 0.974000 S670 331 - 350 0.101 - 0.101 0.030000 - 0.981000 S671 330 - 353 0.0987 - 0.101 0.000000 - 1.000000 S672 318 - 349 0.0317 - 0.0987 0.012800 - 0.996800 S673 303 - 340 0.0307 - 0.0695 0.004100 - 0.998300 S566 298 - 298 0.0127 - 0.0244 0.000000 - 1.000000 S567 298 - 298 0.0221 - 0.0244 0.100000 - 0.900000 S674 331 - 347 0.101 - 0.101 0.055000 - 0.990000 S675 308 - 308 0.0197 - 0.0391 0.000000 - 1.000000 S150 298 - 298 0.0185 - 0.0243 0.042000 - 0.937000 S676 330 - 353 0.1 - 0.1 0.000000 - 1.000000 S570 331 - 337 0.101 - 0.101 0.046000 - 0.945000 S677 332 - 345 0.101 - 0.101 0.054000 - 0.977000 S233 309 - 331 0.0411 - 0.101 0.384000 - 0.438000 S571 313 - 313 0.0244 - 0.0488 0.000000 - 1.000000 S510 298 - 298 0.0127 - 0.0244 0.000000 - 1.000000 S678 318 - 341 0.0299 - 0.0695 0.000000 - 1.000000 S679 332 - 336 0.0995 - 0.101 0.026200 - 0.165900 S680 329 - 336 0.101 - 0.101 0.030000 - 0.956000 BENZENE & MXYLENE S681 298 - 323 0.00294 - 0.0339 0.037000 - 0.929000 S682 353 - 399 0.101 - 0.101 0.102400 - 1.000000 S683 364 - 398 0.101 - 0.101 0.102000 - 0.681000 BENZENE & NEOPENTN S684 273 - 273 0.00353 - 0.0714 0.000000 - 1.000000 BENZENE & NITROGEN S685 373 - 448 7.6 - 9.93 0.940500 - 0.955000 S686 303 - 373 6.74 - 35.6 0.799000 - 0.969000 S687 352 - 445 3.47 - 167 0.049400 - 0.960900 S688 373 - 411 3.24 - 15.8 0.896500 - 0.980000 S689 303 - 423 6.21 - 31.9 0.000000 - 0.965500 BENZENE & NONANE Continued on next page... S529
S111
N 85 16 13 19 20 8 5 16 16 6 20 42 32 43 16 68 54 10 15 26 45 74 27 9 13 10 10 12 14 10 11 75 13 63 6 105 35 10 9 8 3 15 187 15 55
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 333 - 353 0.00397 - 0.1 0.000000 - 1.000000 S691 333 - 353 0.00397 - 0.1 0.000000 - 1.000000 S692 353 - 424 0.101 - 0.101 0.000000 - 1.000000 BENZENE & OCTANE S445 353 - 399 0.101 - 0.101 0.000000 - 1.000000 S546 358 - 393 0.101 - 0.101 0.061000 - 0.789000 S693 328 - 348 0.0169 - 0.0838 0.183300 - 0.957000 S600 298 - 328 0.00186 - 0.0439 0.000000 - 1.000000 S525 313 - 313 0.00415 - 0.0244 0.000000 - 1.000000 BENZENE & OXYGEN S694 303 - 333 0.0158 - 0.425 0.996748 - 1.000000 S254 298 - 298 0.101 - 0.101 0.999180 - 0.999180 BENZENE & OXYLENE S536 354 - 417 0.101 - 0.101 0.003100 - 0.974000 S692 353 - 418 0.101 - 0.101 0.000000 - 1.000000 BENZENE & PENTANE S587 309 - 353 0.101 - 0.101 0.000000 - 1.000000 S695 255 - 289 0.00687 - 0.0469 0.040000 - 0.948000 S696 308 - 323 0.0276 - 0.128 0.100200 - 0.974500 S697 421 - 538 1.38 - 4.41 0.199038 - 0.814290 BENZENE & PROPANE S698 311 - 511 0.0221 - 5.98 0.000000 - 1.000000 BENZENE & PROPYLEN S699 283 - 343 0.101 - 0.101 0.925400 - 0.993200 S258 293 - 333 0.0628 - 0.734 0.390000 - 0.967000 S700 283 - 338 0.203 - 0.507 0.635000 - 0.957000 S259 303 - 343 0.147 - 0.686 0.621000 - 0.969000 S701 298 - 298 0.148 - 1.09 0.049100 - 0.922700 S702 453 - 543 1.5 - 6 0.543500 - 0.968200 BENZENE & PXYLENE S597 357 - 402 0.101 - 0.101 0.086000 - 0.886000 S703 308 - 308 0.00327 - 0.0177 0.066400 - 0.885200 S704 353 - 412 0.101 - 0.101 0.000000 - 1.000000 S705 353 - 412 0.101 - 0.101 0.000000 - 1.000000 S536 356 - 408 0.101 - 0.101 0.042000 - 0.915800 BENZENE & R113 S706 278 - 298 0.0104 - 0.0389 0.260000 - 0.776000 S707 283 - 308 0.01 - 0.0595 0.199800 - 0.915000 BENZENE & R114 S708 363 - 423 0.6 - 2.71 0.260300 - 0.704900 BENZENE & R116 S709 297 - 297 0.101 - 0.101 0.998889 - 0.998898 BENZENE & R12 S710 298 - 308 0.101 - 0.101 0.055000 - 0.072000 BENZENE & R13 S710 297 - 309 0.101 - 0.101 0.005680 - 0.006140 BENZENE & R14 S709 288 - 297 0.101 - 0.101 0.999468 - 0.999507 S711 288 - 308 0.101 - 0.101 0.999449 - 0.999575 Continued on next page... S690
S112
N 25 25 17 22 8 67 33 15 21 1 13 19 42 40 53 22 106 7 9 15 12 11 31 13 15 20 20 15 21 48 12 2 3 4 5 9
Table S4 – continued from previous page Reference T (K) p (MPa) x1 (-) BENZENE & R218 S709 297 - 298 0.101 - 0.101 0.997560 - 0.997570 BENZENE & R22 S712 236 - 330 0.0416 - 0.133 0.207000 - 0.959700 S265 293 - 293 0.0973 - 0.0973 0.923300 - 0.923300 BENZENE & R23 S711 288 - 308 0.101 - 0.101 0.992700 - 0.995490 BENZENE & R32 S711 288 - 308 0.101 - 0.101 0.982020 - 0.987140 BENZENE & R41 S711 288 - 308 0.101 - 0.101 0.983890 - 0.988180 BENZENE & RC318 S709 297 - 297 0.101 - 0.101 0.988800 - 0.990700 BENZENE & SO2 S695 255 - 255 0.0273 - 0.0689 0.035000 - 0.660000 BENZENE & TOLUENE S713 353 - 383 0.0385 - 0.1 0.000000 - 1.000000 S468 353 - 353 0.0387 - 0.0992 0.000000 - 1.000000 S714 393 - 553 0.151 - 3.86 0.117000 - 0.777000 S715 355 - 374 0.101 - 0.101 0.282000 - 0.914000 S716 353 - 384 0.101 - 0.101 0.000000 - 1.000000 S717 353 - 384 0.101 - 0.101 0.000000 - 1.000000 S718 353 - 384 0.101 - 0.101 0.000000 - 1.000000 S597 354 - 382 0.101 - 0.101 0.052000 - 0.961000 S719 313 - 334 0.00787 - 0.0541 0.000000 - 1.000000 S683 362 - 384 0.101 - 0.101 0.008000 - 0.599000 S705 353 - 384 0.101 - 0.101 0.000000 - 1.000000 S186 353 - 384 0.101 - 0.101 0.000000 - 1.000000 S720 355 - 382 0.101 - 0.101 0.037400 - 0.914800 S721 333 - 353 0.0183 - 0.101 0.000000 - 1.000000 S722 353 - 384 0.101 - 0.101 0.000000 - 1.000000 S723 353 - 384 0.101 - 0.101 0.000000 - 1.000000 S724 325 - 410 0.0134 - 0.448 0.000000 - 1.000000 BENZENE & WATER S542 342 - 342 1.01 - 1.01 0.704247 - 0.704247 S545 293 - 293 0.00999 - 0.0123 0.997400 - 1.000000 S725 546 - 636 10 - 21 0.028800 - 0.447000 S726 303 - 532 0.0201 - 13.7 0.384200 - 0.783900 S727 573 - 573 10 - 10 0.001800 - 0.001800 S728 346 - 349 0.101 - 0.101 0.050000 - 0.950000 S729 342 - 371 0.101 - 0.101 0.002000 - 0.990500 S730 298 - 333 -1 - -1 0.001790 - 0.999410 BUTANE & C14 S731 323 - 454 0.12 - 4.4 0.202700 - 0.907400 BUTANE & C2BUTENE S732 278 - 358 0.114 - 1.12 0.264200 - 0.893700 BUTANE & CO2 S733 300 - 416 1.36 - 8.14 0.139100 - 0.860700 S734 311 - 411 0.355 - 8.16 0.060000 - 1.000000 Continued on next page...
S113
N 2 28 1 9 9 9 2 19 14 9 27 6 13 11 17 21 33 9 19 2 16 22 11 13 18 1 11 43 9 1 10 14 6 134 20 40 89
Table S4 – continued from previous page Reference S735 S736 S79 S737 S738 S739 S740 S741 S742 S743 S744 S745 S746 S747 S124 S748 S749 S750 S751 S752 S753 S754 S755 S756 S757 S758 S759 S760 S761 S762 S763 S764 S765
BUTANE S117
BUTANE S766 S767 S768 S769 S770
BUTANE S771 S772
BUTANE S773 S774 S775 S776
T (K) p (MPa) 278 - 311 2.76 - 5.52 273 - 273 0.135 - 0.18 273 - 273 0.105 - 3.49 283 - 283 0.358 - 4.13 228 - 283 0.0331 - 4.13 228 - 283 0.0331 - 4.13 319 - 378 2.18 - 8.12 250 - 280 0.0391 - 4.16 368 - 418 1.39 - 7.9 250 - 270 0.04 - 2.81 311 - 395 0.357 - 8.06 278 - 418 0.345 - 8.07 311 - 411 0.356 - 8.06 309 - 394 0.336 - 8.11 311 - 311 2.37 - 7.08 300 - 416 0.29 - 8.16 260 - 260 0.061 - 2.42 311 - 395 0.357 - 8.06 309 - 394 0.347 - 7.95 273 - 273 0.105 - 3.49 311 - 311 0.507 - 7.38 311 - 411 0.355 - 8.16 311 - 411 0.356 - 8.06 278 - 418 0.125 - 8.22 368 - 418 1.39 - 7.9 319 - 378 1.66 - 8.12 228 - 283 0.0331 - 4.13 311 - 311 0.958 - 7.13 273 - 273 0.116 - 0.21 283 - 283 0.358 - 4.13 250 - 270 0.0395 - 2.81 228 - 283 0.0331 - 4.13 250 - 280 0.0391 - 4.16 & CYCLOHEX 283 - 313 0.101 - 0.101 & DECANE 311 - 511 0.0005 - 4.83 311 - 511 0.172 - 4.92 313 - 482 0.16 - 4.76 344 - 344 9.56 - 9.76 344 - 344 9.03 - 11.6 & DME 283 - 414 0.147 - 4.81 293 - 293 0.207 - 0.512 & ETHANE 269 - 406 0.517 - 5.79 339 - 422 3.98 - 5.77 339 - 394 3.24 - 5.55 303 - 363 0.441 - 5.33
S114
x1 (-) 0.259400 - 0.699600 0.988000 - 0.996500 0.000000 - 1.000000 0.074600 - 0.970400 0.074600 - 0.992350 0.074600 - 0.992350 0.125000 - 0.912000 0.000000 - 1.000000 0.421700 - 1.000000 0.097600 - 1.000000 0.061200 - 1.000000 0.065700 - 0.980900 0.078600 - 1.000000 0.145000 - 1.000000 0.122000 - 0.747000 0.000000 - 0.860700 0.000000 - 1.000000 0.061200 - 1.000000 0.145000 - 1.000000 0.000000 - 1.000000 0.000000 - 0.974000 0.000000 - 1.000000 0.078600 - 1.000000 0.000000 - 1.000000 0.421700 - 1.000000 0.125000 - 1.000000 0.074600 - 0.992350 0.129200 - 0.931600 0.000000 - 0.996500 0.074600 - 0.970400 0.097600 - 1.000000 0.074600 - 0.992350 0.000000 - 1.000000
N 3 5 15 10 29 29 54 72 30 36 109 109 36 59 11 97 11 109 56 15 16 71 36 130 30 55 29 14 18 10 36 29 73
0.249000 - 0.671200
3
0.000000 0.032400 0.202000 0.670000 0.053000
-
1.000000 0.975100 1.000000 0.754000 0.157000
119 67 100 6 24
0.000000 - 1.000000 0.000000 - 1.000000
151 11
0.052800 - 0.825100 0.187000 - 0.950000 0.247000 - 0.882000 0.068000 - 0.956000 Continued on next page...
119 4 19 43
Table S4 – continued from previous page Reference S777 S778 S749 S779 S780 S781 S782 S783 S784
BUTANE S785 S117 S786 S787 S788 S772 S789 S790 S791
BUTANE S792 S793
BUTANE S794 S795 S796
BUTANE S797
BUTANE S798
BUTANE S799 S800 S801
BUTANE S802 S803 S804 S805
BUTANE S806 S807 S808
BUTANE S809
BUTANE S810 S736 S803
T (K) p (MPa) x1 (-) 304 - 307 4.46 - 4.93 0.004270 - 0.035100 273 - 323 0.144 - 4.69 0.196200 - 0.978900 260 - 280 0.0611 - 2.79 0.000000 - 1.000000 366 - 422 0.352 - 6.49 0.000000 - 0.638000 310 - 404 1.43 - 6.79 0.135000 - 0.748000 229 - 419 0.689 - 5.79 0.000000 - 1.000000 339 - 339 3.49 - 6.06 0.030000 - 0.378000 422 - 450 3.53 - 8.32 0.000000 - 0.598000 339 - 394 3.12 - 8.17 0.000000 - 0.463000 & ETHANOL 298 - 323 0.00787 - 0.0986 0.000000 - 0.070920 283 - 313 0.101 - 0.101 0.046640 - 0.164700 298 - 346 0.008 - 0.881 0.000000 - 1.000000 323 - 514 0.24 - 6.13 0.000000 - 1.000000 364 - 364 0.161 - 1.29 0.000000 - 1.000000 293 - 293 0.0058 - 0.207 0.000000 - 1.000000 323 - 323 0.0294 - 0.501 0.000000 - 1.000000 323 - 423 0.0282 - 3.8 0.000000 - 1.000000 313 - 403 0.018 - 2.73 0.000000 - 1.000000 & ETHYLENE 273 - 398 0.098 - 6.49 0.000000 - 1.000000 284 - 407 0.394 - 6.72 0.000000 - 0.801500 & H2S 182 - 182 0.000419 - 0.0151 0.357700 - 1.000000 223 - 293 0.0291 - 1.79 0.000000 - 1.000000 366 - 418 1.35 - 8.07 0.000000 - 1.000000 & HCL 294 - 355 0.455 - 3.66 0.436000 - 0.980000 & HELIUM 153 - 273 0.49 - 3.92 0.988790 - 0.999990 & HEPTANE 329 - 525 0.276 - 4.1 0.159000 - 0.941000 404 - 448 0.557 - 0.773 0.090400 - 0.185600 336 - 540 0.689 - 3.96 0.000000 - 1.000000 & HEXANE 253 - 293 0.00195 - 0.207 0.000000 - 1.000000 362 - 423 1.01 - 1.01 0.133000 - 0.812000 375 - 505 0.621 - 3.86 0.000000 - 1.000000 374 - 502 0.276 - 3.9 0.000000 - 0.898000 & HYDROGEN 297 - 389 2.25 - 10.7 0.889000 - 0.980000 328 - 394 2.78 - 16.9 0.734000 - 0.981000 144 - 297 2.07 - 53.4 0.659000 - 0.992000 & IBUTENE 278 - 344 0.132 - 0.969 0.250000 - 0.750000 & ISOBUTAN 344 - 407 0.9 - 3.37 0.250000 - 0.754000 273 - 273 0.109 - 0.153 0.067900 - 0.910500 347 - 373 1.03 - 1.96 0.037000 - 0.948000 Continued on next page...
S115
N 27 42 42 104 47 263 21 54 73 17 3 72 210 30 15 26 64 48 101 502 7 123 63 33 50 133 3 175 60 6 180 193 13 60 45 15 15 24 38
Table S4 – continued from previous page Reference S811 S812 S813 S761 S814
BUTANE S815 S816 S817 S818 S819 S820 S821 S822 S823 S824 S825 S826 S827 S828 S829 S830 S831 S832 S833 S834
BUTANE S835 S836 S117 S262 S837 S788 S838 S789 S839
BUTANE S840
BUTANE S841 S842 S743 S350 S843 S844 S845 S755 S846 S847
T (K) p (MPa) x1 (-) 344 - 407 0.888 - 3.37 0.000000 - 0.754000 289 - 328 0.197 - 0.71 0.202100 - 0.794200 278 - 344 0.138 - 1.04 0.250000 - 0.750000 334 - 374 0.653 - 2.02 0.000000 - 1.000000 330 - 369 0.8 - 1.4 0.000000 - 1.000000 & METHANE 252 - 316 1.01 - 3.04 0.803000 - 0.970000 294 - 394 0.216 - 13.3 0.228769 - 1.000000 311 - 311 6.62 - 12.8 0.323000 - 0.689000 211 - 411 0.179 - 13.2 0.078600 - 0.985000 205 - 294 0.0689 - 12.4 0.219000 - 0.999770 166 - 283 6.9e-05 - 11 0.000000 - 1.000000 311 - 311 10.8 - 12.6 0.388900 - 0.484500 203 - 273 1.31 - 10.1 0.223600 - 0.892900 274 - 310 10.1 - 12.1 0.000000 - 0.177000 316 - 381 8.77 - 12 0.466700 - 0.654200 178 - 311 0.503 - 11.7 0.000000 - 0.878000 311 - 411 3.45 - 20.7 0.000000 - 0.989000 311 - 511 0.161 - 28 0.000000 - 0.835800 126 - 186 0.319 - 4.89 0.008000 - 0.089000 294 - 394 0.307 - 13.3 0.000000 - 0.915000 311 - 511 0.23 - 25.3 0.066000 - 0.660000 311 - 411 13.7 - 27.6 0.000000 - 0.001840 144 - 278 0.137 - 12.9 0.000000 - 0.000000 311 - 378 0.689 - 20.7 0.381600 - 0.989500 205 - 283 0.00282 - 11.6 0.000000 - 0.900000 & METHANOL 298 - 323 0.0279 - 0.102 0.000000 - 0.031710 323 - 323 0.0553 - 0.532 0.000000 - 1.000000 283 - 313 0.101 - 0.101 0.023220 - 0.044570 273 - 373 0.0039 - 1.72 0.000000 - 1.000000 470 - 470 3.79 - 6.92 0.000000 - 0.261000 363 - 363 0.258 - 1.41 0.000000 - 1.000000 364 - 364 0.268 - 1.44 0.000000 - 1.000000 323 - 323 0.0555 - 0.528 0.000000 - 1.000000 323 - 443 0.337 - 5.43 0.009400 - 0.991800 & MPALMITA 334 - 484 0.491 - 5.77 0.494700 - 0.976600 & NITROGEN 378 - 378 3.45 - 3.45 0.952000 - 0.952000 273 - 293 0.405 - 1.11 0.968800 - 0.992200 250 - 344 0.04 - 15.8 0.732200 - 1.000000 339 - 380 1.24 - 22.1 0.495000 - 1.000000 311 - 411 1.63 - 23.5 0.000000 - 0.984000 311 - 311 13.9 - 28.8 0.000000 - 0.770000 311 - 422 3.57 - 29.1 0.000000 - 0.989400 111 - 411 0.356 - 28.5 0.122800 - 1.000000 153 - 273 0.49 - 19.6 0.717200 - 0.999200 240 - 310 0.158 - 6.9 0.000000 - 0.000000 Continued on next page...
S116
N 30 16 30 33 153 9 124 7 77 102 67 3 19 30 6 121 84 179 24 96 77 16 173 34 99 6 11 3 35 7 29 27 26 60 76 1 12 52 31 34 21 27 80 49 50
Table S4 – continued from previous page Reference S833 S848 S849
BUTANE S850
BUTANE S850 S851 S852
BUTANE S853 S804 S854 S855 S856
BUTANE S857 S858 S859 S854 S860 S861 S850 S862 S863 S864 S865 S812 S866 S867 S868 S869
BUTANE S708
BUTANE S870 S871 S872
BUTANE S873
BUTANE S874 S872 S875
BUTANE S876 S877
BUTANE S878
T (K) p (MPa) x1 (-) 311 - 378 0.696 - 20.7 0.000000 - 0.998100 273 - 293 0.392 - 1.08 0.968800 - 0.992200 250 - 270 1.5 - 14 0.000000 - 0.326300 & NONANE 270 - 370 0.0223 - 0.979 0.214000 - 0.749000 & OCTANE 270 - 375 0.0294 - 0.907 0.254360 - 0.694330 335 - 556 0.524 - 4.32 0.000000 - 0.946100 273 - 567 0 - 4.31 0.000000 - 1.000000 & PENTANE 298 - 298 0.0733 - 0.108 0.017640 - 0.187000 358 - 464 1.03 - 3.72 0.000000 - 1.000000 241 - 410 0.014 - 2.48 0.147000 - 0.790000 340 - 465 0.689 - 3.78 0.000000 - 0.874500 358 - 464 1.03 - 3.72 0.000000 - 0.874500 & PROPANE 390 - 404 4.3 - 4.36 0.300000 - 0.544000 303 - 363 0.354 - 3.41 0.090000 - 0.937000 260 - 280 0.0611 - 0.586 0.000000 - 1.000000 237 - 414 0.058 - 3.94 0.175000 - 0.853000 260 - 350 0.226 - 2.12 0.414700 - 0.414700 0.103 - 1.71 273 - 323 0.000000 - 1.000000 270 - 365 0.162 - 1.75 0.783040 - 0.783040 273 - 323 0.203 - 1.63 0.031000 - 0.800300 340 - 419 1.39 - 4.31 0.000000 - 0.853200 270 - 310 0.143 - 0.906 0.000000 - 0.830800 260 - 350 0.226 - 2.12 0.349610 - 0.349610 289 - 328 0.258 - 1.63 0.155900 - 0.851300 332 - 425 1.55 - 4.31 0.000000 - 1.000000 237 - 249 0.0208 - 0.214 0.000000 - 1.000000 311 - 411 0.555 - 4.24 0.000000 - 0.796930 253 - 273 0.0451 - 0.472 0.000000 - 1.000000 & R113 363 - 423 0.589 - 2.97 0.252800 - 0.752300 & R125 278 - 298 0.125 - 1.37 0.000000 - 1.000000 313 - 333 0.378 - 3.16 0.000000 - 1.000000 241 - 333 0.139 - 2.49 0.000000 - 0.871760 & R13 311 - 400 0.434 - 4.75 0.082900 - 0.987600 & R134A 273 - 323 0.103 - 1.38 0.000000 - 1.000000 241 - 333 0.092 - 1.74 0.000000 - 0.838990 313 - 333 0.378 - 1.75 0.000000 - 1.000000 & R143A 313 - 363 0.377 - 3.72 0.000000 - 1.000000 273 - 323 0.104 - 2.3 0.000000 - 1.000000 & R152A 313 - 363 0.377 - 2.92 0.000000 - 1.000000 Continued on next page...
S117
N 14 12 93 140 145 146 245 11 90 81 125 73 2 29 30 69 12 82 27 41 170 20 12 20 247 35 48 48 12 26 38 15 49 91 14 47 50 84 61
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 273 - 323 0.104 - 1.2 0.000000 - 1.000000 BUTANE & R227EA S880 273 - 323 0.104 - 0.994 0.000000 - 1.000000 BUTANE & R23 S881 283 - 313 0.148 - 4.78 0.000000 - 1.000000 BUTANE & R245FA S882 280 - 380 0.163 - 2.17 0.308000 - 0.722000 BUTANE & R32 S883 283 - 313 0.152 - 2.48 0.000000 - 1.000000 S884 263 - 293 0.0696 - 1.48 0.000000 - 1.000000 S871 313 - 333 0.378 - 3.93 0.000000 - 1.000000 BUTANE & RC318 S885 233 - 233 0.0167 - 0.0297 0.000000 - 1.000000 BUTANE & T2BUTENE S732 278 - 358 0.122 - 1.13 0.248800 - 0.900100 BUTANE & WATER S886 311 - 425 0.362 - 4.4 0.951700 - 0.999500 S93 311 - 411 0.359 - 3.39 0.000044 - 0.999400 S887 311 - 411 0.136 - 3.38 0.000016 - 0.000176 S94 298 - 298 0.101 - 0.101 0.000019 - 0.000019 S888 628 - 637 25.5 - 112 0.025000 - 0.077000 S889 276 - 292 0.101 - 0.101 0.000019 - 0.000057 S726 311 - 425 0.362 - 4.39 0.929200 - 0.983300 S890 496 - 707 9 - 310 0.050000 - 0.900000 S891 298 - 423 0.104 - 4.13 0.000011 - 0.000300 S892 344 - 344 10 - 100 0.009200 - 0.010300 S893 311 - 425 0.362 - 4.4 0.000500 - 0.056800 C11 & CO2 S894 315 - 418 2.05 - 20 0.083900 - 0.887500 C11 & ETHANE S895 298 - 318 1.2 - 5.43 0.031000 - 0.721800 C11 & ETHANOL S896 333 - 353 0.00055 - 0.108 0.000000 - 1.000000 C11 & HELIUM S352 298 - 298 0.101 - 0.101 0.999756 - 0.999756 C11 & HEXANE S897 308 - 308 0.000119 - 0.0306 0.000000 - 1.000000 C11 & KRYPTON S352 298 - 298 0.101 - 0.101 0.992550 - 0.992550 C11 & METHANE S352 298 - 298 0.101 - 0.101 0.994554 - 0.994554 C11 & METHANOL S898 322 - 444 0.0541 - 0.0541 0.002000 - 1.000000 C11 & MXYLENE S899 343 - 393 0.01 - 0.01 0.000000 - 1.000000 C11 & NEON S352 298 - 298 0.101 - 0.101 0.999643 - 0.999643 C11 & NITROGEN S352 298 - 298 0.101 - 0.101 0.998676 - 0.998676 Continued on next page... S879
S118
N 73 72 43 23 84 42 53 10 19 26 15 39 1 5 5 10 71 26 5 26 42 19 38 1 14 1 1 10 15 1 1
Table S4 – continued from previous page Reference T (K) C11 & OXYGEN S352 298 - 298 C11 & OXYLENE S899 347 - 393 C11 & PXYLENE S899 342 - 393 C11 & R14 S352 298 - 298 C11 & SF6 S352 298 - 298 C12 & CO S900 344 - 411 C12 & CO2 S901 283 - 313 S902 254 - 267 S903 313 - 393 S904 318 - 318 S905 318 - 418 S906 308 - 348 C12 & CYCLOHEX S907 288 - 312 C12 & DECANE S908 393 - 431 C12 & DME S534 323 - 323 C12 & ETHANE S909 273 - 373 S910 195 - 255 S911 298 - 373 S912 308 - 373 S913 373 - 373 C12 & ETHYLENE S914 283 - 348 S915 264 - 339 S916 195 - 255 C12 & H2S S917 313 - 434 C12 & HCL S918 258 - 369 C12 & HELIUM S352 298 - 298 C12 & HEPTANE S919 345 - 482 C12 & HEXANE S920 308 - 308 C12 & HYDROGEN S921 366 - 422 C12 & KRYPTON S352 298 - 298
p (MPa)
x1 (-)
N
0.101 - 0.101
0.997737 - 0.997737
1
0.01 - 0.01
0.000000 - 1.000000
15
0.01 - 0.01
0.000000 - 1.000000
14
0.101 - 0.101
0.998168 - 0.998168
1
0.101 - 0.101
0.991504 - 0.991504
1
0.69 - 8.75
0.850700 - 0.988700
26
0.101 - 0.101 2.01 - 2.88 0.093 - 8.18 0.95 - 8.94 1.64 - 20.4 6.43 - 15.1
0.985100 0.130000 0.288000 0.194800 0.094200 0.013360
0.989100 0.343000 0.990300 0.886000 0.896100 0.306424
3 8 39 10 40 40
3e-06 - 0.024
0.000000 - 1.000000
40
0.02 - 0.02
0.000000 - 1.000000
29
0.0002 - 1.14
0.000000 - 1.000000
36
0.405 - 6.28 0.168 - 0.879 0.375 - 5.64 0.36 - 5.84 0.776 - 5.23
0.020000 0.000624 0.020000 0.153000 0.466000
0.950000 0.555800 0.912000 0.912600 0.889000
64 13 50 31 10
0.507 - 9.12 0.101 - 0.101 0.365 - 1.69
0.050000 - 0.935000 0.959800 - 0.986900 0.000614 - 0.561400
58 4 13
0.524 - 5.67
0.098000 - 0.933100
33
0.705 - 12.1
0.033000 - 0.807000
63
0.101 - 0.101
0.999749 - 0.999749
1
0.04 - 0.1
0.083700 - 0.995500
18
0.00221 - 0.0276
0.094500 - 0.924900
12
3.62 - 34.7
0.701000 - 0.962700
12
0.992427 - 0.992427 Continued on next page...
1
0.101 - 0.101
S119
-
-
Table S4 – continued from previous page Reference T (K) C12 & METHANE S922 348 - 423 S923 255 - 318 S924 323 - 373 S352 298 - 298 C12 & METHANOL S925 421 - 536 C12 & N2O S903 313 - 393 C12 & NEON S352 298 - 298 C12 & NITROGEN S922 348 - 423 S686 328 - 366 S352 298 - 298 S900 344 - 411 S926 344 - 594 C12 & OCTANE S908 349 - 431 C12 & OXYGEN S352 298 - 298 C12 & PENTANE S919 300 - 481 C12 & PROPANE S901 298 - 318 S927 206 - 257 S904 419 - 458 C12 & R14 S352 298 - 298 C12 & SF6 S352 298 - 298 C12 & TOLUENE S928 333 - 353 C12 & WATER S929 604 - 633 C14 & CO2 S902 269 - 311 S930 344 - 344 S931 279 - 303 S932 290 - 331 S933 298 - 303 S934 323 - 323 S935 373 - 373 S936 344 - 344 C14 & CYCLOHEX S442 308 - 308 C14 & DECANE S850 451 - 463 C14 & ETHANE
p (MPa) 7.75 1.39 1.33 0.101
-
x1 (-)
9.33 50.6 10.4 0.101
0.000413 0.101100 0.643400 0.994549
-
N
0.005470 0.905200 0.938500 0.994549
9 85 13 1
1.3 - 8.7
0.000000 - 0.151000
60
0.094 - 9.62
0.039000 - 0.992900
58
0.101 - 0.101
0.999652 - 0.999652
1
7.1 - 9.39 3.1 - 34.7 0.101 - 0.101 1.29 - 9.55 0.55 - 60.1
0.000219 0.651000 0.998694 0.874900 0.234200
0.004170 0.952000 0.998694 0.980500 0.997100
9 16 1 24 169
0.02 - 0.02
0.000000 - 1.000000
28
0.101 - 0.101
0.997705 - 0.997705
1
0.07 - 0.1
0.016800 - 0.998900
19
0.101 - 0.101 0.0345 - 0.138 0.406 - 7.68
0.877000 - 0.916900 0.008270 - 0.739500 0.122600 - 0.954900
3 22 25
0.101 - 0.101
0.998208 - 0.998208
1
0.101 - 0.101
0.991694 - 0.991694
1
0.00409 - 0.0387
0.000000 - 0.820000
21
0.88 - 21.8
0.002300 - 1.000000
20
3.08 11.1 3.98 0.91 6.24 0.98 0.96 7.08 -
0.160000 0.101000 0.168100 0.408500 0.160900 0.504000 0.642000 0.000000
0.297000 0.315000 0.237800 0.822600 0.167400 0.903000 0.930000 0.315000
11 17 13 24 2 6 6 40
8e-06 - 0.0201
0.000000 - 1.000000
27
0.0825 - 0.0838
0.250000 - 0.500000
2
8.26 16.4 6.92 4.04 6.97 -6 5.97 16.4
-
-
Continued on next page...
S120
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 323 - 423 1.01 - 8 0.122000 - 0.898000 C14 & HELIUM S352 298 - 298 0.101 - 0.101 0.999732 - 0.999732 C14 & HYDROGEN S938 328 - 473 3.92 - 29.4 0.674000 - 0.967000 C14 & KRYPTON S352 298 - 298 0.101 - 0.101 0.991954 - 0.991954 C14 & METHANE S731 321 - 433 2.7 - 48.9 0.183000 - 0.895000 S352 298 - 298 0.101 - 0.101 0.994199 - 0.994199 C14 & METHANOL S925 422 - 535 1.32 - 9.22 0.000000 - 0.089000 C14 & NEON S352 298 - 298 0.101 - 0.101 0.999655 - 0.999655 C14 & NITROGEN S731 321 - 434 8.4 - 214 0.199000 - 0.885000 S352 298 - 298 0.101 - 0.101 0.998685 - 0.998685 C14 & OXYGEN S352 298 - 298 0.101 - 0.101 0.997634 - 0.997634 C14 & PROPANE S939 378 - 408 2.97 - 6.48 0.003328 - 0.279727 C14 & R14 S352 298 - 298 0.101 - 0.101 0.998215 - 0.998215 C14 & SF6 S352 298 - 298 0.101 - 0.101 0.991787 - 0.991787 C1CC6 & CO2 S940 311 - 477 0.345 - 14.9 0.021000 - 0.973000 S941 263 - 353 0.408 - 11.4 0.050000 - 0.951000 C1CC6 & CYCLOHEX S470 357 - 371 0.101 - 0.101 0.048000 - 0.909000 S942 308 - 308 0.0107 - 0.0196 0.040400 - 0.918600 C1CC6 & DMC S120 318 - 318 0.0151 - 0.0203 0.000000 - 1.000000 C1CC6 & EBENZENE S641 313 - 353 0.00286 - 0.0539 0.000000 - 1.000000 S447 313 - 313 0.00287 - 0.0122 0.000000 - 1.000000 S448 303 - 323 0.00169 - 0.0185 0.000000 - 1.000000 S943 373 - 373 0.0343 - 0.0987 0.000000 - 1.000000 C1CC6 & ETHANE S944 313 - 473 0.6 - 9.18 0.077000 - 0.928000 C1CC6 & ETHANOL S945 273 - 303 0.0016 - 0.016 0.000000 - 1.000000 S946 308 - 328 0.00982 - 0.0507 0.000000 - 1.000000 S947 345 - 369 0.101 - 0.101 0.024000 - 0.992000 C1CC6 & H2S S940 311 - 418 0.25 - 9.45 0.030000 - 0.971000 C1CC6 & HEPTANE S948 372 - 374 0.101 - 0.101 0.000000 - 1.000000 S468 370 - 370 0.0913 - 0.0977 0.000000 - 1.000000 Continued on next page... S937
S121
N 21 1 12 1 94 1 47 1 84 1 1 35 1 1 31 255 8 13 9 36 19 28 12 27 73 20 22 29 11 5
Table S4 – continued from previous page Reference S949 S445 S950 S951 S952 S953 S954 S520
C1CC6 & S955
C1CC6 & S956 S637
C1CC6 & S957 S445 S958
C1CC6 & S959 S944
C1CC6 & S960 S961 S962
C1CC6 & S963
C1CC6 & S964 S965 S966
C1CC6 & S963 S447
C1CC6 & S955
C1CC6 & S944
C1CC6 & S963 S447 S947
C1CC6 & S967 S951 S968 S969 S970 S971 S972
T (K) p (MPa) x1 (-) 373 - 533 0.101 - 2.24 0.000000 - 0.546000 372 - 374 0.101 - 0.101 0.000000 - 1.000000 372 - 374 0.101 - 0.101 0.000000 - 1.000000 372 - 374 0.101 - 0.101 0.067500 - 0.948500 321 - 321 0.0168 - 0.0171 0.115800 - 0.936000 372 - 373 0.101 - 0.101 0.030500 - 0.757500 323 - 323 0.0186 - 0.0189 0.166900 - 0.710300 343 - 371 0.04 - 0.0933 0.050000 - 0.950000 HEXANE 342 - 374 0.101 - 0.101 0.000000 - 1.000000 HYDROGEN 424 - 499 0.34 - 96 0.210000 - 1.000000 303 - 303 1.24 - 4.32 0.978167 - 0.993770 IOCTANE 371 - 373 0.0988 - 0.0988 0.000000 - 1.000000 372 - 374 0.101 - 0.101 0.000000 - 1.000000 370 - 371 0.094 - 0.094 0.000000 - 1.000000 METHANE 200 - 255 0.689 - 25.9 0.144000 - 0.966700 313 - 473 2.52 - 27.7 0.263000 - 0.935000 METHANOL 333 - 337 0.101 - 0.101 0.100000 - 0.900000 333 - 337 0.101 - 0.101 0.049000 - 0.858000 333 - 333 0.0271 - 0.103 0.000000 - 1.000000 MXYLENE 348 - 348 0.0124 - 0.0457 0.000000 - 1.000000 NITROGEN 376 - 453 1.96 - 88.3 0.191000 - 0.978300 323 - 473 2.74 - 22.5 0.704000 - 0.968000 453 - 497 5.2 - 37.1 0.350000 - 0.936000 OXYLENE 348 - 348 0.0104 - 0.0457 0.000000 - 1.000000 313 - 313 0.00206 - 0.0122 0.000000 - 1.000000 PENTANE 309 - 374 0.101 - 0.101 0.000000 - 1.000000 PROPANE 233 - 473 0.194 - 6.15 0.047000 - 0.902000 PXYLENE 348 - 348 0.0129 - 0.0457 0.000000 - 1.000000 313 - 313 0.00265 - 0.0122 0.000000 - 1.000000 374 - 408 0.101 - 0.101 0.056000 - 0.980000 TOLUENE 374 - 384 0.101 - 0.101 0.000000 - 1.000000 374 - 382 0.101 - 0.101 0.100000 - 0.900000 333 - 363 0.0267 - 0.0533 0.000500 - 0.990000 333 - 373 0.0202 - 0.0981 0.097000 - 0.901000 333 - 384 0.0267 - 0.101 0.000000 - 1.000000 374 - 384 0.101 - 0.101 0.000000 - 1.000000 473 - 503 0.769 - 1.41 0.000000 - 1.000000 Continued on next page...
S122
N 5 13 7 11 13 11 7 93 34 31 8 13 11 24 98 24 5 5 28 28 20 21 21 31 17 47 25 26 20 18 21 9 31 51 78 33 20
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 374 - 382 0.101 - 0.101 0.066000 - 0.928000 S447 313 - 313 0.00789 - 0.0122 0.000000 - 1.000000 S448 303 - 323 0.00488 - 0.0185 0.000000 - 1.000000 S449 348 - 348 0.0344 - 0.0454 0.064900 - 0.894100 S973 344 - 368 0.04 - 0.0667 0.045700 - 0.957700 S954 323 - 323 0.0136 - 0.0181 0.094200 - 0.817500 C2BUTENE & ETHANOL S974 324 - 375 0.182 - 1.46 0.084700 - 0.985000 S975 337 - 337 0.0562 - 0.647 0.000000 - 1.000000 C2BUTENE & METHANOL S975 337 - 337 0.0995 - 0.683 0.000000 - 1.000000 S976 365 - 365 0.267 - 1.3 0.000000 - 1.000000 C2BUTENE & T2BUTENE S732 278 - 358 0.11 - 1.1 0.113000 - 0.724500 C3CC6 & CO2 S977 315 - 560 0.994 - 5.07 0.590600 - 0.968900 S978 313 - 473 1.03 - 18.4 0.208000 - 0.933000 C3CC6 & ETHANE S944 313 - 473 0.76 - 11.8 0.046000 - 0.948000 C3CC6 & H2S S979 311 - 478 0.177 - 13.1 0.016800 - 0.958200 C3CC6 & METHANE S944 314 - 473 1.5 - 39 0.237000 - 0.962000 C3CC6 & NITROGEN S978 314 - 473 1.64 - 99.7 0.541000 - 0.979600 C3CC6 & PROPANE S944 313 - 473 0.357 - 6.62 0.052000 - 0.913000 C4F10 & CO S980 293 - 333 0.965 - 16.1 0.407000 - 0.979000 C4F10 & CO2 S981 263 - 353 0.183 - 6.86 0.052700 - 0.978200 C4F10 & DME S982 313 - 393 0.495 - 4.95 0.004500 - 0.978200 C4F10 & ETHANE S983 263 - 353 0.194 - 4.57 0.041000 - 0.970000 C4F10 & ETHYLENE S984 268 - 298 0.091 - 5.12 0.000000 - 1.000000 C4F10 & H2S S985 293 - 333 0.394 - 4.87 0.003000 - 0.973000 C4F10 & METHANE S985 293 - 333 0.473 - 10.7 0.394000 - 0.988000 C4F10 & PROPANE S77 313 - 343 0.726 - 2.6 0.035000 - 0.947000 C4F10 & R365MFC S986 333 - 442 0.386 - 3.15 0.008900 - 0.742000 C5F12 & PENTANE S987 244 - 294 0.0107 - 0.104 0.000000 - 1.000000 S988 333 - 450 0.277 - 3.14 0.000000 - 1.000000 Continued on next page... S674
S123
N 13 20 35 27 24 9 14 24 24 27 19 19 24 26 35 31 31 27 39 83 92 84 56 45 34 37 75 58 38
Table S4 – continued from previous page Reference T (K) C5F12 & SF6 S989 298 - 298 CF3I & ISOBUTAN S990 263 - 293 CF3I & NITROGEN S991 293 - 313 CF3I & PROPANE S992 258 - 283 CF3I & R1234ZE S993 258 - 298 CF3I & R152A S994 258 - 283 CHLORINE & HCL S995 213 - 273 CHLORINE & R12 S996 283 - 283 CHLORINE & R22 S996 283 - 283 CHLORINE & R32 S996 283 - 283 CHLORINE & SO2 S997 238 - 259 S995 243 - 323 CO & CO2 S356 223 - 283 S998 223 - 283 S999 253 - 303 S361 223 - 283 S1000 223 - 283 CO & CYCLOHEX S1001 283 - 309 S1002 344 - 411 CO & DECANE S1003 311 - 378 S1004 311 - 339 CO & DMC S1005 293 - 373 CO & DME S1006 288 - 316 CO & ETHANE S1007 173 - 273 S1008 100 - 130 CO & ETHANOL S1009 298 - 323 CO & ETHYLENE S1010 234 - 273 CO & H2S S1011 203 - 293
p (MPa)
x1 (-)
N
0.2 - 0.2
0.949000 - 0.949000
1
0.108 - 0.428
0.000000 - 1.000000
36
3 - 10
0.784700 - 0.942800
24
0.133 - 0.637
0.000000 - 1.000000
32
0.12 - 0.56
0.000000 - 1.000000
54
0.133 - 0.404
0.000000 - 1.000000
36
0.0278 - 2.63
0.000000 - 1.000000
36
0.423 - 0.525
0.000000 - 1.000000
22
0.502 - 0.718
0.000000 - 1.000000
23
0.502 - 1.21
0.000000 - 1.000000
22
0.101 - 0.101 0.0378 - 1.57
0.173000 - 0.983000 0.000000 - 1.000000
27 57
5.27 - 13.1 0.679 - 14.2 4.02 - 8.81 2.39 - 13.1 0.679 - 14.2
0.043000 0.000000 0.000700 0.000000 0.000000
0.369000 0.463000 0.002500 0.369000 0.463000
19 38 52 22 38
0.101 - 0.101 1.59 - 15.2
0.000968 - 0.001003 0.016600 - 0.154400
6 33
2.22 - 10.2 1.27 - 5.27
0.038500 - 0.159900 0.022200 - 0.092800
18 11
2 - 12
0.041800 - 0.160600
24
0.42 - 7.7
0.000000 - 0.151500
52
0.862 - 11.7 0.457 - 2.81
0.011700 - 0.828000 0.107500 - 0.953600
25 28
1-4
0.005000 - 0.022100
8
1.48 - 9.03
0.000000 - 0.418000
88
0.000000 - 0.172000 Continued on next page...
