Advanced Materials/Structures - University of Washington

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Center for Intelligent Materials and Systems (CIMS). (Profs. Minoru Taya and ... • UW: Center for Advanced Materials in Transport Aircraft. Structures (AMTAS).
Advanced Materials 1. FAA Center of Excellence: AMTAS (Prof. Mark Tuttle) 2. Center for Intelligent Materials and Systems (CIMS) (Profs. Minoru Taya and Chunye Xu) • Actuator and sensor materials • Electro-chromic window technology • MURI 2006 Project on Energy Harvesting and Storage System 3. Fracture Mechanics and Fatigue (Prof. M. Ramulu) 4. Multifunctional Materials (Prof. Jiangyu Li) 5. Multifunctional composite (Prof. Jae Chung)

FAA Center of Excellence for Advanced Materials in Transport Aircraft Structures (AMTAS) • Joint Advanced Materials and Structures (JAMS) Center

announced by FAA in Dec ‘03 with two co-lead universities: •UW: Center for Advanced Materials in Transport Aircraft Structures (AMTAS) •WiSU: Center of Excellence for Composites and Advanced Materials (CECAM)

•UW/AMTAS Administrative Personnel: •Mark Tuttle, Director, ME Department •Kuen Lin, Co-Director, A&A Department •Ellen Barker, Assistant to Director, ME Department

• Detailed website:

http://depts.washington.edu/amtas/

AMTAS Participants Academic Partners • University of Washington (UW; ME, AA, MSE Depts) • Washington State University (WSU) • Oregon State University (OSU) • Edmonds Community College (EdCC) Eleven industrial partners (large & small), all with significant presence within the greater Puget Sound Region. Most active and engaged is Boeing-Commercial

AMTAS Funding Levels Summary of total funding levels to date (8/2006): •

FAA Cash:

$1,257k



AMTAS Match: $1,230k



Total:

$2,487k

UW: $958k/WSU: $104k/EdCC: $195k Cash: Boeing: $200k UW: $200k In-Kind: Boeing: $811k UW:$573k/WSU: $27k/ EdCC: $211k Heaton: $10k (UW:$2k/EdCC: $8k) Intec: $9k (UW) Recent mat’l donations from Cytec and Toray not yet included)

AMTAS – Future Initial 3-yr Phase I funding expires Sept ’07. Phase II funding likely Intend to evolve AMTAS into regional center for composite-advanced mat’ls and manufacturing, supporting multiple industries (aerospace, automotive, trucking, marine, energy, bio, etc) Possible links to (or collaborations with) Advanced Materials Center being developed by Alex Jen and announced Spring ’06 not yet explored International collaborations evolving (e.g., with U. of Manchester) Challenges: • • • •

Well-established competitors (within US and abroad) receive substantial support from federal/national/local governments UW lab infrastructure/facilities non-competitive Must expand funding base beyond FAA and Boeing Research directions dictated by FAA - frustrating

Center for Intelligent Materials and Systems (CIMS) •

Established in 2000.



Participating faculty: Taya (ME), Xu(ME) and Kuga(EE).



Annual research expenditure: increasing from $500K(2000) to $1.2M(2005).



Researchers supported annualy(2005): one research faculty, 5 post docs, 5 RA students.



Funding sources: NSF, AFOSR, ONR, Darpa, Army, Boeing, Honda, Noastec Foundation, Hitachi Powdered Metals, TGIF.



Objectives: Research on design, synthesis of active and sensing materials and their devices.



CIMS researchers are ranked among top 1-5 inventors of the year in UWOTT report in 2004 and 2005.



New research starting on May 2006: AFOSR- MURI on Energy Harvesting and Storage for Future AF vehicles. $6M budget for five years (2006-2011)



Threat: Lab space currently in Fluke Hall is not semi-permanent, threatened to move out !!! UW - Center for Intelligent Materials and Systems

New Actuator Material : shape memory alloy (SMA) and Ferromagnetic SMA Fe

Fe-Pd spring

Fe-Pd

5 cm

H field on

5 mm

Hybrid magnet (b) 1A

(a) 0A

3D-phase diagram

Fie

ld ( H)

austenite phase Temperature (T)

Young’s modulus (GPa)

120

Stress martensite phase (σ)

Ma gn e tic

(c) 3A

80

martensite phase

austenite phase

40

0 -50

Ms 0

50

100

Temperature (°C)

UW - Center for Intelligent Materials and Systems

150

Applications for SMA / FSMA Bio-inspired flight FSMA composite synthetic jet actuator

High temperature SMA actuator/sensor FSMA composite linear inchworm actuator High energy absorbing SMA foam

UW - Center for Intelligent Materials and Systems

UW design of Synthetic Jet Actuator (SJA) for control of unstable low Mach number flight

Jet slots Wing box SJA cylindrical package FSMA composite diaphragm

electromagnet

slot

Flow Velocity (m/s)

250 200 150 100 50 50

100

150

200

250

Frequency (Hz)

UW - Center for Intelligent Materials and Systems

300

Flapping motions of a FSMA composite wing for MAV a

b

10 mm

Power input: 5V, 0.9A Flapping frequency: 19Hz Flapping angle = 115°

d

30mm

31mm NiTi/polymer wing

c

e

57mm

NiTi wing frame: thickness = 0.3mm width ranging from 2.2mm to 0.5mm (depending on location) UW - Center for Intelligent Materials and Systems

