USES OF SUBSTANCE: RemOx® S ISCO Reagent is an oxidant recommended
... RemOx® S ISCO Reagent , if swallowed, may cause severe burns to mucous ...
HydroPro MSDS Material Safety Data Sheet The following information pertains the to the chemicals used in the HydroPro system and process provided by Remediation Express. These attached MSDS reports are provided by either our chemical suppliers or by the U.S. OSHA Hazard Communication Standard. The HydroPro system and process will utilize any of the following chemicals depending on the pre-treatment condition of the soil found on the site. The chemicals that are used in the HydroPro system and process will have zero negative effect on the surrounding environment because of the dilution rate used in the HydroPro.
993 South Lake Summit Road • Saluda, NC 28773 • 828.290.8961 (office) • 828.696.9063 (fax)
RemOx®S ISCO Reagent EC- SAFETY DATA SHEET according to EC directive 2001/58/EC MATERIAL SAFETY DATA SHEET Page 1 of 9
Section 1 Chemical Product and Company Identification PRODUCT NAME: RemOx® S ISCO Reagent TRADE NAME: RemOx® S ISCO Reagent
Revised Date: January 2006
USES OF SUBSTANCE: RemOx® S ISCO Reagent is an oxidant recommended for applications that require a strong oxidant. COMPANY NAME (Europe): COMPANY ADDRESS: Carus Nalon S.L. CARUS NALON S.L. Barrio Nalon, s/n 33100 Trubia-Oviedo Espana, Spain INFORMATION: (34) 985-785-513 (34) 985-785-513 www.caruseurope.com (Web) COMPANY NAME (US):
[email protected] (Email) CARUS CHEMICAL COMPANY EMERGENCY TELEPHONE: (34) 985-785-513 COMPANY ADDRESS:
315 Fifth Street Peru, IL 61354, USA INFORMATION: (815)-223-1500 www.caruschem.com (Web)
[email protected] (Email) EMERGENCY TELEPHONE: (800) 435 –6856 (USA) (800) 424-9300 (CHEMTREC, USA) (815-223-1500 (Other countries)
Section 2
Hazardous Ingredients
MATERIAL OR COMPONENT
CAS NO.
EINECS
HAZARD DATA
Potassium Permanganate
7722-64-7
231-760-3
PEL/C 5 mg Mn per cubic meter of air TLV-TWA
0.2 mg Mn per cubic meter of air
HAZARD SYMBOLS:
RISK PHRASES: 8 Contact with combustibles may case fire. 22 Harmful if swallowed. 50/53 Very toxic to aquatic organisms, may cause long-term effects in the aquatic environment. SAFETY PHRASES: 60 This material and its container must be disposed of as hazardous waste. 61 Avoid releases to the environment. Refer to special instructions / Safety data sheet.
RemOx®S ISCO Reagent EC- SAFETY DATA SHEET according to EC directive 2001/58/EC MATERIAL SAFETY DATA SHEET Page 2 of 9
Section 3
Hazards Identification
1.
EYE CONTACT RemOx® S ISCO Reagent is damaging to eye tissue on contact. It may cause severe burns that result in damage to the eye.
2.
SKIN CONTACT Contact of solutions at room temperature may be irritating to the skin, leaving brown stains. Concentrated solutions at elevated temperature and crystals are damaging to the skin.
3.
INHALATION Acute inhalation toxicity data are not available. However, airborne concentrations of RemOx® S ISCO Reagent the form of dust or mist may cause damage to the respiratory tract.
4.
INGESTION RemOx® S ISCO Reagent , if swallowed, may cause severe burns to mucous membranes of the mouth, throat, esophagus, and stomach.
Section 4
First Aid Measures
1. EYES Immediately flush eyes with large amounts of water for at least 15 minutes holding lids apart to ensure flushing of the entire surface. Do not attempt to neutralize chemically. Seek medical attention immediately. Note to physician: Soluble decomposition products are alkaline. Insoluble decomposition product is brown manganese dioxide. 2. SKIN Immediately wash contaminated areas with water. Remove contaminated clothing and footwear. Wash clothing and decontaminate footwear before reuse. Seek medical attention immediately if irritation is severe or persistent. 3. INHALATION Remove person from contaminated area to fresh air. If breathing has stopped, resuscitate and administer oxygen if readily available. Seek medical attention immediately. 4. INGESTION Never give anything by mouth to an unconscious or convulsing person. If person is conscious, give large quantities of water. Seek medical attention immediately.
RemOx®S ISCO Reagent EC- SAFETY DATA SHEET according to EC directive 2001/58/EC MATERIAL SAFETY DATA SHEET Page 3 of 9
Section 5
Fire Fighting Measures
NFPA* HAZARD SIGNS Health Hazard 1 = Flammability Hazard Reactivity Hazard
0 0
= =
Special Hazard
OX =
Materials which under fire conditions would give off irritating combustion products. (less than 1 hour exposure) Materials that on the skin could cause irritation. Materials that will not burn. Materials which in themselves are normally stable, even under fire exposure conditions, and which are not reactive with water. Oxidizer
*National Fire Protection Association 704 (USA) FIRST RESPONDERS:
Wear protective gloves, boots, goggles, and respirator. In case of fire, wear positive pressure breathing apparatus. Approach incident with caution. FLASHPOINT None FLAMMABLE OR EXPLOSIVE LIMITS Lower: Nonflammable Upper: Nonflammable EXTINGUISHING MEDIA Use large quantities of water. Water will turn pink to purple if in contact with RemOx® S ISCO Reagent. Dike to contain. Do not use dry chemicals, CO2 Halon® or foams. SPECIAL FIREFIGHTING PROCEDURES If material is involved in fire, flood with water. Cool all affected containers with large quantities of water. Apply water from as far a distance as possible. Wear self-contained breathing apparatus and full protective clothing. UNUSUAL FIRE AND EXPLOSION Powerful oxidizing material. May decompose spontaneously if exposed to heat (150°C / 302°F). May be explosive in contact with certain other chemicals (Section 10). May react violently with finely divided and readily oxidizable substances. Increases burning rate of combustible material.
