May 17, 2012 - Mario R. Eden, Mahmoud M. El-Halwagi, and Paul R. Stuart ... Trevor H. Treasure, Hasan Jameel, Richard B. Phillips, Hou-min Chang, Yongcan Jin, .... Shijie Liu, Yang Wang, Ling Liang, John P. Buyondo, Yuanzhen Wang,.
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Contents Series Preface.................................................................................................................................. ix Preface.............................................................................................................................................. xi Contributors..................................................................................................................................xiii
Section I Biorefinery Product and Process Design 1 Product Portfolio Selection and Process Design for the Forest Biorefinery................3 Dieudonné R. Batsy, Charles C. Solvason, Norm E. Sammons, Virginie Chambost, Mario R. Eden, Mahmoud M. El-Halwagi, and Paul R. Stuart 2 Systematic Screening of Multiple Processing Paths in Biorefineries: The ABC (Accessing Biomass to Chemicals) Project and Its Potential to Build Process Synthesis Capabilities........................................................................................... 37 Antonis C. Kokossis, Aidong Yang, Marinella Tsakalova, and Ta-Chen Lin 3 Technoeconomic Assessment and Risk Analysis of Biorefinery Processes.............. 59 Eemeli Hytönen and Paul R. Stuart 4 Technoeconomic Analysis of Cellulosic Ethanol Production from Hardwoods in a Repurposed Kraft Mill.......................................................................... 93 Trevor H. Treasure, Hasan Jameel, Richard B. Phillips, Hou-min Chang, Yongcan Jin, and Bon Wook Koo 5 Cost Integration Methodology and the Forest Biorefinery......................................... 129 Milan Korbel and Paul R. Stuart 6 Technoeconomic Analysis of a Lignocellulose-to-Hydrocarbons Process Using a Carboxylate Platform........................................................................................... 157 Viet Pham, Mark Holtzapple, and Mahmoud M. El-Halwagi
Section II Biorefinery Supply Chains 7 Value-Chain Management Considerations for the Biorefinery................................. 195 Louis Patrick Dansereau, Mahmoud El-Halwagi, and Paul R. Stuart 8 Integrated Forest Biorefinery Supply Chain Network Design Using Mathematical Programming Approach.............................................................. 251 Yan Feng, Sophie D’Amours, Luc LeBel, and Mustapha Nourelfath 9 Forest Biorefinery Supply Chain Design and Process Flexibility............................. 283 Behrang Mansoornejad and Paul R. Stuart v
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Section III Biorefinery Process Analysis 10 Optimal Synthesis of Sustainable Biorefineries........................................................... 325 Mariano Martín and Ignacio E. Grossmann 11 Methodologies Developed and Applied in Process Integration Studies for the Swedish Kraft Pulp and Paper Industry: A Review.............................................. 349 Maryam Mahmoudkhani and Thore Berntsson 12 Design of a Lignocellulosic Feedstock Biorefinery Based on a Biochemical Processing Platform Using Process Integration Methodologies and Exergy Analysis................................................................................................................... 369 Karina Ojeda, Mahmoud M. El-Halwagi, and Vyacheslav Kafarov 13 Automated Targeting for the Synthesis of an Integrated Biorefinery...................... 397 Douglas H. S. Tay and Denny K. S. Ng 14 Synthesis of Flexible Heat-Exchanger Networks for Multifeedstock Biodiesel Production Processes........................................................................................ 417 Grace Pokoo-Aikins and Mahmoud M. El-Halwagi
Section IV Biorefinery Feedstocks 15 A Literature Review of Biomass Feedstocks for a Biorefinery................................... 435 José Meléndez, Luc LeBel, and Paul R. Stuart 16 Lignocellulosic Biomass: A Raw Material for the Future...........................................463 Agustin Jaime Castro-Montoya and Arturo Jiménez-Gutiérrez 17 Food Waste as a Renewable Raw Material for the Development of Integrated Biorefineries: Current Status and Future Potential.................................. 471 Antonis C. Kokossis and Athanasios A. Koutinas
Section V Biorefinery Technologies 18 The Forest Biorefinery: Current State of the Art........................................................... 493 Tom Browne, Naceur Jemaa, Ibrahim Karidio, Talat Mahmood, Mike Paice, Mike Paleologou, Doug Singbeil, and Xiao Zhang 19 Thermochemical Conversion of Biomass to Liquid Fuels and Chemicals.............. 519 W. J. Frederick, Jr. 20 Enzyme Applications in the Forest-Based Biorefinery................................................ 569 Alexey Vishtal and Andrzej Kraslawski