54
0.0608 - 23.7
S124
-
Table S4 – continued from previous page Reference T (K) CO & HELIUM S373 77 - 128 S1012 80 - 120 S1013 80 - 120 CO & HEXANE S1014 293 - 473 S1015 295 - 323 CO & HYDROGEN S1016 70 - 125 S1017 120 - 120 S1018 57 - 88 S1019 77 - 123 S1020 108 - 123 CO & METHANE S1021 114 - 186 S393 91 - 124 S394 91 - 91 S354 123 - 178 S1022 143 - 173 S1017 120 - 140 S1023 143 - 143 S1024 91 - 91 S1025 120 - 140 CO & METHANOL S1026 223 - 273 S1009 298 - 323 S1027 273 - 328 S1028 298 - 499 CO & MXYLENE S1029 353 - 433 S1030 353 - 433 CO & NITROGEN S1031 83 - 119 S1032 70 - 122 S1033 70 - 122 S412 84 - 84 S353 68 - 68 S394 84 - 84 S1018 70 - 79 S1034 68 - 78 S1035 83 - 119 CO & OCTANE S453 463 - 533 CO & PROPANE S1036 248 - 298 S393 86 - 128 S1037 120 - 130 S1008 120 - 130 S1004 252 - 357
p (MPa)
x1 (-)
N
1.72 - 13.8 0.0786 - 13.8 0.0787 - 13.8
0.832700 - 0.997000 0.899700 - 1.000000 0.000000 - 1.000000
29 32 79
1.23 - 22.3 1.3 - 16.7
0.020700 - 0.523000 0.023400 - 0.247500
49 8
0.49 - 52.9 5-5 0.0334 - 22.8 0.608 - 15.2 2.76 - 6.89
0.444000 0.110300 0.000000 0.000000 0.815000
-
0.991600 0.110300 1.000000 0.953000 0.977500
134 1 96 24 11
0.69 - 4.96 0.0268 - 0.521 0.0117 - 0.252 0.364 - 4.74 2.76 - 4.14 1.5 - 2.89 1.52 - 3.9 0.0117 - 0.253 2.89 - 5
0.015700 0.030000 0.000000 0.026000 0.143000 0.383700 0.194000 0.000000 0.000000
-
0.787500 0.246000 1.000000 0.966000 0.505700 0.826400 0.803000 1.000000 0.110300
30 22 11 33 4 3 7 17 38
5-5 1-4 101 - 608 2.13 - 101
0.017600 0.003200 0.270000 0.000000
-
0.020300 0.017800 0.745000 0.616100
3 8 43 155
0.002720 - 0.018260 0.003600 - 0.018020
24 25
0.160000 0.000000 0.000000 0.000000 0.000000 0.000000 0.199000 0.974000 0.166000
0.890000 1.000000 1.000000 1.000000 1.000000 1.000000 0.799500 0.974000 0.890000
48 75 132 10 10 10 24 8 48
0.000000 - 0.166670
51
1.52 - 21.7 0.012700 - 0.680000 0.0204 - 0.599 0.007580 - 0.209000 0.673 - 2.81 0.054800 - 0.944700 0.682 - 3.03 0.054800 - 0.246200 0 - 18.4 0.000000 - 0.621000 Continued on next page...
28 13 28 19 80
0.371 - 2.35 0.371 - 2.35 0.158 - 2.2 0.0226 - 2.78 0.0223 - 2.79 0.128 - 0.204 0.0154 - 0.0292 0.128 - 0.204 0.0253 - 0.118 0.0163 - 0.0661 0.163 - 2.28 0.455 - 6.89
S125
-
Table S4 – continued from previous page Reference
T (K) 148 - 323 CO & PXYLENE S78 313 - 473 CO & WATER S1039 311 - 589 CO2 & COS S1040 248 - 273 CO2 & CYCLOHEX S1041 473 - 533 S1001 284 - 313 S459 273 - 303 S460 344 - 344 S1042 313 - 353 S1043 366 - 411 S1044 313 - 323 S1045 303 - 323 S1046 293 - 333 S1047 314 - 392 S465 344 - 344 S1048 366 - 411 CO2 & CYCLOPEN S1049 311 - 333 S351 367 - 412 S1050 277 - 493 CO2 & CYCLOPRO S1051 179 - 237 CO2 & DECANE S1052 278 - 511 S1053 237 - 243 S1054 463 - 584 S1055 343 - 594 S1056 344 - 378 S1057 313 - 313 S1058 344 - 378 S1059 311 - 344 S1060 344 - 344 S1061 344 - 344 S1062 319 - 373 S1063 311 - 344 S1064 308 - 349 S934 323 - 323 S1065 323 - 323 S935 373 - 373 S1066 344 - 344 S1067 344 - 344 S1068 278 - 511 S1069 463 - 584 S1070 343 - 594 S1071 344 - 378 S1038
p (MPa) 1.38 - 17.2
x1 (-) 0.000000 - 0.426000
N 86
5.07 - 30.4
0.045000 - 0.325000
30
0.345 - 13.8
0.000030 - 0.003340
18
0.282 - 3.49
0.000000 - 1.000000
60
1.34 - 13 0.101 - 0.101 0.767 - 5.8 6.87 - 11 0.89 - 10 0.171 - 14.5 2.41 - 7.55 0.97 - 8.65 3.9 - 9.81 2.44 - 6.03 6.87 - 11 0.171 - 14.5
0.000000 0.006850 0.081000 0.426000 0.066300 0.000000 0.201000 0.068000 0.451000 0.127000 0.426000 0.000000
0.570000 0.008560 0.806400 0.848000 0.648300 0.790100 0.885600 0.974700 0.981000 0.292000 0.880000 0.790100
45 3 28 15 27 20 16 29 45 20 16 20
0.175 - 8.26 0.366 - 12 0.0166 - 12
0.006700 - 0.857000 0.000000 - 0.735000 0.000000 - 1.000000
39 28 215
0.0268 - 0.21
0.048000 - 0.391000
33
0.345 - 18.8 0.045000 - 0.994600 0.218 - 0.971 0.564000 - 0.966000 1.44 - 5.17 0.042700 - 0.235800 3.09 - 18 0.111000 - 0.903000 6.38 - 16.5 0.457000 - 0.925000 1.43 - 7.41 0.147400 - 0.825900 4.07 - 15.4 0.310000 - 0.841000 4.55 - 11.8 0.383400 - 0.805800 4.33 - 11.9 0.338300 - 0.821100 0.89 - 12.7 0.069000 - 0.907000 3.24 - 16.1 0.214600 - 0.973100 2.51 - 11.5 0.191200 - 0.935000 5.91 - 13.5 0.666496 - 0.991233 1.02 - 5.96 0.094000 - 0.513000 1.02 - 5.96 0.094000 - 0.513000 1.12 - 6.19 0.075000 - 0.367000 0.89 - 12.7 0.000000 - 0.996000 4.33 - 11.9 0.338300 - 0.821100 2.76e-05 - 18.8 0.000000 - 1.000000 1.44 - 5.17 0.042700 - 0.235800 3.09 - 18 0.000000 - 0.903000 4.07 - 15.4 0.310000 - 0.841000 Continued on next page...
89 2 16 22 45 5 8 5 6 28 29 13 50 6 6 6 99 6 105 16 24 8
S126
-
Table S4 – continued from previous page Reference S1072
CO2 & S1073 S126 S1074
CO2 & S1075 S1076 S1077 S1078 S1079 S1080 S1081 S1082 S1083
CO2 & S1084 S1006 S1085 S1086
CO2 & S1087 S1088 S1089 S1090 S1091
CO2 & S1092 S1093 S1094 S1095 S79 S737 S1096 S1097 S1098 S1099 S1100 S1101 S1102 S1103 S1104 S1105 S1106 S1107 S1108 S1109 S749 S1110
T (K) 344 - 378 DEE 298 - 313 290 - 303 298 - 318 DMC 323 - 374 310 - 340 295 - 313 273 - 293 310 - 374 281 - 328 308 - 337 283 - 353 293 - 303 DME 273 - 387 288 - 320 298 - 320 283 - 333 EBENZENE 313 - 366 308 - 328 283 - 303 313 - 393 303 - 333 ETHANE 283 - 293 223 - 293 241 - 283 222 - 289 253 - 253 289 - 289 250 - 250 263 - 263 223 - 283 283 - 298 207 - 270 220 - 270 234 - 292 207 - 270 285 - 296 282 - 297 207 - 270 234 - 292 250 - 250 223 - 293 260 - 260 207 - 270
p (MPa) 6.38 - 16.5
x1 (-) 0.457000 - 0.930000
N 47
0.702 - 7.22 5.19 - 6.93 0.72 - 8.31
0.119000 - 0.900300 0.983700 - 0.983700 0.125600 - 0.965900
18 10 33
1.33 - 12.8 0.827 - 10 0.0203 - 0.257 0.66 - 4.19 1.11 - 14.1 0.0736 - 5.48 6.16 - 10.4 0.101 - 0.101 5.72 - 7.2
0.170000 0.107600 0.002802 0.240100 0.111500 0.014000 0.851600 0.005040 1.000000
-
0.962000 0.929000 0.035572 0.803500 0.933900 0.673400 0.975800 0.019460 1.000000
40 36 22 15 55 75 27 5 2
0.26 - 7.93 0.42 - 6.79 0.6 - 7.32 0.374 - 7.22
0.000000 0.000000 0.000000 0.000000
-
0.914900 0.857700 0.847800 1.000000
144 55 27 52
2.4 - 14.2 1.38 - 8.44 0.101 - 0.101 5.69 - 16.1 6.42 - 10.6
0.209700 0.107000 0.010000 0.271400 0.900200
-
0.845400 0.921000 0.013560 0.837400 0.978900
19 18 4 19 35
0.000000 - 1.000000 0.000000 - 1.000000 0.000000 - 1.000000 0.071500 - 0.917500 0.000000 - 1.000000 0.016700 - 0.915700 0.000000 - 1.000000 0.575000 - 0.784800 0.000000 - 1.000000 0.000000 - 1.000000 0.000000 - 1.000000 0.383500 - 0.914200 0.500420 - 0.500420 0.000000 - 1.000000 0.251660 - 0.739780 0.430000 - 0.850000 0.000000 - 1.000000 0.500420 - 0.500420 0.000000 - 1.000000 0.000000 - 1.000000 0.000000 - 1.000000 0.000000 - 1.000000 Continued on next page...
42 61 51 37 14 8 16 2 51 71 133 5 12 78 13 22 84 18 15 65 13 136
3.07 - 6.27 0.552 - 6.3 1.01 - 4.99 0.701 - 5.7 1.43 - 2.31 3.56 - 5.75 1.3 - 2.13 3.02 - 3.04 0.552 - 5 3.04 - 6.63 0.294 - 3.64 0.803 - 3.45 1.29 - 5.77 0.292 - 3.57 4.92 - 6.27 4.63 - 6.74 0.292 - 3.57 1.29 - 5.77 1.3 - 2.13 0.552 - 6.3 1.7 - 2.79 0.294 - 3.64
S127
Table S4 – continued from previous page Reference
T (K) 253 - 253 S1111 222 - 289 S1112 283 - 293 S1113 273 - 273 S1114 223 - 283 S762 289 - 289 S1115 241 - 283 S1116 283 - 298 S1117 284 - 297 CO2 & ETHANOL S1118 304 - 308 S1119 304 - 323 S1120 313 - 333 S1121 313 - 333 S1122 314 - 337 S1123 283 - 308 S1124 313 - 313 S1125 313 - 343 S1126 298 - 298 S1127 308 - 308 S1128 304 - 304 S128 291 - 313 S130 291 - 313 S1129 303 - 329 S131 291 - 313 S1130 323 - 392 S1131 373 - 373 S1132 323 - 323 S1133 323 - 333 S1134 313 - 373 S1135 298 - 409 S1136 313 - 345 S1137 333 - 453 S1138 314 - 324 S1139 313 - 328 S1140 333 - 333 S1141 323 - 373 S1142 291 - 291 S1143 288 - 323 S136 333 - 483 S1144 333 - 333 S137 291 - 313 S1145 313 - 353 S1146 293 - 353 S1147 313 - 313 S1148 293 - 303 S1149 313 - 313 S1150 313 - 313 S1151 333 - 373 S752
p (MPa) 1.43 - 2.31 0.701 - 5.7 3.04 - 6.27 2.4 - 3.98 0.552 - 5 3.56 - 5.75 1.01 - 4.99 3.04 - 6.63 4.73 - 6.27
x1 (-) 0.000000 - 1.000000 0.071500 - 1.000000 0.000000 - 1.000000 0.000000 - 1.000000 0.000000 - 1.000000 0.016700 - 0.915700 0.000000 - 1.000000 0.000000 - 1.000000 0.000000 - 0.739780
N 15 40 84 17 52 8 57 74 32
3.75 - 7.67 0.273000 - 0.996000 3.31 - 7.96 0.190200 - 0.996600 0.533 - 10.7 0.018700 - 0.967000 0.514 - 10.7 0.020000 - 0.873000 5.55 - 10.8 0.272000 - 0.845000 0.86 - 7.14 0.066000 - 0.820000 0.6 - 8.15 0.033000 - 0.970000 5.03 - 11.8 0.266000 - 0.950000 1.55 - 5.9 0.114000 - 0.876000 1.55 - 7.79 0.109800 - 0.994500 3.65 - 5.83 0.281800 - 0.504800 0.86 - 7.92 0.052900 - 0.830200 0.91 - 7.92 0.052900 - 0.848600 1.78 - 9.1 0.121300 - 0.907600 0.91 - 7.92 0.053000 - 0.849000 1.32 - 14.6 0.029000 - 0.850000 7 - 13.3 0.220000 - 0.536000 5.03 - 8.2 0.248000 - 0.506000 0.729 - 9.46 0.028500 - 0.643300 0.476 - 14.1 0.023700 - 0.945900 6.18 - 15.2 0.597000 - 0.956000 0.57 - 11.9 0.026900 - 0.966800 4 - 14.5 0.072600 - 0.813100 7.07 - 8.3 0.549900 - 0.949700 1.6 - 9.42 0.077800 - 0.843700 3.05 - 10.4 0.134200 - 0.780800 0.407 - 0.772 0.017010 - 0.019310 0.184000 - 0.996000 2.09 - 5.4 0.0855 - 0.538 0.003280 - 0.034280 7 - 14.9 0.200000 - 0.800000 7.05 - 10.5 0.350800 - 0.734800 2.45 - 8.18 0.192000 - 0.985000 1.31 - 13.9 0.057800 - 0.754700 0.52 - 11.1 0.018700 - 0.912500 1.97 - 8.18 0.100000 - 0.950000 0.75 - 3.05 0.055500 - 0.218500 0.613 - 7.72 0.048000 - 0.726100 0.514 - 3.81 0.027000 - 0.212000 1.12 - 14.2 0.059800 - 0.770000 Continued on next page...
19 30 26 23 23 17 11 29 18 20 4 68 60 52 60 22 3 4 22 43 16 55 22 7 22 7 5 9 23 57 3 64 31 46 10 6 16 8 36
S128
Table S4 – continued from previous page Reference S1152 S1153 S1154 S1155 S1156 S1157 S1158 S1159 S1160 S144 S1161 S1162 S1163
CO2 & S1164 S79 S1165 S1166 S1167 S752 S1168 S1169 S1170 S1113
CO2 & S1171 S1172 S1173 S1174 S1175 S1176 S1177 S1178 S1179 S1180
CO2 & S1181 S1182 S1183 S1184 S1185
CO2 & S1186 S1187 S901 S1188 S1189 S1190 S1055
T (K) 303 - 323 293 - 303 313 - 333 293 - 303 313 - 323 313 - 313 333 - 373 333 - 333 333 - 333 291 - 313 313 - 313 314 - 337 308 - 338 ETHYLENE 243 - 283 232 - 253 223 - 293 278 - 284 263 - 298 232 - 253 181 - 302 243 - 283 263 - 298 273 - 273 H2S 254 - 366 311 - 311 278 - 344 225 - 364 258 - 313 248 - 332 254 - 366 225 - 364 311 - 311 278 - 344 HELIUM 220 - 290 253 - 293 220 - 290 253 - 293 181 - 220 HEPTANE 238 - 238 183 - 215 283 - 313 311 - 394 311 - 477 220 - 300 394 - 502
p (MPa) 1.02 - 6.08 0.716 - 2.9 3.84 - 10.1 0.716 - 2.9 8-9 3.04 - 7.95 4 - 12 7.05 - 10.5 9.02 - 10.7 0.86 - 7.92 0.6 - 8.15 5.55 - 10.8 10.2 - 17
x1 (-) 0.049000 - 0.589000 0.053000 - 0.206100 0.259000 - 0.712000 0.053000 - 0.206100 0.701600 - 0.845000 0.162700 - 0.844100 0.170000 - 0.640000 0.348300 - 0.730500 0.493400 - 0.816400 0.052900 - 0.830200 0.033000 - 0.970000 0.272000 - 0.845000 0.021000 - 0.430000
N 12 6 12 6 3 10 9 3 3 68 11 23 29
1.62 - 5.51 0.952 - 2.62 0.678 - 6.49 4.05 - 5.59 2.65 - 6.91 0.952 - 2.62 2.03 - 6.08 1.64 - 5.49 2.65 - 6.91 3.84 - 4.4
0.012000 0.000000 0.000000 0.036000 0.000000 0.000000 0.000000 0.000000 0.000000 0.067100
-
0.932000 1.000000 1.000000 0.980000 1.000000 1.000000 0.906000 0.803400 1.000000 1.000000
29 27 52 28 60 27 160 25 60 14
2.03 - 8.11 4.14 - 4.14 2.76 - 6.89 0.689 - 8.27 0.644 - 5.47 1.65 - 8.86 2.03 - 8.11 0.689 - 8.27 4.14 - 4.14 2.76 - 6.89
0.000000 0.160000 0.109000 0.011000 0.000000 0.000000 0.000000 0.011000 0.160000 0.109000
-
1.000000 0.160000 0.403000 0.910000 0.755500 0.939400 1.000000 0.910000 0.185000 0.403000
83 1 2 83 27 52 83 83 2 2
1.48 - 20.1 1.98 - 14.1 0.993 - 20.2 1.98 - 14.1 2.15 - 14.6
0.939600 0.950700 0.000000 0.950700 0.000000
-
0.999360 1.000000 0.999360 1.000000 0.000000
41 33 62 33 77
0.203 - 1.01 0.060000 - 0.502000 0.0415 - 0.476 0.055000 - 0.581000 0.101 - 0.101 0.009500 - 0.013900 0.186 - 13.3 0.000000 - 0.949000 0.186 - 13.3 0.022000 - 0.949000 0.16 - 6.57 0.023300 - 1.000000 3.04 - 12.8 0.065000 - 0.724000 Continued on next page...
9 10 3 51 62 63 23
S129
Table S4 – continued from previous page Reference S1191 S1192 S1193 S1194 S463 S1195 S800 S1196 S1070 S1197 S1198 S1199
CO2 & S1186 S1187 S454 S1200 S459 S1201 S1202 S1192 S461 S463 S1203 S1204 S1197 S1205 S1206
CO2 & S1207 S1208 S1209 S1210 S1211 S1212 S1213 S1214 S1215 S1216 S1217 S1218
CO2 & S1194 S1219
CO2 & S1220 S1221 S1222 S1223
T (K) 311 - 311 313 - 364 302 - 363 311 - 413 293 - 313 353 - 394 302 - 363 311 - 477 394 - 502 182 - 216 225 - 245 311 - 394 HEXANE 238 - 238 177 - 216 298 - 313 313 - 393 273 - 303 303 - 323 303 - 323 311 - 352 293 - 308 293 - 313 298 - 313 313 - 393 177 - 216 308 - 343 303 - 323 HYDROGEN 233 - 298 220 - 290 220 - 290 258 - 273 278 - 298 220 - 290 278 - 290 273 - 273 273 - 273 220 - 290 233 - 298 273 - 273 IOCTANE 278 - 393 271 - 282 IPENTANE 278 - 378 308 - 379 312 - 377 408 - 453
p (MPa) 3.13 - 6.55 7.55 - 11.9 3.46 - 4.38 2.3 - 13.4 3.48 - 7.41 1.89 - 13.4 3.46 - 4.38 0.186 - 13.3 3.04 - 12.8 0.0415 - 0.476 13.9 - 114 0 - 13.3
x1 (-) 0.346000 - 0.806000 0.885000 - 0.958000 0.291800 - 0.427000 0.183000 - 0.914000 0.503000 - 0.904000 0.114800 - 0.777400 0.291800 - 0.427000 0.022000 - 0.949000 0.065000 - 0.724000 0.051900 - 0.680100 0.725000 - 0.725000 0.000000 - 0.949000
N 8 24 3 112 25 12 3 60 23 13 5 56
0.203 - 1.01 0.0213 - 0.479 0.444 - 7.66 0.779 - 11.6 1.07 - 6.11 1.86 - 8.49 1.82 - 8.46 7.18 - 10.2 1.7 - 7.31 3.28 - 7.31 0.444 - 7.66 0.779 - 11.6 0.0213 - 0.479 0.69 - 25.8 1.86 - 8.49
0.058000 0.027700 0.049500 0.028000 0.188000 0.174500 0.172000 0.834000 0.180000 0.503000 0.049500 0.028000 0.038200 0.065500 0.174500
-
0.526000 0.961800 0.924000 0.915000 0.901900 0.965600 0.970000 0.974000 0.955000 0.910000 0.924000 0.915000 0.972300 0.969200 0.965600
9 17 20 39 24 26 24 25 29 25 20 39 19 76 26
5.08 - 20 1.08 - 20.3 0.93 - 192 6.89 - 27.6 4.8 - 19.3 0.93 - 172 4.8 - 19.3 6.08 - 37.5 3.92 - 6.86 1.08 - 20.3 5.08 - 20 6.08 - 37.5
0.821000 0.861000 0.360000 0.807000 0.842900 0.000000 0.842900 0.000000 0.930000 0.000000 0.000000 0.000000
-
0.989000 0.998700 0.998500 0.976000 0.991200 1.000000 0.991200 0.953000 0.986000 0.998700 0.989000 0.953300
19 46 145 6 42 143 42 12 7 58 23 12
1.2 - 11.1 1.46 - 3.64
0.233000 - 0.752000 0.296500 - 0.786600
141 15
0.000000 - 1.000000 0.177300 - 0.627900 0.042000 - 0.695000 0.000000 - 0.528400 Continued on next page...
46 17 12 29
0.0421 - 8.89 1.69 - 4.95 0.717 - 9.46 1.48 - 8.29
S130
Table S4 – continued from previous page Reference
T (K) 253 - 444 S1225 378 - 378 S1226 253 - 444 S1227 378 - 378 S1228 308 - 379 S1229 278 - 378 S1230 408 - 453 CO2 & ISOBUTAN S1231 311 - 394 S79 273 - 273 S741 250 - 280 S742 383 - 398 S747 311 - 394 S1232 300 - 330 S751 311 - 394 S1233 311 - 394 S752 273 - 273 S757 383 - 398 S765 250 - 280 CO2 & KRYPTON S1234 301 - 304 CO2 & METHANE S1235 200 - 271 S1236 143 - 205 S1173 278 - 278 S1237 242 - 242 S356 233 - 283 S1238 173 - 220 S1239 253 - 288 S1096 230 - 270 S1240 153 - 219 S1241 270 - 270 S1242 273 - 298 S1243 219 - 270 S1210 258 - 258 S1244 219 - 253 S1245 220 - 223 S1246 288 - 293 S1247 298 - 298 S1225 301 - 301 S1103 230 - 270 S1248 230 - 270 S1249 112 - 170 S359 278 - 302 S1250 227 - 258 S1251 91 - 91 S1227 301 - 301 S1252 230 - 270 S1106 230 - 270 S1224
p (MPa) 0.207 - 8.98 2.03 - 9.23 0.207 - 8.98 2.03 - 9.35 1.69 - 5.41 0.0421 - 8.89 1.48 - 8.29
x1 (-) 0.017800 - 0.938300 0.085000 - 0.646000 0.017800 - 0.938300 0.085000 - 0.706000 0.117300 - 0.695300 0.000000 - 1.000000 0.000000 - 0.528400
N 87 11 87 12 28 46 29
0.503 - 7.18 0.157 - 3.49 0.0641 - 4.16 2.46 - 6 0.497 - 7.4 0.652 - 6.97 0.497 - 7.4 0.503 - 7.18 0.157 - 3.49 2.46 - 6 0.0641 - 4.16
0.000000 0.000000 0.000000 0.000000 0.000000 0.013000 0.000000 0.000000 0.000000 0.000000 0.000000
0.884500 1.000000 1.000000 0.343600 0.900400 0.776000 0.900400 0.884500 1.000000 0.343600 1.000000
33 20 76 19 69 28 69 33 20 19 76
0.968056 - 0.998945
91
1.48 - 7.9 0.090000 - 0.968500 0.758 - 5.2 0.800000 - 0.990000 6.89 - 6.89 0.867000 - 0.867000 2.41 - 2.41 0.949000 - 0.949000 5.27 - 8.19 0.481000 - 0.931000 2.66 - 6.15 0.000000 - 0.750000 6.23 - 8.52 0.556000 - 0.957000 0.892 - 8.52 0.416000 - 1.000000 1.19 - 6.49 0.001050 - 0.896500 3.2 - 8.43 0.694000 - 1.000000 4.1 - 8.1 0.814000 - 0.997600 0.581 - 8.41 0.417000 - 1.000000 6.89 - 6.89 0.767000 - 0.767000 5.83 - 8.29 0.476100 - 0.476100 2-5 0.672400 - 0.959000 5.12 - 8.15 0.825000 - 1.000000 6.45 - 7.78 0.933000 - 1.000000 6.86 - 7.56 0.974600 - 1.000000 0.892 - 8.38 0.418600 - 1.000000 0.894 - 8.42 0.411200 - 1.000000 0.093 - 2.31 0.000213 - 0.028960 4.59 - 7.54 0.026000 - 0.052700 6.89 - 27.6 0.000000 - 0.976000 0.0117 - 0.252 0.000000 - 1.000000 6.86 - 7.7 0.966200 - 1.000000 0.894 - 8.42 0.000000 - 1.000000 0.892 - 8.38 0.418600 - 1.000000 Continued on next page...
46 62 1 1 15 60 12 36 45 11 38 31 1 4 7 22 7 6 60 44 9 11 37 11 7 42 52
7.37 - 7.53
S131
-
Table S4 – continued from previous page Reference
T (K) 288 - 293 S1108 230 - 270 S1254 253 - 288 S1255 209 - 271 S1256 270 - 270 S1257 222 - 239 S361 233 - 283 S1258 200 - 271 S1259 153 - 219 S1260 153 - 219 S1179 311 - 311 S1180 278 - 344 S1261 199 - 285 S1262 205 - 256 S1215 255 - 255 S1263 219 - 270 S1000 223 - 243 S1264 173 - 220 S1265 143 - 228 CO2 & METHANOL S1266 273 - 348 S1267 213 - 247 S1268 243 - 273 S123 298 - 298 S454 298 - 313 S1269 323 - 398 S1270 233 - 298 S1271 243 - 298 S1272 313 - 313 S1273 298 - 473 S1274 230 - 330 S1121 313 - 313 S1275 323 - 478 S126 288 - 302 S1124 313 - 313 S1276 313 - 313 S1277 298 - 373 S130 291 - 313 S131 291 - 313 S1133 313 - 313 S1135 298 - 421 S1136 313 - 343 S1211 278 - 308 S1085 298 - 313 S1278 323 - 473 S1279 313 - 313 S1280 303 - 303 S1281 263 - 373 S140 313 - 330 S1253
p (MPa) 5.12 - 8.15 0.892 - 8.52 2.63 - 8.52 3.43 - 7.25 3.2 - 8.43 2.07 - 4.83 3.7 - 8.19 1.11 - 8.14 0.582 - 6.45 1.17 - 6.47 4.14 - 12.4 2.76 - 11 1.5 - 11.8 0.52 - 8.29 3.92 - 6.86 0.581 - 8.51 3.42 - 6.9 2.66 - 6.2 0.758 - 5.32
x1 (-) 0.825000 - 1.000000 0.000000 - 1.000000 0.000000 - 0.957000 0.358000 - 0.897000 0.000000 - 1.000000 0.108000 - 0.776000 0.000000 - 0.931000 0.078000 - 1.000000 0.000000 - 1.000000 0.000000 - 0.000000 0.029000 - 0.563000 0.000000 - 0.867000 0.076900 - 0.148800 0.476080 - 0.476080 0.800000 - 0.945000 0.000000 - 1.000000 0.550000 - 0.951000 0.000000 - 0.750000 0.000000 - 0.990000
N 23 37 32 12 13 17 18 78 62 127 17 28 14 9 7 32 17 61 217
0.689 - 6.97 0.0981 - 1.57 0.203 - 3.33 0.219 - 6.13 0.577 - 8.06 0.5 - 18.5 0.3 - 5.08 0.194 - 5.45 2.2 - 3.2 0.99 - 16.1 0.69 - 10.6 0.683 - 7.71 0.439 - 16.5 5.03 - 6.78 0.7 - 8.21 2.01 - 8.19 1.54 - 15.5 0.56 - 8.03 0.56 - 7.72 1.14 - 7.53 5.87 - 16.4 0.6 - 12.4 1.5 - 7.43 1.24 - 6.34 6 - 16.2 0.93 - 7.93 0.84 - 5.4 0.792 - 12.1 3.62 - 10.7
0.024500 - 0.360600 0.024600 - 1.000000 0.048000 - 0.789000 0.015000 - 0.957300 0.028500 - 0.990200 0.005000 - 0.750000 0.057800 - 1.000000 0.018000 - 0.717900 0.142000 - 0.172000 0.039200 - 0.969300 0.024490 - 0.986500 0.031000 - 0.616000 0.008700 - 0.850000 0.925000 - 0.925000 0.038000 - 0.968000 0.106000 - 0.950000 0.105000 - 0.911700 0.059500 - 0.884000 0.060000 - 0.884000 0.068000 - 0.599400 0.492000 - 0.976000 0.024700 - 0.935000 0.090300 - 0.886900 0.074800 - 0.539900 0.058000 - 0.851000 0.051000 - 0.786000 0.050800 - 0.421100 0.027300 - 0.675300 0.160519 - 0.714923 Continued on next page...
27 39 21 13 17 67 59 26 3 54 64 8 36 10 13 12 60 78 77 11 26 56 33 18 25 7 6 33 16
S132
Table S4 – continued from previous page Reference S1149 S1282 S1283 S1284 S1152 S1285 S1286 S1287 S1288 S1289 S1161 S1028
CO2 & S1057 S1290 S1291
CO2 & S1292 S1290 S1293 S1291
CO2 & S1292
CO2 & S1292
CO2 & S1294 S1295 S1296 S1087 S1297 S1298 S1145
CO2 & S1299
CO2 & S1300 S1301 S1302
CO2 & S1303 S1304 S1305 S1207 S1239 S1241 S1243 S1222 S1270
T (K) 313 - 313 303 - 313 323 - 323 299 - 327 303 - 323 228 - 273 298 - 313 323 - 398 323 - 478 333 - 383 313 - 313 298 - 473 MLINOLEA 313 - 343 313 - 333 313 - 333 MOLEATE 313 - 343 313 - 333 313 - 353 313 - 333 MPALMITA 313 - 343 MSTEARAT 313 - 343 MXYLENE 462 - 583 311 - 478 303 - 343 313 - 366 313 - 393 313 - 393 313 - 353 NEON 303 - 304 NEOPENTN 220 - 300 313 - 423 261 - 424 NITROGEN 288 - 301 218 - 273 273 - 273 233 - 293 253 - 288 270 - 270 220 - 240 288 - 288 223 - 273
p (MPa) 0.573 - 7.87 3.24 - 7.82 0.99 - 9.79 0.103 - 0.103 1.02 - 5.95 0.154 - 3.02 0.468 - 3.77 0.5 - 18.5 0.0558 - 16.5 8.18 - 15.6 0.7 - 8.21 0.41 - 16.1
x1 (-) 0.031500 - 0.741800 0.238300 - 0.870000 0.031000 - 0.796000 0.000366 - 0.005370 0.054000 - 0.439000 0.065200 - 0.547800 0.031000 - 0.268000 0.000000 - 0.750000 0.000000 - 1.000000 0.042200 - 0.228300 0.064000 - 1.000000 0.000000 - 0.969300
N 16 10 14 6 11 22 26 70 40 68 13 99
4.14 - 17.2 3.81 - 20.3 2.86 - 18
0.500000 - 0.935000 0.505000 - 0.945000 0.521700 - 0.950900
8 13 26
1.8 - 20 4.05 - 19 5.12 - 22.3 2.86 - 18
0.271000 0.528000 0.508600 0.487600
0.925000 0.937000 0.944410 0.943000
38 13 23 25
1.01 - 18.3
0.258000 - 1.000000
40
2.15 - 19.7
0.457000 - 1.000000
28
2.08 - 5.26 0.31 - 17 0.67 - 3.52 1.33 - 15.4 6.1 - 16.3 6.1 - 16.3 0.7 - 10.4
0.025200 0.018000 0.076000 0.115600 0.260200 0.260200 0.040000
0.173500 0.981200 0.375000 0.840900 0.905000 0.905000 0.697100
16 39 15 21 29 29 31
7.35 - 9.42
0.949240 - 1.000000
103
0.0428 - 6.71 0.283 - 8.31 0.0464 - 8.31
0.000000 - 1.000000 0.000000 - 0.939500 0.000000 - 1.000000
118 58 122
0.813000 - 1.000000 0.702500 - 0.991000 0.769000 - 0.975000 0.754000 - 0.949000 0.653000 - 1.000000 0.744400 - 1.000000 0.522300 - 1.000000 0.806000 - 0.940000 0.838400 - 0.970900 Continued on next page...
22 31 10 13 16 35 30 7 6
5.07 - 10.3 1.28 - 13.9 4.77 - 11.7 5.07 - 12.7 3.5 - 14.3 3.2 - 12.1 0.6 - 16.7 7.58 - 9.86 5 - 10
S133
-
-
Table S4 – continued from previous page Reference
T (K) 250 - 270 S1101 220 - 270 S1306 230 - 250 S1246 288 - 293 S1247 298 - 298 S1225 301 - 303 S1307 240 - 270 S359 278 - 298 S1227 301 - 303 S1308 209 - 268 S1253 288 - 293 S1214 273 - 273 S1254 253 - 288 S1309 273 - 273 S1310 273 - 273 S1256 270 - 270 S1311 218 - 273 S1312 288 - 303 S763 250 - 270 S1313 220 - 270 S1314 273 - 298 S1315 273 - 283 S1262 209 - 258 S1215 273 - 273 S1263 220 - 240 S1217 233 - 298 S1218 273 - 273 CO2 & NONANE S1316 298 - 323 S1060 343 - 343 S1192 323 - 387 S894 315 - 419 S1067 343 - 343 CO2 & NOVEC649 S1317 313 - 343 CO2 & OCTANE S1186 238 - 238 S1318 283 - 531 S1319 216 - 231 S1202 304 - 323 S1320 313 - 348 S1316 298 - 333 S932 290 - 311 S1192 313 - 360 S1062 322 - 373 S1321 313 - 393 S1149 313 - 313 S1322 313 - 348 S1323 283 - 531 S743
p (MPa) 1.78 - 14.1 0.492 - 12 6.21 - 10.3 5.11 - 9.7 6.46 - 8.41 6.88 - 8.01 1.28 - 13 5.04 - 8.41 6.88 - 8.05 10.8 - 21.4 5.11 - 9.7 3.49 - 11.8 2.42 - 14.4 4.77 - 11.7 4.05 - 15.2 3.2 - 12.3 1.28 - 13.9 5.07 - 10.3 1.78 - 14.1 0.492 - 13 4.5 - 11.4 1.6 - 4.07 0.685 - 18.2 3.92 - 6.86 0.06 - 16.7 3.7 - 12.7 3.49 - 11.8
x1 (-) 0.699200 - 1.000000 0.809700 - 1.000000 0.823300 - 0.918800 0.852000 - 1.000000 0.936000 - 1.000000 0.965200 - 1.000000 0.753300 - 1.000000 0.945000 - 0.975200 0.962100 - 1.000000 0.399100 - 0.503700 0.852000 - 1.000000 0.703000 - 1.000000 0.000000 - 1.000000 0.000000 - 0.975000 0.715000 - 0.990000 0.000000 - 1.000000 0.702500 - 0.991000 0.813000 - 1.000000 0.699200 - 1.000000 0.000000 - 1.000000 0.786000 - 0.981000 0.030000 - 0.727000 0.446960 - 0.446960 0.814000 - 0.955000 0.522300 - 1.000000 0.000000 - 1.000000 0.728000 - 1.000000
N 17 24 5 19 11 12 20 10 14 23 20 16 44 11 4 36 31 27 17 61 34 31 11 7 29 22 15
0.52 3.73 9.14 2.03 3.73
0.058200 0.295900 0.878000 0.146000 0.295900
0.963600 0.882900 0.941000 0.934000 0.882900
33 6 15 38 6
0.222900 - 0.948400
26
0.060000 - 0.512500 0.436700 - 0.936800 0.444000 - 0.975800 0.201000 - 0.979000 0.143300 - 0.890000 0.048400 - 0.948500 0.134400 - 0.616700 0.878000 - 0.958000 0.142200 - 0.889200 0.110000 - 0.944700 0.058800 - 0.904900 0.143300 - 0.890000 0.230000 - 0.851000 Continued on next page...
9 80 25 27 20 43 10 22 28 47 14 20 80
-
9.08 11.8 14.8 16.8 11.8
1.6 - 8.72 0.203 - 1.01 3.45 - 15.6 0.507 - 0.922 1.95 - 8.82 1.5 - 11.3 0.6 - 9.41 0.747 - 3.67 7.65 - 13 2.01 - 13.8 1.11 - 14.4 0.52 - 7.68 1.5 - 11.3 3.45 - 15.6
S134
-
Table S4 – continued from previous page Reference S1198
CO2 & S1304 S1305 S1207 S1324 S1325 S359 S1309 S1311 S1326 S1327 S1217
CO2 & S1087 S1298 S1145
CO2 & S733 S1328 S1223 S1329 S1330 S1331 S133 S748 S1250 S143 S1332 S1230 S1333
CO2 & S733 S1334 S1335 S79 S1336 S459 S1337 S1307 S1248 S1338 S1339 S748 S1252 S1232 S1340 S1341 S1342
T (K) 234 - 251 OXYGEN 218 - 273 273 - 273 233 - 298 223 - 283 224 - 224 277 - 298 273 - 273 218 - 273 223 - 283 224 - 224 233 - 298 OXYLENE 313 - 366 313 - 393 313 - 353 PENTANE 295 - 405 278 - 378 408 - 463 253 - 459 343 - 343 310 - 363 318 - 323 295 - 444 273 - 323 312 - 328 253 - 459 408 - 463 278 - 378 PROPANE 290 - 366 278 - 344 233 - 273 253 - 273 244 - 266 294 - 294 311 - 361 240 - 330 230 - 270 253 - 323 260 - 290 290 - 367 230 - 270 300 - 330 311 - 361 289 - 289 278 - 344
p (MPa) 14.4 - 103
x1 (-) 0.691000 - 0.691000
N 5
2.19 - 14.8 5.11 - 11.7 3.7 - 12.7 1.01 - 13.2 0.931 - 14.2 4.99 - 8.1 4.17 - 11.7 2.19 - 14.9 1.01 - 13.2 0.931 - 14.2 3.7 - 12.7
0.469000 0.695000 0.629000 0.607000 0.553800 0.950600 0.695000 0.000000 0.607000 0.553800 0.300000
0.967000 0.965000 0.970000 0.994000 0.996000 0.975100 1.000000 0.967000 1.000000 0.996000 0.933000
28 13 18 71 10 11 21 33 72 11 17
1.47 - 15 6.1 - 17.3 0.79 - 14.9
0.120200 - 0.936100 0.237200 - 0.900600 0.053600 - 0.834500
44 35 23
0.455300 0.000000 0.000000 0.006200 0.023000 0.029000 0.214000 0.000000 0.077000 0.000000 0.000000 0.000000 0.000000
0.951100 1.000000 0.621400 0.932900 0.777000 0.925000 0.901000 0.951100 0.973400 0.960000 0.932900 0.621400 1.000000
30 53 29 108 8 41 7 84 29 13 110 29 53
0.151900 - 0.960100 0.000000 - 1.000000 0.000000 - 1.000000 0.000000 - 1.000000 0.088600 - 0.818900 0.208500 - 0.725300 0.000000 - 0.769500 0.000000 - 1.000000 0.000000 - 0.956500 0.000000 - 1.000000 0.028000 - 0.850000 0.000000 - 0.960100 0.000000 - 0.956500 0.074000 - 0.586000 0.220000 - 0.987500 0.936000 - 0.976700 0.000000 - 1.000000 Continued on next page...