Section 6 Accidental Release Measures PERSONAL PRECAUTIONS: Ensure adequate ventilation. Avoid dust formation. Avoid inhalation and contact with eyes and skin. Personnel should wear protective clothing suitable for the task. Remove all ignition sources and incompatible materials before attempting clean up. ENVIRONMENTAL PRECAUTIONS: Do not flush into sanitary sewer system or surface water. If accidental release into the environment occurs, inform the responsible authorities. Keep the product away from drains, sewers, surface and ground water and soil. STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Clean up spills immediately by sweeping or shoveling up the material. Do not return spilled material to the original container – transfer to a clean metal drum. To clean contaminated surfaces or floors, flush with abundant quantities of water into sewer, if permitted by federal, state, and local regulations - if not, collect water and treat chemically (Section 13).
RemOx®S ISCO Reagent EC- SAFETY DATA SHEET according to EC directive 2001/58/EC MATERIAL SAFETY DATA SHEET Page 4 of 9
Section 7 Handling and Storage WORK/HYGIENIC PRACTICES Wash hands thoroughly with soap and water after handling RemOx® S ISCO Reagent. Do not eat, drink or smoke when working with RemOx® S ISCO Reagent. Wear proper protective equipment. Remove clothing, if it becomes contaminated. VENTILATION REQUIREMETNS Provide sufficient mechanical and/or local exhaust to maintain exposure below the TLV/TWA. CONDITIONS FOR SAFE STORAGE Store in accordance with NFPA 430 requirements for Class II oxidizers. Protect containers from physical damage. Store in a cool, dry area in closed containers. Segregate from acids, peroxides, formaldehyde, and all combustible, organic, or easily oxidizable materials including antifreeze and hydraulic fluid.
Section 8 Exposure Controls and Personal Protection RESPIRATORY PROTECTION In cases where overexposure to dust may occur, the use of an approved NIOSH-MSHA dust respirator or an air supplied respirator is advised. Engineering or administrative controls should be implemented to control dust EYE Faceshield, goggles, or safety glasses with side shields should be worn. Provide eyewash in working area. GLOVES Rubber or plastic gloves should be worn. OTHER PROTECTIVE EQUIPMENT Normal work clothing covering arms and legs, and rubber, or plastic apron should be worn.
Section 9 Physical and Chemical Properties APPEARANCE AND ODOR BOILING POINT, 760 mm Hg VAPOR PRESSURE (mm Hg) SOLUBILITY IN WATER % BY SOLUTION PERCENT VOLATILE BY VOLUME EVAPORATION RATE MELTING POINT SPECIFIC GRAVITY BULK DENSITY VAPOR DENSITY (AIR=1) OXIDIZING PROPERTIES
Dark purple solid with metallic luster, odorless Not applicable Not applicable 6% at 20oC (68oF) and 20% at 65oC (149oF) Not volatile Not applicable Starts to decompose with evolution of oxygen (O2) at temperatures above 150oC (302oF). Once initiated, the decomposition is exothermic and self-sustaining. 2.7 at 20oC (68oF) Approximately 1.45 - 1.6 kg / l Not applicable Strong oxidizer
RemOx®S ISCO Reagent EC- SAFETY DATA SHEET according to EC directive 2001/58/EC MATERIAL SAFETY DATA SHEET Page 5 of 9
Section 10 Stability and Reactivity STABILITY
Under normal conditions, the material is stable.
CONDITIONS TO AVOID
Contact with incompatible materials or heat (150!C / 302ºF) could result in violent exothermic chemical reaction.
INCOMPATIBLE MATERIALS
Acids, peroxides, formaldehyde, anti-freeze, hydraulic fluids and all combustible organic or readily oxidizable inorganic materials including metal powders. With hydrochloric acid, chlorine gas is liberated.
HAZARDOUS DECOMPOSITION PRODUCTS
When involved in a fire, RemOx® S ISCO Reagent may liberate corrosive fumes.
CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION
Material is not known to polymerize.
Section 11 Toxicological Information POTASSIUM PERMANGANATE: 1. ACUTE TOXICITY INGESTION: LD 50 oral rat: 780 mg/kg male (14 days); 525 mg/kg female (14 days). Harmful if swallowed. ALD: 10g. Ingestion may cause nausea, vomiting, sore throat, stomach-ache and eventually lead to a perforation of the intestine. Liver and kidney injuries may occur. SKIN CONTACT: LD 5O dermal no data available. The product may be absorbed into the body through the skin. Major effects of exposure: severe irritation, brown staining of skin. INHALATION: LC 5O inhalation: No data available. The product may be absorbed into the body by inhalation. Major effects of exposure: respiratory disorder, cough. 2. CHRONIC TOXICITY No known cases of chronic poisoning due to permanganates have been reported. Prolonged exposure, usually over many years, to heavy concentrations of manganese oxides in the form of dust and fumes may lead to chronic manganese poisoning, chiefly involving the central nervous system. 3. CARCINOGENICITY Potassium permanganate has not been classified as a carcinogen by ACGIH, NIOSH, OSHA, NTP, or IARC. 4. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE Potassium permanganate solution will cause further irritation of tissue, open wounds, burns or mucous membranes.
RemOx®S ISCO Reagent EC- SAFETY DATA SHEET according to EC directive 2001/58/EC MATERIAL SAFETY DATA SHEET Page 6 of 9
Section 12 Ecological Information ENTRY TO THE ENVIRONMENT Potassium permanganate has a low estimated lifetime in the environment, being readily converted by oxidizable materials to insoluble MnO2. BIOCONCENTRATION POTENTIAL In non-reducing and non-acidic environments, MnO2 is insoluble and has a very low bioaccumulative potential. AQUATIC TOXICITY The toxicity data for Potassium permanganate is given below: Rainbow trout, 96 hour LC50: Bluegill sunfish, 96 hour LC50: Milk fish (Chanos Chanos)/ 96 hour LC50:
1.8 mg/L 2.3 mg/L >1.4mgl
Section 13 Disposal Considerations Offer surplus and non-recyclable product or solutions to a licensed disposal company. Reduce RemOx® S ISCO Reagent in aqueous solutions with sodium thiosulfate, a bisulfite or ferrous salt solution. The bisulfite or ferrous salt may require some dilute sulfuric acid (10% w/w) to promote reduction. Neutralize with sodium carbonate to neutral pH, if acid was used. Decant or filter and deposit sludge in approved landfill. Where permitted, the sludge may be drained into sewer with large quantities of water. Contact Carus Chemical Company for additional recommendations. Packaging materials must be triple rinsed to remove all RemOx® S ISCO Reagent prior to re-cycling or disposal.