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21 Biochemical Conversion..................................................................................................... 593 Shijie Liu, Yang Wang, Ling Liang, John P. Buyondo, Yuanzhen Wang, and Michael Garver 22 Separation of Hemicellulose by Hot-Water Extraction from Woody Biomass........ 653 Shijie Liu, Houfang Lu, Yichao Lei, Christopher D. Wood, Thomas E. Amidon, Bin Liang, Runcang Sun, Gary M. Scott, Daryl Nichol, and Al Ward 23 Integrated Utilization of Algae Biomass in a Biorefinery Based on a Biochemical Processing Platform..................................................................................... 709 Eduardo Sánchez-Tuirán, Mahmoud M. El-Halwagi, and Vyacheslav Kafarov
Section VI Biorefinery Policy and Environmental Analysis 24 Policy Options to Support Biorefining........................................................................... 731 Warren E. Mabee 25 Biopower in the U.S. South: Barriers, Drivers, and Potential for Expansion......... 753 Youngsun Baek and Marilyn A. Brown 26 Biorefinery Design from an Earth Systems Perspective............................................. 773 Damon Honnery, Gil Garnier, and Patrick Moriarty 27 LCA-Based Environmental Evaluation of Biorefinery Projects................................. 795 Shabnam Sanaei, Matty Janssen, Mahmoud M. El-Halwagi, and Paul R. Stuart Index.............................................................................................................................................. 821
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Series Preface
Q1
ix
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Preface
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Contributors Thomas E. Amidon Department of Paper and Bioprocess Engineering SUNY College of Environmental Science and Forestry Syracuse, New York Youngsun Baek Oak Ridge National Laboratory Oak Ridge, Tennessee Dieudonné R. Batsy Ecole Polytechnique Montreal NSERC Environmental Design Chair in Process Integration Montreal, Québec, Canada Thore Berntsson Department of Energy and Environment Chalmers University of Technology Gothenburg, Sweden Marilyn A. Brown Georgia Institute of Technology Atlanta, Georgia Tom Browne FPInnovations–Pulp & Paper Division Pointe-Claire, Québec, Canada and Vancouver, British Columbia, Canada John P. Buyondo Department of Paper and Bioprocess Engineering SUNY College of Environmental Science and Forestry Syracuse, New York Agustin Jaime Castro-Montoya Universidad Michoacana de San Nicolás de Hidalgo Morelia, México
Q2
Virginie Chambost Ecole Polytechnique Montreal NSERC Environmental Design Chair in Process Integration Montreal, Québec, Canada Hou-min Chang North Carolina State University Raleigh, North Carolina Sophie D’Amours Département de génie mécanique Université Laval Laval, Québec, Canada Louis Patrick Dansereau Department of Chemical Engineering Ecole Polytechnique Montreal NSERC Environmental Design Chair in Process Integration Montreal, Québec, Canada Mario R. Eden Department of Chemical Engineering Auburn University Auburn, Alabama Mahmoud M. El-Halwagi The Artie McFerrin Department of Chemical Engineering Texas A&M University College Station, Texas Yan Feng Département de génie mécanique Université Laval Laval, Québec, Canada W. J. Frederick, Jr. Table Mountain Consulting, LLC Boulder, Colorado Gil Garnier Department of Chemical Engineering Monash University Victoria, Australia xiii
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Michael Garver Department of Paper and Bioprocess Engineering SUNY College of Environmental Science and Forestry Syracuse, New York Ignacio E. Grossmann Department of Chemical Engineering Carnegie-Mellon University Pittsburgh, Pennsylvania Mark Holtzapple Department of Chemical Engineering Texas A&M University College Station, Texas Damon Honnery Department of Mechanical and Aerospace Engineering Monash University Victoria, Australia Eemeli Hytönen Department of Chemical Engineering Ecole Polytechnique Montreal NSERC Environmental Design Chair in Process Integration Montreal, Québec, Canada Hasan Jameel Department of Forest Biomaterials North Carolina State University Raleigh, North Carolina Matty Janssen Department of Energy and Environment Chalmers University of Technology Göteborg, Sweden Naceur Jemaa FPInnovations–Pulp & Paper Division Pointe-Claire, Québec, Canada and Vancouver, British Columbia, Canada Arturo Jiménez-Gutiérrez Departamento de Ingeniería Química Instituto Tecnológico de Celaya Celaya, México
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Contributors
Yongcan Jin North Carolina State University Raleigh, North Carolina Vyacheslav Kafarov Department of Chemical Engineering Industrial University of Santander Santander, Colombia Ibrahim Karidio FPInnovations–Pulp & Paper Division Pointe-Claire, Québec, Canada and Vancouver, British Columbia, Canada Antonis C. Kokossis School of Chemical Engineering National Technical University of Athens Athens, Greece Bon Wook Koo Department of Forest Biomaterials North Carolina State University Raleigh, North Carolina Milan Korbel Department of Chemical Engineering Ecole Polytechnique Montreal NSERC Environmental Design Chair in Process Integration Montreal, Québec, Canada Athanasios A. Koutinas Department of Food Science and Technology Agricultural University of Athens Athens, Greece Andrzej Kraslawski Lappeenranta University of Technology Lappeenranta, Finland Luc LeBel Départment des sciences du bois et de la forêt Université Laval Laval, Québec, Canada