33 88 15 24 21 3 90 31 58 124 33 70 65 14 90 22 81
2.48 - 9.94 0.0296 - 9.63 1.2 - 9 0.159 - 9.62 0.621 - 9.1 0.566 - 9.67 2.25 - 8.35 0.138 - 9.94 6.89 - 27.6 2.25 - 8.63 0.159 - 9.62 1.2 - 9 0.0296 - 9.63 2.1 - 7.11 0.545 - 6.91 0.103 - 3.5 0.243 - 3.49 0.503 - 2.61 2.21 - 4.71 1.3 - 6.68 0.151 - 5.85 0.0971 - 3.13 0.244 - 7.21 0.409 - 4.71 1.1 - 7.11 0.0971 - 3.13 1.53 - 6.1 1.49 - 6.7 4.9 - 5.06 0.545 - 6.91
S135
-
-
Table S4 – continued from previous page Reference S1343 S752 S1344 S1345 S1346 S1347
CO2 & S1051 S79 S1348 S752 S1168 S1169 S1349 S1350
CO2 & S457 S1087 S1298 S1145
CO2 & S1351 S1352
CO2 & S1353
CO2 & S1354 S1355
CO2 & S1356
CO2 & S1357 S850
CO2 & S850
CO2 & S1356
CO2 & S1358 S1317
CO2 & S1359 S1360 S1361 S1362 S1363
CO2 & S1353 S1364
T (K) 244 - 266 253 - 273 233 - 273 211 - 350 305 - 361 166 - 234 PROPYLEN 166 - 225 253 - 273 283 - 298 253 - 273 245 - 352 243 - 355 283 - 298 230 - 273 PXYLENE 353 - 393 313 - 366 313 - 393 313 - 353 R116 228 - 228 253 - 297 R12 233 - 313 R1216 273 - 313 273 - 313 R123 313 - 333 R1234YF 283 - 353 273 - 313 R1234ZE 273 - 293 R124 313 - 333 R125 158 - 217 313 - 333 R134A 253 - 293 330 - 354 323 - 343 253 - 293 330 - 354 R142B 233 - 293 233 - 293
p (MPa) 0.503 - 2.61 0.243 - 3.5 0.103 - 3.5 0.059 - 5.86 5.02 - 6.93 0.00931 - 0.218
x1 (-) 0.088600 - 0.818900 0.000000 - 1.000000 0.000000 - 1.000000 0.000000 - 0.442000 0.130000 - 0.920000 0.000000 - 0.911000
N 21 24 15 289 6 45
0.00931 - 0.218 0.301 - 3.49 0.97 - 6.02 0.301 - 3.49 0.507 - 6.08 0.242 - 6.84 0.97 - 6.02 0.131 - 3.5
0.089000 0.000000 0.041000 0.000000 0.000000 0.000000 0.041000 0.000000
-
0.453000 1.000000 0.917100 1.000000 0.843700 0.841900 0.917100 1.000000
25 27 29 27 101 79 29 17
0.459 - 6.15 1.2 - 14.4 5.69 - 15.5 0.61 - 12.4
0.026000 0.107600 0.250600 0.040000
-
0.397000 0.867400 0.925000 0.837700
22 39 30 28
0.44 - 0.953 1.05 - 6.45
0.000000 - 1.000000 0.000000 - 0.991000
11 72
0.272 - 5.49
0.146700 - 0.966600
25
0.406 - 5.62 0.406 - 5.62
0.032000 - 0.760000 0.032000 - 0.760000
14 14
0.873 - 8.07
0.121900 - 0.920900
18
0.815 - 7.21 1 - 4.5
0.025500 - 0.941800 0.246000 - 0.591000
65 6
0.5 - 3.5
0.128000 - 0.696000
8
0.594 - 7.75
0.000000 - 0.909600
22
0.007 - 0.514 2.01 - 6.46
0.027000 - 1.000000 0.000000 - 0.748100
19 22
0.131 - 2.05 1.99 - 7.37 1.69 - 7.12 0.131 - 2.05 1.99 - 7.37
0.000000 0.066600 0.062000 0.000000 0.066600
0.867000 0.745000 0.715000 0.867000 0.745000
30 23 37 30 23
0.280600 - 0.740900 0.280600 - 0.740900 Continued on next page...
17 17
0.412 - 3.13 0.412 - 3.13
S136
-
Table S4 – continued from previous page Reference T (K) CO2 & R143A S1365 273 - 333 CO2 & R152A S1366 258 - 343 S1367 273 - 313 S850 258 - 343 CO2 & R22 S435 273 - 348 S1368 263 - 288 S1369 273 - 358 S1370 319 - 366 S1371 299 - 365 S1372 273 - 348 S1315 263 - 288 S1373 273 - 358 CO2 & R227EA S1374 276 - 367 S1375 278 - 328 S1376 276 - 367 CO2 & R23 S1369 254 - 293 S1377 263 - 303 S1373 254 - 293 CO2 & R32 S1378 222 - 283 S1379 280 - 310 S1380 280 - 310 S1381 222 - 283 CO2 & R41 S1382 218 - 290 S1383 218 - 290 CO2 & SO2 S1384 263 - 333 CO2 & TOLUENE S1385 311 - 477 S1294 393 - 543 S1386 353 - 413 S1387 253 - 263 S457 353 - 393 S1388 308 - 353 S1389 352 - 352 S1088 311 - 311 S1390 476 - 476 S1391 298 - 298 S1392 298 - 298 S1089 283 - 303 S1298 352 - 389 S1393 353 - 353 S1394 353 - 353
p (MPa)
x1 (-)
N
0.614 - 7.21
0.000000 - 1.000000
72
0.144 - 7.65 0.262 - 7.2 0.144 - 7.65
0.000000 - 1.000000 0.000000 - 1.000000 0.000000 - 1.000000
67 58 66
0.942 - 7.33 0.355 - 5.04 0.789 - 7.01 1.74 - 7.5 1.51 - 7.35 0.942 - 7.33 0.355 - 5.04 0.789 - 7.01
0.084000 0.000000 0.020500 0.000000 0.103600 0.084000 0.000000 0.020500
0.890000 1.000000 0.917500 0.826000 0.896400 0.890000 1.000000 0.917500
40 81 52 53 54 40 81 52
0.217 - 7.19 0.234 - 6.42 0.217 - 7.19
0.000000 - 1.000000 0.000000 - 1.000000 0.000000 - 1.000000
93 64 94
1.5 - 5.59 1.88 - 7.02 1.5 - 5.59
0.046900 - 0.927900 0.000000 - 0.895000 0.046900 - 0.927900
41 183 41
0.105 - 4.49 1.66 - 6.42 1.66 - 6.42 0.105 - 4.49
0.000000 0.208000 0.208000 0.000000
1.000000 0.728000 0.728000 1.000000
56 9 9 56
0.306 - 5.31 0.306 - 5.31
0.000000 - 1.000000 0.000000 - 1.000000
35 37
0.104 - 8.79
0.000000 - 0.897000
24
0.14 - 15.3 0.976 - 5.2 0.259 - 13.2 0.689 - 2.22 0.515 - 6.45 0.518 - 12.3 0.876 - 11 1.49 - 6.93 1.71 - 14.7 1.63 - 5.6 1.63 - 5.6 0.101 - 0.101 6.15 - 14.3 1.4 - 5.72 1.4 - 5.72
0.012700 - 0.971000 0.016600 - 0.226100 0.012000 - 0.783000 0.149400 - 0.751900 0.019000 - 0.361000 0.023200 - 0.908200 0.049500 - 0.708000 0.131000 - 0.866000 0.030000 - 0.528000 0.166000 - 0.810000 0.166000 - 0.810000 0.009550 - 0.013290 0.262000 - 0.784600 0.077000 - 0.328000 0.077000 - 0.328000 Continued on next page...
34 21 31 10 22 50 9 4 10 8 8 4 10 3 3
S137
-
-
Table S4 – continued from previous page Reference
T (K) 323 - 333 S1395 353 - 353 S135 323 - 323 S1396 353 - 353 S461 293 - 308 S136 333 - 572 S1397 323 - 323 S1398 353 - 353 S1281 283 - 391 S1399 323 - 323 S463 293 - 313 S1400 298 - 363 S464 353 - 393 S1401 304 - 335 S1402 476 - 476 S1403 311 - 477 S1404 352 - 352 CO2 & WATER S1405 285 - 350 S1406 323 - 623 S1407 383 - 623 S1408 273 - 298 S1409 323 - 473 S1410 289 - 533 S304 293 - 303 S1411 323 - 323 S1412 298 - 298 S1413 323 - 348 S340 373 - 493 S1414 353 - 471 S124 313 - 313 S1415 348 - 421 S1416 623 - 643 S1417 323 - 323 S1128 309 - 309 S1418 303 - 318 S1419 278 - 338 S1420 304 - 313 S1421 323 - 353 S1422 278 - 283 S1423 293 - 293 S1424 278 - 318 S1077 303 - 318 S1425 297 - 370 S1426 304 - 313 S1143 288 - 323 S1427 323 - 373 S1428 293 - 313 S1429 290 - 303 S1331
p (MPa) 1.08 - 9.88 0.16 - 2.98 1.2 - 8.66 0.16 - 2.98 1.7 - 7.31 6.74 - 16.5 1.87 - 8.72 0.28 - 3.03 0.405 - 12.1 1.64 - 8.17 3.68 - 7.49 0.93 - 5.07 0.515 - 6.45 7.34 - 11.4 1.71 - 14.7 0.334 - 15.3 0.876 - 11
x1 (-) 0.080000 - 0.889000 0.004900 - 0.167200 0.091000 - 0.883000 0.004900 - 0.167200 0.217000 - 0.971000 0.200000 - 0.800000 0.133000 - 0.892000 0.011800 - 0.169600 0.035700 - 0.887100 0.120100 - 0.780000 0.502000 - 0.903000 0.041000 - 0.755000 0.006000 - 0.361000 0.907500 - 0.991500 0.030000 - 0.528000 0.012700 - 0.971000 0.049500 - 0.708000
N 15 9 14 9 29 64 10 7 43 3 25 28 22 138 10 34 9
0.0128 - 0.0975 0.000026 - 0.000826 20 - 350 0.008000 - 0.430000 10 - 150 0.004000 - 0.250000 1.01 - 4.56 0.008530 - 0.026360 0.154 - 5.39 0.000500 - 0.007600 0.689 - 20.3 0.000499 - 0.025800 0.109 - 0.109 0.000508 - 0.000615 6.82 - 17.7 0.016510 - 0.022620 3.63 - 3.63 0.018300 - 0.018300 10.1 - 15.2 0.015600 - 0.021000 0.325 - 8.11 0.000390 - 0.010320 2.04 - 10.2 0.002193 - 0.016600 4 - 10 0.014000 - 0.027000 10.2 - 19.7 0.015400 - 0.020400 17.6 - 22.5 0.004802 - 0.008745 10.1 - 30.1 0.020750 - 0.025140 1.17 - 7.96 0.008000 - 0.050600 0.101 - 0.101 0.000328 - 0.000522 0.0491 - 0.0842 0.000163 - 0.000569 0.007410 - 0.020820 1.71 - 5.83 4.05 - 14.1 0.008000 - 0.021700 2 - 3.7 0.015600 - 0.033300 1.01 - 2.53 0.006604 - 0.014662 0.465 - 7.96 0.001820 - 0.027970 0.101 - 0.101 0.000330 - 0.000521 1.55 - 8.34 0.007640 - 0.012580 1.01 - 4.59 0.004960 - 0.018000 0.092 - 0.473 0.000380 - 0.003650 2.06 - 20.2 0.006400 - 0.022700 0.101 - 0.101 0.000398 - 0.000687 0.101 - 0.101 0.000535 - 0.000770 Continued on next page...
52 103 113 12 33 30 2 7 1 4 49 31 2 7 9 3 7 4 10 10 29 6 4 47 4 26 8 49 8 4 14
S138
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 324 - 376 10.6 - 49.9 0.015300 - 0.030200 S1431 303 - 323 0.0638 - 0.535 0.000200 - 0.003070 S1432 353 - 393 10 - 30 0.013351 - 0.024584 S1433 298 - 299 0.0029 - 0.747 0.000000 - 0.004600 S1434 274 - 283 1.37 - 4.2 0.016300 - 0.027200 S1435 313 - 333 0.105 - 2.5 0.000375 - 0.009123 S1436 298 - 393 0.54 - 5.14 0.001260 - 0.022200 S1284 303 - 333 0.103 - 0.103 0.000315 - 0.000713 S1437 298 - 448 1.09 - 17.5 0.000630 - 0.022550 S1438 288 - 303 0.125 - 0.408 0.000400 - 0.002300 S1439 374 - 375 7.21 - 27.3 0.011000 - 0.021900 S1440 283 - 363 0.31 - 12.1 0.003000 - 0.020000 S1441 333 - 353 0.1 - 21.3 0.000126 - 0.021523 S1442 286 - 298 0.2 - 4 0.000900 - 0.023200 S1443 353 - 471 2.04 - 10.2 0.002200 - 0.016600 S1444 323 - 353 4.05 - 14.1 0.008000 - 0.021700 S1445 323 - 623 20 - 350 0.645000 - 0.992000 S1446 383 - 623 10 - 150 0.750000 - 0.996000 S1447 405 - 613 5.7 - 24 0.208700 - 0.938800 COS & H2S S1448 233 - 293 0.161 - 1.81 0.000000 - 1.000000 COS & METHANE S1449 298 - 373 2.47 - 10.7 0.513400 - 0.989800 COS & METHANOL S1450 233 - 293 0.0383 - 1.13 0.023600 - 0.966600 COS & PROPANE S1451 266 - 355 0.385 - 3.92 0.000000 - 1.000000 CYCLOHEX & CYCLOPEN S1452 298 - 298 0.0149 - 0.0396 0.093480 - 0.933960 CYCLOHEX & D4 S1453 308 - 308 0.00202 - 0.0196 0.094090 - 0.973220 CYCLOHEX & DEE S1454 298 - 298 0.013 - 0.0714 0.000000 - 1.000000 CYCLOHEX & DMC S531 283 - 373 0.00317 - 0.219 0.000000 - 1.000000 S1455 283 - 373 0.00568 - 0.201 0.069300 - 0.895600 S1456 346 - 363 0.101 - 0.101 0.012200 - 0.984100 CYCLOHEX & EBENZENE S1457 303 - 323 0.00178 - 0.0367 0.000000 - 1.000000 S1458 355 - 405 0.101 - 0.101 0.030100 - 0.964200 CYCLOHEX & ETHANE S1459 232 - 535 0.689 - 9.1 0.138300 - 0.862200 S539 185 - 255 0.0963 - 0.21 0.574600 - 0.903000 S1460 231 - 550 0.689 - 9.17 0.000000 - 1.000000 CYCLOHEX & ETHANOL S1461 273 - 303 0.00164 - 0.0239 0.000000 - 1.000000 S1462 273 - 303 0.00164 - 0.0239 0.000000 - 1.000000 S1463 273 - 303 0.00164 - 0.0239 0.000000 - 1.000000 S1464 298 - 298 0.00764 - 0.0187 0.000000 - 1.000000 Continued on next page... S1430
S139
N 7 18 5 8 7 17 29 7 38 9 5 66 20 15 33 29 105 116 11 114 22 53 60 9 26 16 88 103 30 39 18 127 14 418 72 71 69 11
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 338 - 347 0.101 - 0.101 0.049000 - 0.980000 S482 315 - 354 0.0296 - 0.101 0.000000 - 1.000000 S559 338 - 347 0.101 - 0.101 0.049000 - 0.980000 S1466 278 - 338 0.00224 - 0.101 0.000000 - 1.000000 S1467 323 - 323 0.0297 - 0.0571 0.000000 - 1.000000 S566 298 - 298 0.00787 - 0.0186 0.000000 - 1.000000 S567 298 - 298 0.0152 - 0.0186 0.100000 - 0.900000 S150 298 - 298 0.0148 - 0.0186 0.103000 - 0.932000 S1468 338 - 350 0.101 - 0.101 0.041000 - 0.995000 S1469 338 - 354 0.101 - 0.101 0.000000 - 1.000000 S1470 298 - 298 0.00791 - 0.0186 0.000000 - 1.000000 S1471 315 - 330 0.04 - 0.04 0.000000 - 1.000000 S1472 338 - 350 0.101 - 0.101 0.010000 - 0.980000 S519 322 - 353 0.0533 - 0.0987 0.000000 - 1.000000 S1473 323 - 323 0.036 - 0.0577 0.021000 - 0.982000 S1474 315 - 368 0.04 - 0.15 0.000000 - 1.000000 CYCLOHEX & ETHYLENE S577 303 - 423 1.01 - 11.1 0.140000 - 0.975000 S579 140 - 270 0.0304 - 0.414 0.021700 - 0.970600 S580 298 - 318 0.0661 - 0.13 0.983000 - 0.996019 CYCLOHEX & H2S S583 323 - 423 0.4 - 9.49 0.110000 - 0.945600 CYCLOHEX & HEPTANE S1475 313 - 333 0.0123 - 0.0519 0.000000 - 1.000000 S445 354 - 372 0.101 - 0.101 0.000000 - 1.000000 S955 354 - 372 0.101 - 0.101 0.000000 - 1.000000 S1476 354 - 372 0.101 - 0.101 0.000000 - 1.000000 S1477 298 - 298 0.0064 - 0.0127 0.046800 - 0.945900 S500 298 - 298 0.00678 - 0.0123 0.075800 - 0.876700 S1478 298 - 298 0.00609 - 0.013 0.000000 - 1.000000 S627 333 - 333 0.0308 - 0.0515 0.112000 - 0.982700 S1479 354 - 371 0.101 - 0.101 0.000000 - 1.000000 S512 298 - 313 0.00611 - 0.0246 0.000000 - 1.000000 S1480 313 - 313 0.0123 - 0.0246 0.000000 - 1.000000 S1481 354 - 371 0.101 - 0.101 0.000000 - 1.000000 S1482 313 - 313 0.016 - 0.021 0.280800 - 0.683600 CYCLOHEX & HEXANE S1483 293 - 293 0.0103 - 0.0161 0.000000 - 1.000000 S955 342 - 354 0.101 - 0.101 0.000000 - 1.000000 S483 343 - 343 0.0773 - 0.098 0.258000 - 0.875000 S487 343 - 353 0.101 - 0.101 0.123000 - 0.918000 S494 274 - 299 0.00414 - 0.0186 0.150000 - 0.936000 S1478 298 - 298 0.013 - 0.0202 0.000000 - 1.000000 S942 308 - 308 0.0212 - 0.0299 0.080600 - 0.917700 S1484 298 - 298 0.013 - 0.0202 0.000000 - 1.000000 S1485 283 - 283 0.00689 - 0.0101 0.000000 - 0.902300 S1479 342 - 354 0.101 - 0.101 0.000000 - 1.000000 S1486 303 - 303 0.0162 - 0.025 0.000000 - 1.000000 S1487 293 - 293 0.0103 - 0.0162 0.000000 - 1.000000 Continued on next page... S1465
S140
N 30 20 30 45 7 26 8 12 31 17 25 29 14 71 13 59 55 14 14 24 15 19 27 15 11 11 32 17 16 42 27 17 2 8 34 6 16 43 31 14 11 9 17 12 10
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 313 - 313 0.0246 - 0.0699 0.000000 - 1.000000 CYCLOHEX & HYDROGEN S634 339 - 394 0.688 - 69 0.650000 - 0.996830 S1489 311 - 411 0.0221 - 62.1 0.708100 - 1.000000 S635 366 - 422 3.78 - 14.7 0.890300 - 0.976900 S1490 303 - 373 0.791 - 7 0.963200 - 0.997270 S1491 413 - 523 0.91 - 14.5 0.861700 - 0.997900 S637 303 - 303 0.887 - 4.74 0.980339 - 0.996544 S1492 323 - 403 3 - 10 0.911600 - 0.983700 S639 150 - 250 0.688 - 69 0.000000 - 0.996830 CYCLOHEX & IBUTENE S640 298 - 298 0.0272 - 0.102 0.731000 - 0.961000 CYCLOHEX & IOCTANE S1493 308 - 348 0.0127 - 0.0811 0.069700 - 0.887200 S1494 298 - 328 0.00659 - 0.0442 0.000000 - 1.000000 S1495 308 - 308 0.0104 - 0.0201 0.000000 - 1.000000 S1496 351 - 370 0.094 - 0.094 0.000000 - 1.000000 CYCLOHEX & METHANE S648 311 - 378 14.1 - 18.9 0.551104 - 0.631497 S1497 311 - 378 4.15 - 27.1 0.216200 - 0.882500 S1498 294 - 444 0.0109 - 28.2 0.235000 - 1.000000 S208 298 - 298 0.101 - 0.101 0.996730 - 0.996730 S1499 273 - 333 4.9 - 28.2 0.160000 - 0.875000 S1500 154 - 270 0.942 - 7.6 0.003100 - 0.963200 S1501 323 - 423 1.25 - 9.43 0.778000 - 0.973000 S1502 293 - 323 2.02 - 12.2 0.650000 - 0.941000 CYCLOHEX & METHANOL S476 312 - 354 0.0231 - 0.104 0.000000 - 1.000000 S1503 308 - 354 0.0196 - 0.104 0.000000 - 1.000000 S484 318 - 333 0.0489 - 0.101 0.011700 - 0.973400 S1504 298 - 298 0.0131 - 0.0288 0.000000 - 1.000000 S1505 323 - 328 0.0514 - 0.0965 0.012300 - 0.996600 S1506 327 - 354 0.101 - 0.101 0.000000 - 1.000000 S566 298 - 298 0.013 - 0.0285 0.000000 - 1.000000 S567 298 - 298 0.026 - 0.0284 0.050000 - 0.950000 S510 298 - 298 0.013 - 0.0283 0.000000 - 1.000000 S1507 313 - 313 0.0246 - 0.0564 0.000000 - 1.000000 S154 293 - 303 0.0103 - 0.0362 0.000000 - 1.000000 CYCLOHEX & MXYLENE S1508 303 - 323 0.00152 - 0.0367 0.000000 - 1.000000 S500 298 - 298 0.00361 - 0.0121 0.149800 - 0.914000 S1458 354 - 409 0.101 - 0.101 0.020700 - 0.974300 CYCLOHEX & NEOPENTN S684 273 - 273 0.00389 - 0.0714 0.000000 - 1.000000 CYCLOHEX & NITROGEN S1001 283 - 298 0.101 - 0.101 0.999240 - 0.999274 S250 288 - 308 0.101 - 0.101 0.999206 - 0.999255 S688 366 - 411 2.08 - 12.1 0.876000 - 0.983200 S1048 366 - 411 0.171 - 27.6 0.230300 - 1.000000 Continued on next page... S1488
S141
N 64 16 62 4 15 57 11 15 18 5 32 52 11 30 6 32 95 1 45 36 28 18 20 40 39 8 17 8 14 5 14 36 90 24 13 20 6 3 3 16 86
Table S4 – continued from previous page Reference T (K) p (MPa) x1 (-) CYCLOHEX & NONANE S722 354 - 424 0.101 - 0.101 0.000000 - 1.000000 CYCLOHEX & OCTANE S1509 298 - 328 0.00186 - 0.0442 0.000000 - 1.000000 S1495 308 - 308 0.00322 - 0.0201 0.000000 - 1.000000 S1478 298 - 298 0.00187 - 0.013 0.000000 - 1.000000 S1510 354 - 399 0.101 - 0.101 0.000000 - 1.000000 CYCLOHEX & OXYGEN S1001 283 - 313 0.101 - 0.101 0.998730 - 0.998770 S250 298 - 298 0.101 - 0.101 0.998750 - 0.998750 S254 298 - 298 0.101 - 0.101 0.998720 - 0.998720 CYCLOHEX & OXYLENE S1508 303 - 323 0.0012 - 0.0367 0.000000 - 1.000000 S1458 354 - 413 0.101 - 0.101 0.023000 - 0.995600 CYCLOHEX & PENTANE S955 309 - 354 0.101 - 0.101 0.000000 - 1.000000 S1511 407 - 521 1.03 - 3.45 0.207000 - 0.803000 CYCLOHEX & PROPANE S944 313 - 473 0.255 - 5.9 0.030000 - 0.946000 CYCLOHEX & PROPYLEN S580 298 - 318 0.0317 - 0.127 0.928550 - 0.986830 CYCLOHEX & PXYLENE S1512 298 - 328 0.00121 - 0.0442 0.000000 - 1.000000 S1508 303 - 323 0.00158 - 0.0367 0.000000 - 1.000000 S1458 355 - 407 0.101 - 0.101 0.028900 - 0.974000 CYCLOHEX & R12 S710 298 - 309 0.101 - 0.101 0.905000 - 0.929000 CYCLOHEX & R13 S710 297 - 309 0.101 - 0.101 0.990000 - 0.991250 CYCLOHEX & R22 S712 234 - 322 0.056 - 0.133 0.202000 - 0.981100 S1330 363 - 401 1.35 - 5.71 0.042000 - 0.821000 S1513 363 - 401 1.35 - 5.71 0.041800 - 0.820700 CYCLOHEX & TOLUENE S445 354 - 384 0.101 - 0.101 0.000000 - 1.000000 S446 354 - 384 0.101 - 0.101 0.000000 - 1.000000 S1476 354 - 384 0.101 - 0.101 0.000000 - 1.000000 S1477 298 - 298 0.00458 - 0.0126 0.050500 - 0.950100 S1467 323 - 323 0.0124 - 0.0363 0.000000 - 1.000000 S1514 315 - 384 0.0267 - 0.101 0.000000 - 1.000000 S1515 293 - 313 0.00292 - 0.0246 0.000000 - 1.000000 S1516 353 - 382 0.0987 - 0.0987 0.000000 - 1.000000 S953 354 - 383 0.101 - 0.101 0.006000 - 0.990500 S1468 354 - 382 0.101 - 0.101 0.023000 - 0.974000 S1517 323 - 343 0.0125 - 0.0727 0.000000 - 1.000000 S1518 323 - 323 0.0123 - 0.0364 0.000000 - 1.000000 S1519 355 - 483 0.101 - 0.912 0.000000 - 1.000000 S1520 318 - 318 0.00991 - 0.03 0.000000 - 1.000000 S1521 313 - 313 0.0151 - 0.0205 0.326500 - 0.681700 Continued on next page...
S142
N 14 40 11 28 30 5 1 1 22 21 30 20 26 12 40 30 21 2 3 25 26 26 22 32 15 11 7 169 60 6 21 62 27 26 74 12 2
Table S4 – continued from previous page Reference T (K) p (MPa) x1 (-) CYCLOHEX & WATER S1522 529 - 529 8.01 - 8.01 0.506000 - 0.506000 S1523 311 - 339 0.0298 - 0.0877 0.196500 - 0.196500 CYCLOPEN & D4 S1524 291 - 308 0.00311 - 0.057 0.119820 - 0.928600 CYCLOPEN & ETHANOL S974 323 - 374 0.095 - 0.568 0.163700 - 0.943200 CYCLOPEN & NITROGEN S351 366 - 410 0.358 - 31.3 0.626000 - 1.000000 CYCLOPEN & R245FA S1525 285 - 288 0.0993 - 0.0993 0.000000 - 0.846079 CYCLOPEN & XENON S1526 255 - 314 0.0545 - 0.167 0.965220 - 0.985090 CYCLOPRO & PROPANE S1527 175 - 211 0.00318 - 0.0323 0.204500 - 0.750400 CYCLOPRO & R125 S1528 253 - 293 0.171 - 1.26 0.000000 - 1.000000 CYCLOPRO & R134A S1528 253 - 293 0.134 - 0.821 0.000000 - 1.000000 CYCLOPRO & XENON S1529 161 - 182 0.000467 - 0.248 0.000000 - 1.000000 D2 & HELIUM S1530 19 - 25 0.0415 - 0.17 0.999240 - 0.999900 S1531 20 - 30 0.0294 - 2.07 0.000000 - 1.000000 D2 & HYDROGEN S1532 15 - 20 0.00957 - 0.0943 0.150000 - 0.940000 S1533 18 - 20 0.0312 - 0.0464 0.000000 - 0.556000 D2 & NEON S1534 25 - 40 0.0608 - 2.14 0.000000 - 0.999800 S1535 25 - 25 0.0433 - 0.155 0.000000 - 1.000000 D2 & NITROGEN S1536 90 - 95 0.359 - 6.97 0.000000 - 0.907700 D2O & ETHANE S365 278 - 303 0.101 - 0.101 0.999930 - 0.999970 D2O & KRYPTON S365 278 - 313 0.101 - 0.101 0.999914 - 0.999962 D2O & METHANE S365 278 - 318 0.101 - 0.101 0.999956 - 0.999981 D2O & METHANOL S1537 298 - 298 0.00361 - 0.0155 0.102100 - 0.963800 D2O & NITROGEN S365 278 - 313 0.101 - 0.101 0.999981 - 0.999989 D2O & OXYGEN S365 278 - 313 0.101 - 0.101 0.999963 - 0.999980 D2O & R14 S365 293 - 303 0.101 - 0.101 0.999995 - 0.999996 D2O & SF6 S365 278 - 318 0.101 - 0.101 0.999989 - 0.999997 Continued on next page...
S143
N 1 3 33 13 33 13 10 13 40 37 19 26 60 150 3 87 22 8 6 7 8 11 8 8 2 9
Table S4 – continued from previous page Reference T (K) p (MPa) x1 (-) D2O & WATER S1538 353 - 493 0.0474 - 2.32 0.000000 - 1.000000 S1539 517 - 680 3.58 - 36 0.400000 - 0.500000 D4 & MDM S1540 346 - 445 0.00521 - 0.116 0.000000 - 1.000000 DECANE & DMC S1541 363 - 441 0.101 - 0.101 0.019000 - 0.993400 DECANE & DME S534 323 - 323 0.00118 - 1.14 0.000000 - 1.000000 DECANE & EBENZENE S525 313 - 313 0.00048 - 0.00287 0.000000 - 1.000000 DECANE & ETHANE S910 185 - 235 0.0861 - 0.483 0.007510 - 0.595300 S1542 278 - 411 0.394 - 8.24 0.187000 - 0.898000 S904 411 - 444 0.704 - 11.5 0.225600 - 0.935100 S1543 310 - 360 4.67 - 9.32 0.003035 - 0.084507 S1544 308 - 373 0.36 - 5.84 0.153000 - 0.912600 S1545 278 - 511 2.76e-05 - 11.8 0.000000 - 1.000000 DECANE & ETHANOL S524 353 - 361 0.101 - 0.101 0.300000 - 0.850000 S1546 351 - 447 0.101 - 0.101 0.000000 - 1.000000 S1547 351 - 355 0.101 - 0.101 0.004000 - 0.595000 DECANE & ETHYLENE S916 175 - 235 0.137 - 0.903 0.001090 - 0.592400 DECANE & H2S S1548 278 - 444 0.000503 - 13.3 0.000000 - 1.000000 S1549 323 - 523 0.227 - 1.29 0.712300 - 0.981900 DECANE & HELIUM S352 298 - 298 0.101 - 0.101 0.999761 - 0.999761 DECANE & HEXANE S897 308 - 308 0.00036 - 0.0306 0.000000 - 1.000000 DECANE & HYDROGEN S938 358 - 483 3.92 - 29.4 0.655000 - 0.964000 S1550 462 - 583 1.93 - 25.5 0.498700 - 0.974900 S204 298 - 373 2.04 - 10.3 0.911550 - 0.984210 S1551 503 - 503 1.48 - 10.1 0.849300 - 0.982200 S1552 344 - 423 3.71 - 17.4 0.871200 - 0.963100 S1553 343 - 473 4.93 - 12.3 0.869800 - 0.945730 S1554 344 - 423 0.0369 - 0.129 0.826100 - 0.962900 DECANE & KRYPTON S352 298 - 298 0.101 - 0.101 0.992755 - 0.992755 DECANE & METHANE S1555 311 - 511 11.5 - 36.1 0.142716 - 0.605664 S1556 248 - 423 1.01 - 10.1 0.529200 - 0.967600 S1557 400 - 400 6.89 - 6.89 0.772800 - 0.772800 S652 423 - 583 2.76 - 18.7 0.331800 - 0.914300 S1558 245 - 351 1.41 - 36.9 0.099400 - 0.900800 S924 311 - 411 1.04 - 8.65 0.692000 - 0.950500 S352 298 - 298 0.101 - 0.101 0.994688 - 0.994688 Continued on next page...
S144
N 75 25 49 21 38 18 11 66 22 47 31 126 3 15 12 13 124 24 1 14 12 26 9 6 18 15 18 1 25 67 1 28 110 32 1
Table S4 – continued from previous page Reference S1559 S1560 S1561 S1562
DECANE S898 S1563 S925
DECANE S1564 S1565 S1566
DECANE S352
DECANE S922 S686 S352 S1567 S1568 S1569
DECANE S908
DECANE S352
DECANE S1565 S1566
DECANE S1570
DECANE S927 S1553 S850 S1067 S1571
DECANE S1572
DECANE S525 S1573 S1565 S1566
DECANE S352
DECANE S352
DECANE S1564
T (K) p (MPa) x1 (-) 263 - 311 0.3 - 10.1 0.000000 - 0.000000 311 - 411 6.89 - 34.5 0.205000 - 0.888000 244 - 278 1.57 - 6.9 0.635900 - 0.908000 478 - 478 6.89 - 6.89 0.769300 - 0.772800 & METHANOL 322 - 423 0.0541 - 0.0541 0.001000 - 1.000000 338 - 339 0.101 - 0.101 0.800000 - 0.900000 422 - 540 1.3 - 8.06 0.000000 - 0.272000 & MXYLENE 373 - 394 0.00956 - 0.0609 0.000000 - 1.000000 410 - 445 0.0958 - 0.0958 0.000000 - 1.000000 361 - 393 0.02 - 0.02 0.000000 - 1.000000 & NEON 298 - 298 0.101 - 0.101 0.999654 - 0.999654 & NITROGEN 323 - 398 3.19 - 10.2 0.000395 - 0.006570 344 - 344 4.02 - 34.6 0.620000 - 0.931000 298 - 298 0.101 - 0.101 0.998722 - 0.998722 344 - 411 3.91 - 16 0.803300 - 0.944400 345 - 563 1.04 - 50.3 0.294700 - 0.984800 311 - 411 0.276 - 34.5 0.000000 - 0.967100 & OCTANE 349 - 393 0.02 - 0.02 0.000000 - 1.000000 & OXYGEN 298 - 298 0.101 - 0.101 0.997822 - 0.997822 & OXYLENE 416 - 445 0.0958 - 0.0958 0.000000 - 1.000000 365 - 393 0.02 - 0.02 0.000000 - 1.000000 & PENTANE 318 - 334 0.00065 - 0.218 0.000000 - 1.000000 & PROPANE 200 - 240 0.0314 - 0.0689 0.040300 - 0.805900 411 - 478 3.74 - 6.57 0.101700 - 0.601400 270 - 370 0.0628 - 2.55 0.268650 - 0.851710 311 - 394 0.593 - 4.61 0.061000 - 0.713100 278 - 511 2.76e-05 - 7.09 0.000000 - 1.000000 & PROPYLEN 299 - 324 0.101 - 0.101 0.853000 - 0.917600 & PXYLENE 313 - 313 0.00048 - 0.00265 0.000000 - 1.000000 410 - 446 0.0973 - 0.0973 0.000000 - 1.000000 409 - 445 0.0958 - 0.0958 0.000000 - 1.000000 360 - 393 0.02 - 0.02 0.000000 - 1.000000 & R14 298 - 298 0.101 - 0.101 0.998129 - 0.998129 & SF6 298 - 298 0.101 - 0.101 0.991151 - 0.991151 & TOLUENE 373 - 394 0.00945 - 0.133 0.000000 - 1.000000 Continued on next page...
S145
N 32 174 21 3 16 2 85 33 7 14 1 9 6 1 21 142 125 29 1 7 13 23 9 13 134 53 71 3 24 20 8 13 1 1 34
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 313 - 313 0.00048 - 0.00789 0.000000 - 1.000000 DECANE & WATER S1574 573 - 613 1.3 - 9.27 0.331600 - 0.993300 DEE & ETHANE S168 298 - 298 0.956 - 3.86 0.041200 - 0.747100 DEE & ETHANOL S158 308 - 352 0.103 - 0.103 0.000000 - 1.000000 S1575 273 - 323 0.00577 - 0.161 0.100400 - 0.900300 S1576 293 - 293 0.006 - 0.0587 0.000000 - 1.000000 S1577 309 - 351 0.101 - 0.101 0.000000 - 1.000000 S1461 273 - 323 0.00491 - 0.167 0.050000 - 0.950000 S1463 273 - 323 0.00491 - 0.167 0.050000 - 0.950000 S1578 298 - 298 0.00785 - 0.0714 0.000000 - 1.000000 S1579 347 - 418 0.255 - 0.862 0.024000 - 0.943000 S1580 308 - 351 0.101 - 0.101 0.002300 - 0.992500 DEE & ETHYLENE S1581 298 - 313 0.787 - 6.64 0.062400 - 0.851700 DEE & HEXANE S1582 308 - 342 0.101 - 0.101 0.000000 - 1.000000 S163 308 - 342 0.101 - 0.101 0.000000 - 1.000000 DEE & IPENTANE S1583 301 - 308 0.101 - 0.101 0.020000 - 0.999100 DEE & ISOBUTAN S1584 323 - 323 0.168 - 0.678 0.000000 - 1.000000 DEE & METHANE S1585 284 - 342 2.07 - 17.1 0.229000 - 0.927000 S209 273 - 293 0.101 - 0.101 0.994830 - 0.995380 DEE & METHANOL S527 308 - 338 0.102 - 0.102 0.000000 - 1.000000 S210 307 - 338 0.0984 - 0.0986 0.000000 - 1.000000 S1586 298 - 298 0.0169 - 0.0715 0.000000 - 1.000000 S1587 304 - 329 0.0933 - 0.0933 0.039000 - 0.977000 S1588 303 - 329 0.025 - 0.0933 0.012100 - 0.977000 S163 308 - 338 0.101 - 0.101 0.000000 - 1.000000 S165 298 - 388 0.017 - 0.998 0.000000 - 1.000000 DEE & PENTANE S1582 307 - 309 0.101 - 0.101 0.000000 - 0.994200 DEE & PROPYLEN S260 298 - 298 0.0712 - 1.16 0.000000 - 1.000000 DEE & R12 S166 333 - 343 0.231 - 1.88 0.000000 - 1.000000 DEE & SO2 S1589 258 - 258 0.0118 - 0.0807 0.000000 - 1.000000 S1590 373 - 423 0.66 - 5.19 0.262900 - 1.000000 S1591 293 - 293 0.0848 - 0.295 0.104000 - 0.779100 DEE & TOLUENE S1592 273 - 293 0.00092 - 0.0616 0.001300 - 0.988800 DEE & WATER S1593 307 - 308 0.101 - 0.101 0.627000 - 1.000000 Continued on next page... S525
S146
N 13 22 6 12 121 11 29 114 114 13 35 20 32 16 18 18 49 27 4 13 12 21 19 29 16 45 13 14 42 8 10 8 26 10
Table S4 – continued from previous page Reference S1575 S1594 S1595 S1596
DMC & S1005
DMC & S1597 S1598 S1599 S1600 S1601 S1602
DMC & S531 S1455 S1456
DMC & S1456 S1603 S1604
DMC & S1605
DMC & S1606 S1597 S1598 S1607 S1600 S1608 S1603 S1609 S1610 S1602 S1611 S1612 S1613 S1614 S1615 S1616 S1617 S1618
DMC & S1541
DMC & S1456
DMC & S1005
DMC &
T (K) 273 - 323 323 - 368 298 - 298 308 - 308 DME 293 - 373 ETHANOL 313 - 313 348 - 361 348 - 361 348 - 362 347 - 361 325 - 361 HEPTANE 283 - 373 283 - 373 355 - 369 HEXANE 339 - 360 339 - 361 339 - 363 METHANE 286 - 327 METHANOL 337 - 355 313 - 313 337 - 356 337 - 363 337 - 362 337 - 356 337 - 363 337 - 363 337 - 428 314 - 361 337 - 350 337 - 363 326 - 361 337 - 363 337 - 363 311 - 351 337 - 357 337 - 363 NONANE 363 - 422 OCTANE 362 - 396 OXYGEN 293 - 373 TOLUENE
p (MPa) 0.025 - 0.176 0.101 - 0.101 0.00317 - 0.0719 0.00563 - 0.105
x1 (-) 0.666700 - 0.714300 0.000120 - 0.003450 0.000000 - 1.000000 0.000000 - 1.000000
N 22 9 13 15
0.01 - 3.26
0.000000 - 1.000000
34
0.0169 - 0.024 0.101 - 0.101 0.101 - 0.101 0.101 - 0.101 0.0958 - 0.0958 0.04 - 0.0933
0.015000 0.089500 0.089500 0.012500 0.068400 0.000000
0.972000 0.988600 0.988600 0.982000 1.000000 1.000000
27 10 10 36 8 104
0.00276 - 0.173 0.0046 - 0.172 0.101 - 0.101
0.000000 - 1.000000 0.195400 - 0.923600 0.025300 - 0.983000
88 61 28
0.101 - 0.101 0.101 - 0.101 0.101 - 0.101
0.029600 - 0.980500 0.000000 - 1.000000 0.000800 - 1.000000
30 11 30
0.0296 - 0.0665
0.999346 - 0.999523
6
0.101 - 0.101 0.018 - 0.0386 0.101 - 0.101 0.101 - 0.101 0.101 - 0.101 0.101 - 0.101 0.101 - 0.101 0.101 - 0.101 0.041 - 1.57 0.04 - 0.0933 0.101 - 0.101 0.101 - 0.101 0.0667 - 0.0933 0.101 - 0.101 0.101 - 0.101 0.0344 - 0.0677 0.101 - 0.101 0.101 - 0.101
0.042100 0.012000 0.020600 0.000000 0.011100 0.020600 0.000000 0.000000 0.000000 0.000000 0.048000 0.000000 0.000000 0.000000 0.000000 0.000000 0.102000 0.000000
0.933800 0.978000 0.955300 1.000000 0.989700 0.955300 1.000000 1.000000 1.000000 1.000000 0.874000 1.000000 1.000000 1.000000 1.000000 1.000000 0.962000 1.000000
18 25 16 19 29 16 11 11 66 74 15 20 46 17 16 38 17 15
0.101 - 0.101
0.002200 - 0.977800
37
0.101 - 0.101
0.014200 - 0.980100
32
2 - 12
0.802300 - 0.976700
24
-
-
Continued on next page...