High energy absorbing SMA for use in protecting human against blast loading and collision

Buckling load (kN)

Buckling load (kN)

10 8 30mm 34mm 60mm 120mm 150mm

6 4 2

30mm 60mm 120mm 150mm

8 6 4 2 0

0 0

5

10

Displacement (mm)

15

0

5

10

15

Displacement (mm)

UW - Center for Intelligent Materials and Systems

High energy absorbing SMA foam Specimen length (mm)

(a)

300

250

5000 Pc2

(b)

With side force

3000

Without side force Pc1

2000

Side constrain

σys=131MPa, E=205GPa t=2mm, W=20mm

1000

Open : elastic buckling (Euler’s estimation) Solid : plastic buckling (Johnson’s estimation) 0 0

100

200

300

400

Side force F required for buckling mode change (N) 1200 13% porosity NiT i

1000

Stress (MPa)

Buckling load (N)

4000

180 170 160

200

Solid NiT i

800 600 400 200

1mm

0 0

1

2

3

4

5

Strain (%)

UW - Center for Intelligent Materials and Systems

6

Electrochromic Windows

• Enlarge size • Scale down

ECW of aircraft

welding shields

http://www.sage-ec.com/pages

Xu, C., Kong, X., Liu, L. Su, F., Kim, S. and Taya, M., “Smart Glass Based on Electrochromic Polymers” Smart Structures and Materials, Proc. SPIE, Vol. 6168, pp.61681N, 2006

UW - Center for Intelligent Materials and Systems

ECWs in Various Scales

1x1, 3x3, 6x6, 12x12 inch

12 x 20 inch (30.5 x 50.8 cm) Xu, C., Liu, L., Legenski, S. E., Ning, D., and Taya, M., “Switchable Window Based on Electrochromic (EC) Polymers”, Journal of Materials Research, Vol.19, No.7, pp. 2072-2080, 2004

UW - Center for Intelligent Materials and Systems

Electroactive polymer for Bio-sensors and actuators F2 C

F2 C

F C

F2 C

x

Ionic polymer F2 C

F2 C

F2 C

y

(OCF2CF) O

F C

m

F2 C

n

COOH

x

n

O CF 2 CF

Nafion (Dupont)

O CF 2 CF 2 m

CF 3

CF3

SO 3 H

Flemion (Asahi Glass)

3x3 array actuator

Compliant Electrode key technology for durable use Gold plating by impregnation reduction Cross section 16 μm

Scheme

2s

5s

2s

5s

0.7s

2s

0s 180 micron thick

0s

Fish fin

125 micron thick

0s 50 micron thick

Le Guilly, M., Xu, C., Cheng, V., Taya, M., Lucien Opperman and Yasuo Kuga, “Flemion Based Actuator for Mechanically Alkali metals, alkaline earth metals, alkyl ammonium Controlled Microwave Switch”, Smart Structures and Materials, Proc. SPIE, Vol. 5051, pp.362-371, 2003

Solvent and counter ion

UW - Center for Intelligent Materials and Systems

MURI on Energy Harvesting and Storage Systems (EHSS) Period: May/2006-May/2011 Funding: $6M Funding Agency, AFOSR Researchers: Minoru Taya, PI of the entire team UW: Chunye Xu (ME), G. Cao(MSE), S. Jenekhe(ChemE), Y. Kuga(EE) CU: M. Dunn, K. Maute, R. Yang UCLA : T. Hahn, S Ju VPI : D. Inman Collaborating Industry, Boeing, etc.

Goal : To develop a set of energy harvesting materials and systems for future AF vehicles April 7, 2006 UW - Center for Intelligent Materials and Systems

Multi-scale approach to design of energy harvesting aircraft systems

+

b. component level Polymer battery cells Polymer solar cells antenna system under the wing with TE

thermo-electric (TE)

antenna

PBC

TEC

PCB antenna

Binder polymer d. nano-composite level n-type TE

Power amplifier p-type TE TEC

Porous Cu collector

Thermal interface material (TIM) UW - Center for Intelligent Materials and Systems

nano-scale

Carbon nano tube network

TEC

micro-scale

Heat spreader

c. material level Polymer solar cell Polymer matrix composite (PMC) cell Battery package layer (BPL) Cathode TIM anode separator BPL PMC

skin

macro-scale

a. system level Polymer solar cells (PSC)

Multifunctional Materials Laboratory PI: Jiangyu Li

Postdoc: L. Zhang; Graduate Students: Q.G. Du, Y.F. Ma, L.J. Li, B. Walsh

Sponsors: NSF/DMI/DMR, ONR/UNL, ACS PRF, UW RRF Experiment

Theory

Computation

Nanostructure Formation

Microcompounding Multi-scale Theory of Ferroelectrics

• Mission: to Analyze, Design & Optimize

Nanoimprinting

Multifunctional Materials/Structures • Systems: Ferroelectrics, Magnetics, Multiferroics, EAP, Nanocomposites… • Applications: Sensing, Actuation, Energy Harvesting/Storage, Information Processing, etc

Domain Configuration

Key Publications in Nature Materials, Physical Review Letters, Applied Physics Letters, JMPS

Multifunctional carbon nanotube composite Chung; nanomanufacturing lab. Objective: multifunctional carbon nanotube composite for extreme specific-strength, toughness, high thermal stability, excellent mechanical damping properties and high electrical conductivities. Carbon nanotube weaver to fabricate CNT texture by capillary reaction with dielectrophoresis.