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Contributors
Yichao Lei State Key Laboratory of Pulp and Paper Engineering South China University of Technology Guangzhou, China
Maryam Mahmoudkhani Department of Energy and Environment Chalmers University of Technology Gothenburg, Sweden
Bin Liang College of Chemical Engineering Sichuan University Chengdu, China
Behrang Mansoornejad Department of Chemical Engineering Ecole Polytechnique Montreal NSERC Environmental Design Chair in Process Integration Montreal, Québec, Canada
Ling Liang Department of Paper and Bioprocess Engineering SUNY College of Environmental Science and Forestry Syracuse, New York Ta-Chen Lin Faculty of Engineering and Physical Sciences University of Surrey Surrey, United Kingdom Shijie Liu Department of Paper and Bioprocess Engineering SUNY College of Environmental Science and Forestry Syracuse, New York and State Key Laboratory of Pulp and Paper Engineering South China University of Technology Guangzhou, China Houfang Lu College of Chemical Engineering Sichuan University Chengdu, China Warren E. Mabee Energy and Environmental Policy Kingston, Queen’s University Kingston, Ontario, Canada Talat Mahmood FPInnovations–Pulp & Paper Division Pointe-Claire, Québec, Canada and Vancouver, British Columbia, Canada
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Mariano Martín Department of Chemical Engineering Carnegie-Mellon University Pittsburgh, Pennsylvania José Meléndez Department of Chemical Engineering Ecole Polytechnique Montreal NSERC Environmental Design Chair in Process Integration Montreal, Québec, Canada Patrick Moriarty Department of Design Monash University Victoria, Australia Denny K. S. Ng Department of Chemical and Environmental Engineering University of Nottingham Malaysia Selangor, Malaysia Daryl Nichol Alberta Pacific Forest Industries Inc. Boyle, Alberta, Canada Mustapha Nourelfath Département de génie mécanique Université Laval Laval, Québec, Canada Karina Ojeda Department of Chemical Engineering University of San Buenaventura Cartagena, Colombia
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Mike Paice FPInnovations–Pulp & Paper Division Pointe-Claire, Québec, Canada and Vancouver, British Columbia, Canada Mike Paleologou FPInnovations–Pulp & Paper Division Pointe-Claire, Québec, Canada and Vancouver, British Columbia, Canada
Contributors
Gary M. Scott Department of Paper and Bioprocess Engineering SUNY College of Environmental Science and Forestry Syracuse, New York Doug Singbeil FPInnovations–Pulp & Paper Division Pointe-Claire, Québec, Canada and Vancouver, British Columbia, Canada
Viet Pham Department of Chemical Engineering Texas A&M University College Station, Texas
Charles C. Solvason Department of Chemical Engineering Auburn University Auburn, Alabama
Richard B. Phillips Department of Forest Biomaterials North Carolina State University Raleigh, North Carolina
Paul R. Stuart Department of Chemical Engineering Ecole Polytechnique Montreal NSERC Environmental Design Chair in Process Integration Montreal, Québec, Canada
Grace Pokoo-Aikins The Artie McFerrin Department of Chemical Engineering Texas A&M University College Station, Texas Norm E. Sammons Department of Chemical Engineering Auburn University Auburn, Alabama Shabnam Sanaei Department of Chemical Engineering Ecole Polytechnique Montreal NSERC Environmental Design Chair in Process Integration Montreal, Québec, Canada Eduardo Sánchez-Tuirán Department of Chemical Engineering Industrial University of Santander, Colombia Santander, Colombia and Department of Chemical Engineering University of San Buenaventura Cartagena, Colombia
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Runcang Sun State Key Laboratory of Pulp and Paper Engineering South China University of Technology Guangzhou, China and Institute of Biomass Chemistry and Technology Beijing Forestry University Beijing, China Douglas H. S. Tay Department of Chemical and Environmental Engineering University of Nottingham Malaysia Selangor, Malaysia Trevor H. Treasure Department of Forest Biomaterials North Carolina State University Raleigh, North Carolina Marinella Tsakalova School of Chemical Engineering National Technical University of Athens Athens, Greece
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Contributors
Alexey Vishtal Lappeenranta University of Technology Lappeenranta, Finland Yang Wang Department of Paper and Bioprocess Engineering SUNY College of Environmental Science and Forestry Syracuse, New York Yuanzhen Wang Department of Paper and Bioprocess Engineering SUNY College of Environmental Science and Forestry Syracuse, New York Al Ward Alberta Pacific Forest Industries Inc. Boyle, Alberta, Canada
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Christopher D. Wood Department of Paper and Bioprocess Engineering SUNY College of Environmental Science and Forestry Syracuse, New York Aidong Yang Faculty of Engineering and Physical Sciences University of Surrey Surrey, United Kingdom Xiao Zhang FPInnovations–Pulp & Paper Division Ponite-Claire, Québec, Canada and Vancouver, British Columbia, Canada
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