S147
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 318 - 318 0.00988 - 0.0186 0.000000 - 1.000000 DMC & WATER S1075 351 - 370 0.101 - 0.101 0.003100 - 1.000000 DME & ETHANOL S772 293 - 293 0.0058 - 0.512 0.000000 - 1.000000 S1619 332 - 374 0.191 - 3.16 0.034500 - 0.963800 S1620 298 - 318 0.42 - 0.61 0.471500 - 0.560100 S1621 323 - 323 0.0294 - 1.14 0.000000 - 1.000000 DME & HEXANE S1622 308 - 336 0.0308 - 1.54 0.000000 - 1.000000 DME & HYDROGEN S1623 288 - 316 0.43 - 7.99 0.928000 - 1.000000 DME & ISOBUTAN S1624 280 - 320 0.202 - 1.06 0.000000 - 1.000000 DME & METHANE S1585 283 - 344 1.97 - 12.4 0.367000 - 0.956000 DME & METHANOL S1625 273 - 453 0.004 - 6.67 0.000000 - 1.000000 S1626 254 - 353 0.0352 - 1.08 0.122600 - 0.871900 S1627 288 - 353 0.16 - 2.24 0.000000 - 1.000000 S1628 293 - 373 0.013 - 1.44 0.000000 - 0.556800 S1621 323 - 323 0.0553 - 1.14 0.000000 - 1.000000 S1629 308 - 328 0.0273 - 1.27 0.000000 - 1.000000 DME & NITROGEN S1627 288 - 318 0.44 - 8.48 0.929000 - 1.000000 S1085 298 - 318 0.6 - 10.3 0.873500 - 1.000000 DME & PENTANE S882 270 - 380 0.186 - 2.75 0.392000 - 0.679000 DME & PROPANE S1630 323 - 363 1.15 - 3.85 0.000000 - 1.000000 S1631 273 - 323 0.266 - 1.71 0.000000 - 1.000000 S1632 298 - 313 0.59 - 1.39 0.000000 - 1.000000 DME & PROPYLEN S1632 313 - 313 0.892 - 1.66 0.000000 - 1.000000 S1633 253 - 293 0.125 - 1.02 0.000000 - 1.000000 DME & R125 S1634 258 - 303 0.152 - 1.57 0.000000 - 1.000000 S1635 313 - 363 0.887 - 3.9 0.000000 - 1.000000 DME & R134A S1636 293 - 358 0.488 - 2.86 0.086300 - 0.987100 S1637 313 - 343 0.869 - 2.11 0.000000 - 0.989900 DME & R143A S1638 313 - 363 0.884 - 4.23 0.000000 - 1.000000 DME & R22 S1639 283 - 395 0.338 - 4.98 0.000000 - 1.000000 DME & R227EA S1640 278 - 308 0.19 - 0.778 0.000000 - 1.000000 DME & R236EA S1641 283 - 313 0.118 - 0.89 0.000000 - 1.000000 Continued on next page... S120
S148
N 10 24 16 44 3 37 52 47 64 23 172 72 19 52 37 50 46 34 23 10 36 57 56 32 46 75 48 44 64 66 40 40
Table S4 – continued from previous page Reference T (K) p (MPa) x1 (-) DME & R236FA S1642 304 - 324 0.326 - 1.16 0.000000 - 1.000000 S1641 283 - 283 0.159 - 0.371 0.000000 - 1.000000 DME & R32 S1643 283 - 363 0.5 - 5.51 0.117500 - 0.918600 S1644 258 - 293 0.153 - 1.47 0.000000 - 1.000000 S1645 313 - 343 1.04 - 4.88 0.000000 - 0.952500 DME & R40 S1646 253 - 323 0.115 - 1.11 0.113000 - 0.889300 DME & SO2 S1647 329 - 382 0.679 - 3.73 0.250000 - 1.000000 S1648 233 - 248 0.0114 - 0.0978 0.067000 - 0.977000 S1649 323 - 393 0.642 - 4.73 0.000000 - 1.000000 S1650 283 - 428 0.153 - 7.19 0.000000 - 1.000000 DME & TOLUENE S534 323 - 323 0.0122 - 1.14 0.000000 - 1.000000 DME & WATER S1651 323 - 493 0.012 - 26 0.000000 - 1.000000 S1652 253 - 343 0.0167 - 1.12 0.008000 - 0.990600 S772 293 - 293 0.0023 - 0.512 0.000000 - 1.000000 S1653 309 - 393 0.00595 - 2.17 0.000000 - 0.089100 S534 323 - 323 0.0123 - 1.14 0.000000 - 1.000000 DME & XENON S1654 182 - 182 0.00164 - 0.248 0.000000 - 1.000000 EBENZENE & ETHANOL S1546 351 - 409 0.101 - 0.101 0.000000 - 1.000000 S1655 351 - 409 0.101 - 0.101 0.028000 - 1.000000 S1656 350 - 407 0.0958 - 0.0958 0.000000 - 1.000000 EBENZENE & HEPTANE S587 315 - 409 0.0133 - 0.101 0.000000 - 1.000000 S505 298 - 328 0.00199 - 0.021 0.114100 - 0.985300 S943 373 - 373 0.0343 - 0.106 0.000000 - 1.000000 S525 313 - 313 0.00287 - 0.0123 0.000000 - 1.000000 S1657 373 - 408 0.101 - 0.101 0.050200 - 0.983500 EBENZENE & HEXANE S1658 338 - 338 0.00917 - 0.09 0.000000 - 1.000000 S525 313 - 313 0.00287 - 0.0372 0.000000 - 1.000000 EBENZENE & IOCTANE S641 313 - 353 0.00287 - 0.0568 0.000000 - 1.000000 S645 313 - 313 0.00287 - 0.013 0.000000 - 1.000000 S1659 408 - 447 0.25 - 0.25 0.000000 - 1.000000 EBENZENE & METHANOL S1660 338 - 409 0.101 - 0.101 0.050000 - 1.000000 S1656 336 - 407 0.0958 - 0.0958 0.000000 - 1.000000 EBENZENE & MXYLENE S1661 358 - 410 0.0203 - 0.096 0.000000 - 1.000000 S1662 330 - 368 0.00666 - 0.0267 0.000000 - 1.000000 S1663 409 - 412 0.101 - 0.101 0.000000 - 1.000000 S520 378 - 409 0.04 - 0.0933 0.106800 - 0.895500 Continued on next page...
S149
N 26 11 47 30 55 65 12 48 21 67 37 215 83 15 92 42 10 12 14 11 72 42 12 15 20 26 11 36 18 19 12 11 52 29 13 45
Table S4 – continued from previous page Reference T (K) p (MPa) x1 (-) EBENZENE & NONANE S1664 333 - 363 0.00401 - 0.0243 0.000000 - 1.000000 EBENZENE & OCTANE S1665 323 - 409 0.00667 - 0.101 0.000000 - 1.000000 S1666 357 - 366 0.0267 - 0.0267 0.000000 - 1.000000 S943 373 - 373 0.0343 - 0.0468 0.000000 - 1.000000 S525 313 - 313 0.00287 - 0.00415 0.000000 - 1.000000 EBENZENE & OXYLENE S943 373 - 373 0.0265 - 0.0343 0.000000 - 1.000000 S1662 330 - 373 0.00666 - 0.0267 0.000000 - 1.000000 S1663 409 - 418 0.101 - 0.101 0.000000 - 1.000000 EBENZENE & PXYLENE S1667 394 - 438 0.0667 - 0.2 0.048000 - 0.945000 S943 373 - 373 0.0321 - 0.0343 0.000000 - 1.000000 S536 409 - 418 0.101 - 0.102 0.032700 - 0.987900 S1661 358 - 410 0.0204 - 0.0964 0.000000 - 1.000000 S1663 409 - 412 0.101 - 0.101 0.000000 - 1.000000 S1668 378 - 408 0.04 - 0.0933 0.031000 - 0.978000 EBENZENE & TOLUENE S1669 298 - 298 0.00151 - 0.00395 0.000000 - 1.000000 S943 373 - 373 0.0343 - 0.0742 0.000000 - 1.000000 S536 384 - 409 0.101 - 0.101 0.024500 - 0.994000 S1670 343 - 409 0.0267 - 0.101 0.000000 - 1.000000 EBENZENE & WATER S1671 592 - 660 17.4 - 200 0.100000 - 0.100000 ETHANE & ETHANOL S370 298 - 298 0.101 - 0.101 0.006860 - 0.006860 S1121 313 - 333 1.31 - 7.9 0.057000 - 0.602000 S1672 295 - 314 1.05 - 5.13 0.062940 - 0.491669 S1673 298 - 498 0.25 - 11.8 0.000000 - 1.000000 ETHANE & ETHYLENE S1674 278 - 278 3.2 - 4.92 0.400000 - 0.750000 S1675 140 - 175 0.0043 - 0.118 0.000000 - 1.000000 S1676 200 - 255 0.216 - 2.66 0.000000 - 1.000000 S1677 161 - 161 0.0237 - 0.0617 0.000000 - 1.000000 S1678 198 - 278 0.213 - 4.53 0.000000 - 0.954200 S1679 200 - 255 0.248 - 2.63 0.023000 - 0.950000 S1680 263 - 293 1.86 - 6.09 0.000000 - 1.000000 S1681 169 - 273 0.0423 - 4.11 0.000000 - 1.000000 ETHANE & H2S S737 283 - 283 1.58 - 3.16 0.024100 - 0.951000 S794 182 - 182 0.0712 - 0.0921 0.068100 - 1.000000 S1682 252 - 369 1.38 - 8.27 0.000000 - 1.000000 S1683 200 - 283 0.0652 - 3.05 0.008500 - 0.974100 ETHANE & HCL S1684 213 - 243 0.35 - 1.44 0.000000 - 1.000000 S1685 278 - 324 2.7 - 8.28 0.000000 - 1.000000 ETHANE & HELIUM S1686 170 - 290 2.85 - 20.2 0.910900 - 0.997620 Continued on next page...
S150
N 56 53 11 12 13 12 30 14 55 12 37 48 13 51 6 12 20 52 9 1 14 13 121 6 39 28 10 184 22 49 166 14 7 302 45 47 89 39
Table S4 – continued from previous page Reference S1687
ETHANE S1688 S1689 S1190 S1690
ETHANE S1691 S168 S1692 S1693
ETHANE S1694 S1695 S1696 S1697
ETHANE S1698 S540
ETHANE S1699 S778 S869
ETHANE S1700 S1701 S392
ETHANE S1702 S1703 S1704 S1705 S1706 S1245 S1707 S1708 S1709 S822 S850 S1710 S1711 S1712 S1106 S1713 S1714 S1715 S1108 S1716 S1717
T (K) p (MPa) x1 (-) 113 - 273 0.49 - 11.8 0.978230 - 0.999960 & HEPTANE 339 - 450 2.76 - 8.82 0.188000 - 0.940000 339 - 450 3.14 - 8.52 0.296000 - 0.903000 185 - 300 0.07 - 4.37 0.055000 - 1.000000 231 - 540 0.345 - 8.62 0.000000 - 1.000000 & HEXANE 339 - 450 1.34 - 7.88 0.075000 - 0.907000 298 - 298 0.508 - 3.55 0.149700 - 0.913500 311 - 394 0.393 - 5.4 0.072000 - 0.652000 339 - 450 0.41 - 7.88 0.000000 - 0.907000 & HYDROGEN 144 - 200 3.45 - 6.89 0.961000 - 0.988000 108 - 190 1.9 - 15.6 0.922500 - 0.993300 148 - 223 2.03 - 8.11 0.944300 - 0.993820 93 - 280 3.18 - 560 0.251700 - 0.992800 & IOCTANE 287 - 305 0.101 - 0.101 0.026034 - 0.035327 303 - 303 0.101 - 0.101 0.033390 - 0.033390 & ISOBUTAN 311 - 394 0.503 - 5.37 0.000000 - 0.962600 273 - 323 0.195 - 4.72 0.021200 - 0.797700 203 - 273 0.00049 - 2.39 0.000000 - 1.000000 & KRYPTON 116 - 116 0.0184 - 0.073 0.000000 - 0.795510 150 - 296 0.0105 - 6.87 0.000000 - 1.000000 179 - 279 0.067 - 4.95 0.000000 - 1.000000 & METHANE 139 - 302 0.28 - 6.78 0.025400 - 0.950000 191 - 197 4.46 - 5.02 0.003470 - 0.075700 130 - 200 0.00128 - 5.16 0.000000 - 1.000000 260 - 280 1.7 - 6.6 0.538500 - 1.000000 91 - 104 1e-06 - 0.0512 0.000000 - 1.000000 233 - 250 3.04 - 5 0.611500 - 0.826200 140 - 270 0.392 - 6.63 0.055000 - 0.949600 126 - 140 0.148 - 0.642 0.000000 - 0.742200 93 - 283 0.002 - 3.92 0.000000 - 1.000000 203 - 244 2.12 - 6.88 0.378200 - 0.718800 203 - 210 2.13 - 5.97 0.039610 - 0.039610 73 - 323 0.689 - 6.89 0.071900 - 0.994000 273 - 373 5.4 - 200 0.000000 - 0.649000 254 - 273 1.27 - 9.25 0.000000 - 0.000000 210 - 270 0.334 - 6.59 0.000000 - 1.000000 143 - 263 0.507 - 2.03 0.285000 - 0.991000 144 - 283 0.689 - 8.96 0.000000 - 0.994000 160 - 180 0.0215 - 3.29 0.000000 - 1.000000 250 - 250 1.3 - 6.66 0.000000 - 1.000000 139 - 302 0.28 - 6.78 0.000000 - 0.950000 140 - 220 2 - 12 0.000000 - 0.944700 Continued on next page...
S151
N 85 62 32 47 440 22 7 48 32 4 31 16 253 4 1 43 36 80 9 232 37 113 27 135 44 19 3 31 68 73 17 7 21 73 100 153 37 184 25 30 224 94
Table S4 – continued from previous page Reference S1718 S1719 S1720 S1721 S1722 S1723 S1724 S1725 S1726 S1727 S1728 S1729 S1730 S1731 S1732 S1733 S1734 S369 S869 S1735
ETHANE S370 S1736 S168 S1737 S1738 S1739 S1740
ETHANE S1741
ETHANE S1741
ETHANE S944
ETHANE ETHANE S1742
ETHANE S1694 S393 S1743 S1744 S1705 S1008 S1737 S1745 S1746 S1707 S1747
T (K) p (MPa) x1 (-) 200 - 200 2-4 0.000000 - 0.631300 108 - 108 0.02 - 0.065 0.133200 - 0.809800 144 - 200 3.45 - 6.89 0.199500 - 0.904400 222 - 244 0.689 - 6.89 0.000000 - 0.977000 158 - 214 0.221 - 6.03 0.000000 - 0.987100 142 - 300 0.689 - 6.55 0.000000 - 0.950000 198 - 248 1.02 - 6.08 0.262000 - 0.919000 122 - 200 1.31 - 6.89 0.198200 - 0.637200 122 - 171 0.000483 - 2.8 0.000000 - 1.000000 144 - 244 0.689 - 7.24 0.000000 - 0.100700 195 - 195 0.507 - 6.08 0.140000 - 0.945000 153 - 203 1.05 - 4.94 0.113000 - 0.628800 305 - 333 1.38 - 20.7 0.000000 - 0.000000 311 - 311 3.45 - 13.8 0.017300 - 0.965000 111 - 111 0.0164 - 0.0965 0.000000 - 0.879700 139 - 155 0.101 - 0.101 0.902000 - 0.999000 178 - 188 3.04 - 4.05 0.110000 - 0.280000 116 - 116 0.352 - 0.741 0.029800 - 0.556900 123 - 153 0.00049 - 1.19 0.000000 - 1.000000 116 - 116 0.000192 - 0.14 0.000000 - 1.000000 & METHANOL 298 - 298 0.101 - 0.101 0.004050 - 0.004050 248 - 373 0.00394 - 6.08 0.000000 - 0.978000 298 - 298 1.09 - 4.12 0.040300 - 0.351100 240 - 298 0.401 - 4.2 0.019900 - 1.000000 263 - 309 1.82 - 5.13 0.347600 - 0.937100 298 - 298 0.963 - 4.19 0.053000 - 1.000000 283 - 303 0.5 - 4 0.027030 - 0.280100 & MPALMITA 312 - 355 5.21 - 13.6 0.840824 - 0.955749 & MSTEARAT 312 - 355 5.57 - 14.8 0.859870 - 0.957856 & MXYLENE 313 - 473 0.51 - 12 0.036000 - 0.925000 & N2O & NEON 112 - 130 1.58 - 3.31 0.000000 - 0.000000 & NITROGEN 144 - 200 3.45 - 6.89 0.787100 - 0.904400 93 - 93 0.0208 - 0.0445 0.004570 - 0.010000 139 - 194 0.00345 - 13.5 0.268000 - 1.000000 200 - 290 0.218 - 13.2 0.426200 - 1.000000 260 - 280 1.7 - 9.9 0.625800 - 1.000000 120 - 133 0.644 - 4.14 0.005000 - 0.958900 240 - 260 0.967 - 7.5 0.799400 - 1.000000 91 - 91 1.2e-06 - 0.382 0.000000 - 1.000000 120 - 138 0.863 - 3.28 0.733400 - 0.950100 150 - 270 0.56 - 10.1 0.641900 - 0.981600 102 - 302 0.533 - 12.2 0.000000 - 0.950200 Continued on next page...
S152
N 17 5 8 66 93 248 12 14 82 36 9 15 14 19 15 11 3 23 41 11 1 33 5 34 12 9 20 20 16 34
6 3 2 52 35 61 25 17 9 21 25 320
Table S4 – continued from previous page Reference S1723 S308 S1726 S1313 S1732 S1748
ETHANE S1749 S910 S1320
ETHANE S774 S1750 S1751 S1752
ETHANE S1753 S1754 S1755 S1756 S1757 S1758 S854 S1759 S1710 S1717 S749 S1760 S1761 S1762 S869
ETHANE S1763 S1753 S1348 S1764 S1765
ETHANE S1766 S1767
ETHANE S1768
ETHANE S1769
ETHANE S1770
ETHANE S1771
ETHANE
T (K) p (MPa) x1 (-) 101 - 301 0.689 - 12.8 0.000000 - 0.950200 144 - 228 2.07 - 4.83 0.722000 - 0.955000 122 - 171 0.344 - 3.41 0.027340 - 0.975000 220 - 270 0.492 - 12 0.000000 - 1.000000 111 - 111 7.58e-05 - 1.54 0.000000 - 1.000000 93 - 93 0.0208 - 0.0445 0.990000 - 0.995430 & OCTANE 273 - 373 0.405 - 5.27 0.047000 - 0.984000 185 - 210 0.073 - 0.165 0.299000 - 0.883100 318 - 338 1.5 - 6.8 0.249320 - 0.921340 & PENTANE 339 - 422 6.23 - 6.78 0.481000 - 0.865000 309 - 309 3.1 - 4.63 0.680000 - 0.950000 278 - 444 0.0303 - 6.83 0.000000 - 1.000000 253 - 291 0.689 - 5.46 0.008520 - 0.271100 & PROPANE 197 - 273 0.0164 - 2.34 0.000000 - 1.000000 128 - 255 1.31e-05 - 1.5 0.000000 - 1.000000 289 - 289 0.965 - 2.92 0.107800 - 0.863500 303 - 369 1.08 - 5.09 0.000000 - 1.000000 303 - 303 1.06 - 4.68 0.000000 - 1.000000 195 - 270 0.0147 - 2.2 0.000000 - 1.000000 240 - 355 0.296 - 5.01 0.069000 - 0.800000 255 - 283 0.266 - 1.66 0.000000 - 0.479900 255 - 283 0.689 - 2.76 0.023600 - 0.910800 140 - 200 2 - 12 0.000000 - 0.944700 0 - 280 0 - 2.79 0.000000 - 1.000000 311 - 366 0.956 - 5.18 0.000000 - 0.935000 244 - 267 0.603 - 4.39 0.033900 - 0.812400 305 - 306 0.657 - 4.92 0.000500 - 0.994800 203 - 273 0.0245 - 2.39 0.000000 - 1.000000 & PROPYLEN 261 - 344 0.634 - 4.55 0.182100 - 0.824900 198 - 273 0.0221 - 2.34 0.000000 - 1.000000 283 - 298 0.891 - 4.07 0.035100 - 0.973600 242 - 365 0.21 - 5.16 0.000000 - 1.000000 261 - 411 0.4 - 4.98 0.000000 - 1.000000 & R116 200 - 243 0.129 - 1.28 0.000000 - 0.804000 189 - 253 0.0739 - 1.69 0.000000 - 0.787400 & R1216 283 - 323 0.689 - 4.58 0.032000 - 0.950000 & R14 180 - 210 0.077 - 2.16 0.000000 - 1.000000 & R218 264 - 308 0.298 - 4.6 0.000000 - 1.000000 & R23 188 - 244 0.0854 - 1.62 0.000000 - 1.000000 & TOLUENE Continued on next page...
S153
N 333 32 22 141 15 2 64 6 18 4 3 164 83 36 59 10 110 11 164 94 9 6 62 101 71 48 59 80 10 31 25 245 63 34 34 50 37 50 56
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 313 - 473 0.63 - 11.5 0.027000 - 0.905000 S1400 294 - 363 1.03 - 3.65 0.074000 - 0.732000 ETHANE & WATER S1772 344 - 378 3.48 - 28.2 0.000837 - 0.004070 S888 473 - 673 20 - 370 0.005000 - 0.340000 S1773 305 - 311 2.86 - 5.07 0.999612 - 0.999923 S365 278 - 303 0.101 - 0.101 0.000029 - 0.000065 S1774 273 - 288 0.66 - 0.66 0.000270 - 0.007100 S892 344 - 344 20 - 100 0.092600 - 0.139800 S1740 283 - 303 0.5 - 4 0.000119 - 0.000864 S1775 274 - 303 0.373 - 4.13 0.000134 - 0.000970 S1776 278 - 281 10.1 - 15.1 0.000353 - 0.000452 S1777 439 - 573 10 - 94.5 0.004000 - 0.047000 S1778 311 - 511 2.21 - 68.2 0.000000 - 0.000000 ETHANE & XENON S1779 210 - 304 0.331 - 5.82 0.000000 - 1.000000 S1780 161 - 182 0.0237 - 0.248 0.000000 - 1.000000 ETHANOL & ETHYLENE S370 298 - 298 0.101 - 0.101 0.994030 - 0.994030 S1781 423 - 493 0.963 - 12.9 0.425000 - 1.000000 S580 298 - 298 0.0535 - 0.13 0.992829 - 0.997329 S1782 284 - 284 1.24 - 5.04 0.011000 - 0.899000 S1783 298 - 298 3.15 - 4.19 0.319100 - 1.000000 ETHANOL & HEPTANE S1784 303 - 343 0.00776 - 0.0957 0.000000 - 1.000000 S1785 303 - 303 0.00779 - 0.0163 0.000000 - 1.000000 S1786 309 - 364 0.024 - 0.101 0.013000 - 0.997000 S1787 345 - 346 0.101 - 0.101 0.452000 - 0.670000 S1788 303 - 371 0.00783 - 0.101 0.000000 - 1.000000 S1789 343 - 363 0.0406 - 0.223 0.000000 - 1.000000 S1790 313 - 313 0.0208 - 0.0264 0.035200 - 0.961500 S1791 313 - 333 0.0123 - 0.0648 0.000000 - 1.000000 S1792 344 - 372 0.101 - 0.101 0.000000 - 1.000000 S1793 333 - 382 0.0482 - 0.153 0.000000 - 1.000000 S180 303 - 323 0.00785 - 0.042 0.000000 - 1.000000 S1794 303 - 303 0.00779 - 0.0161 0.000000 - 1.000000 S1795 303 - 343 0.00783 - 0.0965 0.000000 - 1.000000 S1796 313 - 313 0.0123 - 0.0265 0.000000 - 1.000000 S572 344 - 462 0.101 - 0.811 0.000000 - 0.999000 S1797 303 - 303 0.012 - 0.0162 0.027600 - 0.979600 S1798 313 - 313 0.0216 - 0.0265 0.097400 - 0.962300 S1799 313 - 313 0.0203 - 0.0264 0.029200 - 0.969900 S1800 483 - 523 1.16 - 5.66 0.000000 - 1.000000 S1801 344 - 364 0.101 - 0.101 0.031000 - 0.987000 ETHANOL & HEXANE S945 263 - 303 0.000813 - 0.033 0.000000 - 1.000000 S1802 331 - 351 0.101 - 0.101 0.000000 - 1.000000 S198 308 - 351 0.0137 - 0.101 0.000000 - 1.000000 S559 328 - 328 0.046 - 0.0902 0.039000 - 0.989000 Continued on next page... S944
S154
N 26 18 5 70 30 6 7 4 17 23 6 12 41 167 21 1 41 5 8 43 44 11 37 2 37 33 10 31 23 59 65 23 84 24 74 22 16 6 31 23 92 18 44 17
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 323 - 323 0.0294 - 0.074 0.000000 - 1.000000 S565 298 - 298 0.00787 - 0.0254 0.000000 - 1.000000 S1803 333 - 333 0.0931 - 0.108 0.119000 - 0.867000 S1804 303 - 353 0.0105 - 0.212 0.000000 - 1.000000 S566 298 - 298 0.00787 - 0.0254 0.000000 - 1.000000 S567 298 - 298 0.0199 - 0.0254 0.100000 - 0.900000 S1805 313 - 313 0.018 - 0.0499 0.000000 - 1.000000 S1796 313 - 313 0.0179 - 0.0493 0.000000 - 1.000000 S1806 318 - 318 0.0231 - 0.0605 0.000000 - 1.000000 S1807 298 - 328 0.0191 - 0.0896 0.100000 - 0.900000 S1808 473 - 503 1.81 - 5.56 0.000000 - 1.000000 S1809 330 - 350 0.095 - 0.095 0.000000 - 1.000000 S1810 333 - 514 0.106 - 6.14 0.000000 - 1.000000 ETHANOL & HYDROGEN S1811 291 - 291 1.39 - 3.12 0.993300 - 0.996900 S1812 298 - 508 4.1 - 33.3 0.589500 - 0.989490 S205 298 - 323 0.101 - 0.101 0.999773 - 0.999805 S1813 300 - 476 3.7 - 9.03 0.929600 - 0.986800 S638 298 - 298 0.101 - 0.101 0.999807 - 0.999807 S1673 298 - 508 0.5 - 33.8 0.000000 - 0.989490 ETHANOL & IBUTENE S788 364 - 364 0.161 - 1.52 0.000000 - 1.000000 S974 324 - 375 0.268 - 1.86 0.022000 - 0.909500 S1814 323 - 323 0.0293 - 0.611 0.000000 - 1.000000 ETHANOL & IHEXANE S1815 326 - 352 0.101 - 0.101 0.000000 - 1.000000 ETHANOL & IOCTANE S1790 313 - 313 0.0198 - 0.0271 0.020000 - 0.936700 S1816 313 - 313 0.013 - 0.027 0.000000 - 1.000000 S1817 333 - 333 0.057 - 0.0653 0.087700 - 0.918700 S1818 344 - 349 0.101 - 0.101 0.087400 - 0.929600 S187 344 - 372 0.101 - 0.101 0.000000 - 1.000000 S1819 344 - 371 0.0958 - 0.0958 0.000000 - 1.000000 S1820 345 - 372 0.101 - 0.101 0.000000 - 1.000000 S1821 273 - 323 0.00159 - 0.0425 0.000000 - 1.000000 ETHANOL & IPENTANE S1822 300 - 352 0.101 - 0.101 0.000000 - 1.000000 ETHANOL & ISOBUTAN S785 283 - 323 0.00312 - 0.101 0.945570 - 1.000000 S1823 309 - 364 0.338 - 1.67 0.000000 - 0.979000 S1824 313 - 313 0.0178 - 0.532 0.000000 - 1.000000 S791 313 - 403 0.018 - 3.38 0.000000 - 1.000000 ETHANOL & KRYPTON S1825 159 - 223 0.0267 - 0.0267 0.995770 - 0.999040 S371 298 - 298 0.101 - 0.101 0.917890 - 0.917890 S372 283 - 313 0.101 - 0.101 0.998275 - 0.998688 ETHANOL & METHANE S208 298 - 298 0.101 - 0.101 0.998720 - 0.998720 S1812 298 - 498 3.32 - 31.5 0.565400 - 0.975630 Continued on next page... S489
S155
N 20 12 8 154 24 9 18 15 39 17 46 9 180 4 35 2 18 1 93 20 14 24 23 17 15 17 16 21 8 18 57 13 18 30 23 38 8 1 3 1 27
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 313 - 333 1.81 - 10.5 0.893000 - 0.979000 S1826 280 - 280 1.57 - 11.4 0.874000 - 0.982000 S1141 323 - 373 2.12 - 2.66 0.972980 - 0.976370 S1827 295 - 295 1.02 - 7.99 0.901000 - 0.987000 S1502 280 - 333 2.1 - 12.1 0.876000 - 0.977000 S1673 298 - 498 0.5 - 36.4 0.000000 - 0.975630 ETHANOL & METHANOL S527 338 - 352 0.102 - 0.102 0.000000 - 1.000000 S528 293 - 373 0.00587 - 0.329 0.000000 - 1.000000 S1828 293 - 373 0.00587 - 0.329 0.000000 - 1.000000 S529 273 - 373 0.00169 - 0.329 0.000000 - 1.000000 S1829 339 - 349 0.101 - 0.101 0.125000 - 0.875000 S173 338 - 351 0.101 - 0.101 0.000000 - 1.000000 S175 338 - 351 0.101 - 0.101 0.000000 - 1.000000 S1830 339 - 350 0.101 - 0.101 0.112000 - 0.927000 S1831 373 - 433 0.233 - 1.71 0.058000 - 0.940000 S1832 338 - 352 0.101 - 0.101 0.000000 - 1.000000 S1833 338 - 351 0.101 - 0.101 0.000000 - 1.000000 S1834 298 - 298 0.00856 - 0.0161 0.083500 - 0.915900 S1835 298 - 298 0.00786 - 0.0169 0.000000 - 1.000000 S1836 373 - 413 0.246 - 1.08 0.000000 - 1.000000 S1837 313 - 313 0.0179 - 0.0355 0.000000 - 1.000000 S508 303 - 313 0.0105 - 0.0354 0.000000 - 1.000000 S1838 303 - 303 0.0105 - 0.0219 0.000000 - 1.000000 S1839 338 - 350 0.101 - 0.101 0.065000 - 0.926000 S1840 338 - 351 0.101 - 0.101 0.020700 - 0.958200 S1602 316 - 349 0.04 - 0.0933 0.000000 - 1.000000 S1841 339 - 349 0.101 - 0.101 0.156000 - 0.865000 S1842 338 - 351 0.101 - 0.101 0.059000 - 0.982000 ETHANOL & MM S1843 333 - 343 0.0263 - 0.0939 0.000000 - 1.000000 S1844 293 - 358 0.00789 - 0.102 0.090000 - 0.951000 S1845 303 - 312 0.0147 - 0.0147 0.040000 - 0.920000 S1846 333 - 357 0.06 - 0.101 0.100000 - 0.900000 ETHANOL & MXYLENE S150 298 - 298 0.00426 - 0.00766 0.033000 - 0.842000 S1847 350 - 408 0.095 - 0.095 0.000000 - 0.913200 ETHANOL & NITROGEN S370 298 - 298 0.101 - 0.101 0.999652 - 0.999652 S1848 298 - 398 0.008 - 9.87 0.956360 - 1.000000 S1141 323 - 373 3.5 - 7 0.972560 - 0.987470 ETHANOL & NONANE S1547 351 - 388 0.101 - 0.101 0.048000 - 0.923000 S1795 343 - 343 0.00633 - 0.0727 0.000000 - 1.000000 ETHANOL & OCTANE S1849 318 - 348 0.0103 - 0.0949 0.001400 - 0.984500 S1547 349 - 373 0.101 - 0.101 0.087000 - 0.988000 S1796 313 - 313 0.00415 - 0.0197 0.000000 - 1.000000 S1818 350 - 359 0.101 - 0.101 0.071600 - 0.955700 Continued on next page... S1121
S156
N 10 10 4 8 19 75 13 55 55 99 7 24 14 8 40 30 11 11 16 12 15 33 24 11 20 105 11 26 39 22 14 16 10 8 1 39 6 10 27 70 9 14 20
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 343 - 343 0.016 - 0.0783 0.000000 - 1.000000 S1851 322 - 398 0.03 - 0.101 0.000000 - 1.000000 ETHANOL & OXYGEN S1141 323 - 373 3.49 - 6.93 0.999671 - 0.999852 S254 298 - 298 0.101 - 0.101 0.999429 - 0.999429 ETHANOL & OXYLENE S1852 351 - 410 0.101 - 0.101 0.006500 - 0.995200 ETHANOL & PENTANE S555 401 - 494 0.689 - 5.52 0.250000 - 0.750000 S556 391 - 495 0.689 - 5.7 0.250000 - 0.750000 S1853 373 - 423 0.224 - 1.96 0.000000 - 1.000000 S1838 303 - 303 0.0105 - 0.0871 0.000000 - 1.000000 S1854 423 - 500 0.975 - 5.72 0.000000 - 1.000000 ETHANOL & PROPANE S785 273 - 323 0.00157 - 0.102 0.959460 - 1.000000 S1855 325 - 425 0.0323 - 5.62 0.000000 - 1.000000 S1856 325 - 375 0.032 - 4.3 0.000000 - 1.000000 S1823 325 - 375 0.974 - 4.38 0.000000 - 0.840000 S1857 314 - 350 0.37 - 2.83 0.025000 - 0.962700 ETHANOL & PROPYLEN S259 293 - 333 0.196 - 0.686 0.880000 - 0.982000 S1858 333 - 368 0.951 - 4.56 0.000000 - 0.911600 ETHANOL & PXYLENE S1655 351 - 412 0.101 - 0.101 0.000000 - 1.000000 S1859 352 - 412 0.101 - 0.101 0.000000 - 1.000000 S1860 318 - 318 0.00445 - 0.023 0.003550 - 0.962100 S571 313 - 313 0.00265 - 0.0179 0.000000 - 1.000000 S1847 349 - 409 0.095 - 0.095 0.000000 - 1.000000 S947 351 - 405 0.101 - 0.101 0.008000 - 0.979000 S1861 330 - 411 0.04 - 0.101 0.000000 - 1.000000 ETHANOL & R113 S1862 378 - 393 0.468 - 0.866 0.000000 - 0.853400 ETHANOL & R114 S1862 363 - 384 0.161 - 1.78 0.247500 - 1.000000 ETHANOL & R115 S1863 283 - 313 0.101 - 0.101 0.989300 - 0.994900 ETHANOL & R125 S1863 283 - 313 0.101 - 0.101 0.960600 - 0.984300 S1864 308 - 323 0.0547 - 0.0891 0.988300 - 0.991700 ETHANOL & R134A S1863 283 - 313 0.101 - 0.101 0.942100 - 0.975400 S1864 303 - 323 0.0354 - 0.0754 0.986600 - 0.990100 ETHANOL & R152A S1863 283 - 313 0.101 - 0.101 0.938900 - 0.974700 S1864 303 - 323 0.0356 - 0.0786 0.985900 - 0.989400 ETHANOL & R21 S1863 283 - 313 0.101 - 0.101 0.951800 - 0.980900 ETHANOL & R22 S1330 343 - 383 0.836 - 5.43 0.013000 - 0.899000 Continued on next page... S1850
S157
N 23 79 6 1 14 19 22 34 26 30 13 26 19 17 24 11 43 13 17 44 33 9 21 73 8 8 4 4 7 4 11 4 9 4 35
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 313 - 383 0.545 - 4.89 0.096100 - 0.967000 S1863 283 - 313 0.101 - 0.101 0.931000 - 0.972600 S1864 303 - 323 0.0272 - 0.0663 0.983400 - 0.988700 ETHANOL & R23 S1865 287 - 308 0.101 - 0.101 0.964800 - 0.974680 ETHANOL & R32 S1863 283 - 313 0.101 - 0.101 0.972200 - 0.986600 S1864 303 - 323 0.0514 - 0.102 0.989900 - 0.993500 S1865 288 - 313 0.101 - 0.101 0.974240 - 0.986390 ETHANOL & R41 S1865 288 - 308 0.101 - 0.101 0.991218 - 0.994212 ETHANOL & SO2 S1591 293 - 293 0.0553 - 0.327 0.000000 - 0.858500 S1866 293 - 293 0.0126 - 0.33 0.000000 - 0.974700 ETHANOL & T2BUTENE S974 324 - 375 0.236 - 1.55 0.019600 - 0.894300 S1867 332 - 332 0.0447 - 0.609 0.000000 - 1.000000 ETHANOL & TOLUENE S541 323 - 323 0.0266 - 0.0332 0.138000 - 0.946000 S1868 323 - 323 0.0124 - 0.0332 0.000000 - 1.000000 S1869 333 - 358 0.0186 - 0.14 0.000000 - 1.000000 S1870 308 - 328 0.00624 - 0.041 0.000000 - 1.000000 S1787 350 - 351 0.101 - 0.101 0.452000 - 0.810000 S553 350 - 384 0.101 - 0.101 0.000000 - 1.000000 S1871 335 - 350 0.0549 - 0.101 0.778000 - 0.818000 S1872 298 - 346 0.00439 - 0.078 0.000000 - 1.000000 S1467 323 - 323 0.0124 - 0.0329 0.000000 - 1.000000 S1873 350 - 356 0.101 - 0.101 0.164600 - 0.958300 S1874 350 - 384 0.101 - 0.101 0.000000 - 0.980000 S1843 333 - 348 0.0186 - 0.0953 0.000000 - 1.000000 S571 313 - 313 0.00789 - 0.0203 0.000000 - 1.000000 S1875 300 - 383 0.0103 - 0.101 0.000000 - 1.000000 S1876 323 - 323 0.0146 - 0.0328 0.008000 - 0.991000 S1877 323 - 323 0.0141 - 0.0317 0.009000 - 0.981000 S519 334 - 383 0.0533 - 0.0987 0.000000 - 1.000000 S1878 350 - 410 0.101 - 0.201 0.000000 - 1.000000 ETHANOL & WATER S158 351 - 372 0.1 - 0.101 0.000000 - 1.000000 S1879 313 - 348 0.00724 - 0.0872 0.000000 - 1.000000 S162 351 - 373 0.101 - 0.101 0.000000 - 0.900000 S1880 295 - 371 0.00667 - 0.0987 0.005522 - 0.830317 S1881 423 - 548 0.738 - 10.3 0.058000 - 0.688000 S1882 323 - 373 0.0177 - 0.101 0.000000 - 1.000000 S1883 323 - 323 0.0123 - 0.0293 0.000000 - 1.000000 S1884 298 - 348 0.00316 - 0.0891 0.000000 - 1.000000 S1885 351 - 373 0.101 - 0.101 0.000000 - 0.917000 S1886 373 - 373 0.101 - 0.101 0.000000 - 0.000000 S1887 378 - 432 0.288 - 0.963 0.007517 - 0.992364 S1888 351 - 368 0.101 - 0.101 0.015000 - 0.826000 Continued on next page... S1133
S158
N 26 4 11 9 4 11 7 9 12 6 16 24 9 11 72 24 2 18 5 60 7 8 14 52 42 53 15 4 105 60 15 70 10 106 18 33 8 23 33 1 41 16
Table S4 – continued from previous page Reference S1889 S1890 S1891 S1892 S1893 S1894 S1895 S1896 S1897 S1898 S1899 S1900 S1901 S179 S1902 S1903 S1904 S1905 S1906 S1907 S1908 S1909 S183 S1910 S1911 S1912 S1913 S233 S1836 S1914 S1915 S1916 S1917 S1918 S1919 S1920 S1921 S1922 S1923 S1924 S1925 S1926 S1927 S1928 S1929 S1930 S1851 S1931 S1932
T (K) 313 - 333 351 - 373 423 - 623 273 - 323 573 - 573 341 - 361 351 - 370 351 - 373 320 - 437 351 - 373 283 - 303 313 - 343 351 - 373 303 - 308 296 - 310 351 - 365 323 - 323 303 - 363 323 - 323 298 - 298 323 - 323 333 - 333 323 - 323 333 - 333 323 - 323 298 - 308 363 - 424 339 - 351 423 - 523 370 - 373 313 - 313 343 - 343 323 - 333 340 - 420 322 - 372 313 - 313 313 - 313 457 - 546 351 - 351 345 - 349 353 - 373 334 - 352 363 - 423 307 - 335 353 - 363 363 - 424 323 - 351 473 - 573 350 - 371
p (MPa) x1 (-) 0.00737 - 0.0474 0.000000 - 1.000000 0.101 - 0.101 0.000000 - 1.000000 0.558 - 19 0.006000 - 0.934000 0.00062 - 0.0296 0.002000 - 1.000000 8.83 - 13.1 0.010000 - 0.260000 0.066 - 0.066 0.000000 - 0.978000 0.0993 - 0.0993 0.008000 - 0.914000 0.101 - 0.101 0.000000 - 0.839300 0.0253 - 0.69 0.000000 - 1.000000 0.101 - 0.101 0.000000 - 1.000000 0.00191 - 0.0104 0.100000 - 0.900000 0.01 - 0.0726 0.051000 - 0.957000 0.101 - 0.101 0.001000 - 0.919000 0.0092 - 0.0133 0.600000 - 0.920000 0.00667 - 0.00667 0.012000 - 0.601000 0.101 - 0.101 0.045000 - 0.966000 0.0123 - 0.0301 0.000000 - 1.000000 0.00441 - 0.159 0.004290 - 0.981530 0.0123 - 0.0295 0.000000 - 1.000000 0.00316 - 0.00786 0.000000 - 1.000000 0.0124 - 0.0295 0.000000 - 1.000000 0.0199 - 0.0469 0.000000 - 0.950000 0.0124 - 0.0296 0.000000 - 1.000000 0.0199 - 0.0469 0.000000 - 1.000000 0.0178 - 0.0295 0.051200 - 0.950100 0.00318 - 0.0103 0.000442 - 0.234920 0.0703 - 1 0.000000 - 1.000000 0.0603 - 0.101 0.894000 - 0.908000 0.743 - 7.12 0.097000 - 0.691000 0.101 - 0.101 0.000070 - 0.008582 0.01 - 0.0179 0.042500 - 0.982800 0.0312 - 0.0725 0.000000 - 0.999081 0.0203 - 0.0471 0.074200 - 0.958300 0.0452 - 0.916 0.100200 - 0.890400 0.0117 - 0.0989 0.000019 - 0.000027 0.0123 - 0.0179 0.095300 - 0.914100 0.00741 - 0.018 0.000000 - 0.943000 2.1 - 9.65 0.500000 - 0.500000 0.1 - 0.1 0.798500 - 0.990510 0.0773 - 0.0773 0.281000 - 0.763000 0.1 - 0.1 0.000000 - 0.448800 0.0507 - 0.0507 0.008200 - 0.943500 0.144 - 0.918 0.323384 - 0.323384 0.0132 - 0.0329 0.063000 - 0.971000 0.0473 - 0.159 0.000000 - 1.000000 0.126 - 0.988 0.013700 - 0.999100 0.03 - 0.101 0.930300 - 0.967400 2.18 - 11.9 0.107000 - 0.792000 0.0927 - 0.0953 0.000000 - 0.786000 Continued on next page...