Section 14 Transport Information USA (land, D.O.T.)
European Labeling in accordance Road/Rail Transport (ADR/RID) European Labeling in accordance with EC directive (Water, I.M.O.)
Proper Shipping Name: 49 CFR172.101….Potassium Permanganate Hazard Class: 49 CFR172.101….Oxidizer ID Number: 49 CFR172.101….UN 1490 Packing Group: 49 CFR172.101….II Division: 49 CFR172.101….5.1 ID Number: UN 1490 ADR/RID Class 5.1 Description of Goods: Potassium Permanganate Hazard Identification No. 50 Proper Shipping Name: Potassium Permanganate Hazard Class: Oxidizer ID Number: UN 1490 Packing Group: II Division: 5.1 Marine Pollutant: No
RemOx®S ISCO Reagent EC- SAFETY DATA SHEET according to EC directive 2001/58/EC MATERIAL SAFETY DATA SHEET Page 7 of 9
Section 14 Transport Information (contd.) European Labeling in accordance with EC directive (Air, I.C.A.O.)
Proper Shipping Name: Hazard Class: ID Number: Packing Group: Division:
Potassium Permanganate Oxidizer UN 1490 II 5.1
Section 15 Regulatory Information EUROPEAN AND INTERNATIONAL REGULATIONS: MARKINGS ACCORDING TO EU GUIDELINES: The product has been classified and marked in accordance with EU directives/ordinances on hazardous materials. CHEMICAL NAME Potassium Permanganate
CAS NO. 7722-64-7
EINECS 231-760-3
UN NUMBER UN 1490
CODE LETTER AND HAZARD DESIGNATION OF THE PRODUCT:
Oxidizer
Harmful
Dangerous to the Environment
RISK PHRASES: 8 Contact with combustibles may case fire. 22 Harmful if swallowed. 50/53 Very toxic to aquatic organisms, may cause long-term effects in the aquatic environment. SAFETY PHRASES: 60 61
This material and its container must be disposed of as hazardous waste. Avoid releases to the environment. Refer to special instructions / Safety data sheet.
RemOx®S ISCO Reagent EC- SAFETY DATA SHEET according to EC directive 2001/58/EC MATERIAL SAFETY DATA SHEET Page 8 of 9
Section 15 Regulatory Information (contd.) US FEDERAL REGULATIONS: CHEMICAL INVENTORY STATUS – PART 1 Ingredient Potassium Permanganate
CAS. NO. 7722-64-7
TSCA Yes
EC Yes
Japan
Australia
CHEMICAL INVENTORY STATUS – PART 2 --- CANADA--Ingredient Potassium Permanganate
CAS. NO. 7722-64-7
Korea No
DSL Yes
NDSL PHIL
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR, Canada) and the MSDS contains all of the information required by the CPR. FEDERAL, STATE & INTERNATIONAL REGULATIONS – PART 1 SARA 302 CAS. NO. RQ TPQ Ingredient Potassium Permanganate 7722-64-7 N/A N/A
SARA 313 List Chemical Catg. Yes Yes (Manganese compounds)
FEDERAL, STATE & INTERNATIONAL REGULATIONS – PART 2 Ingredient Potassium Permanganate
CAS. NO. 7722-64-7
CERCLA Yes (RQ =100 lbs)
RCRA TSCA 8(d) D001 No
Ingredient
CAS. NO.
CWC
Potassium Permanganate
7722-64-7
No
CDTA SARA 311/312 4545 Kg
TSCA 12(b) No
Ingredient Potassium Permanganate
CAS. NO. 7722-64-7
Acute Yes
Chronic Fire Pressure Reactivity Pure/Liquid Yes Yes No No Pure
Ingredient Potassium Permanganate
CAS. NO.
Australian Hazchem Code Poison Schedule WHMIS C, D2B
RemOx®S ISCO Reagent EC- SAFETY DATA SHEET according to EC directive 2001/58/EC MATERIAL SAFETY DATA SHEET Page 9 of 9
Section 16 Other Information NIOSH National Institute for Occupational Safety and Health MSHA Mine Safety and Health Administration OSHA Occupational Safety and Health Administration NTP National Toxicology Program IARC International Agency for Research on Cancer PEL Permissible Exposure Limit C Ceiling Exposure Limit TLV-TWA Threshold Limit Value-Time Weighted Average CAS Chemical Abstract Service EINECS Inventory of Existing Chemical Substances (European)
Chithambarathanu Pillai (S.O.F.) January 2006
The information contained herein is accurate to the best of our knowledge. However, data, safety standards and government regulations are subject to change and, therefore, holders and users should satisfy themselves that they are aware of all current data and regulations relevant to their particular use of product. CARUS CHEMICAL COMPANY DISCLAIMS ALL LIABILITY FOR RELIANCE ON THE COMPLETENESS OR ACCURACY OR THE INFORMATION INCLUDED HEREIN. CARUS CHEMICAL COMPANY MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY WARRANTIES OF MERCHANTIABILITY OR FITNESS FOR PARTICULAR USE OR PURPOSE OF THE PRODUCT DESCRIBED HEREIN. All conditions relating to storage, handling, and use of the product are beyond the control of Carus Chemical Company, and shall be the sole responsibility of the holder or user of the product. CARUS CHEMICAL COMPANY IS A DIVISION OF CARUS CORPORATION, 315 5TH STREET, PERU, ILLINOIS 61354 CARUS NALON S.L. IS A DIVISION OF CARUS CORPORATION, 315 5TH STREET, PERU, ILLINOIS 61354
(Carus and Design) is a registered service mark of Carus Corporation. CARUS® is a registered trademark of Carus Corporation. RemOx® is a trademark of Carus Corporation. Responsible Care® is a registered service mark of the American Chemistry Council.
RemOx® L ISCO Reagent EC- SAFETY DATA SHEET according to EC directive 2001/58/EC MATERIAL SAFETY DATA SHEET Page 1 of 8 Section 1 Chemical Product and Company Identification PRODUCT NAME: TRADE NAME:
RemOx® L ISCO Reagent RemOx® L ISCO Reagent
Revision Date: January 2006
USES OF SUBSTANCE: RemOx® L ISCO Reagent is a liquid oxidant recommended for in-situ and ex-situ remediation of sites that require a strong oxidant. COMPANY NAME (Europe): CARUS NALON S.L.
