The Syntheses, Crystal Structures and Characterizations of the First

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930. 10000. 11000. 12000. 13000. 14000. 15000. 16000. Binding Energy (E) co ... 6000. 8000. 10000. 12000. 14000. 16000. 18000. Binding Energy (E) c oun ts. /s ... 850. 8000. 8500. 9000. 9500. 10000. 10500. Binding Energy (E) counts/s.
Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry 2010

Electronic Supplementary Information

The Syntheses, Crystal Structures and Characterizations of the First Examples of Extended Structures Constructed from {PMo12Sb2O40} Polyoxoanions and Coordination Fragments Shu-Yun Shi, Ying-Hua Sun, Yan Chen, Jia-Ning Xu, Xiao-Bing Cui, Yan Wang, Guo-Wu Wang, Guang-Di Yang, Ji-Qing Xu

Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry 2010

weight

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Fig. s1. The TG curve of compound 1

weight

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temperature

Fig. s2. The TG curve of compound 2.

Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry 2010

16000

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counts/s

14000

Cu2p

13000

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Binding Energy (E)

Fig. s3. The XPS spectrum of the Cu2p region of compound 1.

Sb3d

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counts/s

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0 545

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Binding Energy (E)

Fig. s4. The XPS spectrum of the Sb3d region of compound 1.

Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry 2010

18000 16000 14000

counts/s

12000 10000 8000 6000 4000 2000 0 242

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Binding Energy (E)

Fig. s5. The XPS spectrum of the Mo3d region of compound 1.

Ni2p

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counts/s

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Binding Energy (E)

850

Fig. s6. The XPS spectrum of the Ni2p region of compound 2.

Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry 2010

35000

Sb3d 30000

counts/s

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Binding Energy (E)

Fig. s7. The XPS spectrum of the Sb3d region of compound 2.

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Binding Energy (E)

Fig. s8. The XPS spectrum of the Mo3d region of compound 2.

Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry 2010

9000 8500 8000 7500

Cu2p

counts/s

7000 6500 6000 5500 980

970

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930

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binding energy (eV)

Fig. s9. The XPS spectrum of the Cu2p region of compound 3.

20000

Sb3d 18000

counts/s

16000 14000 12000 10000 8000 6000 4000 2000 544

542

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536

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binding energy (eV)

Fig s10. The XPS spectrum of the Sb3d region of compound 3.

Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry 2010

7000

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counts/s

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0 242

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binding energy (eV)

Fig s11, The XPS spectrum of the Mo3d region of compound 3.

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