S159
N 36 13 79 114 6 9 12 16 156 21 24 38 126 8 8 13 14 94 26 13 17 21 24 13 20 1200 120 6 21 22 22 60 105 25 6 9 27 18 6 5 15 16 7 43 24 74 7 21 54
Table S4 – continued from previous page Reference T (K) p (MPa) x1 (-) ETHANOL & XENON S371 298 - 298 0.101 - 0.101 0.996440 - 0.996440 S372 283 - 313 0.101 - 0.101 0.994379 - 0.996609 ETHYLENE & HELIUM S1933 130 - 216 2.31 - 12.1 0.980550 - 0.999599 ETHYLENE & HEPTANE S1934 273 - 522 0.689 - 10.3 0.070400 - 0.969900 S258 293 - 333 0.274 - 3.15 0.031000 - 0.576000 S580 298 - 298 0.0815 - 0.132 0.015100 - 0.025270 S1935 423 - 473 0.37 - 4.05 0.000000 - 0.260000 ETHYLENE & HEXANE S577 303 - 423 1.01 - 10.1 0.022000 - 0.850000 S258 293 - 333 0.279 - 3.14 0.025000 - 0.573000 S1936 391 - 495 1.51 - 9.09 0.099400 - 0.700700 ETHYLENE & HYDROGEN S1937 200 - 200 1.72 - 55.2 0.692200 - 0.991500 S1696 123 - 248 2.03 - 8.11 0.939700 - 0.994690 S1938 114 - 247 4.63 - 600 0.301200 - 0.975100 ETHYLENE & IOCTANE S1398 323 - 423 0.44 - 2.42 0.019100 - 0.316100 ETHYLENE & ISOBUTAN S1939 311 - 344 3.45 - 3.45 0.296000 - 0.497000 S1940 293 - 393 0.298 - 6.08 0.000000 - 0.895000 ETHYLENE & KRYPTON S1941 116 - 116 0.000684 - 0.073 0.000000 - 1.000000 ETHYLENE & METHANE S1942 127 - 253 0.00304 - 4.42 0.000000 - 1.000000 S1943 177 - 263 2.02 - 4.3 0.244000 - 0.977000 S1944 104 - 116 9.2e-05 - 0.14 0.000000 - 1.000000 S1945 150 - 190 0.0276 - 3.72 0.113400 - 1.000000 S1724 198 - 248 1.02 - 6.08 0.262000 - 0.919100 ETHYLENE & METHANOL S370 298 - 298 0.101 - 0.101 0.004390 - 0.004390 S1946 228 - 248 0.101 - 1.82 0.010000 - 0.570000 S258 293 - 333 0.128 - 3.12 0.005000 - 0.165000 S1947 298 - 313 1.02 - 13 0.040200 - 0.872700 S1948 284 - 298 0.948 - 9.96 0.045600 - 0.985270 S580 298 - 298 0.0987 - 0.133 0.003390 - 0.004855 S1949 240 - 298 0.42 - 6.02 0.042900 - 1.000000 S1950 278 - 284 2.05 - 5.06 0.140000 - 0.989000 S1951 293 - 373 1.99 - 11.9 0.099000 - 0.300000 S1952 304 - 432 2.21 - 16 0.000000 - 0.749000 ETHYLENE & N2O S1953 182 - 182 0.0879 - 0.205 0.000000 - 1.000000 ETHYLENE & NEON S1742 102 - 122 0.745 - 4.61 0.000000 - 0.000000 ETHYLENE & NITROGEN S1744 200 - 260 0.454 - 11 0.526500 - 1.000000 S1954 120 - 200 0.0012 - 9.34 0.346200 - 1.000000 Continued on next page...
S160
N 1 3 39 124 12 5 24 50 13 99 6 22 195 15 2 34 9 91 12 22 52 12 1 18 13 31 25 5 46 11 27 44 11 12 15 59
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 240 - 260 1.77 - 9.09 0.717100 - 1.000000 S308 144 - 228 2.07 - 4.83 0.749000 - 0.974200 ETHYLENE & NONANE S258 293 - 333 0.278 - 3.09 0.035000 - 0.562000 ETHYLENE & OCTANE S916 140 - 210 0.0314 - 0.346 0.295500 - 0.999295 S1320 318 - 338 1.5 - 9.5 0.192420 - 0.889700 ETHYLENE & PROPANE S397 200 - 273 0.143 - 3.92 0.054000 - 0.963500 ETHYLENE & PROPYLEN S83 263 - 293 0.424 - 5.34 0.000000 - 1.000000 S1348 283 - 298 1.03 - 5.38 0.074900 - 0.972400 S1955 283 - 348 0.784 - 5.57 0.000000 - 0.977000 S1169 243 - 288 0.261 - 4.23 0.000000 - 0.794200 ETHYLENE & R1216 S1956 258 - 307 0.601 - 4.56 0.058000 - 0.965000 ETHYLENE & TOLUENE S189 228 - 248 0.101 - 1.82 0.033000 - 0.826300 S258 293 - 333 0.275 - 3.06 0.022000 - 0.430000 S1957 293 - 333 0.0608 - 3.16 0.006938 - 0.430000 S1396 323 - 423 0.47 - 2.89 0.026500 - 0.230600 S1958 303 - 363 0.305 - 2.04 0.016300 - 0.068500 S1959 323 - 363 0.66 - 5.68 0.053500 - 0.355700 ETHYLENE & WATER S1960 308 - 379 0.461 - 53.1 0.000190 - 0.004420 S1961 311 - 394 0.117 - 3.74 0.000027 - 0.001860 S1893 473 - 573 2.94 - 15.7 0.000950 - 0.014000 S94 298 - 298 0.101 - 0.101 0.000084 - 0.000084 S1772 311 - 411 3.43 - 34.4 0.001329 - 0.005631 S1962 439 - 573 10 - 94.5 0.004000 - 0.047000 ETHYLENE & XENON S1963 161 - 161 0.0618 - 0.0834 0.000000 - 1.000000 S1964 203 - 287 0.515 - 5.68 0.000000 - 1.000000 H2S & HEPTANE S1965 293 - 373 0.398 - 6.83 0.052100 - 0.877700 S1966 311 - 478 0.16 - 9.55 0.017700 - 0.927000 S1199 311 - 394 0.16 - 9.55 0.073000 - 0.963000 H2S & HEXANE S270 268 - 298 0.1 - 0.101 0.029900 - 0.090200 S583 323 - 423 0.43 - 7.54 0.023000 - 0.914000 H2S & HYDROGEN S1268 243 - 273 1.01 - 5.07 0.980000 - 0.998000 H2S & IOCTANE S1549 323 - 473 0.239 - 1.66 0.024600 - 0.259800 H2S & IPENTANE S1967 323 - 413 0.21 - 8.38 0.000000 - 1.000000 H2S & ISOBUTAN S1968 278 - 378 0.182 - 6.17 0.000000 - 1.000000 S796 344 - 398 1.11 - 8.91 0.000000 - 1.000000 Continued on next page... S1949
S161
N 17 32 12 15 20 34 47 46 45 31 46 17 11 15 18 15 18 51 45 18 1 38 12 9 157 35 50 39 2 25 11 19 41 42 65
Table S4 – continued from previous page Reference T (K) H2S & METHANE S1172 311 - 311 S1969 222 - 273 S1970 186 - 313 S1971 222 - 273 S1972 278 - 444 S1973 189 - 366 S1974 192 - 353 S1179 311 - 311 H2S & METHANOL S1268 248 - 273 S97 263 - 298 S1975 298 - 448 H2S & MXYLENE S1976 311 - 478 H2S & NEOPENTN S1967 323 - 413 S1977 323 - 413 H2S & NITROGEN S1978 256 - 344 S739 200 - 228 H2S & NONANE S1979 311 - 478 S1980 311 - 478 H2S & PENTANE S1981 278 - 444 S795 223 - 263 H2S & PROPANE S1982 324 - 367 S1983 272 - 361 S794 182 - 182 S795 243 - 273 S1984 252 - 370 S1985 217 - 344 S1986 272 - 366 S1987 243 - 288 H2S & TOLUENE S1988 311 - 478 H2S & WATER S1989 273 - 323 S1039 311 - 589 S1990 311 - 377 S1410 422 - 589 S1991 311 - 444 HCL & HEPTANE S1992 298 - 298 HCL & HEXANE S1992 283 - 323 HCL & IOCTANE
p (MPa)
x1 (-)
4.14 - 12.4 0.16 - 11.8 0.043 - 13.2 0.16 - 13.1 1.17 - 13.4 1.38 - 12.4 0.0483 - 12.3 4.14 - 12.4
0.740000 0.644000 0.653000 0.000000 0.000000 0.000000 0.000000 0.740000
0.967000 1.000000 1.000000 1.000000 1.000000 0.999000 0.933000 0.967000
2 42 39 93 93 61 35 3
0.203 - 1.03 0.101 - 0.101 0.0173 - 11.2
0.092000 - 1.000000 0.027600 - 0.068900 0.000000 - 1.000000
25 2 55
0.146 - 13.1
0.020600 - 0.993100
30
0.359 - 7.45 0.359 - 7.45
0.000000 - 1.000000 0.000000 - 1.000000
36 36
1.17 - 20.7 0.141 - 13.7
0.838600 - 1.000000 0.976800 - 0.999600
57 18
0.137 - 2.76 0.137 - 13.8
0.041900 - 0.208800 0.020700 - 0.208800
15 33
0.0303 - 8.96 0.0173 - 0.745
0.000000 - 1.000000 0.051000 - 0.974000
85 65
0.014000 0.163300 0.000000 0.000000 0.819900 0.015000 0.000000 0.000000
0.465000 0.898400 0.834600 1.000000 0.962200 0.985000 0.898400 1.000000
11 115 7 119 11 49 209 27
0.031000 - 0.954000
27
0.000483 0.004380 0.002800 0.004390 0.000000
0.003053 0.041200 0.021200 0.097200 0.158600
36 15 39 11 67
0.101 - 0.101
0.014700 - 0.014700
1
0.101 - 0.101
0.005410 - 0.016300
6
2.76 - 4.14 0.71 - 7.34 0.00602 - 0.0195 0.168 - 1.08 0.568 - 8.59 0.138 - 2.76 0.71 - 7.99 0.172 - 1.7 0.203 - 11.6 0.0468 - 0.0963 0.345 - 13.8 0.457 - 1.75 5.52 - 20.7 0.689 - 34.5
-
N
-
-
Continued on next page...
S162
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 298 - 298 0.101 - 0.101 0.000200 - 0.000200 HCL & METHANOL S1993 260 - 318 0.00129 - 0.044 0.017500 - 0.333000 HCL & N2O S1994 182 - 182 0.0721 - 0.0904 0.000000 - 1.000000 S1995 182 - 182 0.0763 - 0.0902 0.078600 - 0.928000 HCL & OCTANE S1992 298 - 298 0.101 - 0.101 0.016300 - 0.016300 HCL & PENTANE S1992 298 - 298 0.101 - 0.101 0.004700 - 0.004700 HCL & PROPANE S918 273 - 370 0.471 - 8.28 0.000000 - 1.000000 HCL & R14 S1996 159 - 173 0.0138 - 0.509 0.000000 - 1.000000 HCL & R142B S300 233 - 273 0.0238 - 2.61 0.000000 - 1.000000 HCL & R32 S1997 248 - 273 0.331 - 2.61 0.000000 - 1.000000 HCL & R40 S1998 159 - 182 0.00167 - 0.0721 0.000000 - 1.000000 HCL & R41 S1999 159 - 182 0.00513 - 0.0721 0.000000 - 1.000000 HCL & SO2 S995 203 - 273 0.00263 - 2.62 0.000000 - 1.000000 HCL & WATER S2000 293 - 349 0.00123 - 0.0748 0.000000 - 0.224000 S211 375 - 381 0.1 - 0.1 0.044806 - 0.121010 S2001 322 - 396 0.00667 - 0.163 0.106030 - 0.131270 S2002 374 - 380 0.101 - 0.101 0.080200 - 0.753900 S2003 402 - 482 0.151 - 3.06 0.111500 - 0.111500 S2004 238 - 273 1.31e-05 - 0.00376 0.041100 - 0.214500 S2005 374 - 382 0.101 - 0.101 0.022200 - 0.131700 S2006 368 - 385 0.0771 - 0.19 0.004000 - 0.153320 HCL & XENON S2007 159 - 195 0.0138 - 0.476 0.000000 - 1.000000 HELIUM & HEPTANE S352 298 - 298 0.101 - 0.101 0.000248 - 0.000248 HELIUM & HEXANE S352 298 - 298 0.101 - 0.101 0.000258 - 0.000258 HELIUM & HYDROGEN S1530 16 - 20 0.0629 - 0.161 0.000320 - 0.001810 S1531 20 - 28 0.0907 - 2.06 0.000000 - 0.056600 S2008 17 - 22 0.193 - 5.87 0.000000 - 0.034400 S2009 14 - 16 0.177 - 1.72 0.001000 - 0.005000 S2010 15 - 30 2.36 - 10.4 0.009500 - 0.363000 S2011 15 - 32 0.241 - 3.45 0.000000 - 0.208700 HELIUM & IOCTANE S384 298 - 298 0.101 - 0.101 0.000308 - 0.000308 HELIUM & ISOBUTAN Continued on next page... S1992
S163
N 1 138 11 14 1 1 181 12 38 44 15 31 35 32 8 10 13 18 22 9 36 29 1 1 24 49 131 19 60 95 1
Table S4 – continued from previous page Reference S798
HELIUM S2012
HELIUM S2013 S2014 S2015 S2016 S2017 S2018 S2019 S2020 S2021 S2022
HELIUM S2023
HELIUM S1013
HELIUM S2024 S2025
HELIUM S2026 S2027 S2028 S2029 S2030 S2031 S2032 S2033 S378 S2034 S2035 S2036 S2037 S2038 S2039
HELIUM S352
HELIUM S2040 S352
HELIUM S373 S2041 S406 S308 S378
HELIUM
T (K) p (MPa) x1 (-) 143 - 273 0.49 - 3.92 0.000130 - 0.014330 & KRYPTON 100 - 150 0.265 - 12.2 0.000000 - 0.015900 & METHANE 90 - 106 2.55 - 15.9 0.001300 - 0.009700 91 - 150 0.0124 - 17 0.000000 - 0.041000 95 - 185 0.481 - 20.5 0.000120 - 0.137000 124 - 191 0.254 - 6.9 0.000000 - 0.058700 100 - 185 0.125 - 9.56 0.000000 - 0.064800 91 - 91 1.34 - 10.3 0.000000 - 0.000000 93 - 191 0.0207 - 13.8 0.000000 - 0.265000 94 - 192 6.87 - 26.2 0.000000 - 0.341700 91 - 150 0.012 - 16.4 0.000000 - 0.041000 95 - 290 3.55 - 1.01e+03 0.000000 - 0.753000 & MXYLENE 466 - 584 5.09 - 15.2 0.022500 - 0.143900 & N2O 195 - 285 0.182 - 13.8 0.000000 - 0.041800 & NEON 25 - 27 0.608 - 5.17 0.002400 - 0.025500 27 - 42 0.284 - 20.3 0.000000 - 0.356000 & NITROGEN 78 - 109 0.108 - 28.9 0.000000 - 0.183000 83 - 113 0.507 - 5.07 0.001080 - 0.035400 122 - 126 2.77 - 21 0.000000 - 0.407500 90 - 118 0.363 - 3.99 0.000000 - 0.026400 63 - 87 0.0448 - 3.31 0.000000 - 0.005000 77 - 137 13.1 - 414 0.036600 - 0.640000 174 - 325 1.37e+03 - 1.01e+04 0.434000 - 0.941000 77 - 120 1.39 - 13.8 0.000000 - 0.143600 68 - 90 0.582 - 2.54 0.000680 - 0.008550 77 - 126 2 - 10 0.000000 - 0.000000 78 - 122 6.69 - 82.7 0.012300 - 0.555600 68 - 112 0.033 - 21.8 0.000000 - 0.139500 77 - 77 1.44 - 6.81 0.003100 - 0.014600 112 - 162 111 - 1.02e+03 0.000000 - 0.767000 77 - 123 1.16 - 6.9 0.002500 - 0.082900 & NONANE 298 - 298 0.101 - 0.101 0.000236 - 0.000236 & OCTANE 298 - 313 0.103 - 0.105 0.000097 - 0.000273 298 - 298 0.101 - 0.101 0.000235 - 0.000235 & OXYGEN 77 - 143 1.72 - 13.8 0.000400 - 0.086000 70 - 150 1.07 - 19.9 0.000000 - 0.134400 65 - 116 0.981 - 21.6 0.000200 - 0.056000 78 - 123 2.07 - 4.83 0.000770 - 0.014000 68 - 90 0.582 - 2.55 0.000130 - 0.002250 & PROPANE Continued on next page...
S164
N 55 100 11 52 60 55 100 5 63 164 43 362 20 87 22 76 29 12 77 38 19 151 26 280 25 25 86 84 30 125 30 1 2 1 37 96 110 28 25
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 123 - 348 0.0069 - 20.7 0.000000 - 0.134000 S308 172 - 255 2.07 - 4.83 0.000960 - 0.011400 HELIUM & PROPYLEN S2043 175 - 255 2.31 - 12.2 0.000000 - 0.022670 HELIUM & R12 S2044 298 - 395 5.67 - 33.3 0.155000 - 0.934000 HELIUM & R22 S2045 373 - 377 15.2 - 35.5 0.140000 - 0.315000 HELIUM & TOLUENE S2046 424 - 546 5.06 - 15.2 0.015200 - 0.102200 HELIUM & WATER S2047 523 - 694 16 - 223 0.006000 - 0.800000 HEPTANE & HEXANE S2048 287 - 372 0.0123 - 0.101 0.000000 - 1.000000 S2049 303 - 323 0.00773 - 0.0534 0.000000 - 1.000000 S468 341 - 341 0.0373 - 0.0993 0.000000 - 1.000000 S110 323 - 323 0.0227 - 0.0509 0.100000 - 0.900000 S2050 313 - 313 0.0148 - 0.0354 0.075700 - 0.902400 S2051 340 - 369 0.094 - 0.094 0.000000 - 1.000000 S2052 342 - 371 0.101 - 0.101 0.000000 - 1.000000 S2053 287 - 372 0.0123 - 0.101 0.000000 - 1.000000 HEPTANE & HYDROGEN S956 424 - 499 0.38 - 80 0.190000 - 1.000000 S2054 423 - 473 0.37 - 4.05 0.945000 - 1.000000 HEPTANE & IHEXANE S1658 318 - 328 0.0153 - 0.0854 0.000000 - 1.000000 HEPTANE & IOCTANE S468 370 - 370 0.0958 - 0.0979 0.000000 - 1.000000 S445 372 - 372 0.101 - 0.101 0.000000 - 1.000000 S2055 313 - 313 0.0123 - 0.0129 0.000000 - 1.000000 HEPTANE & KRYPTON S352 298 - 298 0.101 - 0.101 0.992825 - 0.992825 HEPTANE & METHANE S2056 278 - 511 1.38 - 24.9 0.106000 - 0.986800 S2057 200 - 255 0.689 - 20.7 0.100000 - 0.955500 S1190 185 - 300 0.07 - 11.9 0.308000 - 0.987000 S2058 293 - 293 0.101 - 0.101 0.994740 - 0.994740 S352 298 - 298 0.101 - 0.101 0.994932 - 0.994932 S2059 233 - 278 0.137 - 22.6 0.000000 - 0.000000 S2060 183 - 278 0.689 - 10.3 0.360000 - 0.964000 HEPTANE & METHANOL S2061 332 - 372 0.101 - 0.101 0.000000 - 1.000000 S898 317 - 351 0.0541 - 0.0541 0.000000 - 1.000000 S1660 332 - 372 0.101 - 0.101 0.000000 - 1.000000 S925 418 - 540 0.45 - 8.06 0.000000 - 1.000000 S2062 313 - 313 0.0456 - 0.0456 0.301600 - 0.696200 S2063 313 - 313 0.0123 - 0.0456 0.000000 - 1.000000 HEPTANE & MXYLENE S2064 348 - 348 0.0138 - 0.0456 0.027100 - 0.918000 Continued on next page... S2042
S165
N 78 32 303 36 8 20 86 66 19 5 9 16 16 48 66 32 24 46 6 7 24 1 95 69 50 1 1 53 127 9 20 10 134 2 20 27
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 372 - 410 0.101 - 0.101 0.021100 - 0.976600 HEPTANE & NEON S352 298 - 298 0.101 - 0.101 0.999644 - 0.999644 HEPTANE & NITROGEN S966 453 - 497 4.4 - 27.8 0.412000 - 0.925000 S2065 305 - 305 9.2 - 99.8 0.338100 - 0.891000 S686 305 - 366 5.5 - 34.9 0.603000 - 0.944000 S1390 453 - 453 1.52 - 27.7 0.420000 - 0.982000 S352 298 - 298 0.101 - 0.101 0.998634 - 0.998634 S2066 314 - 524 1.99 - 50.2 0.296700 - 0.982800 S2067 305 - 455 7.03 - 69.1 0.000000 - 0.920000 S2068 453 - 497 1.2 - 29.4 0.330000 - 0.992000 S2069 376 - 453 0.49 - 61.3 0.220000 - 1.000000 HEPTANE & NONANE S692 371 - 424 0.101 - 0.101 0.000000 - 1.000000 HEPTANE & OCTANE S2048 313 - 397 0.0123 - 0.101 0.000000 - 1.000000 S468 370 - 370 0.043 - 0.0974 0.000000 - 1.000000 S595 328 - 328 0.00843 - 0.0231 0.000000 - 1.000000 S2070 313 - 313 0.00416 - 0.0122 0.000000 - 1.000000 S2071 293 - 328 0.00139 - 0.0231 0.000000 - 1.000000 S2072 369 - 396 0.094 - 0.094 0.000000 - 1.000000 S2053 313 - 397 0.0123 - 0.101 0.000000 - 1.000000 HEPTANE & OXYGEN S352 298 - 298 0.101 - 0.101 0.997963 - 0.997963 S254 298 - 298 0.101 - 0.101 0.997810 - 0.997810 HEPTANE & OXYLENE S2064 348 - 348 0.0125 - 0.0464 0.035900 - 0.945600 S2073 348 - 368 0.0102 - 0.092 0.000000 - 1.000000 S1657 372 - 416 0.101 - 0.101 0.009900 - 0.994500 HEPTANE & PENTANE S2074 443 - 526 1.48 - 3.33 0.259000 - 0.745000 S2075 399 - 527 0.652 - 3.39 0.000000 - 1.000000 HEPTANE & PROPANE S2076 332 - 539 2.07 - 4.83 0.000000 - 1.000000 S901 298 - 318 0.101 - 0.101 0.883000 - 0.920200 S1190 185 - 300 0.01 - 1 0.000000 - 0.868800 S2077 273 - 524 1.18 - 5.45 0.000000 - 0.786100 S2078 338 - 523 2.07 - 5.17 0.000000 - 0.786100 HEPTANE & PROPYLEN S258 293 - 333 0.239 - 0.739 0.317000 - 0.907000 S580 298 - 318 0.031 - 0.12 0.897700 - 0.982870 S2079 313 - 359 0.136 - 1.26 0.576000 - 0.930000 HEPTANE & PXYLENE S597 373 - 409 0.101 - 0.101 0.022000 - 0.940000 S2064 348 - 348 0.015 - 0.0466 0.041800 - 0.947500 S505 298 - 328 0.00194 - 0.0204 0.100100 - 0.868200 S525 313 - 313 0.00265 - 0.0123 0.000000 - 1.000000 S1657 372 - 408 0.101 - 0.101 0.036700 - 0.995000 Continued on next page... S1657
S166
N 21 1 21 21 22 12 1 136 39 46 27 16 66 5 14 13 24 22 66 1 1 23 34 20 35 127 84 3 29 114 77 9 15 39 23 28 40 14 21
Table S4 – continued from previous page Reference T (K) p (MPa) x1 (-) HEPTANE & R113 S708 363 - 408 0.157 - 0.916 0.000000 - 0.751800 HEPTANE & R114 S708 363 - 408 0.408 - 2.03 0.237400 - 0.744400 HEPTANE & R12 S710 298 - 309 0.101 - 0.101 0.873000 - 0.904000 HEPTANE & R13 S710 298 - 309 0.101 - 0.101 0.983100 - 0.986000 HEPTANE & R14 S352 298 - 298 0.101 - 0.101 0.997880 - 0.997880 HEPTANE & SF6 S352 298 - 298 0.101 - 0.101 0.989730 - 0.989730 HEPTANE & TOLUENE S2080 371 - 384 0.101 - 0.101 0.000000 - 1.000000 S445 372 - 384 0.101 - 0.101 0.000000 - 1.000000 S2081 372 - 384 0.101 - 0.101 0.000000 - 1.000000 S951 372 - 381 0.101 - 0.101 0.100000 - 0.900000 S2082 372 - 384 0.101 - 0.101 0.000000 - 1.000000 S1476 372 - 384 0.101 - 0.101 0.000000 - 1.000000 S2083 372 - 384 0.101 - 0.101 0.000000 - 1.000000 S2084 298 - 298 0.00391 - 0.00612 0.023000 - 0.953000 S2085 303 - 303 0.00489 - 0.00775 0.000000 - 0.878500 S597 372 - 382 0.101 - 0.101 0.048000 - 0.912000 S2086 313 - 313 0.00789 - 0.0123 0.000000 - 1.000000 S602 328 - 328 0.0151 - 0.0231 0.000000 - 1.000000 S2087 332 - 384 0.0267 - 0.101 0.000000 - 1.000000 S2088 298 - 313 0.00375 - 0.0122 0.000000 - 1.000000 S2089 300 - 384 0.00667 - 0.102 0.000000 - 1.000000 S2090 303 - 363 0.00473 - 0.0786 0.000000 - 1.000000 S2091 375 - 375 0.0997 - 0.0997 0.481234 - 0.481234 S2092 374 - 376 0.101 - 0.101 0.380000 - 0.579700 S525 313 - 313 0.00789 - 0.0123 0.000000 - 1.000000 S2093 313 - 313 0.00788 - 0.0123 0.000000 - 1.000000 S2094 313 - 313 0.00789 - 0.0123 0.000000 - 1.000000 S2095 323 - 363 0.0146 - 0.075 0.167000 - 0.788200 S2096 298 - 298 0.00396 - 0.0119 0.050000 - 0.949400 HEPTANE & WATER HEXANE & HYDROGEN S2097 278 - 478 0.00763 - 68.9 0.232000 - 1.000000 S204 298 - 373 1.38 - 9.81 0.906120 - 0.989250 S2098 311 - 378 3.45 - 3.45 0.963800 - 0.968600 S1002 344 - 411 1.24 - 15.1 0.857000 - 0.989500 HEXANE & IHEXANE S2099 298 - 298 0.0202 - 0.0283 0.000000 - 1.000000 S2100 283 - 313 0.0107 - 0.0495 0.100600 - 0.879900 HEXANE & IOCTANE S1819 340 - 371 0.0958 - 0.0958 0.000000 - 1.000000 HEXANE & IPENTANE S2101 298 - 298 0.0543 - 0.0543 0.500000 - 0.500000 Continued on next page...
S167
N 16 12 4 2 1 1 21 24 23 9 13 15 19 26 11 13 12 13 32 33 76 88 1 2 17 27 2 12 27
120 24 3 33 11 44 8 1
Table S4 – continued from previous page Reference S2102
HEXANE S352
HEXANE S648 S2103 S208 S2104 S653 S190 S2058 S2105 S2106 S2107 S2108 S2109 S2110 S2111 S2059 S2112 S2113 S2114 S2115
HEXANE S2116 S2117 S2118 S2119 S962 S1792 S566 S567 S2120 S2121 S925 S2122 S2123 S1487 S1809 S1603 S2124 S2125 S2126 S2127 S2128 S2129 S1801
HEXANE S2130
T (K) p (MPa) x1 (-) 301 - 342 0.101 - 0.101 0.000000 - 1.000000 & KRYPTON 298 - 298 0.101 - 0.101 0.998573 - 0.998573 & METHANE 311 - 378 4.52 - 17.4 0.439282 - 0.807856 311 - 378 4.06 - 20.1 0.217800 - 0.843200 298 - 298 0.101 - 0.101 0.994920 - 0.994920 163 - 423 0.000263 - 16.2 0.000000 - 1.000000 138 - 164 0.588 - 1.72 0.004220 - 0.339500 311 - 311 1.2 - 1.98 0.903500 - 0.943300 288 - 308 0.101 - 0.101 0.994590 - 0.995080 348 - 383 2.07 - 19.5 0.316100 - 0.963800 339 - 339 0.35 - 10.3 0.637900 - 0.997800 311 - 311 2.15 - 6 0.746000 - 0.901500 298 - 298 2.04 - 8.12 0.649600 - 0.905300 183 - 333 1.43 - 14.2 0.041000 - 0.888000 323 - 373 5.09 - 20.1 0.000000 - 0.815900 348 - 383 2.27 - 12 0.587700 - 0.909900 191 - 273 0.137 - 18.4 0.000000 - 0.000000 311 - 444 3.45 - 34.5 0.000000 - 0.940000 311 - 411 0.345 - 1.72 0.000000 - 0.000000 182 - 273 0.137 - 18.3 0.180900 - 0.990510 311 - 378 1.08 - 8.52 0.676600 - 0.950400 & METHANOL 317 - 317 0.0413 - 0.0743 0.072200 - 1.000000 318 - 318 0.0437 - 0.084 0.000000 - 1.000000 322 - 335 0.0993 - 0.0993 0.020000 - 0.967000 308 - 348 0.028 - 0.252 0.000000 - 1.000000 333 - 333 0.0761 - 0.15 0.000000 - 1.000000 322 - 337 0.101 - 0.101 0.004500 - 0.990000 298 - 298 0.0169 - 0.0355 0.000000 - 1.000000 298 - 298 0.0327 - 0.0354 0.050000 - 0.950000 313 - 313 0.0353 - 0.0687 0.000000 - 1.000000 398 - 448 0.446 - 3.08 0.000000 - 1.000000 403 - 512 0.505 - 8.06 0.000000 - 1.000000 313 - 313 0.0355 - 0.0686 0.000000 - 1.000000 332 - 347 0.141 - 0.141 0.010000 - 0.994000 293 - 293 0.013 - 0.028 0.000000 - 1.000000 321 - 340 0.095 - 0.095 0.000000 - 1.000000 323 - 342 0.101 - 0.101 0.000000 - 1.000000 313 - 313 0.0689 - 0.069 0.290600 - 0.688600 308 - 348 0.028 - 0.252 0.000000 - 1.000000 313 - 313 0.0355 - 0.0763 0.000000 - 1.000000 313 - 313 0.0544 - 0.0668 0.014000 - 0.742300 303 - 303 0.0219 - 0.0448 0.000000 - 1.000000 293 - 293 0.0218 - 0.0269 0.013700 - 0.728100 322 - 337 0.101 - 0.101 0.004500 - 0.990000 & MM 303 - 315 0.00714 - 0.0402 0.000000 - 1.000000 Continued on next page...
S168
N 34 1 9 30 1 127 14 8 5 53 11 3 6 55 54 19 114 200 16 127 33 9 14 7 168 30 20 20 7 14 22 108 21 19 45 6 10 2 175 109 51 67 41 26 24
Table S4 – continued from previous page Reference T (K) p (MPa) x1 (-) HEXANE & MXYLENE S2131 342 - 412 0.101 - 0.101 0.000000 - 1.000000 HEXANE & NEON S352 298 - 298 0.101 - 0.101 0.999628 - 0.999628 HEXANE & NITROGEN S2132 233 - 293 0.203 - 0.709 0.072000 - 0.825000 S352 298 - 298 0.101 - 0.101 0.992725 - 0.992725 S2133 345 - 488 0.96 - 51.5 0.329600 - 0.988900 S2134 311 - 444 1.72 - 34.5 0.399000 - 0.979000 HEXANE & OCTANE S2048 287 - 397 0.0123 - 0.101 0.000000 - 1.000000 S602 328 - 328 0.00843 - 0.0644 0.000000 - 1.000000 S2135 298 - 298 0.00414 - 0.0182 0.125500 - 0.896000 S2053 287 - 397 0.0123 - 0.101 0.000000 - 1.000000 S2136 298 - 298 0.00222 - 0.0182 0.000000 - 0.000000 HEXANE & OXYGEN S250 298 - 298 0.101 - 0.101 0.998024 - 0.998024 S352 298 - 298 0.101 - 0.101 0.994965 - 0.994965 S254 298 - 298 0.101 - 0.101 0.997750 - 0.997750 HEXANE & OXYLENE S2131 342 - 417 0.101 - 0.101 0.000000 - 1.000000 HEXANE & PENTANE S2099 298 - 298 0.0202 - 0.0684 0.000000 - 1.000000 S2137 299 - 309 0.0207 - 0.101 0.000000 - 1.000000 HEXANE & PROPANE S901 298 - 298 0.101 - 0.101 0.885000 - 0.885000 S2138 348 - 495 0.45 - 4.98 0.078200 - 0.856500 S2078 325 - 491 1.03 - 4.99 0.000000 - 0.780200 S2139 348 - 497 0.147 - 4.98 0.000000 - 0.856500 HEXANE & PROPYLEN S258 293 - 333 0.233 - 0.741 0.299000 - 0.930000 HEXANE & PXYLENE S597 343 - 409 0.101 - 0.101 0.011000 - 0.953000 S525 313 - 313 0.00265 - 0.0372 0.000000 - 1.000000 HEXANE & R113 S2140 303 - 313 0.0249 - 0.0778 0.000000 - 1.000000 S263 308 - 308 0.0307 - 0.0654 0.000000 - 1.000000 HEXANE & R114 S708 363 - 423 0.54 - 2.69 0.257300 - 0.697400 HEXANE & R14 S352 298 - 298 0.101 - 0.101 0.995702 - 0.995702 HEXANE & R22 S1330 363 - 400 1.61 - 5.41 0.002000 - 0.751000 S1513 363 - 400 1.61 - 5.41 0.002400 - 0.750700 HEXANE & R245FA S1525 287 - 289 0.0999 - 0.0999 0.000000 - 0.785604 HEXANE & SF6 S352 298 - 298 0.101 - 0.101 0.999072 - 0.999072 HEXANE & TOLUENE Continued on next page...
S169
N 13 1 17 1 72 52 66 13 10 66 44 1 1 1 14 10 38 1 76 120 171 9 13 16 34 22 12 1 28 28 13 1
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 342 - 384 0.101 - 0.101 0.000000 - 1.000000 S587 298 - 384 0.02 - 0.101 0.000000 - 1.000000 S2141 343 - 379 0.101 - 0.101 0.047000 - 0.938000 S2142 343 - 343 0.0272 - 0.106 0.000000 - 1.000000 S597 344 - 377 0.101 - 0.101 0.069000 - 0.884000 S1582 342 - 384 0.101 - 0.101 0.000000 - 1.000000 S525 313 - 313 0.00789 - 0.0372 0.000000 - 1.000000 HEXANE & WATER S2143 335 - 335 0.101 - 0.101 0.786000 - 0.786000 S2144 342 - 342 0.101 - 0.101 0.999957 - 0.999957 S890 555 - 699 19.8 - 247 0.200000 - 0.610000 S2145 373 - 464 0.343 - 2.96 0.906900 - 0.986600 S2146 493 - 645 4.63 - 22.2 0.004250 - 0.548930 HEXANE & XENON S2147 258 - 333 0.0244 - 0.187 0.973449 - 0.991056 HYDROGEN & IOCTANE S921 311 - 423 1.21 - 34.9 0.009000 - 0.355000 S956 424 - 499 0.352 - 110 0.000000 - 0.816000 S2148 499 - 523 3.15 - 36.8 0.039000 - 0.580000 HYDROGEN & ISOBUTAN S921 311 - 394 3.45 - 20.7 0.022500 - 0.247000 HYDROGEN & METHANE S1694 144 - 200 3.45 - 6.89 0.034300 - 0.083200 S1696 103 - 174 1.02 - 10.8 0.003100 - 0.225000 S1017 120 - 144 2.89 - 10 0.028800 - 0.098500 S2149 100 - 120 0.237 - 2.27 0.001800 - 0.022400 S2150 90 - 127 3.14 - 22.9 0.000000 - 0.162000 S2151 116 - 172 3.38 - 27.6 0.017000 - 0.349900 S2152 91 - 91 1.71 - 20.8 0.000000 - 0.102000 S2153 108 - 183 0.0752 - 28.4 0.000000 - 0.489200 S1734 158 - 188 3.04 - 8.11 0.019000 - 0.146000 S2154 92 - 180 0.22 - 138 0.000000 - 0.610300 S1019 103 - 163 1.01 - 15.2 0.000000 - 0.286000 S2155 90 - 117 1.03 - 12.7 0.000000 - 0.000000 S1020 108 - 173 2.76 - 10.3 0.016000 - 0.194100 HYDROGEN & METHANOL S2156 298 - 298 4.88 - 59 0.007480 - 0.074700 S1268 243 - 273 1.01 - 5.17 0.003000 - 0.015000 S1026 223 - 273 5-5 0.004900 - 0.007000 S1273 298 - 373 3.44 - 110 0.007200 - 0.174200 S1811 291 - 291 1.1 - 4.85 0.001800 - 0.006100 S2157 296 - 413 0.506 - 1.66 0.000790 - 0.006340 S1813 314 - 477 4.49 - 11 0.010200 - 0.052500 S1211 278 - 308 2 - 11 0.003400 - 0.021100 S2158 248 - 308 0.433 - 3.43 0.000570 - 0.006190 S638 298 - 298 0.101 - 0.101 0.000136 - 0.000136 HYDROGEN & MPALMITA S2159 361 - 450 3.51 - 14.3 0.049500 - 0.128400 HYDROGEN & MXYLENE Continued on next page... S445
S170
N 27 99 22 11 33 18 10 1 1 30 5 60 21 23 37 18 22 2 28 6 23 35 13 21 144 9 196 25 38 28 16 12 3 28 17 31 24 23 24 1 60
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 462 - 582 0.32 - 25.4 0.000000 - 0.324100 S1491 513 - 593 1.21 - 11.1 0.004050 - 0.111170 S1029 353 - 433 0.851 - 4.9 0.005300 - 0.022740 S1030 353 - 433 0.851 - 4.9 0.005300 - 0.023960 HYDROGEN & NEON S2161 20 - 27 0.0141 - 0.111 0.000000 - 0.008700 S2162 25 - 34 0.0448 - 1.39 0.000000 - 1.000000 S2163 26 - 42 0.0719 - 2.51 0.000000 - 1.000000 HYDROGEN & NITROGEN S2164 90 - 113 1.61 - 9.58 0.036000 - 0.389000 S2165 100 - 100 2.17 - 9.65 0.037700 - 0.303000 S312 78 - 78 2.72 - 17.9 0.063000 - 0.451000 S1017 80 - 80 5 - 10 0.111600 - 0.230200 S382 100 - 100 1.39 - 4.56 0.019300 - 0.111900 S1018 57 - 88 0.0122 - 22.8 0.000000 - 0.549000 S1536 90 - 95 0.359 - 4.6 0.000000 - 0.112100 S2166 79 - 109 0.118 - 17.8 0.000000 - 0.457000 S2167 63 - 75 0.101 - 7.09 0.000000 - 0.117000 S2168 63 - 110 1.03 - 57.2 0.000000 - 0.536000 S1019 77 - 77 0.507 - 15.2 0.000000 - 0.362000 S1218 77 - 88 1.67 - 19 0.049000 - 0.465000 HYDROGEN & OCTANE S204 298 - 373 2.4 - 15.3 0.018610 - 0.137010 S2169 463 - 543 1.01 - 15 0.005380 - 0.250010 S2170 295 - 295 0.69 - 1.38 0.004420 - 0.008010 S453 463 - 553 0.455 - 13.8 0.000000 - 0.298250 HYDROGEN & PENTANE S1250 273 - 373 0.347 - 27.6 0.000000 - 0.259000 HYDROGEN & PROPANE S1036 248 - 298 1.52 - 30.4 0.008000 - 0.232000 S2171 144 - 255 3.45 - 6.89 0.008600 - 0.047500 S2172 98 - 348 1.03 - 20.7 0.000000 - 0.352600 S2173 278 - 361 2.53 - 52.8 0.000000 - 0.573900 S2174 172 - 297 1.72 - 55.2 0.006310 - 0.471490 HYDROGEN & PROPYLEN S2175 173 - 248 2.03 - 8.11 0.004360 - 0.040900 S2174 200 - 297 1.72 - 55.2 0.006270 - 0.462510 HYDROGEN & R13 S2176 95 - 165 2.03 - 12.2 0.900200 - 0.995324 HYDROGEN & R14 S2176 135 - 220 2.03 - 12.2 0.894150 - 0.992618 HYDROGEN & TOLUENE S2177 462 - 575 2.02 - 25.4 0.008200 - 0.393500 S2148 542 - 568 3.46 - 32.3 0.019000 - 0.514000 S204 298 - 373 0.874 - 10.1 0.002709 - 0.047100 S637 303 - 303 1.22 - 4.41 0.004006 - 0.014586 S2178 305 - 343 1.48 - 7.13 0.005000 - 0.025000 S638 298 - 298 0.101 - 0.101 0.000301 - 0.000301 S2179 501 - 575 4.99 - 9.98 0.037000 - 0.129000 Continued on next page... S2160
S171
N 31 42 25 25 84 117 92 23 5 6 2 15 89 17 40 34 77 12 17 12 50 5 80 37 27 6 83 96 36 16 30 37 45 25 13 25 9 15 1 14
Table S4 – continued from previous page Reference T (K) p (MPa) x1 (-) HYDROGEN & WATER S1557 366 - 589 1.38 - 11 0.000200 - 0.002710 S1039 311 - 589 0.345 - 13.8 0.000037 - 0.002980 S727 473 - 573 10 - 30 0.001600 - 0.016000 S2180 323 - 423 3.18 - 15.4 0.000402 - 0.002232 S205 298 - 298 0.101 - 0.101 0.000014 - 0.000014 S2181 298 - 333 0.101 - 0.101 0.000013 - 0.000014 S1562 366 - 589 1.38 - 11 0.997300 - 0.999800 S2182 311 - 589 0.345 - 13.8 0.000370 - 0.029800 IBUTENE & ISOBUTAN S809 278 - 344 0.165 - 1.1 0.250000 - 0.750000 IBUTENE & METHANOL S836 323 - 323 0.0553 - 0.631 0.000000 - 1.000000 S640 298 - 298 0.0273 - 0.102 0.004000 - 0.040000 S1814 323 - 323 0.0556 - 0.626 0.000000 - 0.985300 S2183 364 - 365 0.267 - 1.63 0.000000 - 1.000000 IBUTENE & OCTANE S2184 298 - 343 0.152 - 0.853 0.220800 - 0.937500 IBUTENE & PROPANE S2185 321 - 414 1.3 - 4.14 0.147000 - 0.914000 IBUTENE & R143A S2186 273 - 348 0.133 - 3.62 0.000000 - 1.000000 IBUTENE & R152A S2187 273 - 348 0.133 - 2.12 0.000000 - 1.000000 IBUTENE & R227EA S2188 288 - 363 0.223 - 2.4 0.000000 - 1.000000 IBUTENE & R40 S2189 320 - 345 1.03 - 1.03 0.000000 - 1.000000 IBUTENE & SO2 S2190 253 - 283 0.0595 - 0.275 0.000000 - 1.000000 IBUTENE & WATER S94 298 - 298 0.101 - 0.101 0.000084 - 0.000084 IHEXANE & METHANOL S2118 318 - 327 0.0993 - 0.0993 0.119000 - 0.960000 IHEXANE & OCTANE S2191 283 - 313 0.00161 - 0.0458 0.052200 - 0.894700 S1658 328 - 328 0.00841 - 0.0854 0.000000 - 1.000000 IHEXANE & PROPANE S2138 348 - 485 0.485 - 4.8 0.081000 - 0.850300 IHEXANE & R245FA S1525 287 - 289 0.0992 - 0.0992 0.000000 - 0.798405 IOCTANE & KRYPTON S384 298 - 298 0.101 - 0.101 0.992017 - 0.992017 IOCTANE & METHANE S384 298 - 298 0.101 - 0.101 0.994007 - 0.994007 IOCTANE & METHANOL S1660 332 - 372 0.101 - 0.101 0.000000 - 1.000000 IOCTANE & MXYLENE S1819 371 - 409 0.0958 - 0.0958 0.000000 - 1.000000 Continued on next page...