COMPANY NAME (US): CARUS CHEMICAL COMPANY
COMPANY ADDRESS:
Carus Nalon S.L. Barrio Nalon, s/n 33100 Trubia-Oviedo Espana, Spain INFORMATION: (34) 985-785-513 (34) 985-785-513 www.caruseurope.com (Web)
[email protected] (Email) EMERGENCY TELEPHONE: (34) 985-785-513 COMPANY ADDRESS:
315 Fifth Street Peru, IL 61354, USA INFORMATION: (815)-223-1500 www.caruschem.com (Web)
[email protected] (Email) EMERGENCY TELEPHONE: (800) 435 –6856 (USA) (800) 424-9300 (CHEMTREC, USA) (815-223-1500 (Other countries) Section 2
Hazardous Ingredients
Material or Component
CAS No.
%
Sodium Permanganate
10101-50-5
40
Hazard Data PEL/C TLV-TWA
5 mg Mn per cubic meter of air 0.2 mg Mn per cubic meter of air
HAZARD SYMBOLS:
RISK PHRASES: 8 Contact with combustibles may case fire. 22 Harmful if swallowed. 50/53 Very toxic to aquatic organisms, may cause long-term effects in the aquatic environment. SAFETY PHRASES: 17 Keep away from combustible materials. 24/25 Avoid contact with skin and eyes. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
RemOx® L ISCO Reagent EC- SAFETY DATA SHEET according to EC directive 2001/58/EC MATERIAL SAFETY DATA SHEET Page 2 of 8 Section 3 Hazards Identification 1.
Eye Contact RemOx® L ISCO Reagent is damaging to eye tissue on contact. It may cause burns that result in damage to the eye. 2. Skin Contact Momentary contact of solution at room temperature may be irritating to the skin, leaving brown stains. Prolonged contact is damaging to the skin. 3. Inhalation Acute inhalation toxicity data are not available. However, airborne concentrations of RemOx® L ISCO Reagent in the form of mist may cause irritation to the respiratory tract. 4. Ingestion RemOx® L ISCO Reagent if swallowed, may cause burns to mucous membranes of the mouth, throat, esophagus, and stomach. Section 4
First Aid Measures
1. Eyes Immediately flush eyes with large amounts of water for at least 15 minutes holding lids apart to ensure flushing of the entire surface. Do not attempt to neutralize chemically. Seek medical attention immediately. Note to physician: Decomposition products are alkaline. 2. Skin Immediately wash contaminated areas with water. Remove contaminated clothing and footwear. (Caution: Solution may ignite certain textiles). Wash clothing and decontaminate footwear before reuse. Seek medical attention immediately if irritation is severe and persistent. 3. Inhalation Remove person from contaminated area to fresh air. If breathing has stopped, resuscitate and administer oxygen if readily available. Seek medical attention immediately. 4. Ingestion Never give anything by mouth to an unconscious or convulsing person. If person is conscious, give large quantities of water or milk. Seek medical attention immediately. Section 5
Fire Fighting Measures
NFPA* HAZARD SIGNS: Health Hazard 1 = Materials which under fire conditions would give off irritating combustion products. (less than 1 hour exposure) Materials which on the skin could cause irritation. Flammability Hazard 0 = Materials that will not burn. Reactivity Hazard 0 = Materials which in themselves are normally stable, even under fire exposure conditions, and which are not reactive with water. Special Hazard OX = Oxidizer *National Fire Protection Association 704 FIRST RESPONDERS: Wear protective gloves, boots, goggles, and respirator. In case of fire, wear positive pressure breathing apparatus. Approach incident with caution. Use 2004 Emergency Response Guidebook (U.S. DOT RSPA, TC and STC). Guide No. 140. (http://hazmat.dot.gov/pubs/erg2004/erg2004.pdf).
RemOx® L ISCO Reagent EC- SAFETY DATA SHEET according to EC directive 2001/58/EC MATERIAL SAFETY DATA SHEET Page 3 of 8 FLASHPOINT
None
FLAMMABLE OR EXPLOSIVE LIMITS
Lower: Nonflammable
Upper: Nonflammable
EXTINGUISHING MEDIA
Use large quantities of water. Water will turn pink to purple if in contact with RemOx® L ISCO Reagent. Dike to contain. Do not use dry chemicals, CO2Halon® or foams.
SPECIAL FIREFIGHTING PROCEDURES
If material is involved in fire, flood with water. Cool all affected containers with large quantities of water. Apply water from as far as a distance as possible. Wear self-contained breathing apparatus and full protective clothing.
UNUSUAL FIRE AND EXPLOSION
Powerful oxidizing material. May decompose spontaneously if exposed to heat (135°C/275°F). May be explosive in contact with certain other chemicals (Section 10). May react violently with finely divided and readily oxidizable substances. Increases burning rate of combustible material. May ignite wood and cloth.
Section 6 Accidental Release Measures PERSONAL PRECAUTIONS Personnel should wear protective clothing suitable for the task. Remove all ignition sources and incompatible materials before attempting clean up. ENVIRONMENTAL PRECAUTIONS: Do not flush into sanitary sewer system or surface water. If accidental release into the environment occurs, inform the responsible authorities. Keep the product away from drains, sewers, surface and ground water and soil. STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Contain spill by collecting the liquid in a pit or holding behind a dam (sand or soil). Dilute to approximately 6% with water, and then reduce with sodium thiosulfate, a bisulfite or ferrous salt solution. The bisulfite or ferrous salt may require some dilute sulfuric acid (10% w/w) to promote reduction. Neutralize with sodium carbonate to neutral pH, if acid was used. Decant or filter and deposit sludge in approved landfill. Where permitted, the sludge may be drained into sewer with large quantities of water. To clean contaminated floors, flush with abundant quantities of water into sewer, if permitted by federal, state, and local regulations. If not, collect water and treat as above.
RemOx® L ISCO Reagent EC- SAFETY DATA SHEET according to EC directive 2001/58/EC MATERIAL SAFETY DATA SHEET Page 4 of 8 Section 7 Handling and Storage WORK/HYGIENIC PRACTICES Wash hands thoroughly with soap and water after handling RemOx® L ISCO Reagent. Do not eat, drink or smoke when working with RemOx® L ISCO Reagent . Wear proper protective equipment. Remove clothing, if it becomes contaminated. VENTILATION REQUIREMETNS Provide sufficient mechanical and/or local exhaust to maintain exposure below the TLV/TWA. CONDITIONS FOR SAFE STORAGE Store in accordance with NFPA 430 requirements for Class II oxidizers. Protect containers from physical damage. Store in a cool, dry area in closed containers. Segregate from acids, peroxides, formaldehyde, and all combustible, organic, or easily oxidizable materials including antifreeze and hydraulic fluid. Section 8 Exposure Controls and Personal Protection RESPIRATORY PROTECTION In cases where overexposure to mist may occur, the use of an approved NIOSH-MSHA mist respirator or an air supplied respirator is advised. Engineering or administrative controls should be implemented to control mist. EYE Faceshield, goggles, or safety glasses with side shields should be worn. Provide eyewash in working area. GLOVES Rubber or plastic gloves should be worn. OTHER PROTECTIVE EQUIPMENT Normal work clothing covering arms and legs, and rubber, or plastic apron should be worn. Caution: If clothing becomes contaminated, wash off immediately. Spontaneous ignition may occur with cloth or paper. Section 9 Physical and Chemical Properties APPEARANCE AND ODOR
Dark purple solution, odorless
BOILING POINT, 760 mm Hg
105 !C
VAPOR PRESSURE (mm Hg)
760 mm at 105ºC
SOLUBILITY IN WATER % BY SOLUTION
Miscible in all proportions
PERCENT VOLATILE BY VOLUME
61% (as water)
EVAPORATION RATE
Same as water
FREEZING POINT
-15.0 !C
SPECIFIC GRAVITY
1.36-1.39
pH
5-9
OXIDIZING PROPERTIES
Strong oxidizer. May ignite wood and cloth.
EXPLOSIVE PROPERTIES
Explosive in contact with sulfuric acid or peroxides, or
RemOx® L ISCO Reagent EC- SAFETY DATA SHEET according to EC directive 2001/58/EC MATERIAL SAFETY DATA SHEET Page 5 of 8 readily oxidizable substances. Section 10 Stability and Reactivity STABILITY
Under normal conditions, the material is stable.
CONDITIONS TO AVOID could
Contact with incompatible materials or heat (135!C / 275ºF) result in violent exothermic chemical reaction.
INCOMPATIBLE MATERIALS
HAZARDOUS DECOMPOSITION PRODUCTS CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION
Acids, peroxides, formaldehyde, antifreeze, hydraulic fluids, and all combustible organic or readily oxidizable materials, including metal powders. With hydrochloric acid, toxic chlorine gas is liberated. When involved in a fire, liquid permanganate may form corrosive fumes. Material is not known to polymerize.
Section 11 Toxicological Information SODIUM PERMANGANATE:
Acute oral LD50 not known.
1. Acute toxicity Irritating to body tissue with which it comes into contact. No acute toxicity data is available for sodium permanganate. Toxicity is expected to be similar to that of potassium permanganate. The toxicity data for potassium permanganate is given below: Ingestion: LD 50 oral rat: 780 mg/kg male (14 days); 525 mg/kg female (14 days). Harmful if swallowed. ALD: 10g. Ingestion may cause nausea, vomiting, sore throat, stomach-ache and eventually lead to a perforation of the intestine. Liver and kidney injuries may occur. Skin contact: LD 50 dermal no data available. The product may be absorbed into the body through the skin. Major effects of exposure: severe irritation, brown staining of skin. Inhalation: LC 50 inhal. no data available. The product may be absorbed into the body by inhalation. Major effects of exposure: respiratory disorder, cough. 2. Chronic toxicity No known cases of chronic poisoning due to permanganates have been reported. Prolonged exposure, usually over many years, to heavy concentrations of manganese oxides in the form of dust and fumes may lead to
RemOx® L ISCO Reagent EC- SAFETY DATA SHEET according to EC directive 2001/58/EC MATERIAL SAFETY DATA SHEET Page 6 of 8 chronic manganese poisoning, chiefly involving the central nervous system. 3. Carcinogenicity Sodium permanganate has not been classified as a carcinogen by ACGIH, NIOSH, OSHA, NTP, or IARC. 4. Medical Conditions Generally Aggravated by Exposure Sodium permanganate solution will cause further irritation of tissue, open wounds, burns or mucous membranes. Section 12 Ecological Information Entry to the Environment Permanganate has a low estimated lifetime in the environment, being readily converted by oxidizable materials to insoluble MnO2. Bioconcentration Potential In non-reducing and non-acidic environments MnO2 is insoluble and has a very low bioaccumulative potential. Aquatic Toxicity No data. Section 13 Disposal Considerations Waste Disposal RemOx® L ISCO Reagent, once it becomes a waste, is considered a D001 hazardous (ignitable) waste. For disposal of RemOx® L ISCO Reagent solutions, follow procedures in Section 6 and deactivate the permanganate to insoluble manganese dioxide. Dispose of it in a permitted landfill. Contact Carus Chemical Company for additional recommendations. Section 14 Transport Information USA (land, D.O.T.)
European Labeling in accordance Road/Rail Transport (ADR/RID)
European Labeling in accordance with EC directive (Water, I.M.O.)
Proper Shipping Name: 49 CFR172.101 Permanganates, inorganic, aqueous solution, n.o.s .(contains sodium permanganate Hazard Class: 49 CFR172.101….Oxidizer ID Number: 49 CFR172.101….UN 3214 Packing Group: 49 CFR172.101….II Division: 49 CFR172.101….5.1 ID Number: UN 3214 ADR/RID Class 5.1 Description of Goods: Permanganates, inorganic, aqueous solution, n.o.s (contains sodium permanganate) Hazard Identification No. 50 Proper Shipping Name: Permanganates, inorganic, aqueous solution, n.o.s (contains sodium permanganate) Hazard Class: Oxidizer ID Number: UN 3214
RemOx® L ISCO Reagent EC- SAFETY DATA SHEET according to EC directive 2001/58/EC MATERIAL SAFETY DATA SHEET
European Labeling in accordance with EC directive (Air, I.C.A.O.)