S172
N 9 18 4 10 1 3 9 18 15 11 5 23 27 13 51 65 79 72 20 67 1 5 48 25 62 13 1 1 10 8
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 408 - 450 0.25 - 0.25 0.000000 - 1.000000 IOCTANE & NEON S384 298 - 298 0.101 - 0.101 0.999541 - 0.999541 IOCTANE & NITROGEN S964 376 - 453 1.96 - 61.8 0.252000 - 0.973300 S384 298 - 298 0.101 - 0.101 0.998435 - 0.998435 S1219 270 - 282 2.7 - 9.45 0.045800 - 0.171400 IOCTANE & OCTANE S948 372 - 399 0.101 - 0.101 0.000000 - 1.000000 S468 371 - 371 0.0443 - 0.098 0.000000 - 1.000000 S2071 293 - 328 0.00139 - 0.0235 0.000000 - 1.000000 IOCTANE & OXYGEN S1698 283 - 303 0.101 - 0.101 0.997088 - 0.997217 S384 298 - 298 0.101 - 0.101 0.997125 - 0.997125 IOCTANE & OXYLENE S645 313 - 313 0.00206 - 0.013 0.000000 - 1.000000 S1659 408 - 456 0.25 - 0.25 0.000000 - 1.000000 IOCTANE & PROPYLEN S1572 289 - 330 0.101 - 0.101 0.796900 - 0.939900 IOCTANE & PXYLENE S645 313 - 313 0.00265 - 0.013 0.000000 - 1.000000 S1819 371 - 409 0.0958 - 0.0958 0.000000 - 1.000000 S1659 408 - 450 0.25 - 0.25 0.000000 - 1.000000 IOCTANE & R14 S384 298 - 298 0.101 - 0.101 0.997375 - 0.997375 IOCTANE & SF6 S1698 283 - 303 0.101 - 0.101 0.981480 - 0.985720 S540 303 - 303 0.101 - 0.101 0.013800 - 0.013800 S384 298 - 298 0.101 - 0.101 0.015170 - 0.015170 IOCTANE & SO2 S1866 293 - 293 0.0702 - 0.33 0.000000 - 0.955500 IOCTANE & TOLUENE S2192 373 - 383 0.101 - 0.101 0.020200 - 0.966100 S2193 399 - 442 0.192 - 0.407 0.000000 - 1.000000 S445 373 - 384 0.101 - 0.101 0.000000 - 0.796000 S2194 373 - 383 0.104 - 0.104 0.040000 - 0.943000 S2195 372 - 384 0.0742 - 0.104 0.000000 - 1.000000 S1789 373 - 373 0.0742 - 0.104 0.000000 - 1.000000 S645 313 - 313 0.00789 - 0.013 0.000000 - 1.000000 S2196 313 - 402 0.00793 - 0.221 0.000000 - 1.000000 IPENTANE & ISOBUTAN S2197 289 - 437 0.163 - 3.68 0.200100 - 0.509700 S2198 289 - 405 0.163 - 3.17 0.050500 - 0.509700 IPENTANE & METHANE S2199 344 - 411 3.44 - 15.1 0.367000 - 0.908000 S2200 311 - 452 1.38 - 10.3 0.000000 - 0.996000 IPENTANE & METHANOL S1563 297 - 305 0.101 - 0.101 0.089000 - 0.979000 S2201 298 - 338 0.101 - 0.101 0.000000 - 1.000000 Continued on next page... S1659
S173
N 18 1 23 1 15 15 5 30 4 1 20 21 7 18 8 14 1 5 1 1 10 15 12 22 11 22 11 19 351 20 31 21 90 12 19
Table S4 – continued from previous page Reference T (K) p (MPa) x1 (-) IPENTANE & NITROGEN S2202 278 - 377 0.183 - 20.8 0.563000 - 0.999000 IPENTANE & PENTANE IPENTANE & PROPANE S2203 273 - 453 0.0334 - 4.58 0.000000 - 1.000000 IPENTANE & R23 S2204 310 - 343 0.549 - 6.91 0.100000 - 0.986000 IPENTANE & R245FA S1525 280 - 288 0.0997 - 0.0997 0.000000 - 0.799380 S2205 363 - 413 0.773 - 3.06 0.025400 - 0.974700 IPENTANE & R365MFC S2205 363 - 413 0.522 - 1.9 0.019100 - 0.961300 IPENTANE & TOLUENE S2206 301 - 384 0.101 - 0.101 0.000100 - 0.990500 ISOBUTAN & METHANE S2207 151 - 251 1.06 - 8.38 0.077700 - 0.450600 S822 203 - 273 2.64 - 8.68 0.286700 - 0.770000 S2208 311 - 378 0.552 - 11.5 0.000000 - 0.997220 S2209 198 - 378 0.49 - 11.8 0.019000 - 0.998000 ISOBUTAN & METHANOL S835 298 - 323 0.0485 - 0.102 0.006002 - 0.021030 S2210 273 - 423 0.0039 - 4.68 0.000000 - 1.000000 S647 298 - 298 0.0406 - 0.102 0.005000 - 0.021000 S1824 313 - 313 0.0353 - 0.548 0.000000 - 1.000000 S2211 364 - 365 0.268 - 1.82 0.000000 - 1.000000 ISOBUTAN & NITROGEN S842 273 - 293 0.405 - 1.11 0.969700 - 0.994500 S2212 283 - 394 0.565 - 20.7 0.537600 - 0.993800 S2213 255 - 394 0.232 - 20.8 0.542000 - 0.995000 S2214 120 - 220 0.533 - 15 0.733400 - 0.989600 S847 224 - 350 0.101 - 5.51 0.000000 - 0.000000 ISOBUTAN & PROPANE S1753 237 - 249 0.0351 - 0.214 0.000000 - 1.000000 S2215 340 - 340 1.08 - 2.38 0.015000 - 0.950000 S2216 273 - 323 0.209 - 1.49 0.199000 - 0.827100 S2217 283 - 313 0.308 - 1.14 0.197100 - 0.828600 S2218 250 - 395 0.0643 - 3.66 0.000000 - 1.000000 S2219 273 - 303 0.157 - 1.08 0.000000 - 1.000000 S864 260 - 320 0.129 - 1.32 0.000000 - 0.816600 S812 289 - 328 0.327 - 1.67 0.153600 - 0.858500 S2220 267 - 394 0.123 - 4.17 0.000000 - 1.000000 S869 253 - 273 0.0726 - 0.472 0.000000 - 1.000000 ISOBUTAN & PROPYLEN S1982 315 - 396 1.36 - 4.14 0.101000 - 0.935000 ISOBUTAN & R1234YF S2221 283 - 323 0.222 - 1.31 0.000000 - 1.000000 ISOBUTAN & R1234ZE S2222 258 - 288 0.0889 - 0.415 0.000000 - 1.000000 ISOBUTAN & R125 Continued on next page...
S174
N 47
139 26 13 59 47 18 10 17 75 96 5 99 4 24 26 12 26 52 51 141 37 14 23 18 55 44 40 19 86 48 33 59 40
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 293 - 313 0.304 - 2 0.000000 - 1.000000 S2224 243 - 333 0.0462 - 3.17 0.000000 - 1.000000 S872 243 - 333 0.157 - 3.15 0.058080 - 0.861210 ISOBUTAN & R13 S873 311 - 400 0.547 - 4.5 0.106400 - 0.990400 ISOBUTAN & R134A S2225 294 - 304 0.307 - 0.884 0.000000 - 1.000000 S2226 303 - 323 0.407 - 1.43 0.000000 - 1.000000 S2227 303 - 323 0.408 - 1.43 0.000000 - 1.000000 S872 243 - 333 0.0994 - 1.84 0.042390 - 0.838430 ISOBUTAN & R143A S2228 323 - 333 0.683 - 2.87 0.000000 - 1.000000 ISOBUTAN & R152A S2226 303 - 333 0.407 - 1.61 0.000000 - 1.000000 S2227 303 - 333 0.408 - 1.61 0.000000 - 1.000000 ISOBUTAN & R227EA S2229 303 - 323 0.407 - 1.08 0.000000 - 1.000000 ISOBUTAN & R23 S2228 283 - 293 0.224 - 4.2 0.000000 - 1.000000 ISOBUTAN & R236FA S2225 304 - 304 0.326 - 0.535 0.000000 - 1.000000 ISOBUTAN & R245FA S2230 293 - 344 0.123 - 1.24 0.000000 - 1.000000 S2231 293 - 313 0.123 - 0.595 0.000000 - 1.000000 ISOBUTAN & R32 S2232 260 - 322 0.132 - 2.63 0.353900 - 0.983000 S2227 302 - 322 0.392 - 3.08 0.000000 - 1.000000 ISOBUTAN & WATER S94 298 - 298 0.101 - 0.101 0.000015 - 0.000015 S2233 275 - 293 0.155 - 0.208 0.000524 - 0.001370 KRYPTON & METHANE S2234 110 - 118 0.0676 - 0.118 0.329000 - 0.820600 S2235 104 - 145 0.0237 - 0.818 0.000000 - 1.000000 S2236 161 - 205 1.06 - 5.24 0.000000 - 1.000000 S392 125 - 189 0.152 - 4.35 0.000000 - 1.000000 KRYPTON & METHANOL S1825 176 - 213 0.0267 - 0.0267 0.000718 - 0.001768 S372 283 - 313 0.101 - 0.101 0.000739 - 0.001109 KRYPTON & NEON S2237 120 - 150 1.03 - 10.2 0.943600 - 0.996900 S2238 100 - 150 0.35 - 10.8 0.000000 - 0.996900 S2239 123 - 178 0.132 - 187 0.000000 - 1.000000 KRYPTON & NONANE S352 298 - 298 0.101 - 0.101 0.007130 - 0.007130 KRYPTON & OCTANE S352 298 - 298 0.101 - 0.101 0.007040 - 0.007040 KRYPTON & OXYGEN S2240 94 - 151 0.135 - 0.689 0.000000 - 1.000000 S2241 77 - 100 0.0196 - 0.249 0.000000 - 0.505000 Continued on next page... S2223
S175
N 40 100 16 35 28 32 32 20 20 40 40 43 29 15 54 40 35 40 1 11 32 28 97 52 5 3 25 73 112 1 1 87 92
Table S4 – continued from previous page Reference T (K) p (MPa) x1 (-) KRYPTON & PROPYLEN S2242 94 - 163 0.00062 - 0.122 0.010000 - 0.947000 S434 130 - 200 0.11 - 2.94 0.000000 - 0.958000 KRYPTON & WATER S365 278 - 313 0.101 - 0.101 0.000036 - 0.000075 S372 283 - 313 0.101 - 0.101 0.000034 - 0.000065 S2243 610 - 661 31 - 273 0.191000 - 0.623000 KRYPTON & XENON S2244 161 - 161 0.0817 - 1.1 0.000000 - 1.000000 S2245 161 - 161 0.312 - 0.909 0.210600 - 0.825100 S2246 166 - 269 0.106 - 6.61 0.000000 - 1.000000 METHANE & METHANOL S370 298 - 298 0.101 - 0.101 0.000867 - 0.000867 S208 298 - 298 0.101 - 0.101 0.000871 - 0.000871 S1026 223 - 273 5-5 0.046000 - 0.074100 S2247 298 - 338 2.5 - 12.5 0.022110 - 0.094370 S2248 213 - 273 1.08 - 6.97 0.015000 - 0.103000 S1273 298 - 373 5.45 - 107 0.037430 - 0.657200 S2249 200 - 330 0.689 - 41.4 0.009462 - 0.257500 S1826 280 - 280 2.11 - 11.4 0.017000 - 0.088000 S1740 283 - 303 5.05 - 40 0.042310 - 0.289400 S2107 5.45 - 12 298 - 298 0.044180 - 0.091210 S1827 294 - 295 1.05 - 7.99 0.011000 - 0.075000 S2250 299 - 299 5.24 - 18 0.041260 - 0.134830 S2251 298 - 298 3.72 - 15.5 0.029310 - 0.122140 S1028 298 - 373 3 - 111 0.000000 - 0.720000 METHANE & MXYLENE S2252 461 - 582 2.02 - 20.2 0.021900 - 0.455300 S654 313 - 313 10 - 46.5 0.246000 - 0.783000 S1295 311 - 478 0.407 - 14.5 0.011800 - 0.295400 METHANE & N2O S2253 213 - 253 0.415 - 5.27 0.000000 - 0.577000 METHANE & NEOPENTN S2199 344 - 411 2.12 - 12.1 0.051000 - 0.603000 S409 298 - 298 1.21 - 15.1 0.069600 - 0.828700 METHANE & NITROGEN S2254 91 - 190 0.141 - 5.06 0.048500 - 0.986000 S2255 82 - 158 0.145 - 1.57 0.000000 - 1.000000 S2256 137 - 175 3.45 - 3.45 0.292000 - 0.946000 S1694 144 - 200 3.45 - 3.45 0.491000 - 0.510000 S393 92 - 124 0.0212 - 0.565 0.853000 - 0.991000 S394 91 - 91 0.0117 - 0.383 0.000000 - 1.000000 S2234 84 - 91 0.0864 - 0.242 0.334500 - 0.863200 S2257 113 - 113 0.115 - 1.76 0.000000 - 1.000000 S2258 111 - 111 0.0965 - 1.54 0.000000 - 1.000000 S2259 118 - 138 1.88 - 3.71 0.051000 - 0.311000 S2017 112 - 183 0.197 - 4.89 0.003400 - 0.996200 S1707 130 - 180 0.584 - 5.06 0.406200 - 0.977600 S2260 100 - 123 0.0399 - 2.91 0.000000 - 1.000000 Continued on next page...
S176
N 49 82 7 3 39 13 4 139 1 1 3 15 16 30 83 9 24 2 8 9 5 80 22 11 21 52 18 16 107 122 9 2 20 11 20 8 16 4 176 27 84
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 80 - 144 0.689 - 8.27 0.318360 - 0.637790 S2262 230 - 250 6.21 - 10.3 0.000000 - 0.510300 S415 112 - 112 0.154 - 1.32 0.000000 - 0.966200 S2263 220 - 240 2 - 12 0.000000 - 0.431700 S1253 293 - 293 6.04 - 8.26 0.003000 - 0.101000 S2264 77 - 130 1.38 - 13.8 0.136000 - 0.659000 S2265 95 - 120 0.0199 - 2.51 0.000000 - 1.000000 S1256 270 - 270 4.56 - 11.1 0.000000 - 0.328000 S2266 90 - 133 0.0122 - 2.51 0.000000 - 1.000000 S2267 100 - 172 0.138 - 4.48 0.000000 - 0.994000 S2268 233 - 273 6.08 - 10.1 0.004000 - 0.398000 S2269 78 - 186 0.101 - 4.83 0.000000 - 0.938900 S2270 91 - 91 0.0793 - 0.364 0.020000 - 0.811000 S2271 91 - 91 0.0117 - 0.381 0.000000 - 1.000000 S2272 91 - 190 0.0638 - 5.06 0.000000 - 0.986000 S2273 78 - 109 0.101 - 0.101 0.130000 - 1.000000 S1726 122 - 171 0.35 - 4.98 0.000000 - 1.000000 S1732 111 - 111 0.0941 - 1.57 0.000000 - 1.000000 S2274 123 - 123 0.422 - 2.58 0.087900 - 0.948900 S1263 220 - 240 6.08 - 12.2 0.000000 - 0.583000 S869 113 - 113 0.117 - 1.79 0.000000 - 1.000000 S1025 120 - 160 0.655 - 4.93 0.173600 - 0.998030 S2275 77 - 164 0.689 - 8.27 0.031600 - 0.876100 S2276 130 - 180 4 - 10.1 0.366900 - 0.937700 METHANE & NONANE S2277 208 - 423 0.507 - 32.3 0.032900 - 0.885000 S2278 323 - 423 2.15 - 27.7 0.093100 - 0.717600 S352 298 - 298 0.101 - 0.101 0.005208 - 0.005208 METHANE & OCTANE S2279 273 - 333 7.09 - 28.9 0.275000 - 0.820000 S1500 156 - 191 1.36 - 4.65 0.999163 - 0.999786 S2280 223 - 423 0.00203 - 27.3 0.000000 - 0.798000 S2281 273 - 333 6.86 - 28.4 0.000000 - 0.820000 METHANE & OXYGEN S2282 93 - 107 0.137 - 0.444 0.001040 - 0.001120 METHANE & PENTANE S648 311 - 378 5.89 - 16 0.257236 - 0.625254 S2283 311 - 378 0.108 - 12.8 0.000000 - 0.504000 S2279 273 - 273 6.08 - 15.2 0.315000 - 0.775000 S2199 378 - 378 6.9 - 13.8 0.247000 - 0.532000 S2284 176 - 273 1.3e-05 - 15.2 0.000000 - 1.000000 S2285 311 - 411 0.693 - 16.1 0.015200 - 0.712400 S2109 203 - 243 5.18 - 7.94 0.506000 - 0.668000 S2286 311 - 444 0.124 - 16.9 0.000000 - 0.940440 S2287 178 - 283 1.52e-05 - 15.2 0.000000 - 1.000000 S2288 311 - 378 0.108 - 17.2 0.000000 - 0.735000 S2289 298 - 358 3.49 - 19 0.000000 - 0.750000 S828 121 - 180 0.418 - 3.95 0.888000 - 0.894000 S2290 173 - 273 0.139 - 15.2 0.000000 - 0.000000 Continued on next page... S2261
S177
N 40 37 50 56 53 106 60 56 54 143 53 196 15 10 240 24 28 16 19 56 16 55 75 126 138 34 1 35 19 63 40 3 9 7 4 10 55 56 7 96 71 59 33 18 118
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 339 - 450 0 - 8.88 0.062000 - 0.932000 METHANE & PROPANE S2292 278 - 361 0.545 - 10.2 0.000000 - 0.745900 S2293 158 - 273 0.345 - 10 0.012000 - 1.000000 S2171 200 - 255 3.45 - 6.89 0.530000 - 0.620000 S393 92 - 128 0.0011 - 0.164 0.026400 - 0.473000 S2294 90 - 110 0.0011 - 0.0882 0.046200 - 1.000000 S2295 91 - 91 0.00531 - 0.0101 0.267400 - 0.780400 S2296 130 - 214 1.79e-05 - 6.51 0.000000 - 1.000000 S2297 116 - 135 0.0244 - 0.487 0.099560 - 1.000000 S2298 214 - 214 0.752 - 4.73 0.094900 - 0.642000 S2258 111 - 111 0.0225 - 0.0971 0.139100 - 1.000000 S822 203 - 283 0.891 - 8.32 0.071000 - 0.738100 S1710 144 - 283 0.689 - 9.43 0.002800 - 0.958900 S2299 163 - 350 1.72 - 8.96 0.000000 - 0.949300 S1252 230 - 270 0.0973 - 9.29 0.000000 - 0.839800 S1718 200 - 200 2 - 12 0.000000 - 0.723100 S2300 311 - 378 1.38 - 11.7 0.004200 - 0.591000 S2301 278 - 511 2.76 - 27.6 0.010030 - 0.779700 S1721 200 - 244 0.689 - 6.89 0.047000 - 0.842000 S2302 311 - 311 5 - 12.1 0.210000 - 0.613000 S2303 233 - 294 0.134 - 7.05 0.009100 - 0.560000 S2304 293 - 363 1.01 - 9.63 0.000000 - 0.583000 S2305 114 - 122 0.0241 - 2.26 0.013600 - 1.000000 S828 0 - 202 0 - 5.37 0.000000 - 0.926000 S2306 344 - 378 3.45 - 13.8 0.010000 - 0.540000 S2307 311 - 311 3.45 - 13.8 0.607000 - 0.922000 S2308 278 - 511 3.66 - 25.6 0.179900 - 0.692000 S1346 305 - 356 5.67 - 9.12 0.170000 - 0.570000 S1748 92 - 128 0.00107 - 0.164 0.026400 - 0.473000 S869 123 - 153 4.9e-06 - 1.19 0.000000 - 1.000000 S2309 293 - 373 1.05 - 17.6 0.880000 - 0.880000 METHANE & PROPYLEN S2310 88 - 172 0.00387 - 0.124 0.026000 - 0.962000 S2175 173 - 248 2.03 - 8.11 0.149000 - 0.851000 METHANE & R12 S2311 263 - 298 1.36 - 10.2 0.512000 - 0.914000 METHANE & R14 S2312 98 - 98 0.000557 - 0.0282 0.000000 - 1.000000 METHANE & R22 S435 273 - 348 1.64 - 10.5 0.042900 - 0.615000 S1314 263 - 298 1.12 - 11.1 0.401000 - 0.881000 METHANE & SO2 S2313 241 - 301 1.72 - 3.55 0.015200 - 0.034800 METHANE & TOLUENE S650 339 - 339 0.689 - 36.5 0.017000 - 0.729000 S2314 189 - 278 0.345 - 48.7 0.009669 - 0.825900 S652 422 - 543 2.02 - 25.3 0.017900 - 0.633200 S1190 185 - 300 0.12 - 10 0.003600 - 0.261300 Continued on next page... S2291
S178
N 391 128 81 2 10 50 7 106 18 4 15 23 42 47 149 54 48 105 104 29 220 55 99 90 30 19 13 5 10 40 15 71 10 35 15 26 31 5 16 61 26 42
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 313 - 313 10.1 - 42.5 0.237000 - 0.744000 S2315 313 - 423 1.17 - 8.92 0.026000 - 0.181000 S658 188 - 313 1.91 - 13.2 0.053000 - 0.279000 METHANE & WATER S365 278 - 318 0.101 - 0.101 0.000019 - 0.000040 S1410 323 - 589 1.38 - 16.9 0.000173 - 0.006760 S2247 298 - 338 2.5 - 12.5 0.000405 - 0.002210 S2316 298 - 323 3-8 0.000510 - 0.001623 S2317 627 - 635 132 - 298 0.112000 - 0.455000 S2318 283 - 298 1.13 - 5.18 0.000276 - 0.001533 S2319 324 - 375 5.6 - 58 0.000887 - 0.004110 S2320 274 - 286 0.567 - 9.08 0.000258 - 0.002002 S1774 273 - 288 3.45 - 3.45 0.001200 - 0.015200 S892 344 - 344 20 - 100 0.218300 - 0.508500 S1423 298 - 298 7.36 - 17.8 0.000027 - 0.000049 S2321 313 - 373 0.00728 - 9.26 0.000000 - 0.001540 S1740 283 - 303 2 - 40 0.000563 - 0.004049 S2322 293 - 323 0.101 - 0.101 0.000020 - 0.000031 S2323 324 - 324 10 - 40 0.001441 - 0.003412 S1776 280 - 281 10.1 - 14.3 0.001780 - 0.001780 S1430 324 - 376 10.9 - 49.9 0.001400 - 0.004100 S2324 299 - 314 0.993 - 9.98 0.000210 - 0.001600 S2325 303 - 323 0.112 - 0.638 0.000009 - 0.000260 S1434 273 - 285 2.65 - 9.1 0.001080 - 0.002110 S2326 298 - 303 5.33 - 12.2 0.000976 - 0.002026 S2250 284 - 324 4.78 - 19.5 0.000604 - 0.002610 S2327 283 - 298 1.15 - 10.4 0.000385 - 0.002051 S2328 311 - 511 1.38 - 68.9 0.000000 - 0.000000 S2329 427 - 596 7.43 - 22.5 0.323900 - 0.924000 METHANOL & MM S1846 323 - 355 0.06 - 0.101 0.100000 - 0.862000 METHANOL & MOLEATE S2330 310 - 353 0.03 - 0.101 0.358200 - 0.899700 METHANOL & MXYLENE S1660 338 - 412 0.101 - 0.101 0.000000 - 1.000000 METHANOL & NITROGEN S1266 273 - 348 4.9 - 29.5 0.931300 - 0.989100 S2156 298 - 298 25.3 - 75.6 0.877000 - 0.946600 S370 298 - 298 0.101 - 0.101 0.999745 - 0.999745 S2331 258 - 273 1.01 - 7.9 0.982500 - 0.997500 S1026 223 - 248 5-5 0.987500 - 0.987600 S1270 223 - 300 2.1 - 17.9 0.962900 - 0.994600 S2248 213 - 273 3.51 - 7.46 0.980000 - 0.990000 S1737 240 - 260 1.5 - 7.5 0.982500 - 0.996100 S1273 298 - 373 2.63 - 108 0.767800 - 0.992763 S2332 298 - 318 0.67 - 10.2 0.977900 - 0.999000 S1028 298 - 373 2 - 108 0.000000 - 0.992760 METHANOL & NONANE S898 322 - 401 0.0541 - 0.0541 0.000000 - 1.000000 Continued on next page... S654
S179
N 9 19 32 9 13 15 6 23 20 14 18 4 4 4 29 17 13 4 3 7 8 18 13 10 22 13 201 9 15 20 13 21 11 1 10 2 28 12 7 34 24 54 16
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 415 - 537 1.17 - 8.06 0.510000 - 1.000000 METHANOL & OCTANE S898 321 - 378 0.0541 - 0.0541 0.000000 - 1.000000 S1660 336 - 399 0.101 - 0.101 0.000000 - 1.000000 S2333 313 - 313 0.00415 - 0.0381 0.000000 - 1.000000 S925 419 - 541 1.19 - 8.06 0.388000 - 1.000000 METHANOL & OXYGEN S1848 298 - 348 0.0169 - 9.23 0.959720 - 1.000000 S254 298 - 298 0.101 - 0.101 0.999585 - 0.999585 METHANOL & OXYLENE S1816 313 - 313 0.00205 - 0.0354 0.000000 - 1.000000 S1852 338 - 375 0.101 - 0.101 0.024900 - 0.987800 S1847 336 - 415 0.095 - 0.095 0.000000 - 1.000000 METHANOL & PENTANE S2334 303 - 335 0.1 - 0.1 0.001000 - 0.999000 S2335 373 - 423 0.347 - 2.53 0.000000 - 1.000000 S2336 303 - 303 0.0219 - 0.0996 0.000000 - 1.000000 S2123 312 - 344 0.141 - 0.141 0.005000 - 0.998000 METHANOL & PROPANE S835 273 - 323 0.00405 - 0.101 0.979610 - 1.000000 S2337 210 - 297 1.72 - 4.83 0.230000 - 0.230000 S1272 313 - 373 0.35 - 4.28 0.000000 - 0.984700 S837 311 - 474 0.032 - 8.66 0.016000 - 1.000000 S1857 314 - 343 0.28 - 2.58 0.024700 - 0.985700 METHANOL & PROPYLEN S258 293 - 333 0.0951 - 0.74 0.834000 - 0.988000 S260 298 - 298 0.0169 - 1.16 0.000000 - 1.000000 S2338 293 - 373 0.166 - 3.72 0.700400 - 0.974800 METHANOL & PXYLENE S1660 338 - 411 0.101 - 0.101 0.000000 - 1.000000 S571 313 - 313 0.00265 - 0.0355 0.000000 - 1.000000 S2339 336 - 409 0.0957 - 0.0957 0.000000 - 1.000000 METHANOL & R113 S2340 308 - 308 0.028 - 0.085 0.000000 - 1.000000 METHANOL & R115 S1863 283 - 313 0.101 - 0.101 0.994400 - 0.997600 METHANOL & R125 S1863 283 - 313 0.101 - 0.101 0.968200 - 0.989300 S1864 303 - 323 0.0521 - 0.112 0.992100 - 0.994300 METHANOL & R134A S1863 283 - 313 0.101 - 0.101 0.937100 - 0.982400 S1864 303 - 323 0.0424 - 0.0929 0.989300 - 0.994100 METHANOL & R152A S1863 283 - 313 0.101 - 0.101 0.939700 - 0.985400 S1864 303 - 323 0.0477 - 0.0943 0.989400 - 0.992600 METHANOL & R21 S1863 283 - 313 0.101 - 0.101 0.972000 - 0.990700 METHANOL & R22 S1863 283 - 313 0.101 - 0.101 0.914400 - 0.973300 Continued on next page... S925
S180
N 97 15 11 13 98 42 1 14 11 9 22 33 24 21 8 4 32 39 31 10 12 40 13 42 11 24 4 4 10 4 10 4 11 4 4
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 303 - 323 0.0378 - 0.0867 0.988500 - 0.992000 METHANOL & R23 S2341 298 - 372 0.893 - 8.13 0.106800 - 0.906000 S1865 284 - 307 0.101 - 0.101 0.968950 - 0.977130 METHANOL & R32 S1863 283 - 313 0.101 - 0.101 0.973900 - 0.990100 S1864 303 - 323 0.0562 - 0.111 0.992800 - 0.994400 S1865 288 - 307 0.101 - 0.101 0.980680 - 0.985740 METHANOL & R40 S1646 253 - 333 0.0453 - 1.06 0.101600 - 0.876600 METHANOL & R41 S1865 288 - 306 0.101 - 0.101 0.992572 - 0.996281 METHANOL & SO2 S220 293 - 313 0.0135 - 0.0558 0.938100 - 0.995700 S268 293 - 313 0.0135 - 0.0558 0.938100 - 0.995700 S270 268 - 298 0.0997 - 0.101 0.305000 - 0.771000 METHANOL & T2BUTENE S1867 332 - 332 0.081 - 0.64 0.000000 - 1.000000 S2342 365 - 365 0.268 - 1.39 0.000000 - 1.000000 METHANOL & TOLUENE S2061 337 - 374 0.101 - 0.101 0.000000 - 1.000000 S2343 337 - 377 0.101 - 0.101 0.006000 - 0.966000 S2344 337 - 356 0.101 - 0.101 0.030000 - 0.973000 S1871 321 - 337 0.0549 - 0.101 0.870000 - 0.882000 S2345 337 - 384 0.101 - 0.101 0.000000 - 1.000000 S2346 337 - 382 0.101 - 0.101 0.002000 - 0.973200 S2347 337 - 384 0.101 - 0.101 0.000000 - 1.000000 S1660 337 - 384 0.101 - 0.101 0.000000 - 0.900000 S571 313 - 313 0.00789 - 0.0372 0.000000 - 1.000000 S2348 318 - 318 0.0233 - 0.0466 0.025000 - 0.960000 S2349 313 - 313 0.00789 - 0.0372 0.000000 - 1.000000 METHANOL & WATER S1879 313 - 333 0.00729 - 0.0812 0.000000 - 1.000000 S2350 323 - 366 0.0159 - 0.101 0.048600 - 1.000000 S2351 323 - 366 0.0159 - 0.101 0.048600 - 1.000000 S275 337 - 372 0.098 - 0.098 0.000000 - 1.000000 S2352 313 - 313 0.0126 - 0.0263 0.112513 - 0.626425 S1829 342 - 366 0.101 - 0.101 0.100000 - 0.900000 S2353 298 - 298 0.00356 - 0.0169 0.020200 - 1.000000 S2354 338 - 373 0.101 - 0.101 0.002800 - 0.986900 S2355 313 - 313 0.00733 - 0.0324 0.000000 - 0.900000 S1883 298 - 336 0.00316 - 0.0917 0.000000 - 1.000000 S279 309 - 366 0.0267 - 0.101 0.013000 - 0.891000 S2356 338 - 373 0.101 - 0.101 0.000000 - 1.000000 S214 341 - 364 0.101 - 0.101 0.069000 - 0.836000 S1886 338 - 373 0.101 - 0.101 0.000000 - 1.000000 S216 373 - 373 0.104 - 0.337 0.002200 - 0.946000 S950 338 - 370 0.101 - 0.101 0.023000 - 0.996000 S1888 338 - 367 0.101 - 0.101 0.038000 - 0.989000 Continued on next page... S1864
S181
N 15 60 7 4 6 7 43 8 16 16 2 23 28 12 13 11 5 15 79 33 11 42 11 15 24 33 33 10 5 9 10 29 10 24 44 17 7 2 15 32 16
Table S4 – continued from previous page Reference S217 S2357 S2358 S2359 S2360 S2361 S2362 S2363 S2364 S2365 S2366 S1896 S1790 S2367 S2368 S2369 S2370 S222 S194 S2371 S2372 S224 S2373 S1903 S2374 S1834 S1537 S2375 S1914 S2376 S2377 S2378 S2379 S1839 S2380 S2381 S1917 S2382 S2383 S1919 S2384 S2385 S2386 S2387 S2388 S2389 S2390 S2391 S2392
T (K) 338 - 373 443 - 508 338 - 461 338 - 419 338 - 373 413 - 413 339 - 371 339 - 368 371 - 421 338 - 373 333 - 333 338 - 373 313 - 313 338 - 366 339 - 368 340 - 369 339 - 361 338 - 373 339 - 370 318 - 318 318 - 318 340 - 362 333 - 333 340 - 367 308 - 338 298 - 298 298 - 298 298 - 308 371 - 373 298 - 373 252 - 298 252 - 298 313 - 313 338 - 370 338 - 372 353 - 403 323 - 333 239 - 314 338 - 373 333 - 373 363 - 442 320 - 420 318 - 318 373 - 523 320 - 420 523 - 583 314 - 397 323 - 323 338 - 373
p (MPa) x1 (-) 0.101 - 0.101 0.000000 - 1.000000 0.699 - 7.3 0.000000 - 1.000000 0.101 - 1.21 0.000000 - 1.000000 0.101 - 0.427 0.000000 - 1.000000 0.101 - 0.101 0.001700 - 0.988500 0.51 - 1.06 0.096000 - 0.946000 0.101 - 0.101 0.011500 - 0.938000 0.101 - 0.101 0.051000 - 0.959000 0.304 - 0.507 0.017000 - 0.918000 0.101 - 0.101 0.000000 - 1.000000 0.0245 - 0.0718 0.034300 - 0.758200 0.101 - 0.101 0.000000 - 0.987100 0.0168 - 0.0344 0.209500 - 0.951000 0.101 - 0.101 0.043000 - 1.000000 0.101 - 0.101 0.030000 - 0.900000 0.101 - 0.101 0.028000 - 0.891000 0.101 - 0.101 0.100000 - 0.900000 0.101 - 0.101 0.000000 - 1.000000 0.101 - 0.101 0.012000 - 0.920000 0.00987 - 0.0448 0.000000 - 1.000000 0.00987 - 0.0448 0.000000 - 1.000000 0.101 - 0.101 0.083000 - 0.850000 0.0199 - 0.0844 0.000000 - 1.000000 0.101 - 0.101 0.039000 - 0.860000 0.00562 - 0.103 0.000000 - 1.000000 0.00586 - 0.0151 0.120400 - 0.852200 0.0042 - 0.0162 0.044400 - 0.936100 0.00318 - 0.0102 0.000319 - 0.117280 0.101 - 0.101 0.000026 - 0.010410 0.00316 - 0.101 0.000000 - 1.000000 0.00036 - 0.0157 0.096300 - 0.895300 9.2e-05 - 0.0168 0.000000 - 1.000000 0.00848 - 0.0328 0.019800 - 0.895000 0.101 - 0.101 0.019000 - 0.951000 0.101 - 0.101 0.002253 - 0.917702 0.064 - 0.815 0.049000 - 0.944000 0.0291 - 0.0728 0.158700 - 0.780800 0.000128 - 0.0355 0.118000 - 0.977700 0.0998 - 0.101 0.000000 - 1.000000 0.02 - 0.0999 0.000045 - 0.000063 0.117 - 2.09 0.106100 - 0.906100 0.0343 - 0.993 0.499300 - 0.499300 0.0148 - 0.0428 0.075300 - 0.935400 0.191 - 8.61 0.250000 - 0.750000 0.0231 - 0.73 0.203400 - 0.800500 7.14 - 14.7 0.360000 - 0.360000 0.01 - 0.486 0.031700 - 0.493000 0.0123 - 0.0556 0.000000 - 1.000000 0.101 - 0.101 0.000000 - 1.000000 Continued on next page...
S182
N 17 62 41 24 34 6 27 20 21 21 12 17 10 19 10 15 9 12 16 9 9 13 7 14 39 10 13 352 19 76 28 37 14 20 19 36 52 136 12 5 25 8 11 21 20 20 12 14 29
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 313 - 353 0.0105 - 0.177 0.049300 - 0.958900 S1924 336 - 357 0.0773 - 0.0773 0.062000 - 0.781000 S2394 296 - 371 0.0152 - 0.0953 0.000000 - 1.000000 S1842 338 - 373 0.101 - 0.101 0.000100 - 0.977000 S2395 338 - 373 0.101 - 0.101 0.000000 - 1.000000 S2396 314 - 362 0.0375 - 0.0665 0.000000 - 1.000000 METHANOL & XENON S372 283 - 313 0.101 - 0.101 0.996845 - 0.998214 S2397 273 - 291 4.11 - 5.91 0.022000 - 0.073900 MLINOLEA & MPALMITA S2398 484 - 504 0.00396 - 0.00404 0.000000 - 1.000000 MM & TOLUENE S1843 338 - 358 0.0226 - 0.0637 0.000000 - 1.000000 S2399 373 - 382 0.101 - 0.101 0.018000 - 0.961000 MOLEATE & MSTEARAT S2400 469 - 481 0.000932 - 0.00157 0.440100 - 0.712100 MPALMITA & MSTEARAT S2401 436 - 456 0.000533 - 0.000533 0.000000 - 0.872000 S2402 497 - 498 0.00399 - 0.004 0.338000 - 0.376000 S2403 408 - 536 0.0001 - 0.01 0.000000 - 1.000000 MPALMITA & PROPANE S2159 312 - 451 1.23 - 9.78 0.034500 - 0.346300 MXYLENE & NITROGEN S978 313 - 473 2.3 - 100 0.650000 - 0.981000 S2023 465 - 585 5.08 - 15.2 0.722200 - 0.950500 MXYLENE & NONANE S722 412 - 424 0.101 - 0.101 0.000000 - 1.000000 MXYLENE & OCTANE S2131 399 - 412 0.101 - 0.101 0.000000 - 1.000000 S2404 349 - 361 0.02 - 0.02 0.000000 - 1.000000 MXYLENE & OXYLENE S2405 338 - 342 0.008 - 0.008 0.100000 - 0.900000 S2406 333 - 373 0.00666 - 0.0267 0.000000 - 1.000000 S1661 361 - 416 0.0204 - 0.0964 0.000000 - 1.000000 S1481 412 - 418 0.101 - 0.101 0.000000 - 1.000000 MXYLENE & PROPANE S944 313 - 473 0.252 - 7.21 0.051000 - 0.966000 MXYLENE & PROPYLEN S700 293 - 353 0.203 - 0.507 0.553000 - 0.950000 MXYLENE & PXYLENE S2407 411 - 412 0.101 - 0.101 0.000000 - 1.000000 S2408 332 - 368 0.00666 - 0.0267 0.000000 - 1.000000 S1481 412 - 412 0.101 - 0.101 0.000000 - 1.000000 MXYLENE & R14 S711 288 - 308 0.101 - 0.101 0.999207 - 0.999248 MXYLENE & R23 S711 288 - 308 0.101 - 0.101 0.999027 - 0.999296 MXYLENE & R32 S711 288 - 308 0.101 - 0.101 0.975180 - 0.982700 Continued on next page... S2393
S183
N 9 5 66 25 15 32 3 10 10 40 20 5 10 2 45 83 33 20 14 13 15 5 30 44 13 25 16 11 28 13 9 9 9
Table S4 – continued from previous page Reference T (K) p (MPa) x1 (-) MXYLENE & R41 S711 288 - 308 0.101 - 0.101 0.980060 - 0.985060 MXYLENE & SO2 S269 228 - 250 2.93e-05 - 0.0544 0.000000 - 1.000000 MXYLENE & TOLUENE S682 384 - 407 0.101 - 0.101 0.000000 - 0.888600 S1564 374 - 394 0.0316 - 0.133 0.000000 - 1.000000 S683 388 - 406 0.101 - 0.101 0.264000 - 0.889000 S721 333 - 353 0.0068 - 0.0391 0.000000 - 1.000000 MXYLENE & WATER S729 367 - 408 0.101 - 0.101 0.000010 - 0.997800 N2O & NITROGEN S2253 213 - 253 0.405 - 8.2 0.849000 - 1.000000 S2409 253 - 303 1.8 - 10.7 0.599000 - 1.000000 N2O & OXYGEN S2253 213 - 293 0.402 - 8.84 0.322000 - 1.000000 N2O & R125 S1358 144 - 182 0.008 - 0.092 0.044000 - 1.000000 N2O & R41 S2410 182 - 182 0.0482 - 0.0879 0.000000 - 1.000000 S1995 182 - 182 0.0531 - 0.0836 0.110200 - 0.844400 N2O & WATER S1429 290 - 303 0.101 - 0.101 0.000381 - 0.000549 N2O & XENON S2411 182 - 182 0.0879 - 0.25 0.000000 - 1.000000 S2412 182 - 182 0.0879 - 0.248 0.000000 - 1.000000 NEON & NITROGEN S406 66 - 101 0.981 - 11.8 0.619000 - 1.000000 S2413 66 - 114 7.42 - 22 0.000000 - 0.600400 S2414 83 - 113 0.507 - 5.07 0.000120 - 0.154000 S378 67 - 90 0.573 - 2.54 0.916300 - 0.993000 S2415 66 - 121 0.272 - 7.1 0.000000 - 0.265500 NEON & NONANE S352 298 - 298 0.101 - 0.101 0.000343 - 0.000343 NEON & OCTANE S2040 298 - 298 0.103 - 0.103 0.000289 - 0.000289 S352 298 - 298 0.101 - 0.101 0.000363 - 0.000363 NEON & OXYGEN S2416 63 - 152 0.276 - 35.1 0.000000 - 0.493100 S406 64 - 119 0.981 - 20.6 0.003500 - 0.347500 S378 67 - 90 0.586 - 2.55 0.001150 - 0.022600 NEON & R13 S2417 293 - 299 6.55 - 11 0.087000 - 0.265000 NEON & R14 S2417 215 - 223 6.54 - 11 0.112000 - 0.310900 NEON & WATER S2243 651 - 705 45 - 255 0.140000 - 0.447000 NEON & XENON S2418 163 - 279 0.088 - 152 0.000000 - 0.612300 Continued on next page...
S184
N 9 33 10 39 10 22 21 31 40 58 17 18 12 14 10 8 48 33 114 25 77 1 1 1 113 103 25 26 27 28 133
Table S4 – continued from previous page Reference T (K) p (MPa) x1 (-) NEOPENTN & NITROGEN S2419 211 - 294 3.1 - 82.6 0.060000 - 0.954000 NEOPENTN & PENTANE S802 253 - 293 0.00893 - 0.146 0.000000 - 1.000000 NEOPENTN & PROPANE S2420 358 - 426 1.63 - 4.29 0.066100 - 0.841900 S2421 355 - 426 1.13 - 4.29 0.000000 - 0.841900 NEOPENTN & WATER S94 298 - 298 0.101 - 0.101 0.000008 - 0.000008 NITROGEN & NONANE S686 322 - 344 3.72 - 34.7 0.048000 - 0.332000 S352 298 - 298 0.101 - 0.101 0.001334 - 0.001334 S2422 344 - 543 1.97 - 49.8 0.025500 - 0.668800 NITROGEN & OCTANE S2132 233 - 293 0.203 - 0.709 0.109000 - 0.785000 S686 322 - 344 3.23 - 35 0.043000 - 0.347000 S2423 293 - 373 15.8 - 21.2 0.207000 - 0.207000 S352 298 - 298 0.101 - 0.101 0.001305 - 0.001305 S2424 344 - 544 2.05 - 50.1 0.020400 - 0.699100 NITROGEN & OXYGEN S423 75 - 79 0.0133 - 0.124 0.000000 - 1.000000 S2425 77 - 125 0.0604 - 2.97 0.050000 - 0.908600 S2426 65 - 78 0.00291 - 0.0966 0.029900 - 0.936800 S412 84 - 84 0.0492 - 0.204 0.000000 - 1.000000 S2427 88 - 90 0.0981 - 0.107 0.002200 - 0.084300 S353 63 - 63 0.00155 - 0.0125 0.000000 - 1.000000 S414 100 - 123 0.256 - 2.87 0.000000 - 1.000000 S2428 81 - 91 0.122 - 0.14 0.065300 - 0.812500 S416 78 - 136 0.101 - 2.63 0.051200 - 0.988700 S431 80 - 88 0.0316 - 0.119 0.001600 - 0.845600 S421 63 - 100 0.00149 - 0.773 0.000000 - 1.000000 S1309 273 - 273 5.21 - 10.6 0.006000 - 0.087000 S2429 79 - 116 0.114 - 1.02 0.098500 - 0.888000 S1311 218 - 273 5.17 - 13.1 0.013000 - 0.206000 NITROGEN & PENTANE S2430 91 - 97 0.101 - 0.101 0.999999 - 0.999999 S2431 277 - 378 0.25 - 20.8 0.002200 - 0.400000 S2432 344 - 448 1.67 - 35.5 0.010000 - 0.634100 NITROGEN & PROPANE S1036 298 - 298 2.53 - 18.1 0.031500 - 0.550000 S393 92 - 128 0.12 - 0.584 0.010700 - 0.067000 S2433 195 - 296 0.527 - 6.33 0.000000 - 0.087000 S1008 120 - 127 0.686 - 6.22 0.029900 - 0.997800 S1307 240 - 330 0.151 - 15.1 0.000000 - 0.318000 S2434 230 - 290 0.0966 - 21.9 0.000000 - 0.528000 S2042 103 - 353 0.0069 - 20.7 0.000000 - 0.323000 S308 172 - 256 2.07 - 4.83 0.033000 - 0.114000 S2305 114 - 122 0.15 - 2.8 0.007500 - 0.088800 S847 188 - 343 0.083 - 5.78 0.000000 - 0.000000 Continued on next page...
S185
N 121 60 84 178 1 12 1 70 18 12 9 1 73 37 50 70 11 13 11 44 62 138 20 65 12 108 64 2 42 71 8 6 20 20 38 36 88 32 32 127
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 312 - 365 5.16 - 14.8 0.060000 - 1.000000 S2435 78 - 91 0.0311 - 0.258 0.004000 - 1.000000 NITROGEN & PROPYLEN S2436 78 - 90 0.0311 - 0.258 0.004000 - 1.000000 S1744 260 - 290 0.383 - 21.4 0.000000 - 0.488200 NITROGEN & PXYLENE S687 318 - 535 5.38 - 241 0.050600 - 0.943400 NITROGEN & R12 S2437 295 - 348 2.53 - 17.8 0.015000 - 0.610000 NITROGEN & R13 S850 166 - 284 2.05 - 11 0.040000 - 0.818700 NITROGEN & R14 S850 145 - 210 3.4 - 6.27 0.145000 - 0.886200 S2438 134 - 205 0.114 - 4.52 0.000000 - 0.000000 S2439 70 - 116 0.0278 - 0.862 0.025000 - 0.564000 NITROGEN & R22 S2437 295 - 333 2.53 - 19.5 0.003000 - 0.570000 S1368 263 - 288 0.355 - 5.13 0.000000 - 0.083000 S2440 295 - 333 2.45 - 18.8 0.003000 - 0.570000 S1372 273 - 348 2.53 - 21.5 0.021700 - 0.820000 NITROGEN & R227EA S991 293 - 313 3 - 10 0.083600 - 0.321900 NITROGEN & SO2 S2313 241 - 301 1.55 - 3.55 0.003300 - 0.013400 S2441 323 - 413 1.48 - 23.5 0.000000 - 0.174000 NITROGEN & TOLUENE S686 323 - 348 3.64 - 35.4 0.018000 - 0.159000 S2046 424 - 545 5.08 - 15.2 0.038500 - 0.217000 S2442 313 - 473 2.2 - 100 0.018000 - 0.980000 NITROGEN & WATER S1039 311 - 589 0.345 - 13.8 0.000023 - 0.002935 S365 278 - 313 0.0492 - 0.101 0.000006 - 0.000017 S2443 480 - 658 15.5 - 270 0.000000 - 0.866000 S2444 273 - 433 0.1 - 20 0.000003 - 0.001704 S2445 274 - 363 0.915 - 7.16 0.000074 - 0.001073 S437 283 - 298 0.101 - 0.101 0.000025 - 0.000034 NONANE & OXYGEN S352 298 - 298 0.101 - 0.101 0.997866 - 0.997866 NONANE & OXYLENE S2446 417 - 424 0.101 - 0.101 0.000000 - 1.000000 S2447 373 - 424 0.0267 - 0.101 0.000000 - 1.000000 NONANE & PROPANE S1060 377 - 377 0.938 - 3.47 0.145700 - 0.706400 NONANE & PROPYLEN S258 293 - 333 0.243 - 0.746 0.302000 - 0.901000 NONANE & PXYLENE S722 411 - 424 0.101 - 0.101 0.000000 - 1.000000 NONANE & R14 S352 298 - 298 0.101 - 0.101 0.998102 - 0.998102 Continued on next page... S1346
S186
N 4 47 45 22 265 20 95 86 66 12 19 47 21 37 24 5 49 12 20 43 16 9 97 82 52 4 1 11 39 5 9 13 1
Table S4 – continued from previous page Reference T (K) p (MPa) x1 (-) NONANE & SF6 S352 298 - 298 0.101 - 0.101 0.990637 - 0.990637 NONANE & TOLUENE S722 383 - 424 0.101 - 0.101 0.000000 - 1.000000 NOVEC649 & PENTANE S882 290 - 370 0.0654 - 0.689 0.178000 - 0.406000 NOVEC649 & RE347MCC S882 290 - 380 0.0417 - 0.759 0.299000 - 0.692000 OCTANE & OXYGEN S352 298 - 298 0.101 - 0.101 0.997950 - 0.997950 S1848 298 - 348 0.002 - 8.97 0.813710 - 1.000000 S254 298 - 298 0.101 - 0.101 0.997830 - 0.997830 OCTANE & OXYLENE S2448 308 - 308 0.00168 - 0.00313 0.050000 - 0.950000 S2131 399 - 417 0.101 - 0.101 0.000000 - 1.000000 S2404 349 - 365 0.02 - 0.02 0.000000 - 1.000000 OCTANE & PENTANE S2137 304 - 314 0.00255 - 0.118 0.000000 - 1.000000 OCTANE & PROPANE S2449 427 - 523 2.22 - 5.14 0.412000 - 0.740600 S2450 333 - 551 0.731 - 6.05 0.000000 - 0.785700 S852 313 - 567 0.689 - 5.89 0.000000 - 1.000000 OCTANE & PROPYLEN S2184 298 - 343 0.203 - 1.72 0.098000 - 0.816400 S1572 299 - 325 0.101 - 0.101 0.859400 - 0.929800 OCTANE & PROPYNE S2451 217 - 253 0.0013 - 0.101 0.200000 - 0.995000 OCTANE & PXYLENE S445 399 - 412 0.101 - 0.101 0.000000 - 1.000000 S525 313 - 313 0.00265 - 0.00415 0.000000 - 1.000000 S2404 349 - 360 0.02 - 0.02 0.000000 - 1.000000 OCTANE & R12 S710 298 - 309 0.101 - 0.101 0.869000 - 0.898000 OCTANE & R13 S710 298 - 309 0.101 - 0.101 0.983700 - 0.985800 OCTANE & R14 S710 297 - 309 0.101 - 0.101 0.998030 - 0.998050 S352 298 - 298 0.101 - 0.101 0.998027 - 0.998027 OCTANE & SF6 S710 298 - 308 0.101 - 0.101 0.008540 - 0.009680 S352 298 - 298 0.101 - 0.101 0.990232 - 0.990232 OCTANE & TOLUENE S948 384 - 399 0.101 - 0.101 0.000000 - 1.000000 S2452 310 - 398 0.00667 - 0.101 0.000000 - 1.000000 S2453 384 - 397 0.101 - 0.101 0.073500 - 0.961500 S2454 310 - 322 0.00667 - 0.00667 0.054000 - 0.942000 S597 384 - 398 0.101 - 0.101 0.085000 - 0.965000 S2087 343 - 399 0.0267 - 0.101 0.000000 - 1.000000 S2455 333 - 333 0.0111 - 0.0184 0.047200 - 0.954000 Continued on next page...
S187
N 1 15 22 20 1 43 1 13 13 14 39 12 247 271 14 3 26 26 15 16 2 3 3 1 3 1 11 137 16 22 20 25 17
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 313 - 313 0.00415 - 0.00789 0.000000 - 1.000000 OCTANE & WATER S2456 363 - 398 0.101 - 0.101 0.000100 - 0.999900 OXYGEN & PENTANE S254 298 - 298 0.101 - 0.101 0.002650 - 0.002650 OXYGEN & PROPANE S2457 110 - 140 0.247 - 2.61 0.026600 - 0.977600 OXYGEN & SO2 S2441 323 - 413 1.47 - 20.2 0.000000 - 0.190000 OXYGEN & TOLUENE S1848 298 - 348 0.0039 - 9.17 0.000000 - 0.102820 S2458 283 - 393 0.00197 - 0.0105 0.181000 - 0.941000 S254 298 - 298 0.101 - 0.101 0.000981 - 0.000981 OXYGEN & WATER S365 278 - 313 0.0521 - 0.101 0.000012 - 0.000034 S2459 472 - 662 19.5 - 280 0.010000 - 0.942000 S2460 300 - 300 1 - 10 0.000224 - 0.001710 OXYLENE & PXYLENE S536 412 - 417 0.101 - 0.101 0.044200 - 0.952200 S2406 332 - 373 0.00666 - 0.0267 0.000000 - 1.000000 S1481 412 - 418 0.101 - 0.101 0.000000 - 1.000000 OXYLENE & R22 S2461 273 - 373 0.0819 - 2.46 0.183900 - 0.902400 OXYLENE & TOLUENE S536 385 - 417 0.103 - 0.103 0.037700 - 0.987300 S690 333 - 353 0.00532 - 0.0384 0.000000 - 1.000000 S691 333 - 353 0.00532 - 0.0384 0.000000 - 1.000000 S692 383 - 418 0.101 - 0.101 0.000000 - 1.000000 OXYLENE & WATER S1671 590 - 659 15.4 - 200 0.100000 - 0.100000 PENTANE & PROPANE S2462 337 - 383 0.334 - 4.08 0.018000 - 0.953000 S866 321 - 468 0.689 - 4.48 0.000000 - 1.000000 S2463 327 - 461 0.414 - 4.6 0.038000 - 0.996000 PENTANE & R114 S708 363 - 423 0.72 - 3.19 0.246700 - 0.745000 PENTANE & R12 S235 333 - 333 0.117 - 0.235 0.097900 - 0.900000 PENTANE & R1234ZE S882 270 - 380 0.133 - 2.81 0.268000 - 0.697000 PENTANE & R141B S882 290 - 380 0.0574 - 0.806 0.305000 - 0.749000 PENTANE & R152A S2464 304 - 385 0.305 - 2.91 0.085000 - 0.879200 PENTANE & R22 S2464 304 - 384 0.493 - 4 0.093700 - 0.765100 PENTANE & R23 S2204 310 - 343 0.539 - 7.15 0.093000 - 0.963000 PENTANE & R245FA Continued on next page... S525
S188
N 12 22 1 28 28 42 51 1 9 113 10 19 30 16 93 16 22 22 17 10 80 193 100 12 9 28 20 39 29 26
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 282 - 288 0.0993 - 0.0993 0.000000 - 0.858794 S882 290 - 380 0.13 - 1.58 0.224000 - 0.658000 S850 282 - 288 0.0993 - 0.1 0.000000 - 0.766000 PENTANE & RE347MCC S882 270 - 380 0.0319 - 0.926 0.333000 - 0.652000 PENTANE & SF6 S2465 319 - 329 2.45 - 3.94 0.010000 - 0.575800 S2466 313 - 333 1.01 - 4.01 0.024300 - 0.914900 PENTANE & SO2 PENTANE & TOLUENE S622 293 - 314 0.00291 - 0.116 0.000000 - 1.000000 S1582 309 - 384 0.101 - 0.101 0.000000 - 1.000000 PENTANE & WATER S2467 565 - 637 7.7 - 61.3 0.027000 - 0.138000 PROPANE & PROPYLEN S2468 273 - 293 0.473 - 1.02 0.000000 - 1.000000 S2469 230 - 350 0.097 - 3.51 0.000000 - 1.000000 S2470 273 - 313 0.474 - 1.65 0.000000 - 1.000000 S2471 311 - 344 1.3 - 3.14 0.000000 - 1.000000 S2472 305 - 333 1.28 - 2.51 0.413000 - 0.499000 S1004 311 - 311 1.7 - 4.1 0.030500 - 0.037400 S2473 261 - 361 0.342 - 4.16 0.153000 - 0.824800 S2474 224 - 273 0.0759 - 0.585 0.000000 - 1.000000 S2475 270 - 334 0.439 - 2.36 0.034000 - 0.902000 S2476 244 - 311 0.175 - 1.56 0.000000 - 1.000000 PROPANE & PROPYNE S2477 333 - 333 2.35 - 2.51 0.413000 - 0.499000 PROPANE & R113 S2478 363 - 423 1.08 - 4.41 0.247100 - 0.794500 PROPANE & R114 S2478 343 - 403 1.03 - 3.47 0.138900 - 0.773400 PROPANE & R115 S2479 273 - 273 0.559 - 0.559 0.577500 - 0.577500 PROPANE & R116 S2480 263 - 323 0.344 - 3.85 0.039000 - 1.000000 PROPANE & R1216 S2481 313 - 343 1.23 - 3.01 0.070000 - 0.960000 PROPANE & R1234ZE S2482 258 - 283 0.119 - 0.66 0.000000 - 1.000000 PROPANE & R125 S2483 273 - 313 0.475 - 2.31 0.000000 - 1.000000 S2484 253 - 323 0.244 - 2.87 0.000000 - 1.000000 S2485 243 - 313 0.254 - 2.33 0.172800 - 1.000000 S2486 268 - 313 0.408 - 2.29 0.000000 - 1.000000 S2487 263 - 323 0.346 - 2.88 0.000000 - 1.000000 S2488 258 - 303 0.292 - 1.82 0.000000 - 1.000000 S1383 280 - 364 0.59 - 4.18 0.000000 - 1.000000 PROPANE & R134A S2489 255 - 298 0.144 - 1.18 0.000000 - 1.000000 Continued on next page... S1525
S189
N 15 20 19 25 22 31
126 15 48 26 143 90 24 4 4 54 65 23 69 3 11 12 1 67 35 38 30 117 29 42 56 57 63 29
Table S4 – continued from previous page Reference
T (K) p (MPa) 278 - 357 0.379 - 3.95 S2490 283 - 283 0.415 - 0.797 S2491 273 - 323 0.294 - 2.13 S2492 255 - 285 0.144 - 0.834 PROPANE & R14 PROPANE & R143A S2493 313 - 363 1.37 - 4.2 S2491 268 - 318 0.408 - 2.31 S2494 283 - 283 0.637 - 0.999 PROPANE & R152A S2495 273 - 313 0.266 - 1.5 S2496 268 - 333 0.226 - 2.41 S2497 254 - 288 0.127 - 0.831 PROPANE & R22 S2479 273 - 273 0.604 - 0.604 S2498 243 - 325 0.233 - 2.53 PROPANE & R227EA S2499 278 - 308 0.235 - 1.3 S2500 293 - 353 0.457 - 3.37 S2501 273 - 323 0.195 - 1.84 PROPANE & R23 S881 283 - 313 0.638 - 4.67 PROPANE & R236EA S1641 283 - 313 0.119 - 1.37 PROPANE & R236FA S2502 283 - 323 0.161 - 1.75 PROPANE & R245FA S2503 298 - 313 0.15 - 1.37 PROPANE & R32 S1351 258 - 258 0.286 - 0.708 S2504 273 - 313 0.88 - 2.94 S2505 248 - 295 0.203 - 1.9 S2506 278 - 343 0.553 - 5.45 S2484 253 - 323 0.244 - 3.67 S2507 268 - 318 0.408 - 3.29 S2508 280 - 300 0.716 - 2.14 S1383 280 - 341 0.58 - 5.14 PROPANE & RC318 S2509 329 - 388 0.762 - 4.23 PROPANE & SF6 S2510 294 - 355 1.4 - 4.29 PROPANE & SO2 S1630 323 - 363 0.859 - 4.38 PROPANE & TOLUENE S1190 275 - 300 0.1 - 1 S944 313 - 473 0.25 - 6.63 PROPANE & WATER S2511 279 - 422 0.496 - 19.3 S94 298 - 298 0.101 - 0.101 S1382
S190
x1 (-) 0.000000 - 1.000000 0.000000 - 1.000000 0.000000 - 1.000000 0.000000 - 1.000000
N 71 16 66 36
0.000000 - 1.000000 0.000000 - 1.000000 0.000000 - 1.000000
52 41 18
0.000000 - 1.000000 0.000000 - 1.000000 0.000000 - 1.000000
45 90 34
0.489000 - 0.489000 0.046060 - 0.046060
1 12
0.000000 - 1.000000 0.037800 - 0.979600 0.000000 - 1.000000
39 91 76
0.000000 - 1.000000
38
0.000000 - 1.000000
43
0.000000 - 1.000000
49
0.000000 - 1.000000
32
0.000000 0.097400 0.000000 0.000000 0.000000 0.000000 0.002000 0.000000
1.000000 0.833200 1.000000 1.000000 1.000000 1.000000 0.999000 1.000000
11 20 67 94 113 56 98 75
0.000000 - 1.000000
71
0.000000 - 0.836800
129
0.000000 - 1.000000
12
0.043200 - 1.000000 0.043000 - 0.957000
17 24
0.000080 - 0.999863 0.000025 - 0.000025 Continued on next page...
145 1
-
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 586 - 663 17.4 - 187 0.031000 - 0.265000 S2513 333 - 370 2.16 - 4.32 0.991940 - 0.997980 S2514 278 - 368 0.357 - 3.92 0.000032 - 0.000269 S1777 441 - 623 12.6 - 250 0.000000 - 0.086000 S2515 473 - 593 23 - 200 0.000000 - 0.051000 PROPANE & XENON S2516 161 - 195 0.000946 - 0.437 0.000000 - 1.000000 PROPYLEN & PXYLENE S700 293 - 353 0.203 - 0.507 0.043000 - 0.429000 PROPYLEN & R114 S2489 283 - 298 0.129 - 1.15 0.000000 - 1.000000 PROPYLEN & R115 S2489 251 - 298 0.204 - 1.25 0.000000 - 1.000000 PROPYLEN & R116 S2489 251 - 275 0.283 - 1.96 0.000000 - 1.000000 PROPYLEN & R12 S2489 258 - 283 0.181 - 0.777 0.000000 - 1.000000 PROPYLEN & R1216 S2517 263 - 353 0.225 - 4.01 0.000000 - 0.986100 S2518 288 - 318 0.627 - 1.97 0.072000 - 0.960000 PROPYLEN & R125 S2519 263 - 323 0.429 - 2.83 0.000000 - 1.000000 PROPYLEN & R13 S2489 251 - 273 0.283 - 1.96 0.000000 - 1.000000 PROPYLEN & R134A S2489 251 - 298 0.121 - 1.22 0.000000 - 1.000000 PROPYLEN & R14 S2310 90 - 196 0.000313 - 0.127 0.004000 - 0.996000 PROPYLEN & R142B S2489 268 - 298 0.119 - 1.15 0.000000 - 1.000000 PROPYLEN & R152A S2520 298 - 298 0.61 - 1.18 0.000000 - 0.976100 S2489 255 - 285 0.131 - 0.831 0.000000 - 1.000000 PROPYLEN & R22 S2489 258 - 283 0.295 - 0.797 0.000000 - 1.000000 PROPYLEN & R23 S2489 251 - 265 0.283 - 1.99 0.000000 - 1.000000 PROPYLEN & R32 S2521 273 - 313 0.588 - 2.82 0.000000 - 1.000000 PROPYLEN & TOLUENE S699 273 - 353 0.101 - 0.101 0.012700 - 0.126900 S258 293 - 333 0.246 - 0.734 0.074000 - 0.598000 S2522 319 - 459 1.27 - 5.42 0.155000 - 0.850000 S2523 319 - 459 1.27 - 5.42 0.155000 - 0.850000 S2079 313 - 359 0.131 - 1.27 0.064000 - 0.334000 PROPYLEN & WATER S2524 294 - 378 0.101 - 3.45 0.000008 - 0.000951 S2525 311 - 411 0.255 - 34.5 0.000152 - 0.002264 S94 298 - 298 0.101 - 0.101 0.000086 - 0.000086 Continued on next page... S2512
S191
N 242 2 60 34 23 28 16 18 25 17 54 86 47 57 20 29 60 31 19 36 47 17 90 6 9 6 6 40 182 99 1
Table S4 – continued from previous page Reference
T (K) p (MPa) x1 (-) 441 - 623 12.6 - 250 0.002900 - 0.086000 S2526 311 - 311 0.255 - 0.801 0.000152 - 0.000558 PROPYLEN & XENON S2242 156 - 186 0.00567 - 0.121 0.081000 - 0.946000 PROPYNE & WATER S2527 294 - 378 0.12 - 1.18 0.000140 - 0.006772 S94 298 - 298 0.101 - 0.101 0.001634 - 0.001634 PXYLENE & TOLUENE S704 384 - 412 0.101 - 0.101 0.000000 - 1.000000 S705 384 - 412 0.101 - 0.101 0.000000 - 1.000000 S536 385 - 412 0.102 - 0.102 0.044800 - 0.989300 S2528 386 - 408 0.101 - 0.101 0.100000 - 0.900000 PXYLENE & WATER S2529 573 - 603 4.3 - 10.3 0.305000 - 0.697000 S2530 365 - 365 0.101 - 0.101 0.990000 - 0.990000 R11 & R12 S2531 253 - 323 0.028 - 1.08 0.000000 - 0.935000 R11 & R13 S2532 203 - 293 0.0231 - 2.96 0.038484 - 0.935270 R11 & R22 S2533 298 - 323 0.25 - 1.95 0.000000 - 1.000000 R11 & R23 S2534 298 - 373 0.099 - 7.73 0.251200 - 1.000000 R113 & R114 S2535 280 - 319 0.101 - 0.101 0.118200 - 0.972100 S2478 348 - 423 0.238 - 3.27 0.000000 - 1.000000 R113 & R13 S2536 298 - 373 0.42 - 5.4 0.042200 - 0.899800 R113 & R142B S2537 347 - 424 0.238 - 3.77 0.000000 - 1.000000 R113 & R152A S2538 298 - 373 0.112 - 3.46 0.000000 - 1.000000 R113 & R22 S2539 298 - 373 0.051 - 3.6 0.000000 - 1.000000 R113 & R23 S2538 298 - 373 0.112 - 7.68 0.196600 - 1.000000 R113 & SF6 S2540 233 - 329 0.0103 - 0.207 0.979100 - 0.996200 R114 & R115 S2541 315 - 399 0.93 - 3.35 0.231507 - 0.730548 R114 & R12 S2542 253 - 339 0.0724 - 1.64 0.100000 - 0.900000 S2543 278 - 372 0.35 - 1.45 0.000000 - 1.000000 S2544 253 - 313 0.057 - 0.896 0.118000 - 0.939000 R114 & R22 S2542 253 - 333 0.0852 - 2.19 0.161900 - 0.948900 S2539 298 - 373 0.219 - 4.07 0.000000 - 1.000000 S2545 253 - 333 0.059 - 2.22 0.090500 - 0.942800 S2543 296 - 371 0.985 - 1.35 0.000000 - 1.000000 Continued on next page... S1962
S192
N 27 4 51 39 1 15 15 18 9 20 1 47 130 16 14 17 20 48 19 19 20 17 22 18 39 38 25 36 19 47 17
Table S4 – continued from previous page Reference
T (K) 253 - 338 S2546 310 - 400 S2547 298 - 368 S2548 323 - 366 R114 & R23 S2537 288 - 373 R115 & R125 S2549 243 - 333 R115 & R22 S2550 171 - 355 S2551 202 - 347 S2552 273 - 354 S2479 273 - 273 S2553 298 - 366 R116 & R1216 S2554 273 - 313 R116 & R134A S2489 251 - 275 S2555 263 - 353 R116 & R143A S2556 258 - 328 R116 & R22 S2557 263 - 288 R116 & R23 S1351 210 - 228 S2558 194 - 245 R116 & R32 S1351 254 - 254 R116 & XENON S2559 173 - 173 R12 & R1216 S2560 266 - 269 S266 308 - 314 R12 & R13 S2561 255 - 290 S2562 223 - 323 S2542 255 - 290 R12 & R134A S2489 258 - 298 R12 & R142B S1353 303 - 363 R12 & R143A S2563 203 - 313 R12 & R152A S2564 273 - 273 S2565 431 - 618 S2566 303 - 323 R12 & R22 S2560 256 - 269 S2544
p (MPa) 0.076 - 2.59 0.308 - 4.63 0.597 - 3.77 1.85 - 2.04
x1 (-) 0.033000 - 0.963000 0.000000 - 1.000000 0.397000 - 0.856000 0.071300 - 0.747800
N 44 43 43 25
0.219 - 5.54
0.000000 - 1.000000
17
0.149 - 3.17
0.000000 - 1.000000
80
0.512000 0.370003 0.367953 0.383000 0.157000
0.512000 0.370003 0.367953 0.383000 1.000000
46 55 20 1 78
0.506 - 3.3
0.178200 - 0.884600
11
0.121 - 1.94 0.196 - 4.16
0.000000 - 1.000000 0.000000 - 1.000000
18 81
0.388 - 3.81
0.000000 - 1.000000
89
0.365 - 2.74
0.000000 - 1.000000
16
0.209 - 0.708 0.0977 - 1.26
0.000000 - 1.000000 0.000000 - 1.000000
26 53
0.411 - 1.25
0.000000 - 1.000000
14
0.0858 - 0.16
0.000000 - 0.888600
8
0.275 - 0.275 0.986 - 0.986
0.000000 - 0.869000 0.007600 - 1.000000
7 10
0.162 - 3 0.1 - 2.15 0.162 - 3
0.000000 - 1.000000 0.696400 - 0.937700 0.000000 - 1.000000
21 117 21
0.163 - 0.813
0.000000 - 1.000000
30
0.478 - 2.68
0.165800 - 0.859500
16
0.0123 - 1.86
0.000000 - 1.000000
70
0.264 - 0.363 0.0466 - 3.98 0.686 - 1.46
0.000000 - 1.000000 0.606111 - 0.606111 0.000000 - 1.000000
17 11 47
0.275 - 0.275
0.000000 - 1.000000 Continued on next page...
7
0.00276 - 4.06 0.0242 - 3.43 0.567 - 3.99 0.567 - 0.567 0.914 - 4.89
S193
-
Table S4 – continued from previous page Reference
T (K) 232 - 243 S2568 273 - 273 S2569 263 - 362 S2570 193 - 323 S2571 253 - 343 S2572 213 - 343 S2573 253 - 278 S2543 296 - 329 S2574 344 - 374 R12 & R23 S2563 193 - 273 R12 & R32 S2575 283 - 283 R12 & RC318 S2560 269 - 294 S2576 243 - 373 R1216 & R123 S1354 313 - 333 R1216 & R22 S2560 256 - 267 S2577 278 - 303 R1216 & RC318 S2578 293 - 353 R1216 & TOLUENE S2554 273 - 313 R123 & R134A S2579 289 - 333 R123 & R22 S2574 313 - 415 R123 & R32 S2580 295 - 314 R123 & WATER S2581 298 - 354 R1234YF & R125 S2582 273 - 333 R1234YF & R134A S850 300 - 300 S2583 273 - 333 R1234YF & R143A S2584 283 - 323 R1234YF & R152A S2585 283 - 323 R1234YF & R161 S2586 283 - 323 R1234YF & R227EA S2587 283 - 323 R1234YF & R32 S850 273 - 313 S2583 273 - 333 S2567
p (MPa) 0.101 - 0.101 0.401 - 0.499 0.295 - 3.41 0.0076 - 1.93 0.153 - 3 0.0234 - 2.99 0.15 - 0.586 0.985 - 1.4 1.87 - 4.97
x1 (-) 0.000000 - 1.000000 0.000000 - 0.799100 0.750000 - 0.750000 0.100000 - 0.900000 0.000000 - 1.000000 0.000000 - 1.000000 0.009600 - 1.000000 0.000000 - 1.000000 0.000000 - 1.000000
N 19 11 32 122 90 193 47 20 113
0.00618 - 2.51
0.000000 - 1.000000
54
0.42 - 1.14
0.000000 - 1.000000
16
0.275 - 0.275 0.033 - 3.33
0.000000 - 1.000000 0.000000 - 1.000000
8 82
0.433 - 1.53
0.105000 - 0.820000
11
0.275 - 0.275 0.402 - 1.19
0.000000 - 1.000000 0.000000 - 1.000000
7 74
0.286 - 2.61
0.091000 - 0.910000
31
0.087 - 0.79
0.085400 - 0.704000
8
0.12 - 1.5
0.079000 - 0.924000
31
0.157 - 5.18
0.000000 - 1.000000
63
0.0816 - 2.53
0.000000 - 1.000000
27
0.09 - 0.5
0.962500 - 0.990500
4
0.318 - 3.18
0.000000 - 1.000000
84
0.705 - 0.749 0.295 - 1.73
0.000000 - 1.000000 0.000000 - 1.000000
36 63
0.436 - 2.31
0.000000 - 1.000000
45
0.375 - 1.32
0.000000 - 1.000000
60
0.438 - 1.74
0.000000 - 1.000000
60
0.279 - 1.3
0.000000 - 1.000000
50
0.45 - 1.9 0.319 - 3.93
0.500000 - 0.853000 0.000000 - 1.000000 Continued on next page...
10 77
S194
Table S4 – continued from previous page Reference T (K) R1234ZE & R152A S2588 258 - 288 R1234ZE & R32 S850 273 - 313 R124 & R134A S2589 296 - 307 S2590 273 - 273 R124 & R142B S2498 241 - 351 S2590 273 - 273 S2591 298 - 312 R124 & R152A S2498 244 - 335 S2590 273 - 273 R124 & R22 S2592 196 - 384 S2498 240 - 332 S2590 273 - 273 S2593 253 - 333 R124 & RC318 S2594 253 - 353 R125 & R134A S2595 283 - 313 S2596 206 - 365 S1382 280 - 340 S2597 268 - 293 S2598 253 - 303 S2599 263 - 303 S2600 304 - 363 S2601 273 - 313 S2602 224 - 345 S2603 280 - 350 S2604 205 - 364 S2605 253 - 303 S2606 253 - 333 R125 & R143A S2607 205 - 343 S2608 223 - 338 S1382 280 - 326 S2609 250 - 330 S2610 273 - 313 S2611 308 - 341 S2612 280 - 330 R125 & R152A S2613 268 - 373 S2614 293 - 293 R125 & R161 S2615 265 - 313 R125 & R22
p (MPa)
x1 (-)
N
0.123 - 0.43
0.144000 - 0.899000
36
0.4 - 2
0.336000 - 0.871000
10
0.37 - 0.865 0.207 - 0.286
0.000000 - 1.000000 0.094000 - 0.759000
23 6
0.038 - 1.38 0.152 - 0.161 0.338 - 0.573
0.503700 - 0.503700 0.244000 - 0.757000 0.000000 - 1.000000
16 3 23
0.059 - 1.26 0.192 - 0.242
0.496700 - 0.496700 0.244000 - 0.763000
15 3
0.00763 - 4.44 0.101 - 1.64 0.279 - 0.403 0.139 - 1.85
0.199670 0.178480 0.245000 0.000000
0.273280 0.498600 0.763000 0.178480
98 37 3 17
0.074 - 1.63
0.600000 - 0.600000
11
0.412 - 2 0.0172 - 3.97 0.379 - 3.63 0.254 - 1.16 0.178 - 1.5 0.201 - 1.57 0.92 - 3.92 0.597 - 1.88 0.0663 - 3.15 0.425 - 2.97 0.0168 - 3.96 0.147 - 1.5 0.3 - 2.88
0.000000 0.254300 0.000000 0.032000 0.154200 0.000000 0.045000 0.337500 0.316300 0.086600 0.159400 0.000000 0.000000
-
1.000000 0.749100 1.000000 0.944000 0.941900 1.000000 0.938000 0.355900 0.514100 0.923100 0.171700 0.941900 0.357820
25 31 38 33 11 35 53 22 50 36 13 23 16
0.0324 - 3.69 0.0861 - 3.3 0.767 - 2.64 0.281 - 2.78 0.622 - 2.01 1.65 - 3.47 0.773 - 2.83
0.493400 0.460500 0.000000 0.000000 0.000000 0.411820 0.072600
-
0.503000 0.499000 1.000000 1.000000 1.000000 0.412250 0.863100
19 16 32 45 18 7 34
0.276 - 4.24 0.514 - 1.21
0.021000 - 0.973000 0.000000 - 1.000000
87 8
0.336 - 2.01
0.000000 - 1.000000
75
-
Continued on next page...
S195
Table S4 – continued from previous page Reference
T (K) 243 - 334 R125 & R227EA S2487 278 - 323 R125 & R23 S2616 283 - 293 R125 & R236EA S2617 289 - 318 R125 & R236FA S2618 303 - 323 R125 & R245FA S2619 298 - 313 R125 & R32 S2620 280 - 310 S2621 249 - 338 S2622 253 - 333 S2623 283 - 313 S2608 224 - 344 S1382 279 - 340 S2597 273 - 318 S1351 258 - 284 S2624 253 - 333 S2625 303 - 323 S2626 248 - 333 S2627 268 - 308 S2628 308 - 308 S2629 265 - 303 S2630 295 - 334 S2631 318 - 349 S2632 248 - 333 S2601 273 - 323 S2633 250 - 350 S2634 263 - 326 S1383 221 - 345 S2635 205 - 362 S2602 222 - 353 S2603 280 - 340 S2636 253 - 333 S2637 253 - 333 S2638 253 - 333 S2639 253 - 303 R125 & RE143A S2640 280 - 350 R13 & R14 S2641 233 - 253 S2642 200 - 200 S2643 199 - 200 S2644 200 - 289 R13 & R23 S2645 200 - 273 S2498
p (MPa) 0.206 - 2.96
x1 (-) 0.477600 - 0.477600
N 16
0.235 - 2.53
0.000000 - 1.000000
46
0.907 - 4.2
0.000000 - 1.000000
23
0.146 - 2.26
0.000000 - 1.000000
29
0.322 - 2.54
0.000000 - 1.000000
18
0.15 - 2.01
0.000000 - 1.000000
21
0.884 - 2.31 0.348 - 4.3 0.385 - 3.83 0.906 - 2.48 0.108 - 4.91 0.83 - 4.61 0.691 - 2.77 0.401 - 1.15 0.358 - 3.9 1.57 - 3.14 0.284 - 3.18 0.571 - 2.19 1.78 - 2.19 0.517 - 1.93 1.45 - 3.98 2.35 - 5.27 0.284 - 3.93 0.556 - 2.73 0.361 - 5.65 0.448 - 2.41 0.073 - 4.58 0.026 - 5.05 0.0744 - 4.2 0.724 - 3.24 0.385 - 3.83 0.212 - 2.72 0.358 - 3.9 0.25 - 1.39
0.097900 0.237000 0.303900 0.000000 0.248100 0.000000 0.105000 0.000000 0.115100 0.000000 0.000000 0.000000 0.000600 0.000000 0.000000 0.047000 0.000000 0.061200 0.125770 0.000000 0.000000 0.048800 0.131100 0.066900 0.000000 0.000000 0.000000 0.000000
0.795800 0.237000 0.303900 1.000000 0.517300 1.000000 0.945000 1.000000 0.881300 1.000000 1.000000 1.000000 1.000000 1.000000 0.583890 0.866000 1.000000 0.454400 0.125770 0.305550 1.000000 0.758600 0.656900 0.299400 0.303900 0.180400 0.881300 0.568000
24 10 17 22 51 57 28 25 18 17 10 35 34 66 90 39 47 72 11 41 88 63 67 20 18 18 33 9
0.434 - 2.59
0.252600 - 0.735300
21
1.2 - 4 0.345 - 0.345 0.154 - 1.53 0.155 - 4.32
0.145000 0.880800 0.000000 0.000000
0.856000 0.880800 1.000000 1.000000
15 1 14 65
0.000000 - 1.000000 Continued on next page...
75
0.154 - 2.76
S196
-
-
Table S4 – continued from previous page Reference S2642 S2646
R134A & S2647
R134A & S2489 S2590
R134A & S2648 S2607 S2608 S1382 S2649 S2650 S2601
R134A & S2651 S2489 S2621 S2652 S2590
R134A & S2653
R134A & S2654
R134A & S2655 S2656 S2657 S2590
R134A & S2658 S2659 S2584
R134A & S2660 S2661 S2590
R134A & S2225
R134A & S2662
R134A & S2663 S2621 S2664 S2596 S2665 S2666
T (K) 200 - 200 255 - 255 R141B 278 - 333 R142B 268 - 298 273 - 273 R143A 278 - 333 205 - 361 223 - 354 280 - 340 263 - 313 273 - 313 273 - 313 R152A 313 - 378 255 - 298 248 - 368 303 - 323 273 - 273 R161 253 - 293 R218 220 - 340 R22 273 - 323 344 - 372 322 - 372 273 - 273 R227EA 298 - 313 303 - 323 283 - 323 R23 283 - 293 258 - 293 273 - 273 R236FA 284 - 304 R245FA 293 - 313 R32 273 - 273 253 - 358 283 - 313 203 - 369 260 - 300 263 - 323
p (MPa) 0.69 - 0.69 1.29 - 1.7
x1 (-) 0.638300 - 0.638300 0.045200 - 0.943600
N 1 22
0.101 - 1.5
0.019000 - 0.857000
38
0.119 - 0.662 0.177 - 0.285
0.000000 - 1.000000 0.130000 - 0.884000
32 7
0.35 - 2.88 0.0214 - 3.94 0.0595 - 3.39 0.379 - 3.32 0.2 - 1.83 0.294 - 1.83 0.388 - 1.6
0.000000 0.503800 0.501800 0.000000 0.000000 0.000000 0.294300
-
1.000000 0.526300 0.522300 1.000000 1.000000 1.000000 0.750600
41 12 18 38 54 35 9
0.926 - 4.09 0.131 - 0.662 0.104 - 3.43 0.685 - 1.31 0.271 - 0.286
0.229600 0.000000 0.776900 0.000000 0.118000
-
0.750400 1.000000 0.776900 1.000000 0.758000
23 25 13 42 4
0.131 - 0.802
0.000000 - 1.000000
39
0.0455 - 2.77
0.200000 - 0.800000
28
0.292 - 1.94 2.13 - 4.97 1.5 - 4.78 0.359 - 0.453
0.000000 0.000000 0.213000 0.241000
1.000000 1.000000 0.799000 0.765000
20 61 35 3
0.456 - 0.998 0.53 - 1.32 0.279 - 1.31
0.000000 - 1.000000 0.000000 - 1.000000 0.000000 - 1.000000
19 20 50
0.416 - 4.2 0.283 - 3.42 0.401 - 0.948
0.000000 - 1.000000 0.094700 - 0.937900 0.520000 - 0.909000
18 53 2
0.163 - 0.781
0.000000 - 1.000000
19
0.123 - 1.01
0.000000 - 1.000000
31
0.384 - 0.758 0.263 - 4.47 0.567 - 1.91 0.0148 - 5.42 0.177 - 1.77 0.2 - 3.14
0.078000 - 0.796000 0.450000 - 0.504000 0.327000 - 0.878500 0.228100 - 0.787800 0.000000 - 1.000000 0.000000 - 1.000000 Continued on next page...
6 25 12 50 33 35
S197
-
Table S4 – continued from previous page Reference
T (K) 223 - 343 S2667 220 - 340 S1382 279 - 340 S2597 273 - 363 S2668 253 - 333 S2599 258 - 283 S2625 303 - 323 S2626 243 - 333 S2669 263 - 293 S2670 258 - 343 S2600 313 - 363 S2671 243 - 361 S2632 243 - 333 S2633 238 - 301 S2634 261 - 283 S2672 253 - 333 R134A & RE143A S2640 280 - 350 R134A & WATER S1419 278 - 338 R14 & R23 S2673 145 - 283 S2642 200 - 200 R14 & R41 S2674 130 - 130 R14 & TOLUENE S711 288 - 308 R14 & WATER S365 293 - 303 R14 & XENON S2675 159 - 159 R141B & R142B S2676 323 - 323 R142B & R152A S2677 348 - 348 S2678 280 - 400 S2590 273 - 273 R142B & R22 S2539 298 - 373 S2679 329 - 402 S2680 263 - 338 S2681 280 - 400 S2677 349 - 349 S2548 276 - 349 S2682 248 - 283 S2683 313 - 328 S2684 313 - 313 S2498 242 - 354 S2685 321 - 402 S2608
p (MPa) 0.0729 - 3.15 0.056 - 3.1 0.379 - 4.56 0.31 - 4.81 0.181 - 3.6 0.201 - 0.96 0.783 - 3.11 0.084 - 2.48 0.252 - 1.4 0.164 - 4.88 1.17 - 4.83 0.173 - 5.02 0.084 - 3.34 0.135 - 1.29 0.241 - 0.93 0.181 - 3.6
x1 (-) 0.482500 - 0.580600 0.113100 - 0.670900 0.000000 - 1.000000 0.119000 - 0.959000 0.110800 - 0.868900 0.201300 - 1.000000 0.000000 - 1.000000 0.000000 - 1.000000 0.076700 - 0.865000 0.000000 - 1.000000 0.043000 - 0.966000 0.113100 - 0.608300 0.000000 - 1.000000 0.290000 - 0.726400 0.000000 - 0.000000 0.000000 - 0.868900
N 16 48 75 44 23 25 14 11 40 124 38 36 35 34 10 40
0.34 - 2.38
0.249600 - 0.745400
24
0.0609 - 0.0931
0.000078 - 0.000408
6
0.0245 - 5.19 0.345 - 0.69
0.003200 - 0.966400 0.044500 - 0.851200
84 2
0.000381 - 0.0323
0.000000 - 1.000000
5
0.101 - 0.101
0.000645 - 0.000709
8
0.101 - 0.101
0.000003 - 0.000004
3
0.0714 - 0.261
0.000000 - 1.000000
10
0.185 - 0.685
0.000000 - 1.000000
13
1.31 - 2.11 0.25 - 4.19 0.182 - 0.243
0.000000 - 1.000000 0.141100 - 0.724800 0.245000 - 0.760000
10 48 3
0.338 - 4.28 0.000000 - 1.000000 1.06 - 4.89 0.200000 - 0.800000 0.098 - 2.7 0.000000 - 1.000000 0.29 - 4.37 0.177200 - 0.775000 1.32 - 3.35 0.000000 - 1.000000 0.465 - 1.79 0.073200 - 0.929500 0.0659 - 0.621 0.133000 - 0.934000 0.638 - 1.96 0.131900 - 0.911700 1.11 - 1.11 0.498900 - 0.498900 0.099 - 2.44 0.486200 - 0.486200 1.06 - 4.89 0.000000 - 0.774900 Continued on next page...