Packing Group: Division: Marine Pollutant: Proper Shipping Name: Hazard Class: ID Number: Packing Group: Division:
Page 7 of 8 II 5.1 No Permanganates, inorganic, aqueous solution, n.o.s (contains sodium permanganate) Oxidizer UN 3214 II 5.1
Section 15 Regulatory Information (Sodium Permanganate) TSCA CERCLA RCRA
Listed in the Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Not listed. Oxidizers such as RemOx® L ISCO Reagent solution meet the criteria of ignitable waste. 40 CFR 261.21. SARA TITLE III Information Section 302/303 Extremely hazardous substance: Not listed Section 311/312 Hazard categories: Fire, acute and chronic toxicity. Section 313 RemOx® L ISCO Reagent contains 40% manganese compounds as part of the chemical and is subject to the reporting requirements of Section 313 of Title III, Superfund Amendments and Reauthorization Act of 1986 and 40 CFR 372. FOREIGN LIST Canadian Non-Domestic Substance List , EINECS Section 16 Other Information NIOSH National Institute for Occupational Safety and Health MSHA Mine Safety and Health Administration OSHA Occupational Safety and Health Administration NTP National Toxicology Program IARC International Agency for Research on Cancer PEL Permissible Exposure Limit C Ceiling Exposure Limit TLV-TWA Threshold Limit Value-Time Weighted Average CAS Chemical Abstract Service EINECS Inventory of Existing Chemical Substances (European) Chithambarathanu Pillai (S.O.F.) January 2006
The information contained herein is accurate to the best of our knowledge. However, data, safety standards and government regulations are subject to change and, therefore, holders and users should satisfy themselves that they are aware of all current data and regulations relevant to their particular use of product. CARUS CHEMICAL COMPANY DISCLAIMS ALL LIABILITY FOR RELIANCE ON THE COMPLETENESS OR ACCURACY OR THE INFORMATION INCLUDED HEREIN. CARUS CHEMICAL COMPANY MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY WARRANTIES OF MERCHANTIABILITY OR FITNESS FOR PARTICULAR USE OR PURPOSE OF THE PRODUCT DESCRIBED HEREIN. All conditions relating to storage,
RemOx® L ISCO Reagent EC- SAFETY DATA SHEET according to EC directive 2001/58/EC MATERIAL SAFETY DATA SHEET Page 8 of 8 handling, and use of the product are beyond the control of Carus Chemical Company, and shall be the sole responsibility of the holder or user of the product.
(Carus and Design) is a registered service mark of Carus Corporation. CARUS® is a registered trademark of Carus Corporation. RemOx® is a trademark of Carus Corporation. Responsible Care® is a registered service mark of the American Chemistry Council.
MATERIAL SAFETY DATA SHEET Hydrogen Peroxide (20 to 40%) MSDS Ref. No.: 7722-84-1-3 Date Approved: 04/27/2006 Revision No.: 10
This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200; the Canada’s Workplace Hazardous Materials Information System (WHMIS) and, the EC Directive, 2001/58/EC.
1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME:
Hydrogen Peroxide (20 to 40%)
ALTERNATE PRODUCT NAME(S): Durox® Reg. & LR 35%, Oxypure® 35%, Standard 27.5 & 35%, Super D® 25 & 35, Technical 35%, HTP 35%, OHP 35%, Chlorate Grade, 20%, Semiconductor Reg, Seg, RGS, RGS 2, RGS 3, 31% GENERAL USE:
Durox® 35% Reg. & LR - meets the Food Chemical Codex requirements for aseptic packaging and other food related applications. Oxypure® 35% - certified by NSF to meet NSF/ANSI Standard 60 requirements for drinking water treatment. Standard 27.5 and 35% - most suitable grade for industrial bleaching, processing, pollution abatement and general oxidation reactions. Semiconductor Reg, Seg, RGS, RGS 2, RGS 3, 31% - conform to ACS and Semi Specs. for wafer etching and cleaning, and applications requiring low residues. Super D® 25 and 35% - meets US Pharmacopoeia specifications for 3% topical solutions when diluted with proper quality water. While manufactured to the USP standards for purity and to FMC's demanding ISO 9002 quality standards, FMC does not claim that it's Hydrogen Peroxide is manufactured in accordance with all pharmaceutical cGMP conditions. Technical 35% - essentially free of inorganic metals suitable for chemical synthesis. HTP 35% - specially formulated for aerospace equipment conditioning. OHP 35% - specially formulated for OHP process, advanced oxidation, and activated peroxide applications Chlorate Grade 20% - specially formulated for use in chlorate manufacture or processing.
Page 1 of 11
Hydrogen Peroxide (20 to 40%) (7722-84-1-3)
Date: 04/27/2006
MANUFACTURER
EMERGENCY TELEPHONE NUMBERS
FMC CORPORATION FMC Peroxygens 1735 Market Street Philadelphia, PA 19103 (215) 299-6000 (General Information)
(281) 474-8750 (Plant: Pasadena, TX, US - Call Collect) (250) 561-4221 (Plant: Prince George, BC, Canada - Call Collect) (303) 595-9048 (Medical - U.S. - Call Collect) For leak, fire, spill, or accident emergencies, call: (800) 424-9300 (CHEMTREC - U.S.A.) (613) 996-6666 (CANUTEC - Canada)
FMC of Canada Ltd. FMC Peroxygens PG Pulp Mill Road Prince George, BC V2N2S6 (250) 561-4200 (General Information)
2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: • • • • •
Clear, colorless, odorless liquid Oxidizer. Contact with combustibles may cause fire. Decomposes yielding oxygen that supports combustion of organic matters and can cause overpressure if confined. Corrosive to eyes, nose, throat, lungs and gastrointestinal tract.
POTENTIAL HEALTH EFFECTS:
Corrosive to eyes, nose, throat and lungs. May cause irreversible tissue damage to the eyes including blindness. May cause skin irritation.
3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name
CAS#
Wt.%
EC No.
EC Class
Hydrogen Peroxide
7722-84-1
20 - 40
231-765-0
Xn, R22-37/38-41
Water
7732-18-5
60 - 80
231-791-2
Not classified
Page 2 of 11
Hydrogen Peroxide (20 to 40%) (7722-84-1-3)
Date: 04/27/2006
4. FIRST AID MEASURES EYES: Immediately flush with water for at least 15 minutes, lifting the upper and lower eyelids intermittently. See a medical doctor or ophthalmologist immediately. SKIN: Wash with plenty of soap and water. Get medical attention if irritation occurs and persists. INGESTION: Rinse mouth with water. Dilute by giving 1 or 2 glasses of water. Do not induce vomiting. Never give anything by mouth to an unconscious person. See a medical doctor immediately.