19 12 99 46 13 38 85 28 1 18 31
S198
Table S4 – continued from previous page Reference
T (K) 273 - 273 S2686 253 - 333 R142B & R32 S2580 295 - 315 R143A & R152A S2650 273 - 313 R143A & R161 S2687 253 - 303 R143A & R22 S2665 275 - 275 S2688 273 - 338 R143A & R23 S2689 283 - 293 R143A & R236FA S2690 283 - 313 R143A & R32 S1382 279 - 340 S1351 256 - 256 S2625 303 - 323 S2691 250 - 330 S2692 263 - 313 S2693 308 - 329 S2694 273 - 273 R152A & R218 S2695 203 - 313 R152A & R22 S2696 280 - 380 S2697 353 - 397 S2683 313 - 328 S2498 241 - 335 S2590 273 - 273 S2686 254 - 333 S2698 298 - 339 R152A & R227EA S2659 283 - 303 R152A & R23 S2689 283 - 293 R152A & R245FA S2699 323 - 353 R152A & R32 S2663 273 - 273 S2621 248 - 358 S2625 303 - 323 R152A & WATER S1412 323 - 323 S1419 278 - 338 R161 & R227EA S2700 253 - 313 R161 & R32 S2590
p (MPa) 0.204 - 0.435 0.137 - 1.96
x1 (-) 0.330000 - 0.858000 0.278790 - 0.667520
N 4 26
0.31 - 2.59
0.000000 - 1.000000
24
0.263 - 1.83
0.000000 - 1.000000
33
0.22 - 1.42
0.017800 - 0.965300
109
0.529 - 0.656 0.498 - 3.19
0.000000 - 1.000000 0.000000 - 1.000000
11 118
0.838 - 4.2
0.000000 - 1.000000
20
0.161 - 1.83
0.000000 - 1.000000
27
0.767 - 4.59 0.35 - 0.459 1.44 - 3.15 0.281 - 2.92 0.45 - 2.48 1.97 - 3.48 0.689 - 0.818
0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.048000
1.000000 1.000000 1.000000 1.000000 1.000000 0.000000 0.882000
61 13 16 31 60 8 6
0.0045 - 1.49
0.000000 - 1.000000
109
0.34 - 4.76 2.49 - 5.96 0.973 - 2.01 0.104 - 1.96 0.309 - 0.413 0.167 - 1.92 0.871 - 1.89
0.126614 0.852225 0.162700 0.501400 0.243000 0.466030 0.192700
0.921843 0.912926 0.866000 0.501400 0.757000 0.762190 0.847600
66 22 16 16 3 28 46
0.278 - 0.69
0.000000 - 1.000000
20
0.374 - 4.2
0.000000 - 1.000000
20
0.344 - 2.34
0.000000 - 1.000000
36
0.308 - 0.689 0.217 - 4.34 0.677 - 3.09
0.186000 - 0.910000 0.491100 - 0.502000 0.000000 - 1.000000
6 26 18
0.61 - 10.1 0.0367 - 0.0799
0.002400 - 0.004300 0.000196 - 0.000674
4 6
0.133 - 1.2
0.044500 - 0.876100
57
-
-
Continued on next page...
S199
Table S4 – continued from previous page Reference
T (K) 253 - 303 R161 & TOLUENE S2702 253 - 313 R218 & R22 S2557 273 - 298 S2703 323 - 348 R218 & RC318 S2704 263 - 303 R22 & R23 S2705 248 - 268 S1369 273 - 353 S2537 288 - 348 S2590 273 - 273 R22 & R32 S2575 283 - 283 R22 & RC318 S2560 256 - 294 R22 & WATER S2706 283 - 323 S1419 278 - 338 R227EA & R23 S2660 283 - 293 R227EA & R32 S2658 298 - 313 S2659 283 - 303 S2707 283 - 343 R23 & R32 S2614 283 - 293 R23 & SF6 S1379 265 - 295 R23 & TOLUENE S711 288 - 308 R23 & WATER S1419 278 - 338 R236EA & R32 S2617 289 - 318 R236FA & R32 S2618 303 - 323 R32 & R40 S2575 283 - 283 R32 & SF6 S1379 265 - 310 R32 & SO2 S2708 288 - 403 R32 & TOLUENE S711 288 - 308 R40 & R41 S2709 159 - 182 S2701
p (MPa) 0.24 - 1.91
x1 (-) 0.034700 - 0.992700
N 96
0.0133 - 0.0973
0.010800 - 0.452200
16
0.405 - 1.25 1.65 - 3.85
0.000000 - 1.000000 0.000000 - 1.000000
20 54
0.0854 - 1.03
0.000000 - 1.000000
57
0.201 - 2.17 0.715 - 5.39 0.797 - 4.88 0.645 - 0.645
0.000000 0.066200 0.260350 0.911000
1.000000 0.978200 1.000000 0.911000
36 45 21 1
0.677 - 1.1
0.000000 - 1.000000
13
0.275 - 0.275
0.000000 - 1.000000
8
0.101 - 0.101 0.0457 - 0.0885
0.000318 - 0.001127 0.000141 - 0.000595
6 6
0.28 - 4.2
0.000000 - 1.000000
20
0.456 - 2.44 0.278 - 1.92 0.279 - 4.51
0.000000 - 1.000000 0.000000 - 1.000000 0.000000 - 1.000000
20 19 40
1.1 - 4.2
0.000000 - 1.000000
20
1.6 - 4.37
0.213000 - 0.747000
9
0.101 - 0.101
0.006080 - 0.008490
9
0.0688 - 0.0915
0.000070 - 0.000290
6
0.145 - 2.8
0.000000 - 1.000000
31
0.322 - 3.15
0.000000 - 1.000000
19
0.362 - 1.1
0.000000 - 1.000000
13
1.22 - 4.04
0.240000 - 0.778000
12
0.417 - 7.31
0.064000 - 0.881000
52
0.101 - 0.101
0.015040 - 0.020120
9
0.00167 - 0.0482 0.000000 - 1.000000 Continued on next page...
14
S200
-
Table S4 – continued from previous page Reference T (K) R40 & WATER S2710 303 - 303 S2711 288 - 333 S2712 313 - 333 R40 & XENON S2713 175 - 182 R41 & TOLUENE S711 288 - 308 R41 & WATER S2714 280 - 298 R41 & XENON S2715 161 - 195 S2412 182 - 182 SF6 & WATER S365 278 - 313 S2716 293 - 293 SF6 & XENON S2717 235 - 305 SO2 & WATER S850 273 - 403 S2718 293 - 393 SO2 & TOLUENE S269 228 - 250 SO2 & WATER S2719 293 - 393 S2720 293 - 308 S2721 293 - 308 WATER & XENON S2722 489 - 635 S372 283 - 313 S2723 278 - 318
p (MPa)
x1 (-)
N
0.101 - 0.101 0.101 - 0.101 0.722 - 1.27
0.002634 - 0.002634 0.009583 - 0.034089 0.007920 - 0.009300
1 4 2
0.000868 - 0.248
0.000000 - 1.000000
19
0.101 - 0.101
0.013850 - 0.018510
9
0.178 - 1.4
0.002350 - 0.014610
48
0.0105 - 0.45 0.0482 - 0.255
0.000000 - 1.000000 0.000000 - 1.000000
28 11
0.101 - 0.101 0.00229 - 2.08
0.000003 - 0.000009 0.000000 - 1.000000
8 8
0.368 - 5.53
0.000000 - 1.000000
93
0-0 0.0356 - 2.51
0.000010 - 0.053250 0.004070 - 0.090960
359 66
5.6e-05 - 0.054
0.000000 - 1.000000
33
0.0356 - 2.51 0.101 - 0.101 0.101 - 0.101
0.004073 - 0.090955 0.017942 - 0.030791 0.018000 - 0.030790
66 4 4
15 - 270 0.101 - 0.101 0.101 - 0.101
0.229000 - 0.970000 0.999881 - 0.999944 0.999852 - 0.999949
65 3 3
S201
5 5.1
Python code binary fitter.py
""" This ␣ code ␣ carries ␣ out ␣ the ␣ fitting ␣ of ␣ the ␣ binary ␣ interaction ␣ parameters as ␣ described ␣ in : Ian ␣ H . ␣ Bell ␣ and ␣ Eric ␣ W . ␣ Lemmon , ␣ ␣ " Automatic ␣ fitting ␣ of ␣ binary ␣ interaction parameters ␣ for ␣ multi - fluid ␣ Helmholtz - energy - explicit ␣ mixture ␣ models " , ␣ 2016 By ␣ Ian ␣ H . ␣ Bell , ␣ NIST ␣ ( ian . bell@nist . gov ) The ␣ fitting ␣ was ␣ carried ␣ out ␣ using ␣ a ␣ development ␣ version ␣ of ␣ CoolProp : >>>␣ import ␣ CoolProp >>>␣ CoolProp . __version__ u ’5.1.3 dev ’ >>>␣ CoolProp . __gitrevision__ u ’2688 b 5 7 2 a c 7 f c 1 8 d e 4 a 7 7 c 4 b 9 3 0 b 5 b d d d e 5 2 e d a 0 ’ You ␣ will ␣ also ␣ need ␣ numpy , ␣ pandas , ␣ and ␣ deap . ␣ ␣ numpy ␣ and ␣ pandas ␣ can ␣ be ␣ obtained ␣ in the ␣ Anaconda ␣ installer ␣ package , ␣ deap ␣ should ␣ be ␣ installed ␣ from ␣ source . There ␣ is ␣ a ␣ sample ␣ set ␣ of ␣ data ␣ for ␣n - decane ␣ + ␣n - propane ␣ mixture ␣ in ␣ an ␣ Excel spreadsheet ␣ which ␣ will ␣ be ␣ used ␣ if ␣ this ␣ script ␣ is ␣ run . LICENSE : ␣ public ␣ domain , ␣ but ␣ please ␣ reference ␣ paper """ from ␣ __future__ ␣ import ␣ print_function # ␣ Standard ␣ python ␣ modules import ␣ tempfile , ␣ os , ␣ json , ␣ random , ␣ shutil , ␣ sys , ␣ time # ␣ Other ␣ packages import ␣ pandas import ␣ numpy ␣ as ␣ np import ␣ CoolProp , ␣ CoolProp . CoolProp ␣ as ␣ CP from ␣ deap ␣ import ␣ algorithms , ␣ base , ␣ creator , ␣ tools # ␣ Set ␣ the ␣ REFPROP ␣ path ␣ ( if ␣ needed , ␣ mostly ␣ on ␣ linux ␣ where ␣ REFPROP ␣ needs ␣ a ␣ helping ␣ hand ) # jj ␣ = ␣ json . loads ( CP . g e t _ c o n f i g _ a s _ j s o n _ s t r i n g () ) # jj [ ’ A L T E R N A T I V E _ R E F P R O P _ P A T H ’] ␣ = ␣ ’/ home / ihb / fitting / ’ # jj ␣ = ␣ CP . s e t _ c o n f i g _ a s _ j s o n _ s t r i n g ( json . dumps ( jj ) ) # ␣ Open ␣ the ␣ template ␣ file ␣ for ␣ REFPROP with ␣ open ( ’ HMX . BNC . template ’ , ’r ’) ␣ as ␣ fp : ␣ ␣ ␣ ␣ template ␣ = ␣ fp . read () def ␣ pprint (* args ) : ␣ ␣ ␣ ␣ """ ␣ ␣ ␣ ␣ A ␣ pretty - printing ␣ function ␣ that ␣ yields ␣ nicer ␣ output ␣ when ␣ printing ␣ from ␣ a ␣ ␣ ␣ ␣ forked ␣ process ␣ ␣ ␣ ␣ """ ␣ ␣ ␣ ␣ print ( ’␣ ’. join ( str ( a ) ␣ for ␣ a ␣ in ␣ args ) ) def ␣ col lect_binary ( df , ␣ pair ) : ␣ ␣ ␣ ␣ """ ␣ ␣ ␣ ␣ Return ␣ a ␣ subsetted ␣ DataFrame ␣ including ␣ only ␣ the ␣ data ␣ associated ␣ with ␣ the ␣ ␣ ␣ ␣ given ␣ pair ␣ of ␣ fluids ␣ ␣ ␣ ␣ """ ␣ ␣ ␣ ␣ mask ␣ = ␣ (( df [ ’ Ncomp ␣ ( -) ’] ␣ == ␣ 2) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ & ␣ ( df [ ’ fluid [0] ␣ ( -) ’ ]. isin ( pair ) ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ & ␣ ( df [ ’ fluid [1] ␣ ( -) ’ ]. isin ( pair ) ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ & ␣ ( df [ ’x [0] ␣ ( -) ’] ␣ + ␣ df [ ’x [1] ␣ ( -) ’] ␣ >␣ 1e -10) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ & ␣ ( df [ ’x [0] ␣ ( -) ’] ␣ >␣ 1e -10) ␣ & ␣ ( df [ ’x [1] ␣ ( -) ’] ␣ >␣ 1e -10) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ & ␣ (~ np . isnan ( df [ ’p ␣ ( Pa ) ’ ]) ) ␣ & ␣ ( np . isnan ( df [ ’y [0] ␣ ( -) ’ ]) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ | ␣ (( df [ ’y [0] ␣ ( -) ’] ␣ >␣ 0) ␣ & ␣ ( df [ ’y [0] ␣ ( -) ’] ␣ ␣ 1: ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ fluid ␣ = ␣ list ( set ( lib [ ’ fluid [0] ␣ ( -) ’ ]) ) [1] ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ fluid_mask ␣ = ␣ ( lib [ ’ fluid [0] ␣ ( -) ’ ]== fluid ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ # ␣ Columns ␣ with ␣ a ␣ [0] ␣ or ␣ [1] ␣ in ␣ them ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ zeros ␣ = ␣ [ key . replace ( ’0 ’ , ’! @ # $ ’) ␣ for ␣ key ␣ in ␣ lib . keys () ␣ if ␣ ’ [0] ’␣ in ␣ key ] ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ones ␣ = ␣ [ key . replace ( ’1 ’ , ’! @ # $ ’) ␣ for ␣ key ␣ in ␣ lib . keys () ␣ if ␣ ’ [1] ’␣ in ␣ key ] ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ assert ( zeros == ones ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ for ␣ key ␣ in ␣ zeros : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ one ␣ = ␣ key . replace ( ’! @ # $ ’ , ’1 ’) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ zero ␣ = ␣ key . replace ( ’! @ # $ ’ , ’0 ’) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ new_one_chunk ␣ = ␣ list ( lib [ fluid_mask ][ zero ]) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ new_zero_chunk ␣ = ␣ list ( lib [ fluid_mask ][ one ]) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ lib . loc [ fluid_mask , ␣ zero ] ␣ = ␣ new_zero_c hunk ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ lib . loc [ fluid_mask , ␣ one ] ␣ = ␣ new_one_chunk ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ assert ( len ( set ( lib [ ’ fluid [0] ␣ ( -) ’ ]) ) ␣ == ␣ 1) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ return ␣ lib . copy () ␣ ␣ ␣ ␣ else : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ return ␣ lib . copy ()
S202
def ␣ random_subset ( lib , ␣ N ) : ␣ ␣ ␣ ␣ """ ␣ ␣ ␣ ␣ Get ␣ a ␣ random ␣ subset ␣ of ␣ the ␣ data ␣ in ␣ the ␣ dataframe ␣ ␣ ␣ ␣ """ ␣ ␣ ␣ ␣ # random . seed (0) ␣ # ␣ Turn ␣ off ␣ randomness ␣ ␣ ␣ ␣ indices ␣ = ␣ random . sample ( xrange ( len ( lib ) ) ,␣ min (N , ␣ len ( lib ) ) ) ␣ ␣ ␣ ␣ return ␣ lib . iloc [ indices ]. copy () def ␣ write_hmx_bnc ( vle , ␣ params ) : ␣ ␣ ␣ ␣ """ ␣ ␣ ␣ ␣ Write ␣ the ␣ HMX . BNC ␣ file ␣ for ␣ REFPROP , ␣ including ␣ the ␣ binary ␣ interaction ␣ ␣ ␣ ␣ parameters ␣ ␣ ␣ ␣ """ ␣ ␣ ␣ ␣ if ␣ isinstance ( vle , list ) : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ fluids ␣ = ␣ vle ␣ ␣ ␣ ␣ else : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ fluid0 ␣ = ␣ set ( vle [ ’ fluid [0] ␣ ( -) ’ ]) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ fluid1 ␣ = ␣ set ( vle [ ’ fluid [1] ␣ ( -) ’ ]) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ assert ( len ( fluid0 ) ␣ == ␣ 1) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ assert ( len ( fluid1 ) ␣ == ␣ 1) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ fluids ␣ = ␣ fluid0 . pop () ,␣ fluid1 . pop () ␣ ␣ ␣ ␣ # ␣ Create ␣ a ␣ temporary ␣ directory ␣ ␣ ␣ ␣ tmpdir ␣ = ␣ tempfile . mkdtemp () ␣ ␣ ␣ ␣ # ␣ Inputs ␣ to ␣ be ␣ written ␣ into ␣ the ␣ HMX . BNC ␣ file ␣ ␣ ␣ ␣ CAS1 ␣ = ␣ CoolProp . CoolProp . g e t _ f l u i d _ p a r a m _ s t r i n g ( ’ REFPROP :: ’+ fluids [0] , ’ CAS ’) ␣ ␣ ␣ ␣ CAS2 ␣ = ␣ CoolProp . CoolProp . g e t _ f l u i d _ p a r a m _ s t r i n g ( ’ REFPROP :: ’+ fluids [1] , ’ CAS ’) ␣ ␣ ␣ ␣ inputs ␣ = ␣ dict ( ␣ ␣ model ␣ = ␣ ’ KWG ’ , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ Name1 ␣ = ␣ fluids [0] , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ CAS1 ␣ = ␣ CAS1 , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ Name2 ␣ = ␣ fluids [1] , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ CAS2 ␣ = ␣ CAS2 , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ betaT ␣ = ␣ float ( params [0]) , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ gammaT ␣ = ␣ float ( params [1]) , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ betaV ␣ = ␣ params [2] , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ gammaV ␣ = ␣ params [3] , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ Fij ␣ = ␣ params [4] ␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣) ␣ ␣ ␣ ␣ hmx_bnc_path ␣ = ␣ os . path . join ( tmpdir , ␣ ’ HMX . BNC ’) ␣ ␣ ␣ ␣ # ␣ Write ␣ the ␣ custom ␣ HMX . BNC ␣ file ␣ ␣ ␣ ␣ with ␣ open ( hmx_bnc_path , ␣ ’w ’) ␣ as ␣ fp : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ fp . write ( template . format (** inputs ) ) ␣ ␣ ␣ ␣ # ␣ Tell ␣ CoolProp ␣ to ␣ use ␣ this ␣ new ␣ file ␣ for ␣ REFPROP ␣ ␣ ␣ ␣ jj ␣ = ␣ json . loads ( CP . g e t _ c o n f i g _ a s _ j s o n _ s t r i n g () ) ␣ ␣ ␣ ␣ jj [ ’ A L T E R N A T I V E _ R E F P R O P _ H M X _ B N C _ P A T H ’] ␣ = ␣ hmx_bnc_path ␣ ␣ ␣ ␣ jj ␣ = ␣ CP . s e t _ c o n f i g _ a s _ j s o n _ s t r i n g ( json . dumps ( jj ) ) ␣ ␣ ␣ ␣ return ␣ tmpdir def ␣ g e n e r a t e_ v le _ er r or ( vle , ␣ HEOS , ␣ vle_type ␣ = ␣ ’ bubble ’) : ␣ ␣ ␣ ␣ """ ␣ ␣ ␣ ␣ Call ␣ the ␣ VLE ␣ routines ␣ to ␣ generate ␣ the ␣ bubble ␣ pressure , ␣ ␣ ␣ ␣ as ␣ well ␣ as ␣ the ␣ error ␣ in ␣ the ␣ bubble ␣ pressure ␣ as ␣ compared ␣ ␣ ␣ ␣ with ␣ the ␣ experimental ␣ data . ␣ ␣ ␣ ␣ """ ␣ ␣ ␣ ␣ N ␣ = ␣ len ( vle ) ␣ ␣ ␣ ␣ pcalc ␣ = ␣ np . zeros (( N ,1) ) ␣ ␣ ␣ ␣ pgiven ␣ = ␣ np . array ( vle [ ’p ␣ ( Pa ) ’ ]) . reshape (( N ,1) ) ␣ ␣ ␣ ␣ for ␣ i ␣ in ␣ xrange ( N ) : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ if ␣ vle_type ␣ == ␣ ’ bubble ’: ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ HEOS . s e t_ m ol e _f r ac t io n s ([ vle [ ’x [0] ␣ ( -) ’ ]. iloc [ i ] , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ vle [ ’x [1] ␣ ( -) ’ ]. iloc [ i ]]) ␣␣␣␣␣␣␣␣␣␣␣␣Q␣=␣0 ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ elif ␣ vle_type ␣ == ␣ ’ dew ’: ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ HEOS . s e t_ m ol e _f r ac t io n s ([ vle [ ’y [0] ␣ ( -) ’ ]. iloc [ i ] , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ vle [ ’y [1] ␣ ( -) ’ ]. iloc [ i ]]) ␣␣␣␣␣␣␣␣␣␣␣␣Q␣=␣1 ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ else : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ raise ␣ ValueError () ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ try : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ HEOS . update ( CoolProp . QT_INPUTS , ␣Q , ␣ vle [ ’T ␣ ( K90 ) ’ ]. iloc [ i ]) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ pcalc [ i ] ␣ = ␣ HEOS . p () ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ # pprint (i , ␣ vle [ ’ T ␣ ( K90 ) ’]. iloc [ i ] , ␣ HEOS . p () ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ except ␣ ValueError ␣ as ␣ VE : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ # pprint ( VE ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ pcalc [ i ] ␣ = ␣ 1 e20 * vle [ ’p ␣ ( Pa ) ’ ]. iloc [ i ] ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ pass ␣ ␣ ␣ ␣ # ␣ Percentage ␣ relative ␣ error ␣ ␣ ␣ ␣ r ␣ = ␣ ( pgiven ␣ -␣ pcalc ) / pgiven *100 ␣ ␣ ␣ ␣ return ␣r , ␣ pcalc , ␣ pgiven def ␣ ap pl y _b e ta Tga mma T ( df , ␣ betaT , ␣ gammaT , ␣ ofname , ␣ Nloops ␣ = ␣ 100 , ␣ N p o i n t s _ s e l e c t e d ␣ = ␣ 10) : ␣ ␣ ␣ ␣ fluids ␣ = ␣ [ df [ ’ fluid [0] ␣ ( -) ’ ]. iloc [0] , ␣ df [ ’ fluid [1] ␣ ( -) ’ ]. iloc [0]]
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␣ ␣ ␣ ␣ library ␣ = ␣ [] ␣ ␣ ␣ ␣ tic ␣ = ␣ time . time () ␣ ␣ ␣ ␣ for ␣j , ␣ ( _betaT , ␣ _gammaT ) ␣ in ␣ enumerate ( zip ( betaT , ␣ gammaT ) ) : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ runt1 ␣ = ␣ time . time () ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ tmpdir ␣ = ␣ write_hmx_bnc ( df , ␣ [ _betaT , ␣ _gammaT , ␣ 1 , ␣ 1 , ␣ 0]) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ HEOS ␣ = ␣ CoolProp . AbstractState ( " REFPROP " ,␣ " & " . join ( fluids ) ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ Nfail ␣ = ␣ 0 ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ data ␣ = ␣ [] ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ for ␣ dummy_counter ␣ in ␣ xrange ( Nloops ) : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ # ␣ r ␣ is ␣ a ␣ vector ␣ of ␣ percentage ␣ relative ␣ errors ␣ in ␣ p ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣r , ␣ pcalc , ␣ pgiven ␣ = ␣ g en e ra t e_ v l e _ e r r or ( random_subset ( df , ␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣␣ Npoints_selected ), ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ HEOS , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ’ bubble ’) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ Nfail ␣ += ␣ sum ( np . abs ( r ) ␣ >␣ 1 e6 ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ err ␣ = ␣ np . sqrt ( np . sum ( r **2) ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ data . append ( err ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ # ␣ Fraction ␣ (0 ,1) ␣ of ␣ the ␣ runs ␣ that ␣ do ␣ not ␣ succeed ␣ and ␣ error ␣ out ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ # ␣ We ␣ want ␣ to ␣ be ␣ able ␣ to ␣ " correct " ␣ the ␣ objective ␣ function ␣ by ␣ applying ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ # ␣ a ␣ penalty ␣ function ␣ if ␣ runs ␣ fail ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ fail_fraction ␣ = ␣ float ( Nfail ) / float ( Nloops * N p o i n t s _ s e l e c t e d ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ # ␣ pprint ( ’ fail_fraction : ’ , fail_fraction ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ data ␣ = ␣ np . array ( sorted ( data ) ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ err_Nbest ␣ = ␣ np . mean ( data [0:5]) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ err_Nbestmedian ␣ = ␣ np . median ( data [0:5]) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ err_ok ␣ = ␣ data [( data ␣ ␣ 0: ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ err_okmean ␣ = ␣ np . mean ( err_ok ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ err_okmedian ␣ = ␣ np . median ( err_ok ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ err_okrsse ␣ = ␣ np . sqrt ( np . sum ( err_ok **2) / len ( err_ok ) ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ else : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ err_okmean ␣ = ␣ 1 e99 ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ err_okmedian ␣ = ␣ 1 e99 ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ err_okrsse ␣ = ␣ 1 e99 ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ loop_elapsed ␣ = ␣ time . time () ␣ -␣ runt1 ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ pprint ( ’ fluid1 , ␣ fluid2 , ␣ betaT , ␣ gammaT , ␣ err_okmean , ␣ err_okrsse : ’ , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ fluids , ␣ float ( _betaT ) ,␣ float ( _gammaT ) ,␣ err_okmean , ␣ err_okrsse ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ library . append (( err_Nbest , ␣ err_Nbestmedian , ␣ err_okmean , ␣ err_okmedian , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ err_okrsse , ␣ float ( _betaT ) ,␣ float ( _gammaT ) , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ loop_elapsed ) ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ if ␣ ( time . time () ␣ -␣ tic ) ␣ >␣ 7200: ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ with ␣ open ( ofname , ’w ’) ␣ as ␣ fp : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ fp . write ( ’ TIMEOUT ’) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ # ␣ Clean ␣ up ␣ after ␣ ourselves ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ shutil . rmtree ( tmpdir ) ␣ ␣ ␣ ␣ ( err_Nbest , ␣ err_Nbestmedian , ␣ err_okmean , ␣ err_okmedian , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ err_okrsse , ␣ betaT , ␣ gammaT , ␣ loop_elapsed ) ␣ = ␣ zip (* library ) ␣ ␣ ␣ ␣ if ␣ ofname : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ pandas . DataFrame ( dict ( err ␣ = ␣ err_Nbest , ␣ err _N b es tm e di a n ␣ = ␣ err_Nbestmedian , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ err_okmean ␣ = ␣ err_okmean , ␣ err_okmedian ␣ = ␣ err_okmedian , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ betaT ␣ = ␣ betaT , ␣ gammaT ␣ = ␣ gammaT , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ loop_elapsed ␣ = ␣ loop_elapsed ) ) . to_csv ( ofname ) ␣ ␣ ␣ ␣ toc ␣ = ␣ time . time () ␣ ␣ ␣ ␣ # ␣ The ␣ penalty ␣ factor ␣ -␣ F ␣ = ␣ 10^( pe nalty_ factor * fail_fraction ) ␣ ␣ ␣ ␣ pen alty_factor ␣ = ␣ 3 ␣ ␣ ␣ ␣ # ␣ If ␣ no ␣ results ␣ are ␣ ok , ␣ the ␣ mean ␣ of ␣ an ␣ empty ␣ array ␣ is ␣ NAN , ␣ so ␣ just ␣ return ␣ a ␣ huge ␣ number ␣ ␣ ␣ ␣ if ␣ np . isnan ( err_okmean [0]) : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ return ␣ 1 e10 ␣ ␣ ␣ ␣ else : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ if ␣ len ( betaT ) ␣ == ␣ 1: ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ return ␣ err_okmean [0]*10**( penalty_factor * fail_fraction ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ else : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ return ␣ err_okmean *10**( pe nalty_factor * fail_fraction ) def ␣ eaSimple ( population , ␣ toolbox , ␣ cxpb , ␣ mutpb , ␣ ngen , ␣ stats = None , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ halloffame = None , ␣ verbose = True , ␣ timeout ␣ = ␣ 3600) : ␣ ␣ ␣ ␣ """ This ␣ algorithm ␣ reproduce ␣ the ␣ simplest ␣ evolutionary ␣ algorithm ␣ as ␣ ␣ ␣ ␣ presented ␣ in ␣ chapter ␣ 7 ␣ of ␣ [ Back2000 ] _ . ␣ ␣ ␣ ␣ : param ␣ population : ␣ A ␣ list ␣ of ␣ individuals . ␣ ␣ ␣ ␣ : param ␣ toolbox : ␣ A ␣ : class : ‘~ deap . base . Toolbox ‘ ␣ that ␣ contains ␣ the ␣ evolution ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ operators . ␣ ␣ ␣ ␣ : param ␣ cxpb : ␣ The ␣ probability ␣ of ␣ mating ␣ two ␣ individuals . ␣ ␣ ␣ ␣ : param ␣ mutpb : ␣ The ␣ probability ␣ of ␣ mutating ␣ an ␣ individual . ␣ ␣ ␣ ␣ : param ␣ ngen : ␣ The ␣ number ␣ of ␣ generation . ␣ ␣ ␣ ␣ : param ␣ stats : ␣ A ␣ : class : ‘~ deap . tools . Statistics ‘ ␣ object ␣ that ␣ is ␣ updated ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ inplace , ␣ optional . ␣ ␣ ␣ ␣ : param ␣ halloffame : ␣ A ␣ : class : ‘~ deap . tools . HallOfFame ‘ ␣ object ␣ that ␣ will
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␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ contain ␣ the ␣ best ␣ individuals , ␣ optional . ␣ ␣ ␣ ␣ : param ␣ verbose : ␣ Whether ␣ or ␣ not ␣ to ␣ log ␣ the ␣ statistics . ␣ ␣ ␣ ␣ : returns : ␣ The ␣ final ␣ population ␣ ␣ ␣ ␣ : returns : ␣ A ␣ class : ‘~ deap . tools . Logbook ‘ ␣ with ␣ the ␣ statistics ␣ of ␣ the ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ evolution ␣ ␣ ␣ ␣ The ␣ algorithm ␣ takes ␣ in ␣ a ␣ population ␣ and ␣ evolves ␣ it ␣ in ␣ place ␣ using ␣ the ␣ ␣ ␣ ␣ : meth : ‘ varAnd ‘ ␣ method . ␣ It ␣ returns ␣ the ␣ optimized ␣ population ␣ and ␣ a ␣ ␣ ␣ ␣ : class : ‘~ deap . tools . Logbook ‘ ␣ with ␣ the ␣ statistics ␣ of ␣ the ␣ evolution . ␣ The ␣ ␣ ␣ ␣ logbook ␣ will ␣ contain ␣ the ␣ generation ␣ number , ␣ the ␣ number ␣ of ␣ evalutions ␣ for ␣ ␣ ␣ ␣ each ␣ generation ␣ and ␣ the ␣ statistics ␣ if ␣ a ␣ : class : ‘~ deap . tools . Statistics ‘ ␣ is ␣ ␣ ␣ ␣ given ␣ as ␣ argument . ␣ The ␣ * cxpb * ␣ and ␣ * mutpb * ␣ arguments ␣ are ␣ passed ␣ to ␣ the ␣ ␣ ␣ ␣ : func : ‘ varAnd ‘ ␣ function . ␣ The ␣ pseudocode ␣ goes ␣ as ␣ follow ␣ :: ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ evaluate ( population ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ for ␣ g ␣ in ␣ range ( ngen ) : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ population ␣ = ␣ select ( population , ␣ len ( population ) ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ offspring ␣ = ␣ varAnd ( population , ␣ toolbox , ␣ cxpb , ␣ mutpb ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ evaluate ( offspring ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ population ␣ = ␣ offspring ␣ ␣ ␣ ␣ As ␣ stated ␣ in ␣ the ␣ pseudocode ␣ above , ␣ the ␣ algorithm ␣ goes ␣ as ␣ follow . ␣ First , ␣ it ␣ ␣ ␣ ␣ evaluates ␣ the ␣ individuals ␣ with ␣ an ␣ invalid ␣ fitness . ␣ Second , ␣ it ␣ enters ␣ the ␣ ␣ ␣ ␣ generational ␣ loop ␣ where ␣ the ␣ selection ␣ procedure ␣ is ␣ applied ␣ to ␣ entirely ␣ ␣ ␣ ␣ replace ␣ the ␣ parental ␣ population . ␣ The ␣ 1:1 ␣ replacement ␣ ratio ␣ of ␣ this ␣ ␣ ␣ ␣ algorithm ␣ ** requires ** ␣ the ␣ selection ␣ procedure ␣ to ␣ be ␣ stochastic ␣ and ␣ to ␣ ␣ ␣ ␣ select ␣ multiple ␣ times ␣ the ␣ same ␣ individual , ␣ for ␣ example , ␣ ␣ ␣ ␣ : func : ‘~ deap . tools . selTournament ‘ ␣ and ␣ : func : ‘~ deap . tools . selRoulette ‘. ␣ ␣ ␣ ␣ Third , ␣ it ␣ applies ␣ the ␣ : func : ‘ varAnd ‘ ␣ function ␣ to ␣ produce ␣ the ␣ next ␣ ␣ ␣ ␣ generation ␣ population . ␣ Fourth , ␣ it ␣ evaluates ␣ the ␣ new ␣ individuals ␣ and ␣ ␣ ␣ ␣ compute ␣ the ␣ statistics ␣ on ␣ this ␣ population . ␣ Finally , ␣ when ␣ * ngen * ␣ ␣ ␣ ␣ generations ␣ are ␣ done , ␣ the ␣ algorithm ␣ returns ␣ a ␣ tuple ␣ with ␣ the ␣ final ␣ ␣ ␣ ␣ population ␣ and ␣ a ␣ : class : ‘~ deap . tools . Logbook ‘ ␣ of ␣ the ␣ evolution . ␣ ␣ ␣ ␣ .. ␣ note :: ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ Using ␣ a ␣ non - stochastic ␣ selection ␣ method ␣ will ␣ result ␣ in ␣ no ␣ selection ␣ as ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ the ␣ operator ␣ selects ␣ * n * ␣ individuals ␣ from ␣ a ␣ pool ␣ of ␣ * n *. ␣ ␣ ␣ ␣ This ␣ function ␣ expects ␣ the ␣ : meth : ‘ toolbox . mate ‘ , ␣ : meth : ‘ toolbox . mutate ‘ , ␣ ␣ ␣ ␣ : meth : ‘ toolbox . select ‘ ␣ and ␣ : meth : ‘ toolbox . evaluate ‘ ␣ aliases ␣ to ␣ be ␣ ␣ ␣ ␣ registered ␣ in ␣ the ␣ toolbox . ␣ ␣ ␣ ␣ .. ␣ [ Back2000 ] ␣ Back , ␣ Fogel ␣ and ␣ Michalewicz , ␣ " Evolutionary ␣ Computation ␣ 1 ␣ : ␣ ␣ ␣ ␣ ␣ ␣ ␣ Basic ␣ Algorithms ␣ and ␣ Operators " , ␣ 2000. ␣ ␣ ␣ ␣ NOTE : ␣ This ␣ algorithm ␣ was ␣ taken ␣ from ␣ DEAP , ␣ and ␣ modified ␣ by ␣ Ian ␣ Bell ␣ ␣ ␣ ␣ in ␣ order ␣ to ␣ add ␣ a ␣ timeout ␣ ␣ ␣ ␣ """ ␣ ␣ ␣ ␣ tic ␣ = ␣ time . time () ␣ ␣ ␣ ␣ logbook ␣ = ␣ tools . Logbook () ␣ ␣ ␣ ␣ logbook . header ␣ = ␣ [ ’ gen ’ ,␣ ’ nevals ’] ␣ + ␣ ( stats . fields ␣ if ␣ stats ␣ else ␣ []) ␣ ␣ ␣ ␣ # ␣ Evaluate ␣ the ␣ individuals ␣ with ␣ an ␣ invalid ␣ fitness ␣ ␣ ␣ ␣ invalid_ind ␣ = ␣ [ ind ␣ for ␣ ind ␣ in ␣ population ␣ if ␣ not ␣ ind . fitness . valid ] ␣ ␣ ␣ ␣ fitnesses ␣ = ␣ toolbox . map ( toolbox . evaluate , ␣ invalid_ind ) ␣ ␣ ␣ ␣ for ␣ ind , ␣ fit ␣ in ␣ zip ( invalid_ind , ␣ fitnesses ) : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ind . fitness . values ␣ = ␣ fit ␣ ␣ ␣ ␣ if ␣ halloffame ␣ is ␣ not ␣ None : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ halloffame . update ( population ) ␣ ␣ ␣ ␣ record ␣ = ␣ stats . compile ( population ) ␣ if ␣ stats ␣ else ␣ {} ␣ ␣ ␣ ␣ logbook . record ( gen =0 , ␣ nevals = len ( invalid_ind ) ,␣ ** record ) ␣ ␣ ␣ ␣ if ␣ verbose : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ pprint ( logbook . stream ) ␣ ␣ ␣ ␣ # ␣ Begin ␣ the ␣ generational ␣ process ␣ ␣ ␣ ␣ for ␣ gen ␣ in ␣ range (1 , ␣ ngen ␣ + ␣ 1) : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ # ␣ Select ␣ the ␣ next ␣ generation ␣ individuals ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ offspring ␣ = ␣ toolbox . select ( population , ␣ len ( population ) ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ # ␣ Vary ␣ the ␣ pool ␣ of ␣ individuals ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ offspring ␣ = ␣ algorithms . varAnd ( offspring , ␣ toolbox , ␣ cxpb , ␣ mutpb ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ # ␣ Evaluate ␣ the ␣ individuals ␣ with ␣ an ␣ invalid ␣ fitness ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ invalid_ind ␣ = ␣ [ ind ␣ for ␣ ind ␣ in ␣ offspring ␣ if ␣ not ␣ ind . fitness . valid ] ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ fitnesses ␣ = ␣ toolbox . map ( toolbox . evaluate , ␣ invalid_ind ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ for ␣ ind , ␣ fit ␣ in ␣ zip ( invalid_ind , ␣ fitnesses ) : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ind . fitness . values ␣ = ␣ fit ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ # ␣ Update ␣ the ␣ hall ␣ of ␣ fame ␣ with ␣ the ␣ generated ␣ individuals ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ if ␣ halloffame ␣ is ␣ not ␣ None : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ halloffame . update ( offspring ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ # ␣ Replace ␣ the ␣ current ␣ population ␣ by ␣ the ␣ offspring ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ population [:] ␣ = ␣ offspring ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ # ␣ Append ␣ the ␣ current ␣ generation ␣ statistics ␣ to ␣ the ␣ logbook ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ record ␣ = ␣ stats . compile ( population ) ␣ if ␣ stats ␣ else ␣ {} ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ logbook . record ( gen = gen , ␣ nevals = len ( invalid_ind ) ,␣ ** record ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ if ␣ verbose : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ pprint ( logbook . stream ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ if ␣ time . time () ␣ -␣ tic ␣ >␣ timeout : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ pprint ( ’ TIMEOUT : ’ ,␣ time . time () ␣ -␣ tic , ␣ ’s ␣ elapsed ’) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ return ␣ population , ␣ logbook
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␣ ␣ ␣ ␣ return ␣ population , ␣ logbook def ␣ dea p_optimizer ( df , ␣ prefix ␣ = ␣ ’ ’ ,␣ gammaT0 ␣ = ␣ None ) : ␣ ␣ ␣ ␣ """ ␣ ␣ ␣ ␣ This ␣ function ␣ actually ␣ calls ␣ deap ␣ and ␣ does ␣ the ␣ optimization , ␣ arriving ␣ at ␣ ␣ ␣ ␣ the ␣ optimal ␣ values ␣ for ␣ beta_T ␣ and ␣ gamma_T ␣ ␣ ␣ ␣ """ ␣ ␣ ␣ ␣ tic ␣ = ␣ time . time () ␣ ␣ ␣ ␣ fluids ␣ = ␣ df [ ’ fluid [0] ␣ ( -) ’ ]. iloc [0] , ␣ df [ ’ fluid [1] ␣ ( -) ’ ]. iloc [0] ␣ ␣ ␣ ␣ # ␣ weight ␣ is ␣ -1 ␣ because ␣ we ␣ want ␣ to ␣ minimize ␣ the ␣ error ␣ ␣ ␣ ␣ creator . create ( " FitnessMax " ,␣ base . Fitness , ␣ weights =( -1.0 ,) ) ␣ ␣ ␣ ␣ creator . create ( " Individual " ,␣ list , ␣ fitness = creator . FitnessMax ) ␣ ␣ ␣ ␣ x1 ␣ = ␣ list ( set ( df [ ’x [0] ␣ ( -) ’ ]) ) ␣ ␣ ␣ ␣ T ␣ = ␣ list ( set ( df [ ’T ␣ ( K90 ) ’ ]) ) ␣ ␣ ␣ ␣ if ␣ ( len ( x1 ) ␣ == ␣ 1 ␣ or ␣ len ( T ) ␣ == ␣ 1 ␣ or ␣ np . min ( x1 ) ␣ >␣ 0.99* np . max ( x1 ) ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ or ␣ np . min ( T ) ␣ >␣ 0.99* np . max ( T ) ) : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ only_fit_gammaT ␣ = ␣ True ␣ ␣ ␣ ␣ else : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ only_fit_gammaT ␣ = ␣ False ␣ ␣ ␣ ␣ pprint ( ’ number ␣ of ␣ unique ␣ T : ’ ,␣ len ( T ) ,␣ ’ number ␣ of ␣ unique ␣ x : ’ ,␣ len ( x1 ) , ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ’ only_fit_gammaT : ’ ,␣ only_f it_ga mma T ) ␣ ␣ ␣ ␣ def ␣ feasible ( params ) : ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ """ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ Feasibility ␣ function ␣ for ␣ the ␣ individual . ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ Returns ␣ True ␣ if ␣ feasible , ␣ False ␣ otherwise . ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ """ ␣ ␣ ␣ ␣ ␣ ␣ ␣ ␣ if ␣ len ( params ) ␣ == ␣ 1 ␣ and ␣ 0.5 ␣