INHALATION: Remove to fresh air. If breathing difficulty or discomfort occurs and persists, contact a medical doctor.
NOTES TO MEDICAL DOCTOR: Hydrogen peroxide at these concentrations is a strong oxidant. Direct contact with the eye is likely to cause corneal damage especially if not washed immediately. Careful ophthalmologic evaluation is recommended and the possibility of local corticosteroid therapy should be considered. Because of the likelihood of corrosive effects on the gastrointestinal tract after ingestion, and the unlikelihood of systemic effects, attempts at evacuating the stomach via emesis induction or gastric lavage should be avoided. There is a remote possibility, however, that a nasogastric or orogastric tube may be required for the reduction of severe distension due to gas formation.
5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA:
Flood with water.
FIRE / EXPLOSION HAZARDS:
Product is non-combustible. On decomposition releases
oxygen which may intensify fire.
FIRE FIGHTING PROCEDURES:
Any tank or container surrounded by fire should be flooded with water for cooling. Wear full protective clothing and self-contained breathing apparatus.
FLAMMABLE LIMITS:
Non-combustible
SENSITIVITY TO IMPACT:
No data available
SENSITIVITY TO STATIC DISCHARGE:
No data available
6. ACCIDENTAL RELEASE MEASURES RELEASE NOTES:
Dilute with a large volume of water and hold in a pond or diked area until hydrogen peroxide decomposes. Hydrogen peroxide may be decomposed by adding sodium metabisulfite or sodium sulfite after diluting to about 5%. Dispose according to methods outlined for waste disposal.
Page 3 of 11
Hydrogen Peroxide (20 to 40%) (7722-84-1-3)
Date: 04/27/2006
Combustible materials exposed to hydrogen peroxide should be immediately submerged in or rinsed with large amounts of water to ensure that all hydrogen peroxide is removed. Residual hydrogen peroxide that is allowed to dry (upon evaporation hydrogen peroxide can concentrate) on organic materials such as paper, fabrics, cotton, leather, wood or other combustibles can cause the material to ignite and result in a fire.
7. HANDLING AND STORAGE HANDLING:
Wear chemical splash-type monogoggles and full-face shield, impervious clothing, such as rubber, PVC, etc., and rubber or neoprene gloves and shoes. Avoid cotton, wool and leather. Avoid excessive heat and contamination. Contamination may cause decomposition and generation of oxygen gas which could result in high pressures and possible container rupture. Hydrogen peroxide should be stored only in vented containers and transferred only in a prescribed manner (see FMC Technical Bulletins). Never return unused hydrogen peroxide to original container, empty drums should be triple rinsed with water before discarding. Utensils used for handling hydrogen peroxide should only be made of glass, stainless steel, aluminum or plastic.
STORAGE:
Store drums in cool areas out of direct sunlight and away from combustibles. For bulk storage refer to FMC Technical Bulletins.
COMMENTS: VENTILATION: Provide mechanical general and/or local exhaust ventilation to prevent release of vapor or mist into the work environment.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMITS Chemical Name
ACGIH
OSHA
Hydrogen Peroxide
1 ppm (TWA)
1 ppm (PEL)
Supplier
ENGINEERING CONTROLS:
Ventilation should be provided to minimize the release of hydrogen peroxide vapors and mists into the work environment. Spills should be minimized or confined immediately to prevent release into the work area. Remove contaminated clothing immediately and wash before reuse.
PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE:
Use chemical splash-type monogoggles and a full-face shield made of polycarbonate, acetate, polycarbonate/acetate, PETG or thermoplastic.
RESPIRATORY:
If concentrations in excess of 10 ppm are expected, use NIOSH/DHHS approved self-contained breathing apparatus (SCBA), or other approved atmospheric-supplied respirator (ASR) equipment (e.g., a full-face airline respirator (ALR)). DO NOT use any form of air-purifying respirator (APR) or filtering facepiece (AKA dust mask), especially those containing oxidizable sorbants such as activated carbon.
Page 4 of 11
Hydrogen Peroxide (20 to 40%) (7722-84-1-3)
Date: 04/27/2006
PROTECTIVE CLOTHING:
For body protection wear impervious clothing such as an approved splash protective suit made of SBR Rubber, PVC (PVC Outershell w/Polyester Substrate), Gore-Tex (Polyester trilaminate w/Gore-Tex), or a specialized HAZMAT Splash or Protective Suite (Level A, B, or C). For foot protection, wear approved boots made of NBR, PVC, Polyurethane, or neoprene. Overboots made of Latex or PVC, as well as firefighter boots or specialized HAZMAT boots are also permitted. DO NOT wear any form of boot or overboots made of nylon or nylon blends. DO NOT use cotton, wool or leather, as these materials react RAPIDLY with higher concentrations of hydrogen peroxide. Completely submerge hydrogen peroxide contaminated clothing or other materials in water prior to drying. Residual hydrogen peroxide, if allowed to dry on materials such as paper, fabrics, cotton, leather, wood or other combustibles can cause the material to ignite and result in a fire.
GLOVES: For hand protection, wear approved gloves made of nitrile, PVC, or neoprene. DO NOT use cotton, wool or leather for these materials react RAPIDLY with higher concentrations of hydrogen peroxide. Thoroughly rinse the outside of gloves with water prior to removal. Inspect regularly for leaks.
9. PHYSICAL AND CHEMICAL PROPERTIES ODOR:
Odorless
APPEARANCE:
Clear, colorless liquid
AUTOIGNITION TEMPERATURE:
Non-combustible
BOILING POINT:
103ºC/218ºF (20%); 107ºC/225ºF (31%); 108ºC/226ºF (35%)
COEFFICIENT OF OIL / WATER:
Not available
DENSITY / WEIGHT PER VOLUME:
Not available
EVAPORATION RATE:
Above 1 (Butyl Acetate = 1)
FLASH POINT:
Non-combustible
FREEZING POINT:
-15ºC/6ºF (20%); -26ºC/-15ºF (31%); -33ºC/-27ºF (35%)
ODOR THRESHOLD:
Not available
OXIDIZING PROPERTIES:
Strong oxidizer
PERCENT VOLATILE:
100%
pH:
(as is) < / = 3.7
SOLUBILITY IN WATER:
(in H2O % by wt) 100%
SPECIFIC GRAVITY:
1.07 @ 20ºC/4ºC (20%); 1.11 @ 20ºC/4ºC (31%); 1.13 @ 20ºC/4ºC (35%)
VAPOR DENSITY:
(Air = 1): Not available
VAPOR PRESSURE:
28 mmHg @ 30ºC (20%); 24 mmHg @ 30ºC (31%); 23 mmHg @ 30ºC (35%)
COMMENTS: pH (1% solution) @ 25ºC: 5.0 - 6.0
Page 5 of 11
Hydrogen Peroxide (20 to 40%) (7722-84-1-3)
Date: 04/27/2006
10. STABILITY AND REACTIVITY CONDITIONS TO AVOID:
Excessive heat or contamination could cause product to become unstable.
STABILITY:
Stable (heat and contamination could cause decomposition)
POLYMERIZATION:
Will not occur
INCOMPATIBLE MATERIALS:
Reducing agents, wood, paper and other combustibles, iron and other heavy metals, copper alloys and caustic.
HAZARDOUS DECOMPOSITION PRODUCTS:
Oxygen which supports combustion.
COMMENTS:
Materials to Avoid : Dirt, organics, cyanides and combustibles such as wood, paper,
oils, etc.
11. TOXICOLOGICAL INFORMATION EYE EFFECTS:
35% hydrogen peroxide: Extremely irritating/corrosive (rabbit) [FMC Study
Number: I83-748]
SKIN EFFECTS:
35% hydrogen peroxide: Mildly irritating after 4-hour exposure (rabbit) [FMC
Study Number: I83-747]
DERMAL LD50:
35% hydrogen peroxide: > 2,000 mg/kg (rabbit) [FMC Study Number: I83-746]
ORAL LD50: 35% hydrogen peroxide: 1,193 mg/kg (rat) INHALATION LC50: 50% hydrogen peroxide: TARGET ORGANS:
[FMC Study Number: I83-745]
> 0.17 mg/l (rat) [FMC Study Number: I89-1080]
Eyes, nose, throat and lungs
ACUTE EFFECTS FROM OVEREXPOSURE:
Extremely irritating/corrosive to eyes and gastrointestinal tract. May cause irreversible tissue damage to the eyes including blindness. Inhalation of mist or vapors may be severely irritating to nose, throat and lungs. May cause skin irritation.
CHRONIC EFFECTS FROM OVEREXPOSURE:
The International Agency for Research on Cancer (IARC) has concluded that there is inadequate evidence for carcinogenicity of hydrogen peroxide in humans, but limited evidence in experimental animals (Group 3 - not classifiable as to its carcinogenicity to humans). The American Conference of Governmental Industrial Hygienists (ACGIH) has concluded that hydrogen peroxide is a ’Confirmed Animal Carcinogen with Unknown Relevance to Humans’ (A3).
Page 6 of 11
Hydrogen Peroxide (20 to 40%) (7722-84-1-3)
Date: 04/27/2006
CARCINOGENICITY: Chemical Name Hydrogen Peroxide
IARC Listed
NTP Not listed
OSHA Not listed
Other (ACGIH) Listed (A3, Animal Carcinogen)
12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION:
Channel catfish 96-hour LC50 = 37.4 mg/L Fathead minnow 96-hour LC50 = 16.4 mg/L Daphnia magna 24-hour EC50 = 7.7 mg/L Daphnia pulex 48-hour LC50 = 2.4 mg/L Freshwater snail 96-hour LC50 = 17.7 mg/L For more information refer to ECETOC "Joint Assessment of Commodity Chemicals No. 22, Hydrogen Peroxide." ISSN-0773-6339, January 1993
CHEMICAL FATE INFORMATION:
Hydrogen peroxide in the aquatic environment is subject to various reduction or oxidation processes and decomposes into water and oxygen. Hydrogen peroxide half-life in freshwater ranged from 8 hours to 20 days, in air from 10-20 hrs. and in soils from minutes to hours depending upon microbiological activity and metal contaminants.
13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD:
An acceptable method of disposal is to dilute with a large amount of water and allow the hydrogen peroxide to decompose followed by discharge into a suitable treatment system in accordance with all regulatory agencies. The appropriate regulatory agencies should be contacted prior to disposal.
14. TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION (DOT) PROPER SHIPPING NAME:
Hydrogen peroxide, aqueous solutions with not less than 20% but not more than 40% hydrogen peroxide
PRIMARY HAZARD CLASS / DIVISION:
5.1 (Oxidizer)
UN/NA NUMBER:
UN 2014
PACKING GROUP:
II
LABEL(S):
Oxidizer, Corrosive
PLACARD(S):
5.1 (Oxidizer)
Page 7 of 11
Hydrogen Peroxide (20 to 40%) (7722-84-1-3)
Date: 04/27/2006
DOT Marking: Hydrogen Peroxide, aqueous solution with not less than 20%, but not more than 40% Hydrogen Peroxide, UN 2014
ADDITIONAL INFORMATION:
Hazardous Substance/RQ: Not applicable 49 STCC Number: 4918775 DOT Spec: stainless steel/high purity aluminum cargo tanks and rail cars. UN Spec: HDPE drums. Contact FMC for specific details.
INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG) Hydrogen peroxide, aqueous solutions with not less than 20%, but not more than 60% hydrogen peroxide.
PROPER SHIPPING NAME:
INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO) / INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA) Hydrogen peroxide, aqueous solutions with not less than 20%, but not more than 40% hydrogen peroxide (*).
PROPER SHIPPING NAME:
OTHER INFORMATION: (*) Air regulations permit shipment of Hydrogen Peroxide (20 - 40%) in non-vented containers for Air Cargo Only aircraft, as well as for Passenger and Cargo aircraft. HOWEVER, all FMC Hydrogen Peroxide containers are vented and therefore, air shipments of FMC H202 is not permitted. IATA air regulations state that venting of packages containing oxidizing substances is not permitted for air transport. Protect from physical damage. Keep drums in upright position. Drums should not be stacked in transit. Do not store drum on wooden pallets.
15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A): Not listed SECTION 311 HAZARD CATEGORIES (40 CFR 370): Fire Hazard, Immediate (Acute) Health Hazard
Page 8 of 11
Hydrogen Peroxide (20 to 40%) (7722-84-1-3)
Date: 04/27/2006
SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370): The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 lbs; however, this product contains the following ingredients with a TPQ of less than 10,000 lbs.: None, (conc.
